PRODUCTION - C&EN Global Enterprise (ACS Publications)

Nov 5, 2010 - Eleven chemicals have been added to the list of more than 3500 organic chemicals supplied by Distillation Products Industries, division ...
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PRODUCTION

NEW CHEMICALS AND SPECIALTIES Eleven Additions to Eastman's Organic Chemicals List Eleven chemicals have been added to the list of more than 3500 organic chemi­ cals supplied by Distillation Products In­ dustries, division of Eastman Kodak Co.: ο - (2 - Hydroxy - 3,6 - disulfo - 1 naphthylazo)benzenearsonic acid disodium salt, for colorimetric determination of thorium in amounts as small as 5 to 80 micrograms even in the presence of 1000 times this concentration of uranium VI, or in mixtures containing ferric iron. Ν - (4,4' - Dimethoxy - benzohydrilidene)benzylamine, Schonberg's reagent, which will detect as little as 0.04 mg. of elemental sulfur even in the presence of combined sulfur. A blue colored thioketone is formed. m-Aminoacetophenone, melting point 95 to 97° C. N-terf-Butylacrylamide (practical), melt­ ing point 128 to 130° C. 4-Chloro-2-nitroanisole (practical), melt­ ing point 97 to 99° C. Diethyl methyloxalacetate ( practical ), boiling point 112 to 117° C./11 mm. 1,2,6-Hexanetriol (practical), boiling point 138 to 145° C./0.5 mm. 2-Methyl-3-butyn-2-ol (practical), melt­ ing point 2 to 3° C. ;;-Phenylazobenzoic acid, melting point 248° C , decomposes. Sebacyl chloride, boiling point 154 to 156° C./7 mm. 1,1,1 - Trichloro - 3 - nitro - 2 - propanol (practical), boiling point 116 to 120° C./5 mm. CS 1

For further information on any item mentioned here, see cou­ pon on page 4676.

supplied in a 50% aqueous solution, but may also be had in an 82.5% alcoholic solution. BTC 927 is an alkyl dimethyl dimethylbenzyl ammonium chloride, with the same alkyl radical as Onyx BTC. It is supplied in 5 0 % aqueous solution. CS 3

PRODUCT MOTES

on plate glass, and a rubber eraser was drawn in a zig zag line across the paint. The accompanying picture shows the un­ treated paint at the left and the Tenlotreated paint at the right. Tenlo-70 may find applications in the putty, calking compounds, printing ink, and linoleum industries because of the low surface and interfacial tensions it exhibits in nonaqueous systems. CS 2 Improved Quaternaries The industrial division of Onyx Oil & Chemical Co. is producing two qixaternary ammonium salts of great interest to users of these deodorant-sanitizers. These two quaternaries are closely related t o Onyx BTC, alkyl dimethyl benzyl ammonium chloride. They both have materially higher phenol coefficients than BTC, how­ ever, and have other superiorities. BTC 471 is an alkyl dimethyl eth/ylberizyl am­ monium chloride, the alkyl radical being about the same as in Onyx B T C I t is

Radioactive

Decontaminating

Agent.

Εnley Products, Inc.'s, CP Cleaner is said to work effectively as a radioactive surface decontaminating agent. The product con­ tains a wetting agent and a sequestering agent. It is also recommended for many other cleaning uses. According to Enley, the product penetrates and sequesters ions, dirt, and grease, then holds them in suspension. Its neutral pi I makes it effec­ tive for use on the human body and live­ stock. CS 4 Rubber Base Paint. Tropical Floorkof^ enamel, developed on a synthetic rubberresin base, not water latex emulsion, has unusual durability on masonry floors, ac­ cording to the Tropical Paint & Oil Co. Floorkote can be applied to old concrete or new, uncured concrete, to basement lloors, and to floors laid directly on the ground over cinder fill. It dries in four hours to a rich gloss. It seals the floor and will not react with caustic soaps or clean­ ing compounds, according to the manu­ facturer. CS 5

w t h o n .laborcrtory

For

Oil-Soluble W e t t i n g A g e n t Controls Running in Paints

«mounts of

Griffin Chemical Co/s Tenlo-70 is said to olFer a solution to the problem of sag­

/fate*

organic*

L .«ne for example * p .Aminoacetophenone,t

v/rite to

ging and running in paints. Griffin added 7% of the product to a fast drying syn­ thetic enamel, and aged the mixture over­ night. A 3-mil film of paint was applied VOLUME

3 0,

NO.

4 4 .

Eastman Organic Chemicals Department, Distillation Products Industries, Rochester 3, N.Y- (Division of Eastman Kodak Company). There are more than 3500 regularly supplied Eastman Organic Chemi­ cals for science and industry. Also . . . vitamins A. and

. N O V E M B E R

3,

1952

Ε . . . distilled monoglyceridos . . . high vacuum equipment

4663