Perkin and Kipping's Organic Chemistry, Parts I and II. Entirely new

Perkin and Kipping's Organic Chemistry, Parts I and II. Entirely new edition (Kipping, F. Stanley; Kipping, F. Barry). F. B. Dains. J. Chem. Educ. , 1...
0 downloads 0 Views 1MB Size
VOL.9, NO. 7

RECENT BOOKS

The main portion of the book is divided into four sections. I n Part I are discussed simple calculations, such as addition, subtraction, multiplication, and division, with numerous examples. Part I1 covers special aids in multiplication and division such as logarithms, the logarithmic sIide.de and the calculating machine. Part I11 deals with chemical calculations and their algebraic formulation and covers simple gravimetric analysis, volumetric analysis, indirect analysis of two- and three-component systems, critical examination of errors, calculations of analyses of complex mixtures such as rocks, omplea salts, and water, and the calculation of gases. Part IV deals with nomography and includes a review of the literature. The subject matter of the book should certainly be given careful consideration by all teachers of courses in stoichiometry. Its use as a textbook will necessarily be limited t o classes that have had a thorough grounding in German. G. E. F. LUNDELL

1311

form of expression and subject matter, which greatly improve the text and bring i t down t o date. Part I (323 pages), which is devoted t o the open-chain compounds, begins with the usual chapter on "Composition, Purification and Analysis of Organic Compounds and Deduction of Formulae." followed by chapters on hydrocarbons, halogen derivatives, etc., with only slight differences in the order and number of chapters from the older edition. I n contrast with some of the recent American texts, no reference is made t o the electronic theory in explaining organic reactions. What is more surprising, however, is that the Genevaiystem of nomenclature is wholly unused. The chapter on carbohydrates (24 pages) is unduly shortened, owing t o the purpose of the authors t o discuss this subject in more detail in Part 111. I n this connection i t seems unfortunate not to devote some attention t o the space relationship of the sugars, the oxide formula, etc., since many students will never see Volume 111. Part I1 continues with homocyclic compounds, t o which 170 pages are devoted. As a minor point, Ladenburg Perkin and Kipping's Organic Chemistry, and Noltiag's method of proof of the Parts I and I1 (Entirely new edition). equivalence of the sin hydrogens in benF. STANLEYKIPPIm,University Col- zene muld well have been included in the lege. Nottingham, and F . BARRYKIP- author's discussion of that subject (p. PING, Trinity College, Cambridge. J. B. 351). Lippincatt, Philadelphia. Printed in Under heterocyclic derivatives only Great Britain by W. & R. Chambers, nitrogen-containing rings are mentioned; Ltd.. London and Edinburgh. 1932. then follow chapters on the alkaloids, vi 614 xxiv pp. 24 Figs. 12.5 amino acids, and purine bases; on some X 18.8 cm. 83.50. important components of animals and To the older generation of organic chem- plants and dyes, ending with a brief desaiption of methods for the identificaists the name, "Perkin and Kipping's Organic Chemistry," is very familiar as tion of organic compounds. One valuable a much-used text, but one that has been feature of the work is the careful aoss-indexing of allied material, and the sumlargely displaced owing t o lack of revision. Since the lamented death of the great maries that are found a t the end of most master of synthetic chemistry, W. H. of the chapters an the aliphatic series. The author very justly remarks: Perkin, this new edition has been edited by the junior author, assisted by F. Barry "Without a thorough course of laboratory 'Ripping. While the bulk of the material work no sound foundation can be laid, remains the same as in the older edition, and an ill-balanced accumulation of facts many changes have been made both in is the result. For this reason the prepare

+

+

1312

JOURNAL OF CHEIMICAL EDUCATION

tion of many typical compounds is described in sufficient detail t o enable a beginner t o carry out the operation by himself." Some seventy-nine preparations are described accurately, hut briefly, though the reviewer feels that their inclusion does not adequately take the place of a fuller laboratory text. Their presence in the volume may have the advantage that the student can correlate the laboratory methods with the descriptive matter in the text without recourse t o another b o o k a n effort which he sometimes fails to make. The volume has naturally been written for the English school system, with the result that the American teacher will find some of the topics t o which he might wish t o refer, such as the extended treatment of carbohydrates, terpenes, etc., in Part 111, which is to appear shortly. From the standpoint of typography the hook is a very satisfactory one. The formulas are clearly printed and the pages have a pleasing appearance. This new edition can commend itself very definitely t o the teacher who desires a well-written. accurate text containing a wealth of descriptive material correlated with the necessary discussion of group reactions and with theory substantiated by accurate ex~erimentaldata.

Model Essays in Organic Chemistry. D. D. Knnv6, Ph.D.. M.Sc., A.I.I.Sc., Fergusson College, Poona, India, and G. D. ADVANI, B.A.. MSc., A.I.I.Sc., D. J. Sind College, Karachi, India. First edition, Sind Juvenile Co6perative Society, 1873 Elphiustone Street, 300 pp. 13 X Karachi, 1930. iv 20.5 cm. 5 Rs. or 8 Sh. net.

+

The authors say, "the present volume is intended mainly for the use of students preparing for their degree examination in Chemistry. It is generally difficult for a student.. . t o distinguish from the mass of literature.. .available to him.. .what is important and what is not.. . .The es-

JULY,

1932

says.. .are to serve as models to the students as t o how all the available material is to be condensed into a presentable form." The book consists of essays on such topics as an Outline of Stereochemistry, Optical Activity, Geometrical Isomerism, Stereochemistry of Nitrogen Compounds, Walden's Inversion. Mutarotation, Asymmetric Synthesis, Dynamic Isomerism, Constitution of Benzene. Constitution of Diazo Compounds, Relation between Color and Chemical Constitution, Ahsorption Spectra, Synthetic Dyes, Natural and Artificial Rubber. Constitution of Chlorophyll, Chemical Action of Light, Abnormal Valency, O r-~ i n i cCom~ounds of Maz. nesium and Zinc, Organic Compounds of Lead, Keteues, and fifteen similar subjects selected from the field of organic chemistry. The essays are short, concise, and clearly written. The advanced undergraduate and first-year graduate students will find them not only interesting and instructive hut also a valuable guide t o further reading. In keeping with the peculiar purpose for which the hook was written. i t contains no references. This is to he regretted since many readers will find here suggestions which they will want t o follow t o their original source. One wonders whether the hook would not have served its intended purpose equally well if the references had been inserted. The American reader will find both the vocabulary and spelling a little unusual a t some points. CECILE. BOORD TAEORTO STAT*U N ~ Y B R E L T Y ~~

COLUMBUS, 0~x0

Chemistry of the Saccharides. Volume 6 of The George Fisher Baker Non-Resident Lectureship in Chemistry a t Cornell University. HANS PRINGSHETM, University of Berlin. McGraw-Hill Book Company, Inc.. New York City. 1932. 413 pp. 15 X 23 cm. $4.00. The text of the new volume of Pringsheim's "The Chemistry of the Monosaccharides and of the Polysaccharides" is based upon his lectures delivered a t