Protonation of diene complexes of rhodium, iridium, ruthenium, and

The complexes [IrH(77-C6Me5)(diene)]+ (diene = 1,3-cyclohexadiene (2), .... ence of a (diene)iridium(III) hydride [IrH(j7-C5H5)(C6H8)]+, migration of ...
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Organometallics 1992, 11, 127-138 (Grant CHE-8819760) and for the purchase of the Nicolet R3m diffractometer and computing system. K.P. is also grateful to the Deutsche Forschungsgemeinschaft for financial assistance. We also thank E. K. Barefield for helpful discussions. Registry No. 7,137365-76-5;8,137365-77-6;9,137393-39-6; 11,137365787;CF3C02H,76-051; Cp,ZrMe(0,CCF3),99494-55-0;

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tBuNC, 7188-38-7; Cp,Zr(Me)H, 67659-92-1. Available: Lists of complete bond

lengths and anisotropic thermal parameters,and H coordinatesfor 8 and lists of completebond length and angles and anisotropic and isotropic thermal Darameters for 9 (26 Danes): . tables o i structure fa