Publications of Michael R. Wasielewski - ACS Publications - American

Nov 11, 2010 - The Sign of B0, L. M. Stock and M. R. Wasielewski,. J. Am. Chem. Soc. ..... ads, M. R. Wasielewski, G. L. Gaines, III, G. P.. Wiederrec...
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J. Phys. Chem. B 2010, 114, 14119–14133

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Publications of Michael R. Wasielewski 1. On the Stereochemistry of J5HF, L. M. Stock and M. R. Wasielewski, J. Org. Chem. 35, 4240 (1970). 2. The Bromination of t-Butylbenzene in Trifluoroacetic Acid. The Meta Partial Rate Factor, L. M. Stock and M. R. Wasielewski, J. Org. Chem. 36, 1002-1003 (1971). 3. Pseudocontact and Contact Shifts for 4-Aminophenylcyclopropane Derivatives. Signs for the Long Range Electron Paramagnetic Coupling Constants, L. M. Stock and M. R. Wasielewski, J. Am. Chem. Soc. 94, 8276-8277 (1972). 4. Pseudocontact and Contact Shifts for 6-Aminobenzobicyclo(2.2.2.)Octene and 2-Aminotriptycene. The Sign of B0, L. M. Stock and M. R. Wasielewski, J. Am. Chem. Soc. 95, 2743-2744 (1973). 5. The Angular Dependence of Beta Carbon Atom Hyperfine Coupling Constants, L. M. Stock and M. R. Wasielewski, J. Am. Chem. Soc. 96, 583-585 (1974). 6. The EPR Spectra of Alpha-Substituted Nitrotoluene Anion Radicals. The Influence of Electronegative Substituents on the Coupling Constants for Beta-Hydrogen Atoms, L. M. Stock and M. R. Wasielewski, J. Am. Chem. Soc. 97, 5620-5622 (1975). 7. Preparation of 9,10-Difluoroanthracene, L. M. Stock and M. R. Wasielewski, J. Org. Chem. 41, 1660-1661 (1976). 8. Thermodynamic Measurements on Unsubstituted Cyclopropenyl Radical and Anion, and Derivatives by Second Harmonic Alternating Current Voltammetry of Cyclopropenyl Cations, M. R. Wasielewski and R. Breslow, J. Am. Chem. Soc. 98, 4222-4229 (1976). 9. Covalently Linked Chlorophyll a Dimer. A Biomimetic Model of Special Pair Chlorophyll, M. R. Wasielewski, M. H. Studier, and J. J. Katz, Proc. Natl. Acad. Sci. U.S.A. 73, 4282-4286 (1976). 10. Contact Chemical Shifts for the Carbon Atoms of Nickel Complexes of the 4-Alkylanilines. The Factors Governing the Electron Spin Resonance Hyperfine Constants of Carbon Atoms, L. M. Stock and M. R. Wasielewski, J. Am. Chem. Soc. 99, 50-59 (1977). 11. A Mild Method for the Introduction of Magnesium into Bacteriopheophytin a, M. R. Wasielewski, Tetrahedron Lett. 1373-1376 (1977). 12. A Synthetic Biomimetic Model of Special Pair Bacteriochlorophyll a, M. R. Wasielewski, U. H. Smith, B. T. Cope, and J. J. Katz, J. Am. Chem. Soc. 99, 4172-4173 (1977). 13. 9-Desoxo-9,10-dehydrochlorophyll a. A New Chlorophyll with an Effective 20-π Electron Macrocycle, M. R. Wasielewski and J. F. Thompson, Tetrahedron Lett. 1043-1046 (1978). 14. Bis(Chlorophyll) Cyclophanes. New Models of Special Pair Chlorophyll, M. R. Wasielewski, W. A. Svec and B. T. Cope, J. Am. Chem. Soc. 100, 1961-1962 (1978). 15. Chlorophyll, M. R. Wasielewski, Science and Technology Yearbook, McGraw-Hill, New York, 1978, pp 114-116.

16. Chlorophyll Function in the Photosynthetic Reaction Center, J. J. Katz, J. R. Norris, L. L. Shipman, M. Thurnauer, and M. R. Wasielewski, Annu. ReV. Biophys. Bioeng. 7, 393-434 (1978). 17. Coherent Stimulated Emission (Lasing) in Covalently Linked Chlorophyll Dimers, J. C. Hindman, R. Kugel, M. R. Wasielewski, and J. J. Katz, Proc. Natl. Acad. Sci. U.S.A. 75, 2076-2079 (1978). 18. A Biomimetic Approach to Solar Energy Conversion, J. J. Katz, T. R. Janson, and M. R. Wasielewski, in Energy and the Chemical Sciences, S. D. Christian and J. J. Zuckerman, Eds., Pergamon Press, Oxford, U.K., 1978, pp 31-57. 19. Charge and Spin Delocalization to the Trifluoromethyl Group, L. M. Stock and M. R. Wasielewski, in Aspects of Mechanism and Organometallic Chemistry, J. H. Brewster, Ed., Plenum Press, New York, 1978, pp 41-58. 20. Excited and Ionic States of Dimeric Chlorophyll Derivatives. Biomimetic Modeling of the Primary Events of Photosynthesis, M. R. Wasielewski, in Frontiers of Biological Energetics, Vol. I, P. L. Dutton, J. S. Leigh, and A. Scarpa, Eds., Academic Press, New York, 1978, pp 63-72. 21. Biomimetic Approaches to Artificial Photosynthesis, J. J. Katz and M. R. Wasielewski, Biotech. Bioeng. Symp. 8, 423-452, (1978). 22. In Vitro Duplication of the Primary Light Induced Charge Separation in Purple Photosynthetic Bacteria, M. J. Pellin, K. J. Kaufmann, and M. R. Wasielewski, Nature 278, 54-55 (1979). 23. Chlorophylls VI. Epimerization and Enolization of Chlorophyll a and Its Magnesium Free Derivatives, P. H. Hynninen, M. R. Wasielewski, and J. J. Katz, Acta Chem. Scand. B33, 637-648 (1979). 24. Picosecond Photophysics of Covalently Linked Pyrochlorophyllide a Dimer. Unique Kinetics in the Singlet Manifold, M. J. Pellin, M. R. Wasielewski, and K. J. Kaufmann, J. Am. Chem. Soc. 102, 1868-1873 (1980). 25. Synthesis of Covalently Linked Dimeric Derivatives of Chlorophyll a, Pyrochlorophyll a, Chlorophyll b, and Bacteriochlorophyll a, M. R. Wasielewski and W. A. Svec, J. Org. Chem. 45, 1969-1974 (1980). 26. The Electrochemical Production of Chlorophyll a and Pheophytin a Excited States, M. R. Wasielewski, R. L. Smith, and A. G. Kostka, J. Am. Chem. Soc. 102, 6923-6928 (1980). 27. Photophysical Properties of Tris(Zinc and Magnesium Pyrochlorophyllide a) 1,1,1-Tris(hydroxymethyl)ethane Triesters, M. J. Yuen, G. L. Closs, J. J. Katz, J. A. Roper, M. R. Wasielewski, and J. C. Hindman, Proc. Natl. Acad. Sci. U.S.A. 77, 5598-5601 (1980). 28. The Trifluoromethyl Group in Chemistry and Spectroscopy. Carbon-Fluorine Hyperconjugation, L. M. Stock and M. R. Wasielewski, Progress in Physical Organic Chemistry, Vol. 13, Wiley, New York, 1981, pp 253-313.

10.1021/jp1087702  2010 Michael R. Wasielewski Published on Web 11/11/2010

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29. Studies of Chlorophyll In Vitro, K. J. Kaufmann and M. R. Wasielewski, AdV. Chem. Phys. 47, 579-626 (1981). 30. Monomeric Chlorophyll a Enol. Evidence for Its Possible Role as the Primary Electron Donor in Photosystem I of Plant Photosynthesis, M. R. Wasielewski, J. R. Norris, L. L. Shipman, C. P. Lin, and W. A. Svec, Proc. Natl. Acad. Sci. U.S.A. 78, 2957-2961 (1981). 31. Photoinduced ESR Signals from the Primary Electron Donors in Deuterated Highly 13C Enriched Photosynthetic Bacteria and Algae, M. R. Wasielewski, J. R. Norris, H. L. Crespi, and J. Harper, J. Am. Chem. Soc. 103, 7764-7765 (1981). 32. Selectively Metalated Doubly Cofacial Porphyrin Trimers. New Models for the Study of Photoinduced Intramolecular Electron Transfer, M. R. Wasielewski, M. P. Niemczyk, W. A. Svec, and D. Norbeck, Tetrahedron Lett. 23, 3215-3218 (1982). 33. Synthetic Approaches to Photoreaction Center Structure and Function, M. R. Wasielewski, Light Reaction Path of Photosynthesis, Vol. 35 of Molecular Biology, Biochemistry, and Biophysics, Springer Verlag, Berlin, 1982, pp 234-276. 34. ESR Study of the Primary Electron Donor in Highly 13 C Enriched Chlorobium limicola f. thiosulfatophilum, M. R. Wasielewski, U. H. Smith, and J. R. Norris, FEBS Lett. 149, 138-140 (1982). 35. The Photophysics of Bis(Chlorophyll) Cyclophane Models of Photosynthetic Reaction Centers, R. E. Overfield, K. J. Kaufmann, and M. R. Wasielewski, J. Am. Chem. Soc. 105, 4256-4260 (1983). 36. Photoinduced Electron Transfer Reactions in a Chlorophyllide-Pheophorbide Cyclophane. A Model for Photosynthetic Reaction Centers, R. E. Overfield, A. Scherz, K. J. Kaufmann, and M. R. Wasielewski, J. Am. Chem. Soc. 105, 5747-5752 (1983). 37. Nanosecond Time Resolved Magnetic Resonance of the Primary Radical Pair State PF of Bacterial Photosynthesis, M. R. Wasielewski, C. H. Bock, M. K. Bowman, and J. R. Norris, J. Am. Chem. Soc. 105, 2903-2904 (1983). 38. Controlling the Duration of Photosynthetic Charge Separation using Microwave Radiation, M. R. Wasielewski, C. H. Bock, M. K. Bowman, and J. R. Norris, Nature 303, 520-522 (1983). 39. Orientation of the Primary Donor in Single Crystals of R. Viridis Reaction Centres, P. Gast, M. R. Wasielewski, M. Schiffer, and J. R. Norris, Nature 305, 451-452 (1983). 40. Nanosecond Time Resolved Magnetic Resonance Spectra of PF in R. sphaeroides and in R. Viridis Reaction Centers. Orientation of the Primary Donor in Single Crystals of R. Viridis Reaction Centers, M. R. Wasielewski, P. Gast, and J. R. Norris, in AdVances in Photosynthesis Research, C. Sybesma, Ed., Martinus Nijhoff Publishers, The Hague, The Netherlands, 1984, Vol. 1, Part 2, pp 211-214. 41. Photoinduced Electron Transfer in Meso-Triphenyltriptycene-Quinone Porphyrins. Restricting Donor-Acceptor Distances and Orientations, M. R. Wasielewski and M. P. Niemczyk, J. Am. Chem. Soc. 106, 5043-5045 (1984). 42. Time Domain Magnetic Resonance Studies of Short Lived Radical Pairs in Liquid Solution, M. R. Wasielews-

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ki, J. R. Norris, and M. K. Bowman, Faraday Discuss. Chem. Soc. 78, 279-288 (1984). Dependence of Rate Constants for Photoinduced Charge Separation and Dark Charge Recombination on the Free Energy of Reaction in Restricted Distance PorphyrinQuinone Molecules, M. R. Wasielewski, M. P. Niemczyk, W. A. Svec, and E. B. Pewitt, J. Am. Chem. Soc. 107, 1080-1082 (1985). Chemistry of Exciplexes 19. Exciplex Promoted Electron Transfer in 1-(N-Phenylamino)- 3-(9-anthryl)propanes, N. C. Yang, R. Gerald, and M. R. Wasielewski, J. Am. Chem. Soc. 107, 5531-5532 (1985). High Quantum Yield Long Lived Charge Separation in a Photosynthetic Reaction Center Model, M. R. Wasielewski, M. P. Niemczyk, W. A. Svec, and E. B. Pewitt, J. Am. Chem. Soc. 107, 5562-5563 (1985). Ultrafast Electron Transfer in Biomimetic Models of Photosynthetic Reaction Centers, M. R. Wasielewski, M. P. Niemczyk, W. A. Svec, and E. B. Pewitt, in Antennas and Reaction Centers of Photosynthetic Bacteria - Structure, Interactions, and Dynamics, M. E. Michel-Beyerle, Ed., Springer Verlag, Berlin, 1985, pp 242-249. Direct Measurement of the Lowest Excited Singlet State Lifetime of all-trans--Carotene and Related Carotenoids, M. R. Wasielewski and L. D. Kispert, Chem. Phys. Lett. 128, 238-243 (1986). Ultrafast Carotenoid to Pheophorbide Energy Transfer in a Biomimetic Model for Antenna Function in Photosynthesis, M. R. Wasielewski, P. A. Liddell, D. Barrett, T. A. Moore, and D. Gust, Nature 322, 570-572 (1986). Distance Dependent Rates of Photoinduced Charge Separation and Dark Charge Recombination in Fixed Distance Porphyrin-Quinone Molecules, M. R. Wasielewski and M. P. Niemczyk, in Excited States and Dynamics of Porphyrins, American Chemical Society Symposia No. 321, K. D. Straub, M. Goutermann, and P. Rentzepis, Eds., 1986, pp 154-165. Sub-Picosecond Measurements of Primary Electron Transfer in R. Viridis Reaction Centers using NearInfrared Excitation, M. R. Wasielewski and D. M. Tiede, FEBS Lett. 204, 368-372 (1986). Ultrafast Electron and Energy Transfer in Reaction Center and Antenna Proteins from Photosynthetic Bacteria, M. R. Wasielewski, D. M. Tiede, and H. A. Frank, in Ultrafast Phenomena V, G. R. Fleming and A. E. Siegman, Eds., Springer Verlag, Berlin, 1986, pp 388-392. ENDOR and Triple Resonance in Solution of the Chlorophyll a and bis-Chlorophyll Cyclophane Cation Radicals, M. Huber, F. Lendzian, W. Lubitz, E. Trankle, K. Mo¨bius, and M. R. Wasielewski, Chem. Phys. Lett. 132, 467-473 (1986). The Rate of Formation of P700+ - A0- in Photosystem I Particles from Spinach as Measured by Picosecond Transient Absorption Spectroscopy, M. R. Wasielewski, J. Fenton, and Govindjee, Photosynth. Res. 12, 181-190 (1987). Photoinduced Electron Transfer in Fixed Distance Chlorophyll-Quinone Donor-Acceptor Molecules, M. R. Wasielewski, D. G. Johnson, and W. A. Svec, in Supramolecular Photochemistry, V. Balzani, Ed., Reidel, Amsterdam, 1987, pp 255-266.

J. Phys. Chem. B, Vol. 114, No. 45, 2010 14121 55. Intramolecular Photochemical Electron Transfer 4. Singlet and Triplet Mechanisms of Electron Transfer in a Porphyrin-Amide-Quinone, J. A. Schmidt, A. R. McIntosh, A. C. Weedon, J. R. Bolton, J. S. Connolly, J. K. Hurley, and M. R. Wasielewski, J. Am. Chem. Soc. 110, 1733-1740 (1988). 56. Synthetic Models for Photosynthesis, M. R. Wasielewski, Photochem. Photobiol. 47, 923-929 (1988). 57. Distance Dependencies of Electron Transfer Reactions, M. R. Wasielewski, in Photoinduced Electron Transfer, Part A, M. A. Fox and M. Chanon, Eds., Elsevier, Amsterdam, 1988, pp 161-206. 58. Picosecond Charge Separation and Triplet Formation in a Closely Spaced Photosynthetic Model System, U. Hofstra, T. J. Schaafsma, G. M. Sanders, M. van Dijk, H. C. van der Plas, D. G. Johnson, and M. R. Wasielewski, Chem. Phys. Lett. 151, 169-175 (1988). 59. Achieving High Quantum Yield Charge Separation in Porphyrin-Based Donor-Acceptor Molecules at 10 K, M. R. Wasielewski, D. G. Johnson, W. A. Svec, K. M. Kersey, and D. W. Minsek, J. Am. Chem. Soc. 110, 7219-7221 (1988). 60. Solvent Polarity Dependent Photophysics of a Symmetric Chlorophyll Dimer. A Model for Charge Separation within the Primary Donor of Photosynthetic Reaction Centers, D. G. Johnson, W. A. Svec, and M. R. Wasielewski, Isr. J. Chem. 28, 193-203 (1988). 61. Long-Distance Photoinitiated Electron Transfer through Polyene Molecular Wires, M. R. Wasielewski, D. G. Johnson, W. A. Svec, K. M. Kersey, D. E. Cragg, and D. W. Minsek, in Photochemical Energy ConVersion, J. Norris and D. Meisel, Eds., Elsevier, Amsterdam, 1989, pp 135-147. 62. Exciplex Formation and Electron Transfer in Polychromophoric Systems, N. C. Yang, D. W. Minsek, D. G. Johnson, and M. R. Wasielewski, in Photochemical Energy ConVersion, J. Norris and D. Meisel, Eds., Elsevier, Amsterdam, 1989, pp 111-116. 63. Determination of the Primary Charge Separation Rate in Isolated Photosystem II Reaction Centers with 500 fs Time Resolution, M. R. Wasielewski, D. G. Johnson, M. Seibert, and Govindjee, Proc. Natl. Acad. Sci. U.S.A. 86, 524-528 (1989). 64. Photosystem II. From a Femtosecond to a Millisecond, Govindjee and M. R. Wasielewski, in Photosynthesis, W. R. Briggs, Ed., Alan Liss, New York,1989, pp 71-103. 65. Ultrafast Photoinduced Electron Transfer Reactions in Rigid Donor-Spacer-Acceptor Molecules: Modification of Spacer Energetics as a Probe for Superexchange, M. R. Wasielewski, M. P. Niemczyk, D. G. Johnson, W. A. Svec, and D. W. Minsek, Tetrahedron 45, 4785-4806 (1989). 66. Photochemistry of Polychromophoric Arylamines, N. C. Yang, D. W. Minsek, D. G. Johnson, J. R. Larson, J. W. Petrich, R. Gerald, and M. R. Wasielewski, Tetrahedron 45, 4669-4681 (1989). 67. Temperature and Solvent Polarity Dependence of the Absorption and Fluorescence Spectra of a FixedDistance Symmetric Chlorophyll Dimer, S. G. Johnson, G. J. Small, D. G. Johnson, W. A. Svec, and M. R. Wasielewski, J. Phys. Chem. 93, 5437-5444 (1989). 68. Determination of the Primary Charge Separation Rate in Photosystem II Reaction Centers at 15 K, M. R.

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Wasielewski, D. G. Johnson, M. Seibert, and Govindjee, Photosynth. Res. 22, 89-99 (1989). Measurement of the Extent of Electron Transfer to the Bacteriopheophytin in the M-Subunit in Reaction Centers of Rhodopseudomonas Viridis, E. C. Kellogg, S. Kolaczkowski, M. R. Wasielewski, and D. M. Tiede, Photosynth. Res. 22, 47-59 (1989). Photosynthetic Model Systems that Address the Role of Superexchange in Electron Transfer Reactions, M. R. Wasielewski, M. P. Niemczyk, D. G. Johnson, W. A. Svec, and D. W. Minsek, in PerspectiVes in Photosynthesis, J. Jortner and B. Pullman, Eds., Kluwer, Dordrecht, 1989, pp 347-360. Temperature Dependence of the Lowest Excited Singlet State Lifetime of all-trans-β-Carotene and Fully Deuterated all-trans-β-Carotene, M. R. Wasielewski, D. G. Johnson, E. Bradford, and L. D. Kispert, J. Chem. Phys. 91, 6691-6697 (1989). The Primary Charge Separation Rate in Isolated Photosystem II Reaction Center Complex, M. R. Wasielewski, D. G. Johnson, Govindjee, C. Preston, and M. Seibert, in Current Research in Photosynthesis, Vol. I, Part 2, M. Baltscheffsky, Ed., Kluwer Academic Publishers, Dordrecht, 1989, pp 451-454. Measurement of the Extent of Electron Transfer to the Bacteriopheophytin in the M-Subunit in Reaction Centers of Rhodopseudomonas Viridis, D. M. Tiede, E. C. Kellogg, S. Kolaczkowski, and M. R. Wasielewski, in Current Research in Photosynthesis, Vol. I, Part 1, M. Baltscheffsky, Ed., Kluwer Academic Publishers, Dordrecht, 1989, pp 129-132. Photoinduced Electron Transfer and Spin Dynamics in Photosynthetic Model Systems, T. J. Schaafsma, R. B. M. Koehorst, U. Hofstra, F. J. Vergeldt, D. G. Johnson, and M. R. Wasielewski, in Proceedings of the 6th International Conference on Energy and Electron Transfer, J. Fiala and J. Pokorny, Eds., Charles University Press, Prague, 1989, p 23. Intramolecular Light-Induced Electron Transfer in a Rigid, Fixed Distance Anthracene - N,N-Dimethylaniline System. Exciplex-Like Behavior, D. W. Minsek, M. P. Niemczyk, M. R. Wasielewski, and N. C. Yang, J. Am. Chem. Soc. 112, 2823-2824 (1990). Photoinduced Spin-Polarized Radical Ion Pair Formation in a Fixed-Distance Photosynthetic Model System At 5 K, M. R. Wasielewski, G. L. Gaines, M. P. O’Neil, W. A. Svec, and M. P. Niemczyk, J. Am. Chem. Soc. 112, 4459-4560 (1990). Chlorophyll-Porphyrin Heterodimers with Orthogonal Pi-Systems: Solvent Polarity Dependent Photophysics, M. R. Wasielewski, D. G. Johnson, M. P. Niemczyk, G. L. Gaines, M. P. O’Neil, and W. A. Svec, J. Am. Chem. Soc. 112, 6482-6488 (1990). Low Temperature Ultrafast Charge Separation: Rate vs Free Energy, M. P. O’Neil, G. L. Gaines, III, W. A. Svec, M. P. Niemczyk, and M. R. Wasielewski, in Ultrafast Phenomena VII, C. B. Harris, E. P. Ippen, G. A. Mourou, and A. Zewail, Eds., Springer Verlag, Berlin, 1990, pp 411-413. Spin-Polarized Radical Ion Pair Formation Resulting from Two-Step Electron Transfer from the Lowest Excited Singlet State of a Fixed-Distance Photosynthetic Model System at 5 K, M. R. Wasielewski, G. L. Gaines,

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J. Phys. Chem. B, Vol. 114, No. 45, 2010 M. P. O’Neil, W. A. Svec, and M. P. Niemczyk, Mol. Cryst. Liq. Cryst. 194, 201-207 (1991). Multi-Step Electron Transfer in Rigid Photosynthetic Models at Low Temperature: Requirements for Charge Separation and Spin-Polarized Radical Ion Pair Formation, M. R. Wasielewski, G. L. Gaines, M. P. O’Neil, W. A. Svec, M. P. Niemczyk, and D. M. Tiede, in Structure and Function of Bacterial Reaction Centers, M. E. Michel-Beyerle, Ed., Springer-Verlag, Berlin, 1990, pp 349-357. Photoinduced Electron Transfer Reactions in the Solid State. Rate vs Free Energy Dependence in Fixed Distance Porphyrin-Acceptor Molecules, G. L. Gaines, III, M. P. O’Neil, W. A. Svec, M. P. Niemczyk, and M. R. Wasielewski, J. Am. Chem. Soc. 113, 719-721 (1991). Spectrometric Characterization of Purified C60 and C70, K. R. Lykke, M. J. Pellin, P. Wurz, D. M. Gruen, J. E. Hunt, and M. R. Wasielewski, Mater. Res. Soc. Symp. Proc. 206, 679-686 (1991). Energy and Electron Transfer in Covalently-Linked Chlorophyll Containing Donor-Acceptor Molecules, M. R. Wasielewski, in Chlorophylls, H. Scheer, Ed., CRC Press, Boca Raton, 1991, pp 269-286. Solvent Dependent Photophysics of Fixed-Distance Chlorophyll-Porphyrin Molecules: The Possible Role of Low-Lying Charge Transfer States, M. R. Wasielewski, G. L. Gaines, M. P. O’Neil, W. A. Svec, and M. P. Niemczyk, in Electron Transfer in Inorganic, Organic, and Biological Systems, ACS Symposium Series, G. McLendon, J. Bolton, and N. Mataga, Eds., 1991, pp 134-148. Modeling the Primary Electron Transfer Events of Photosynthesis, M. R. Wasielewski, in Metal Ions in Biological Systems, H. Sigel, Ed., Marcel Dekker, New York, Vol. 27, 1991, pp 361-430. Triplet States of Fullerenes C60 and C70: EPR Spectra, Photophysics, and Electronic Structures, M. R. Wasielewski, M. P. O’Neil, K. R. Lykke, M. J. Pellin, and D. M. Gruen, J. Am. Chem. Soc. 113, 2774-2776 (1991). Sub-Picosecond Photoinduced Electron Transfer in Water-Soluble Porphyrin Dimers, F. J. Vergeldt, R. B. M. Koehorst, T. J. Schaafsma, J.-C. Lambry, J.-L. Martin, D. G. Johnson, and M. R. Wasielewski, Chem. Phys. Lett. 182, 107-113, (1991). Solvent and Temperature Dependence of the Lowest Excited Singlet State Lifetime of 7′,7′-Dicyano-7′-βApocarotene, M. P. O’Neil, M. R. Wasielewski, M. M. Khaled, and L. D. Kispert, J. Chem. Phys. 95, 7212-7218 (1991). Fourier-Transform ESR on Model Systems of the Primary Charge Separation in Photosynthesis, A. Angerhofer, M. R. Wasielewski, G. L. Gaines, III, M. P. O’Neil, W. A. Svec, and M. P. Niemczyk, Z. Phys. Chem. 172, 17-30 (1991). Solvent Effects on the Rate vs Free Energy Dependence of Photoinduced Charge Separation in Fixed-Distance Donor-Acceptor Molecules, M. R. Wasielewski, G. L. Gaines, III, M. P. O’Neil, W. A. Svec, M. P. Niemczyk, L. Prodi, and D. Gosztola, in Dynamics and Mechanisms of Photoinduced Electron Transfer and Related Phenomena, N. Mataga, T. Okada, and H. Masuhara, Eds., Elsevier, Amsterdam, 1992, pp 87-103.

91. Photoinduced Electron Transfer in Supramolecular Systems for Artificial Photosynthesis, M. R. Wasielewski, Chem. ReV. 92, 435-461 (1992). 92. Supramolecular Arrays for the Efficient Conversion of Light into Chemical Energy in the Solid State, M. R. Wasielewski, G. L. Gaines, III, M. P. O’Neil, M. P. Niemczyk, and W. A. Svec, in Supramolecular Chemistry, V. Balzani and L. deCola, Eds., Kluwer, Dordrecht, The Netherlands, 1992, pp 201-218. 93. Picosecond Optical Switching Based on Biphotonic Excitation of an Electron Donor-Acceptor-Donor Molecule, M. P. O’Neil, G. L. Gaines, III, M. P. Niemczyk, W. A. Svec, D. Gosztola, and M. R. Wasielewski, Science 257, 63-65 (1992). 94. Ultrafast Photoinduced Electron Transfer Reactions in Supramolecular Arrays: From Charge Separation and Storage to Molecular Switches, M. R. Wasielewski, M. P. O’Neil, D. Gosztola, M. P. Niemczyk, and W. A. Svec, Pure Appl. Chem. 64, 1319-1325 (1992). 95. Primary Charge Separation in Isolated Photosystem II Reaction Centers, M. Seibert, S. Toon, Govindjee, M. P. O’Neil and M. R. Wasielewski, in Research in Photosynthesis, Vol. II, N. Murata, Ed., Kluwer Academic Publishers, Dordrecht, 1992, pp 41-44. 96. Supramolecular Structures for Modeling Photosynthetic Reaction Center Structures, M. R. Wasielewski, G. L. Gaines, III, D. Gosztola, M. P. Niemczyk, and W. A. Svec, in Research in Photosynthesis, Vol. II, N. Murata, Ed., Kluwer Academic Publishers, Dordrecht, 1992, pp 795-800. 97. Nonlinear Optical Parameters of 7′,7′-Dicyano-7′-Apoβ-Carotene in Hexane by Self-Action Techniques, H. A. Abdeldayem, W. Sheng, P. Venkateswarlu, W. K. Witherow, D. O. Frazier, P. Chandra Sekhar, M. C. George, L. Kispert, and M. R. Wasielewski, Opt. Commun. 95, 295-300 (1993). 98. The Dynamics of the S1 Excited States of Carotenoids, H. A. Frank, R. Farhoosh, R. Gebhard, J. Lugtenburg, D. Gosztola, and M. R. Wasielewski, Chem. Phys. Lett. 207, 88-92 (1993). 99. Modeling Primary Electron Transfer Events in Photosynthesis using Supramolecular Structures, M. R. Wasielewski, in The Photosynthetic Reaction Center, Vol. II, J. Deisenhofer and J. Norris, Eds., Academic, New York, 1993, pp 465-511. 100. Photochemical Electron Transfer in Chlorophyll-Porphyrin-Quinone Triads: The Role of the Porphyrin Bridging Molecule, D. G. Johnson, M. P. Niemczyk, D. W. Minsek, G. P. Wiederrecht, W. A. Svec, G. L. Gaines, III, and M. R. Wasielewski, J. Am. Chem. Soc. 115, 5692-5701 (1993). 101. Intramolecular Photoinduced Electron Transfer in a Rigid Anthracene-N,N-Dimethylaniline System. Possible Role of EDA Complex Formation, D. W. Minsek, N. C. Yang, M. P. Niemczyk, W. A. Svec, and M. R. Wasielewski, in Photochemical and Photoelectrochemical ConVersion and Storage of Solar Energy, Z. W. Tian and Y. Cao, Eds., International Academic Publishers, Beijing, China, 1993, pp 121-128. 102. Resonance Raman Spectroscopy of a ChlorophyllPorphyrin Heterodimer: Excitation Profile in the 400-450 nm Region, D. Gosztola and M. R. Wasielewski, J. Phys. Chem. 97, 9599-9602 (1993)

J. Phys. Chem. B, Vol. 114, No. 45, 2010 14123 103. Solvent Effects on the Energetics and Dynamics of Ultrafast Electron Transfer in Chlorophyll-PorphyrinAcceptor Triads, G. P. Wiederrecht, S. Watanabe, and M. R. Wasielewski, Chem. Phys. 176, 601-614 (1993). 104. Biomimetic Modeling of Photosynthetic Reaction Center Function: Long-Lived, Spin-Polarized Radical Ion Pair Formation in Chlorophyll-Porphyrin-Quinone Triads, M. R. Wasielewski, G. L. Gaines, III, G. P. Wiederrecht, W. A. Svec, and M. P. Niemczyk, J. Am. Chem. Soc. 115, 10442-10443 (1993). 105. Photophysics of the Carotenoids Associated with the Xanthophyll Cycle In Photosynthesis, H. Frank, A. Cua, A. Young, D. Gosztola, and M. R. Wasielewski, Photosynthesis Res. 41, 389-395 (1994). 106. Femtosecond Photodichroism Studies of Isolated Photosystem II Reaction Centers, G. P. Wiederrecht, M. Seibert, Govindjee, and M. R. Wasielewski, Proc. Natl. Acad. Sci. U.S.A. 91, 8999-9003 (1994). 107. Effect of Donor-Acceptor Orientation on Ultrafast Photoinduced Electron Transfer and Dark Charge Recombination in Porphyrin-Quinone Molecules, Y. Sakata, H. Tsue, M. P. O’Neil, G. P. Wiederrecht, and M. R. Wasielewski, J. Am. Chem. Soc. 116, 6904-6909 (1994). 108. Ultrafast Photoinduced Charge-Shift Reaction in Electron Donor-Acceptor 9-Arylacridinium Ions, G. Jones, II, M. S. Faharat, S. R. Greenfield, D. J. Gosztola, and M. R. Wasielewski, Chem. Phys. Lett. 229, 40-46 (1994). 109. Ultrafast Optical Switching: Two-Pulse Response of an Electron Donor-Acceptor-Donor Supermolecule, M. R. Wasielewski, D. Gosztola, and W. A. Svec, Mol. Cryst. Liq. Cryst. A 253, 289-296 (1994). 110. Ultrafast Excitation Energy Transfer and Exciton-Exciton Annihilation in Isolated Light Harvesting Complexes of Photosystem II (LHC II) from Spinach, T. Bittner, K.-D. Irrgang, G. Renger, and M. R. Wasielewski, J. Phys. Chem. 98, 11821-11826 (1994). 111. Femtosecond Transient Grating Studies of Electron Transfer in Porphyrin and Chlorophyll Donor-Acceptor Molecules, G. P. Wiederrecht, W. A. Svec, and M. R. Wasielewski, in Ultrafast Phenomena IX, P. Barbara, W. H. Knox, G. A. Mourou and A. H. Zewail, Eds., Springer-Verlag, Berlin, 1994, pp 452-453. 112. Picosecond Laser-Induced Electric Field Modulation of Carotenoid Absorption Bands, D. Gosztola, H. Yamada, and M. R. Wasielewski, in Ultrafast Phenomena IX, P. Barbara, W. H. Knox, G. A. Mourou and A. H. Zewail, Eds., Springer-Verlag, Berlin, 1994, pp 458-459. 113. Electric Field Effects of Photogenerated Ion Pairs on Nearby Molecules: A Model for the Carotenoid Bandshift in Photosynthesis, D. Gosztola, H. Yamada, and M. R. Wasielewski, J. Am. Chem. Soc. 117, 2014-2018 (1995). 114. Quantum Beats of the Radical Pair State in Photosynthetic Models Observed by Transient Electron Paramagnetic Resonance, K. Laukenmann, S. Weber, G. Kothe, C. Oesterle, A. Angerhofer, M. R. Wasielewski, W. A. Svec, and J. R. Norris, J. Phys. Chem. 99, 4324-4329 (1995). 115. Photogenerated Spin Correlated Radical Ion Pairs in Photosynthetic Model Systems, M. R. Wasielewski, Spectrum (Bowling Green, OH, U. S.) 8, 8-12 (1995).

116. Femtosecond Transient Absorption Spectroscopy on the Light-Harvesting Chl a/b Protein Complex of Photosystem II at Room Temperature and 12 K, T. Bittner, G. P. Wiederrecht, K.-D. Irrgang, G. Renger, and M. R. Wasielewski, Chem. Phys. 194, 311-322 (1995). 117. Femtosecond Transient Grating Studies of Chlorophylls and a Chlorophyll-Based Electron Donor-Acceptor Molecule, G. P. Wiederrecht, W. A. Svec, M. P. Niemczyk, and M. R. Wasielewski, J. Phys. Chem. 99, 8918-8926 (1995). 118. Optical Parametric Amplification of Femtosecond Pulses Tunable from the Blue to the IR with Microjoule Energies, S. R. Greenfield and M. R. Wasielewski, Appl. Opt. 34, 2688-2691 (1995). 119. Near Transform-Limited Visible and Near IR Femtosecond Pulses from Optical Parametric Amplification Using Type II β-Barium Borate, S. R. Greenfield and M. R. Wasielewski, Opt. Lett. 20 1394-1396 (1995). 120. Mimicry of the Radical Pair and Triplet States in Photosynthetic Reaction Centers with a Synthetic Model, K. Hasharoni, H. Levanon, S. R. Greenfield, D. J. Gosztola, and M. R. Wasielewski, J. Am. Chem. Soc. 117, 8055-8056 (1995). 121. Chlorin-Based Supramolecular Assemblies for Artificial Photosynthesis, M. R. Wasielewski, G. P. Wiederrecht, W. A. Svec, and M. P. Niemczyk, Sol. Energy Mater. Sol. Cells 38, 127-134 (1995). 122. Photoinduced Electron Transfer for Pyrenesulfonamide Conjugates of Tryptophan-Containing Peptides. Mitigation of Fluoroprobe Behavior in N-Terminal Labeling Experiments, G. Jones, II, L. N. Lily, V. Vullev, D. J. Gosztola, S. R. Greenfield, and M. R. Wasielewski, Bioorg. Med. Chem. Lett. 5, 2385-2390 (1995). 123. High Photorefractive Gain in Nematic Liquid Crystals Doped with Electron Donors and Acceptors, G. P. Wiederrecht, B. A. Yoon, and M. R. Wasielewski, Science 270, 1794-1797 (1995). 124. Femtosecond Spectroscopy of PSII Reaction Centers: New Results, S. R. Greenfield, M. R Wasielewski, Govindjee, and M. Seibert, in Photosynthesis: From Light to Biosphere, Vol. I, P. Mathis, Ed., Kluwer Academic Publishers, Dordrecht, 1995, pp 663-666. 125. Ultrafast Photoinduced Electron Transfer in a Chlorophyll-Based Triad: Vibrationally Hot Ion Pair Intermediates and Dynamic Solvent Effects, G. P. Wiederrecht, M. P. Niemczyk, W. A. Svec, and M. R. Wasielewski, J. Am. Chem. Soc. 118, 81-88 (1996). 126. Molecular Triads that Mimic the Spin-Polarized Triplet State in Photosynthetic Reaction Centers, S. R. Greenfield, W. A. Svec, M. R. Wasielewski, K. Hasharoni, and H. Levanon, in Reaction Centers Of Photosynthetic Bacteria: Structure And Dynamics, M. E. MichelBeyerle, Ed., Springer-Verlag, Berlin, 1996, pp 81-87. 127. Photoinduced Charge Separation. Dipoles, Exciplexes, and Ion Pairs, S. Smirnov, C. Braun, S. Ankner-Mylon, K. Grzeskowiak, S. R. Greenfield, and M. R. Wasielewski, Mol. Cryst. Liq. Cryst. 283, 243-248 (1996). 128. Photorefractive Liquid Crystals, G. P. Wiederrecht, B. A. Yoon, and M. R. Wasielewski, AdV. Mater. 8, 535-539 (1996). 129. Multi-Step Charge Separation Following Direct Excitation of a Charge Transfer State in Rod-Like Molecules Based on Aromatic Imides and Diimides, S. R. Green-

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J. Phys. Chem. B, Vol. 114, No. 45, 2010 field, W. A. Svec, D. Gosztola, and M. R. Wasielewski, J. Am. Chem. Soc. 118, 6767-6777 (1996). A Molecular Probe of the Electric Field Produced by a Photogenerated Ion Pair, M. P. Debreczeny, W. A. Svec, and M. R. Wasielewski, New J. Chem. 20, 815-828 (1996). Giant Dipole Moment in a Triad System. Mechanisms of Anisotropic Photoresponse in the Transient DC Conductivity of Dipolar Solutes, S. N. Smirnov, C. L. Braun, S. R. Greenfield, W. A. Svec, and M. R. Wasielewski, J. Phys. Chem. 100, 12329-12336 (1996). Femtosecond Optical Control of Charge Shift within Electron Donor-Acceptor Arrays: An Approach to Molecular Switches, M. P. Debreczeny, W. A. Svec, E. M. Marsh, and M. R. Wasielewski, J. Am. Chem. Soc. 118, 8174-8175 (1996). Wavelength and Intensity Dependent Primary Photochemistry of Isolated Photosystem II Reaction Centers at 5 °C, S. R. Greenfield, M. Seibert, Govindjee, and M. R. Wasielewski, Chem. Phys. 210, 279-295 (1996). Optical Control of Photogenerated Ion Pair Lifetimes: An Approach to a Molecular Switch, M. P. Debreczeny, W. A. Svec, and M. R. Wasielewski, Science 274, 584-587 (1996). Factoring Through-Space and Through-Bond Contributions to Rates of Photoinduced Electron Transfer in Donor-Spacer-Acceptor Molecules, D. Gosztola, B. Wang, and M. R. Wasielewski, J. Photochem. Photobiol. A 102, 71-80 (1996). Radical Pair and Triplet State Dynamics of a Photosynthetic Reaction Center Model Embedded in Isotropic Media and Liquid Crystals, K. Hasharoni, H. Levanon, S. R. Greenfield, D. J. Gosztola, and M. R. Wasielewski J. Am. Chem. Soc. 118, 10228-10235 (1996). Excitation Energy Transfer and Charge Separation in Isolated Photosystem II Reaction Centers, S. R. Greenfield and M. R. Wasielewski, Photosynth. Res. 48, 83-97 (1996). The Lifetimes and Energies of the First Excited Singlet States of Diadinoxanthin and Diatoxanthin: The Role of These Molecules in Excess Energy Dissipation in Algae, H. A. Frank, A. Cua, V. Chynwat, A. Young, D. Gosztola, and M. R. Wasielewski, Biochim. Biophys. Acta 1277, 243-252 (1996). X- and K-Band Transient EPR of the Light Induced Radical Ion Pairs in Photosynthetic Model Systems, A. J. van der Est, G. Fuechsle, D. Stehlik, and M. R. Wasielewski, Ber. Bunsen-Ges. Phys. Chem. 100, 2081-2085 (1996). Factoring the Contribution of Through-Space and Through-Bond Interactions to Rates of Photoinduced Electron Transfer in Donor-Spacer-Acceptor Molecules using Ultrafast Transient Absorption Spectroscopy, D. Gosztola, B. Wang, and M. R. Wasielewski, in Ultrafast Phenomena X, Springer, Berlin, 1996, pp 230-232. Design and Synthesis of Metal Ion Induced Conjugated Polymers: A New Approach to Metal Ion Sensory Materials, B. Wang and M. R. Wasielewski, J. Am. Chem. Soc. 119, 12-21 (1997). Spectroscopic Properties of Sphaeroidene Analogs having Different Extents of π-Electron Conjugation, H. A. Frank, R. Z. B. Desamero, V. Chynwat, R. Gebhard, I.

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van der Hoef, F. J. Jansen, J. Lugtenburg, D. Gosztola, and M. R. Wasielewski, J. Phys. Chem. A 101, 149-157 (1997). Photorefractivity in Nematic Liquid Crystals Containing Electron Donor-Acceptor Molecules that Undergo Intramolecular Charge Separation, G. P. Wiederrecht, B. A. Yoon, W. A. Svec, and M. R. Wasielewski, J. Am. Chem. Soc. 119, 3358-3364 (1997). Photorefractive Liquid Crystals Doped with Electron Donor and Acceptor Molecules, G. P. Wiederrecht, B. A. Yoon, and M. R. Wasielewski, Synth. Met. 84, 901-902 (1997). Direct Measurement of the Effective Rate of Primary Charge Separation in Isolated Photosystem II Reaction Centers, S. R. Greenfield, M. Seibert, Govindjee, and M. R. Wasielewski, J. Phys. Chem. B 101, 2251-2255 (1997). The Anilide Linker Group as a Participant in Intramolecular Electron Transfer, G. Jones, II, D. X. Yan, S. R. Greenfield, D. J. Gosztola, and M. R. Wasielewski, J. Phys. Chem. A 101, 4939-4942 (1997). Singlet-Singlet Energy Transfer Mechanisms in Covalently-Linked Fucoxanthin- and Zeaxanthin-Pyropheophorbide Molecules, M. P. Debreczeny, M. R. Wasielewski, S. Shinoda, and A. Osuka, J. Am. Chem. Soc. 119, 6407-6414 (1997). Differential Control of Intramolecular Charge Separation and Recombination Rates Using Nematic Liquid Crystal Solvents, G. P. Wiederrecht, W. A. Svec, and M. R. Wasielewski, J. Am. Chem. Soc. 119, 6199-6200 (1997). Spectroscopic Characterization of Quinone-Site Mutants of the Bacterial Photosynthetic Reaction Center, P. D. Laible, Y. Zhang, A. L. Morris, S. W. Snyder, C. Ainsworth, S. R. Greenfield, M. R. Wasielewski, D. K. Hanson, and M. C. Thurnauer, Photosynth. Res. 52, 93-103 (1997). Molecular Structure Determination for Photogenerated Intermediates in Photoinduced Electron Transfer Reactions using Steady-State and Transient XAFS, L. X. Chen, M. R. Wasielewski, T. Rajh, P. L. Lee, M. C. Thurnauer, and P. A. Montano, J. Phys. IV Fr. 7, C2569-C2572 (1997). Antenna Excited State Decay Kinetics Establish Primary Electron Transfer in Reaction Centers as Heterogeneous, P. D. Laible, S. R. Greenfield, M. R. Wasielewski, D. K. Hanson, and R. M. Pearlstein, Biochemistry 36, 8677-8685 (1997). Distance Dependent Electron Transfer in DNA Hairpins, F. D. Lewis, T. Wu, Y. Zhang, R. L. Letsinger, S. R. Greenfield, and M. R. Wasielewski, Science 277, 673-676 (1997). Electron Transfer Rates in Bridged Molecular Systems: A Phenomenological Approach to Relaxation, W. B. Davis, M. R. Wasielewski, M. A. Ratner, V. Mujica, and A. Nitzan, J. Phys. Chem. A 101, 6158-6164 (1997). Photorefractivity in Liquid Crystalline Composite Materials, G. P. Wiederrecht and M. R. Wasielewski, Proc. SPIE 3144, 227-235 (1997). Determination of the Exchange and Dipolar Contributions to the Spin-Spin Coupling in the Donor-Acceptor Complex TAPD-ZnP-NQ, A. van der Est, G. Fuechsle,

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D. Stehlik, and M. R. Wasielewski, Appl. Magn. Reson. 13, 317-335 (1997). Photorefractivity in Polymer-Stabilized Nematic Liquid Crystals, G. P. Wiederrecht and M. R. Wasielewski, J. Am. Chem. Soc. 120, 3231-3236 (1998). The Spectroscopic and Photochemical Properties of Locked-15,15′-cis-sphaeroidene in Solution and Incorporated into the Reaction Center of Rhodobacter sphaeroides R-26.1, J. A. Bautista, V. Chynwat, A. Cua, F. J. Jansen, J. Lugtenburg, D. Gosztola, and M. R. Wasielewski and H. A. Frank, Photosynth. Res. 55, 49-65 (1998). Picosecond Molecular Switch Based on Bidirectional Inhibition of Photoinduced Electron Transfer using Photogenerated Electric Fields, D. Gosztola, M. P. Niemczyk, and M. R. Wasielewski, J. Am. Chem. Soc. 120, 5118-5119 (1998). Characterization of Photovoltaic Cells using Poly(phenylenevinylene) Doped with Perylenediimide Electron Acceptors, M. Angadi, D. Gosztola, and M. R. Wasielewski, J. Appl. Phys. 83, 6187-6189 (1998). Determination of the Energy Levels of Radical Pairs States in Photosynthetic Models Oriented in Liquid Crystals using Time-Resolved Electron Paramagnetic Resonance, H. Levanon, T. Galili, A. Regev, G. P. Wiederrecht, W. A. Svec, and M. R. Wasielewski, J. Am. Chem. Soc. 120, 6366-6373 (1998). Biomolecular Electron Transfer under High Hydrostatic Pressure, M. Tars, A. Ellervee, M. R. Wasielewski, and A. Freiberg, Spectrochim. Acta 54A, 1177-1189 (1998). Molecular Wire Behavior in p-Phenylenevinylene Oligomers, W. B. Davis, W. A. Svec, M. A. Ratner, and M. R. Wasielewski, Nature 396, 60-63 (1998). Photorefractivity in Polymer-stabilized Liquid Crystal Films, M. R. Wasielewski, G. P. Wiederrecht, Polym. Prepr. (Am. Chem. Soc., DiV. Polym. Chem.) 39 (2), 981-982 (1998). Photorefractivity in Polymer Stabilized Nematic Liquid Crystals, G. P. Wiederrecht and M. R. Wasielewski, Proc. SPIE 3471A, 102-109 (1998). Charge Transfer Reactions in Nematic Liquid Crystals, G. P. Wiederrecht, M. R. Wasielewski, T. Galili, and H. Levanon, Proc. SPIE 3475, 102-111 (1998). Mechanisms of Energy Transfer from Carotenoids to Bacteriochlorophyll: Light-harvesting by Carotenoids Having Different Extents of π-Electron Conjugation Incorporated into the B850 Antenna Complex from the Carotenoidless Bacterium Rhodobacter sphaeroides R-26.1, R. Z. B. Desamero, V. Chynwat, I. van der Hoef, F. J. Jansen, J. Lugtenburg, D. Gosztola, M. R. Wasielewski, A. Cua, D. Bocian, and H. A. Frank, J. Phys. Chem. B 102, 8151-8152 (1998). Semigroup Representations, Site Couplings, and Relaxation in Quantum Systems, W. B. Davis, M. R. Wasielewski, R. Kosloff, and M. A. Ratner, J. Phys. Chem. A 102, 9360-9366 (1998). Using Synthetic Model Systems to Understand Charge Separation and Spin Dynamics in Photosynthetic Reaction Centers, M. R. Wasielewski, G. P. Wiederrecht, W. A. Svec, M. P. Niemczyk, K. Hasharoni, T. Galili, A. Regev, and H. Levanon, in Photosynthesis: Mechanisms and Effects, Proceedings of the 11th International Congress on Photosynthesis, Vol. 5, G. Garab,

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Ed., Kluwer Academic Publishers, Dordrecht, 1998, pp 4193-4200. Femtosecond PSII Reaction Center Studies at 7K, S. R. Greenfield, M. R. Wasielewski, and M. Seibert, in Photosynthesis: Mechanisms and Effects, Proceedings of the 11th International Congress on Photosynthesis, Vol. 2, G. Garab, Ed., Kluwer Academic Publishers, Dordrecht, 1998, pp 1029-1032. The Effect of Solvent on the Lifetime of the Lowest Excited Singlet S1 (12Ag) State of Spheroidene, H. A. Frank, J. A. Bautista, D. Gosztola, M. R. Wasielewski, in Photosynthesis: Mechanisms and Effects, Proceedings of the 11th International Congress on Photosynthesis, Vol. 1, G. Garab, Ed., Kluwer Academic Publishers, Dordrecht, 1998, pp 473-476. Exploring the Structure of a Photosynthetic Model by Quantum Chemical Calculations and Time-Resolved Q-Band Electron Magnetic Resonance, A. M. Kiefer, S. M. Kast, J. Brickmann, W. A. Svec, M. R. Wasielewski, K. Laukenmann, and G. Kothe, J. Am. Chem. Soc. 121, 188-198 (1999). Intramolecular Electron Transfer Across Amino Acid Spacers in the Picosecond Time Regime. Charge Transfer Interaction Through Peptide Bonds, G. Jones, II, L. N. Lu, H. Fu, C. W. Farahat, C. Oh, S. R. Greenfield, D. J. Gosztola, and M. R. Wasielewski, J. Phys. Chem. B 103, 572-581(1999). The Influence of Substituents and Chain Length on the Optical Properties of Poly(p-phenylenevinylene) Oligomers, W. B. Davis, M. R. Wasielewski, and M. A. Ratner, Int. J. Quantum Chem. 72, 463-471 (1999). Controlling the Adiabaticity of Electron Transfer Reactions using Nematic Liquid Crystal Solvents, G. P. Wiederrecht and M. R. Wasielewski, J. Phys. Chem. B 103, 1386-1389 (1999). Self-Assembly of Zinc Porphyrin Dimer and Pyromellitimide Using Two Coordination Bonds and Photoinduced Intramolecular Electron Transfer, K. Yamada, H. Imahori, E. Yoshizawa, D. Gosztola, M. R. Wasielewski, and Y. Sakata, Chem. Lett. 235-236 (1999). Picosecond Dynamics of Energy Transfer in a Porphyrin-Sapphyrin Noncovalent Assembly, S. L. Springs, D. Gosztola, M. R. Wasielewski, V. Kral, A. Andrievsky, and J. L. Sessler, J. Am. Chem. Soc. 121, 2281-2289 (1999). Time-resolved X-ray Absorption Determination of Structural Changes following Photoinduced Electron Transfer within Bis-porphyrin Heme Protein Models, L. X. Chen, P. Lee, W. A. Svec, D. Gosztola, P. Montano, and M. R. Wasielewski, J. Phys. Chem. B 103, 3270-3274 (1999). Effects of π-Conjugation Attenuation on the Photophysics and Exciton Dynamics of Poly(p-phenylenevinylene) Derivatives in Solution, L. X. Chen, W. J. H. Ja¨ger, M. P. Niemczyk, and M. R. Wasielewski, J. Phys. Chem. A 103, 4341-4351 (1999). Photorefractive Bragg Gratings in Nematic Liquid Crystals Aligned by a Magnetic Field, G. P. Wiederrecht and M. R. Wasielewski, Appl. Phys. Lett. 74, 3459-3461 (1999). Photorefractivity in Cross-Linked Polymer-Stabilized Nematic Liquid Crystals, G. P. Wiederrecht and M. R. Wasielewski, J. Nonlinear Opt. Phys. Mater. 8, 107-120 (1999).

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181. Photorefractivity in Liquid Crystals Doped with a Conjugated Polymer: Mechanisms for Enhanced Charge Transport, G. P. Wiederrecht, M. P. Niemczyk, W. A. Svec, and M. R. Wasielewski, Chem. Mater. 11, 1409-1412 (1999). 182. Organic Light Emitting Diodes using Poly(phenylenevinylene) Doped with Perylenediimide Electron Acceptors, M. Angadi, D. Gosztola, and M. R. Wasielewski, Mater. Sci. Eng. B 63, 191-194 (1999). 183. Time-resolved Energy Dispersive XAS Studies of Photoinduced Electron Transfer Intermediates in Electron Donor-Acceptor Complexes, L. X. Chen, P. L. Lee, D. Gosztola, W. A. Svec, and M. R. Wasielewski, J. Synchrotron Radiat. 6, 403-405 (1999). 184. Triplet States with Unusual Spin Polarization Resulting from Radical Ion Pair Recombination at Short Distances, G. P. Wiederrecht, W. A. Svec, M. R. Wasielewski, T. Galili, and H. Levanon, J. Am. Chem. Soc., 121, 7726-7727 (1999). 185. 3,4:9,10-Perylenebis(dicarboximide) Chromophores that Function as both Electron Donors and Acceptors, Y. Zhao and M. R. Wasielewski, Tetrahedron Lett. 40, 7047-7050 (1999). 186. Time-resolved Absorption Changes of the Pheophytin Qx Band in Isolated Photosystem II Reaction Centers at 7K: Energy Transfer and Charge Separation, S. R. Greenfield, M. Seibert, and M. R. Wasielewski, J. Phys. Chem. B 103, 8364-8374 (1999). 187. Excited State Properties of Peridinin: Observation of a Solvent Dependence of the Lowest Excited Singlet State Lifetime and Spectral Behavior Unique among Carotenoids, J. A. Bautista, R. E. Connors, B. B. Raju, R. G. Hiller, F. P. Sharples, D. Gosztola, M. R. Wasielewski, and H. A. Frank, J. Phys. Chem. B 103, 8751-8758 (1999). 188. Electronic Interaction between π-Stacked DNA Base Pairs and Diphenylacetylene-4,4’dicarboxamide in Hairpin DNA, F. D. Lewis, S. E. Miller, and M. R. Wasielewski, J. Am. Chem. Soc. 121, 9746-9747 (1999). 189. Structure and Photoinduced Electron Transfer in Exceptionally Stable Synthetic DNA Hairpins with Stilbenediether Linkers, F. D. Lewis, X. Liu, Y. Wu, S. E. Miller, M. R. Wasielewski, R. L. Letsinger, R. Sanishvili, A. Joachimiak, V. Tereshko, and M. Egli, J. Am. Chem. Soc. 121, 9905-9906 (1999). 190. Singlet and Triplet Energy Transfer in the Peridininchlorophyll a-protein from Amphidinium carterae, J. A. Bautista, K. Atticks, R. G. Hiller, F. P. Sharples, D. Gosztola, M. R. Wasielewski, and H. A. Frank, J. Phys. Chem. A 103, 2267-2273 (1999). 191. Photoinduced Charge Migration in the Picosecond Regime for Thianthrene-linked Acridinium Ions, G. Jones, II, D.-X. Yan, D. J. Gosztola, S. R. Greenfield, and M. R. Wasielewski, J. Am. Chem. Soc. 121, 11016-11017 (1999). 192. Photorefractivity in Liquid Crystals Doped with a Soluble Conjugated Polymer, G. P. Wiederrecht, W. A. Svec, M. P. Niemczyk, M. R. Wasielewski, Proc. SPIE -Int. Soc. Opt. Eng. 3800, 13-20 (1999). 193. Femtosecond Optical Switching of Electron Transport Direction in Branched Donor-Acceptor Arrays, A. S. Lukas, S. E. Miller, and M. R. Wasielewski, J. Phys. Chem. B 104, 931-940 (2000).

194. Dynamics of Photoinduced Charge Separation and Charge Recombination in Synthetic DNA Hairpins with Stilbenedicarboxamide Linkers, F. D. Lewis, T. Wu, X. Liu, R. L. Letsinger, S. R. Greenfield, S. E. Miller, and M. R. Wasielewski, J. Am. Chem. Soc. 122, 2889-2902 (2000). 195. Ionochromic Effects and Structures of Metalated Poly(pphenylenevinylene) Polymers Incorporating 2,2′-Bipyridines, L. X. Chen, W. J. H. Ja¨ger, D. J. Gosztola, M. P. Niemczyk, and M. R. Wasielewski, J. Phys. Chem. B 104, 1950-1960 (2000). 196. Electron Transfer Rates in Bridged Molecular Systems 2. A Steady-State Analysis of Coherent Tunneling and Thermal Transitions, D. Segal, A. Nitzan, W. B. Davis, M. R. Wasielewski, and M. A. Ratner, J. Phys. Chem. B 104, 3817-3829 (2000). 197. Porphyrin Based Nanostructures: Routes to Molecular Electronics, A. K. Burrell and M. R. Wasielewski, J. Porphyrins Phthalocyanines 4, 401-406 (2000). 198. Effect of Solvent Environment on the Spectroscopic Properties and Dynamics of the Lowest Excited States of Carotenoids, H. A. Frank, J. A. Bautista, J. Josue, Z. Pendon, R. G. Hiller, F. P. Sharples, D. Gosztola, and M. R. Wasielewski, J. Phys. Chem. B 104, 4569-4577 (2000). 199. Excited Doublet States of Electrochemically Generated Aromatic Imide and Diimide Radical Anions, D. Gosztola, M. P. Niemczyk, W. A. Svec, A. S. Lukas, and M. R. Wasielewski, J. Phys. Chem. A 104, 6545-6551 (2000). 200. Ultrafast Photoswitched Charge Transmission through the Bridge Molecule in a Donor-Bridge-Acceptor System, R. T. Hayes and M. R. Wasielewski, and D. Gosztola, J. Am. Chem. Soc. 122, 5563-5567 (2000). 201. Carotenoids in Liposomes: Photodegradation, Excited State Lifetimes, and Energy Transfer, Z. He, L. D. Kispert, R. M. Metzger, D. Gosztola, and M. R. Wasielewski, J. Phys. Chem. B 104, 6302-6307 (2000). 202. Effect of Terminal Groups, Polyene Chain Length, and Solvent on the First Excited States of Carotenoids, Z. He, D. Gosztola, Y. Deng, G. Gao, M. R. Wasielewski, and L. D. Kispert, J. Phys. Chem. B 104, 6668-6673 (2000). 203. Direct Measurement of Hole Transport Dynamics in DNA, F. D. Lewis, X. Liu, J. Liu, S. E. Miller, R. T. Hayes, and M. R. Wasielewski, Nature 406, 51-53 (2000). 204. Photoinduced Charge Separation Involving an Unusual Double Electron Transfer Mechanism in a DonorBridge-Acceptor Molecule, S. E. Miller, A. S. Lukas, E. Marsh, P. Bushard, and M. R. Wasielewski, J. Am. Chem. Soc. 122, 7802-7810 (2000). 205. Photorefractive Conjugated Polymer-Liquid Crystal Composites, M. R. Wasielewski, B. A. Yoon, M. Fuller, G. P. Wiederrecht, M. P. Niemczyk, and W. A. Svec, Mater. Res. Soc. Symp. Proc. 597, 211-219 (2000). 206. Novel Mechanism for Triplet State Formation in Short Distance Covalently Linked Radical Ion Pairs, G. P. Wiederrecht, W. A. Svec, M. R. Wasielewski, T. Galili, and H. Levanon, J. Am. Chem. Soc. 122, 9715-9722 (2000). 207. Picosecond Molecular Switch Based on the Influence of Photogenerated Electric Fields on Optical Charge

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Transfer Transitions, E. M. Just and M. R. Wasielewski, Superlattices Microstruct. 28, 317-328 (2000). Photorefractivity in Ferroelectric Liquid Crystal Composites Containing Electron Donor and Acceptor Molecules, G. P. Wiederrecht, B. A. Yoon, and M. R. Wasielewski, AdV. Mater. 12, 1533-1536 (2000). Dynamics and Equilibria for Oxidation of G, GG, and GGG sequences in DNA Hairpins, F. D. Lewis, X, Liu, J, Liu, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 122, 12037-12038 (2000). Driving Force Dependence of Electron Transfer Dynamics in DNA, F. D. Lewis, R. S. Kalgutkar, Y. Wu, X. Liu, S. E. Miller, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 122, 12346-12351 (2000). Photorefractivity in Ferroelectric Liquid Crystals, G. P. Wiederrecht, M. R. Wasielewski, and M. J. Fuller, Proc. SPIE-Int. Soc. Opt. Eng. 4104, 104-109 (2000). Effects of Chemical Modifications on Photophysics and Exciton Dynamics of π-Conjugation Attenuated and Metal-Chelated Photoconducting Polymers, L. X. Chen, W. J. H. Ja¨ger, D. J. Gosztola, M. P. Niemczyk, and M. R. Wasielewski, Synth. Met. 116, 229-234 (2001). Dynamics of Photoinduced Charge Transfer and Hole Transport in Synthetic DNA Hairpins, F. D. Lewis, R. L. Letsinger, M. R. Wasielewski, Acc. Chem. Res. 34, 159-170 (2001). Ultrafast Optical Control of Ion Pair Intermediates in Electron Transfer Reactions: Toward a Molecular Switch, M. R. Wasielewski, M. P. Debreczeny, E. M. Marsh, and W. A. Svec, in Hyperstructured Molecules II: Chemistry, Physics, and Applications, H. Sasabe, Ed. Gordon and Breach Publishers, Amsterdam, 2001, pp 197-214. Ultrafast Molecular Logic Gate Based on Optical Switching Between Two Long-Lived Radical Ion Pair States, A. S. Lukas, P. J. Bushard, and M. R. Wasielewski, J. Am. Chem. Soc. 123, 2440-2441 (2001). Approaches to an Optically Controlled Molecular Switch, A. S. Lukas and M. R. Wasielewski, in Electron Transfer in Chemistry, Vol. 5, V. Balzani, Ed., WileyVCH, 2001, pp 48-96. Approaches to a Molecular Switch using Photoinduced Electron and Energy Transfer, A. S. Lukas and M. R. Wasielewski, in Molecular Switches, B. L. Feringa, Ed., Wiley-VCH, 2001, pp 1-35. Competition between Conformation Relaxation and Intramolecular Electron Transfer within PhenothiazinePyrene Dyads, J. Daub, R. Engl, J. Kurzawa, S. E. Miller, S. Schneider, A. Stockmann, and M. R. Wasielewski, J. Phys. Chem. A 105, 5655-5665 (2001). Photorefractivity in Nematic Liquid Crystals Using Donor-Acceptor Dyads with Low-lying Excited Singlet States for Charge Generation, M. J. Fuller, and M. R. Wasielewski, J. Phys. Chem. B 105, 7216-7219 (2001). Conformational Gating of Long Distance Electron Transfer through Wire-like Bridges in Donor-BridgeAcceptor Molecules, W. B. Davis, M. A. Ratner, M. R. Wasielewski, J. Am. Chem. Soc. 123, 7877-7886 (2001). Photophysics of π-Conjugated Metal-Organic Oligomers. Phenylene-ethylenes that Contain the (bpy)Re(CO)3Cl Chromophore, K. A. Walters, K. D. Ley, C. S. P. Cavalaheiro, S. E. Miller, D. Gosztola,

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M. R. Wasielewski, A. P. Bussandri, H. van Willigan, and K. S. Schanze, J. Am. Chem Soc. 123, 8329-8342 (2001). Ultrafast Electron Transfer Reactions Initiated by Excited CT States of Push-Pull Perylenes, S. E. Miller, R. Schaller, V. Mulloni, Y. Zhao, E. M. Just, R. C. Johnson, and M. R. Wasielewski, Chem. Phys. 275, 167-183 (2002). High Time Resolution Q-Band EPR Study of a Sequential Electron transfer in a Triad Oriented in a Liquid Crystal. U. Heinen, T. Berthold, G. Kothe, E. Stavitski, T. Galili, H. Levanon, G. Wiederrecht, and M. R. Wasielewski, J. Phys. Chem. A 106, 1933-1937 (2002). Electron Transfer Involving Non-Bonded Superexchange Interactions in Rigid Donor-Acceptor Arrays, A. S. Lukas, P. J. Bushard, and M. R. Wasielewski, J. Phys. Chem. A 106, 2074-2082 (2002). Biomimetic Electron Transfer using Low Energy Excited States: A Green Perylene-Based Analog of Chlorophyll a, A. S. Lukas, Y. Zhao, S. E. Miller, and M. R. Wasielewski J. Phys. Chem. B 106, 1299-1306 (2002). Hybrid Photorefractive Material Composed of Layered Conjugated Polymer and Dye-Doped Liquid Crystal Films, M. J. Fuller and M. R. Wasielewski, Chem. Mater. 14, 952-953 (2002). Functional Asymmetry of Photosystem II D1 and D2 Peripheral Chlorophyll Mutants of Chlamydomonas reinhardtii, J. Wang, D. Gosztola, S. V. Ruffle, C. Hemann, M. Seibert, M. R. Wasielewski, R. Hille, T. L. Gustafson, R. T. Sayre, Proc. Natl. Acad. Sci. U.S.A. 99, 4091-4096 (2002). Charge Transport in Photofunctional Nanoparticles SelfAssembled from Zinc 5,10,15,20-Tetrakis(perylenediimide)porphyrin Building Blocks, T. van der Boom, R. T. Hayes, Y. Zhao, P. J. Bushard, E. A. Weiss, and M. R. Wasielewski, J. Am. Chem. Soc. 124, 9582-9590 (2002). Dynamics and Energetics of Hole Trapping in DNA by 7-Deazaguanine, F. D. Lewis, J. Liu, X. Zuo, R. T. Hayes, and M. R. Wasielewski, Angew Chemie Int. Ed. Engl. 41, 1026-1028 (2002). Dynamics and Inter- and Intra-Strand Hole Transport in DNA Hairpins, F. D. Lewis, J. Liu, X. Zuo, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 124, 4568-4569 (2002). Excited State Symmetry Breaking in Cofacial and Linear Dimers of a Green Perylenediimide Chlorophyll Analog Leading to Ultrafast Charge Separation, J. M. Giaimo, A. V. Gusev, and M. R. Wasielewski, J. Am. Chem. Soc. 124, 8530-8531 (2002). Charge Transport In Linear Perylene-3,4-Dicarboximide Polymers: A Comparison between Covalent and SelfAssembly Strategies, M. J. Fuller and M. R. Wasielewski, Polym. Prepr. (Am. Chem. Soc., DiV. Polym. Chem.) 43, 516-517 (2002). A Perspective on Four New Porphyrin-Based Functional Materials and Devices, C. M. Drain, J. T. Hupp, K. S. Suslick, M. R. Wasielewski, and X. Chen, J. Porphyrins Phthalocyanines 6, 243-258 (2002). Dependence of Electron Transfer Dynamics in Wirelike Bridge Molecules on Donor-Bridge Energetics and Electronic Interactions, W. B. Davis, M. A. Ratner, and M. R. Wasielewski, Chem. Phys. 281, 333-346 (2002).

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235. Dynamics of electron injection in DNA hairpins, F. D. Lewis, X. Liu, S. E. Miller, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 124, 11280-11281 (2002). 236. DNA-mediated electron transfer across synthetic T:A*T triplex structures, F. D. Lewis, Y. Wu, R. T. Hayes, and M. R. Wasielewski, Angew. Chem. Int. Ed. Engl. 41, 3485-3487 (2002). 237. Formation and Decay of Localized Contact Radical Ion Pairs in DNA Hairpins, F. D. Lewis, X. Liu, S. E. Miller, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 124, 14020-14026 (2002). 238. Effects of Solvent and Structural Dynamics on Electron Transfer Reactions of 4-Aminonaphthalene-1,8-dicarboximide Donor-Acceptor Molecules in Nematic Liquid Crystals and Isotropic Solvents, L. E. Sinks and M. R. Wasielewski, J. Phys. Chem A 107, 611-620 (2003). 239. Mapping the Influence of Molecular Structure on Rates of Electron Transfer Using Direct Measurements of the Electron Spin-Spin-Exchange Interaction, A. S. Lukas, P. J. Bushard, and M. R. Wasielewski, J. Am. Chem. Soc. 125, 3921-3930 (2003). 240. Direct Measurement of Electronic Coupling for Charge Recombination within Rod-like Photogenerated Radical Ion Pairs Using Magnetic Field Effects, E. A. Weiss, M. A. Ratner, and M. R. Wasielewski, J. Phys. Chem. A 107, 3639-3647 (2003). 241. Dynamics and Energetics of Single Step Hole Transport in DNA, F. D. Lewis, J. Liu, X, Zuo, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 125, 4850-4861 (2003). 242. Using Spin Dynamics of Covalently Linked Radical Ion Pairs to Probe the Impact of Structural and Energetic Changes on Charge Recombination, S. Shaakov, T. Galili, E. Stavitski, H. Levanon, A. S. Lukas, and M. R. Wasielewski, J. Am. Chem. Soc. 125, 6563-6572 (2003). 243. Cyanated Perylene-3,4-dicarboximides and Perylene3,4:9,10-bis(dicarboximide): Facile Chromophoric Oxidants for Organic Photonics and Electronics, M. J. Ahrens, M. J. Fuller, and M. R. Wasielewski, Chem. Mater. 15, 2684-2686 (2003). 244. Bioinspired Optically-Controlled Ultrafast Molecular AND Gate, M. Andersson, L. E. Sinks, R. T. Hayes, Y. Zhao, and M. R. Wasielewski, Angew Chem. Int. Ed. Engl. 42, 3139-3143 (2003). 245. The Isolated Photosystem II Reaction Center: First Attempts to Directly Measure the Kinetics of Primary Charge Separation, M. Seibert and M. R. Wasielewski, Photosynth. Res. 76 263-268 (2003). 246. Self-Assembly of Photofunctional Siloxane-Based Calix[4]arene on Oxide Surfaces, T. van der Boom, G. Evmenenko, P. Dutta, and M. R. Wasielewski, Chem. Mater. 15, 4068-4074 (2003). 247. Dynamics and Equilibrium for Single Step Hole Transport Processes in Duplex DNA, F. D. Lewis and M. R. Wasielewski, Top. Curr. Chem. 236, 45-65 (2004). 248. Competitive Electron Transfer from the S2 and S1 Excited States of Zinc meso-Tetraphenylporphyrin to a Covalently-Bound Pyromellitimide: Dependence on Donor-Acceptor Structure and Solvent, R. T. Hayes and M. R. Wasielewski, J. Phys. Chem. A 108, 2375-2381 (2004).

249. Modulation of Radical Ion Pair Lifetimes by the Presence of a Third Spin in Rod-like Donor-Acceptor Triads, E. A. Weiss, E. T. Chernick and M. R. Wasielewski, J. Am. Chem. Soc. 126, 2326-2327 (2004). 250. Using Three Pulse Femtosecond Spectroscopy to Probe Ultrafast Triplet Energy Transfer in Zinc meso-tetraarylporphyrin - Perylene-3,4-dicarboximide Dyads, R. T. Hayes and M. R. Wasielewski, J. Phys. Chem. A 108, 3253-3260 (2004). 251. Making a Molecular Wire: Charge and Spin Transport through para-Phenylene Oligomers, E. A. Weiss, M. J. Ahrens, L. E. Sinks, A. V. Gusev, M. A. Ratner, and M. R. Wasielewski, J. Am. Chem. Soc. 126, 5577-5584 (2004). 252. Novel fluorescent cationic phospholipid, O-4-naphthylimido-1-butyl-DOPC, exhibits unusual foam morphology, forms hexagonal and cubic phases in mixtures, and transfects DNA. R. Koynova, H. S. Rosenzweig, L. Wang, M. Wasielewski, and R. C. MacDonald, Chem. Phys. Lipids 129, 183-194 (2004). 253. DNA-Mediated Exciton Coupling and Electron Transfer Between Donor and Acceptor Stilbenes Separated by a Variable Number of Base Pairs, F. D. Lewis, Y. Wu, L. Zhang, X. Zuo, R. T. Hayes, and M. R. Wasielewski, J. Am. Chem. Soc. 126, 8206-8215 (2004). 254. Self-Assembly of Supramolecular Light-Harvesting Arrays From Covalent Multi-Chromophore Perylene-3,4: 9,10-bis(dicarboximide) Building Blocks, M. J. Ahrens, L. E. Sinks, B. Rybtchinski, W. Liu, B. A. Jones, J. M. Giaimo, A. V. Gusev, A. J. Goshe, D. M. Tiede, and M. R. Wasielewski, J. Am. Chem. Soc. 126, 8284-8294 (2004). 255. Influence of Energetics and Electronic Coupling on Through-bond and Through-space Electron Transfer within U-Shaped Donor-Bridge-Acceptor Arrays, E. A. Weiss, L. E. Sinks, A. S. Lukas, E. T. Chernick, M. A. Ratner, and M. R. Wasielewski, J. Phys. Chem. B 108, 10309-10316 (2004). 256. Solvent Control of Spin-Dependent Charge Recombination Mechanisms within Donor-Conjugated BridgeAcceptor Molecules, E. A. Weiss, M. J. Ahrens, L. E. Sinks, M. A. Ratner, and M. R. Wasielewski, J. Am. Chem. Soc. 126, 9510-9511 (2004). 257. Ultrafast Aggregate-to-Aggregate Energy Transfer within Self-assembled Light-Harvesting Columns of Zinc Phthalocyanine Tetrakis(perylenediimide), X. Li, L. E. Sinks, B. Rybtchinski, and M. R. Wasielewski, J. Am. Chem. Soc. 126, 10810-10811 (2004). 258. Photoinduced Electron Transfer in Self-assembled Dimers of 3-fold Symmetric Donor-Acceptor Molecules Based on Perylene-3,4:9,10-bis(dicarboximide), B. Rybtchinski, L. E. Sinks, and M. R. Wasielewski, J. Phys. Chem. A 108, 7497-7505 (2004). 259. Combining Light-harvesting and Charge Separation in a Self-assembled Artificial Photosynthetic System based on Perylenediimide Chromophores, B. Rybtchinski, L. E. Sinks, and M. R. Wasielewski, J. Am. Chem. Soc. 126, 12268-12269 (2004). 260. Substitution of a Chlorophyll into the Inactive Branch Pheophytin-binding Site Impairs Charge Separation in Photosystem II, L. Xiong, M. Seibert, A. V. Gusev, M. R. Wasielewski, C. Hemann, C. R. Hille, and R. T. Sayre, J. Phys. Chem. B 108, 16904-16911 (2004).

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ing Applications, K. Salikhov, Ed., AXAS Publishing Ltd., Wellington, New Zealand, 2009. Enhanced Intersystem Crossing in Three-Spin Systems: A Perturbation Theory Treatment, S. Yeganeh, M. R. Wasielewski, and M. A. Ratner, J. Am. Chem. Soc. 131, 2268-2273 (2009). Ultrafast Intersystem Crossing and Spin Dynamics of Photoexcited Perylene-3,4:9,10-bis(dicarboximide) Covalently Linked to a Nitroxide Radical at Fixed Distances, E. M. Giacobbe, Q. Mi, M. T. Colvin, B. Cohen, C. Ramanan, A. M. Scott, T. J. Marks, M. A. Ratner, and M. R. Wasielewski, J. Am. Chem. Soc. 131, 3700-3712 (2009). Excited State, Charge Transfer and Spin Dynamics in DNA Hairpin Conjugates with Perylenediimide Hairpin Linkers, R. Carmieli, T. A. Zeidan, R. F. Kelley, Q. Mi, F. D. Lewis, and M. R. Wasielewski, J. Phys. Chem. A 113, 4691-4700 (2009). Temperature Dependent Conformational Change of mesoHexakis(pentafluorophenyl)[28]hexaphyrins(1.1.1.1.1.1) into Mo¨bius Structures, K. S. Kim, Z. S. Yoon, A. B. Ricks, J.-Y. Shin, S. Mori, J. Sankar, S. Saito, Y. M. Jung, M. R. Wasielewski, A. Osuka, and D. Kim, J. Phys. Chem. A 113, 4498-4506 (2009). Hydrophobic Dimerization and Thermal Dissociation of Perylenediimide-Liked DNA Hairpins, M. Hariharan, Y. Zheng, H. Long, T. A. Zeidan, G. C. Schatz, J. VuraWeis, M. R. Wasielewski, X. Zuo, D. M. Tiede, and F. D. Lewis, J. Am. Chem. Soc. 131, 5920-5929 (2009). Synthesis and Photophysical Properties of Donor- and Acceptor-Substituted 1,7-Di(arylalkynyl) Perylene Diimides, Z. An, S. A. Odom, R. F. Kelley, C. Huang, X. Zhang, S. Barlow, L. A. Padilha, J. Fu, D. J. Hagan, E. W. Van Stryland, M. R. Wasielewski, and S. R. Marder, J. Phys. Chem. A 113, 5585-5593 (2009). Toward a n-Type Molecular Wire: Electron Hopping within Linearly linked Perylenediimide Oligomers, T. M. Wilson, M. J. Tauber, and M. R. Wasielewski, J. Am. Chem. Soc. 131, 8952-8957 (2009). Direct Measurement of Photoinduced Charge Separation Distances in Donor-Acceptor Systems for Artificial Photosynthesis using OOP-ESEEM, R. Carmieli, Q. Mi, A. Butler Ricks, E. M. Giacobbe, S. M. Mickley, and M. R. Wasielewski, J. Am. Chem. Soc. 131, 8372-8373 (2009). Excitation Energy Transfer Pathways within Asymmetric Covalent Chlorophyll a Tetramers, V. L. Gunderson, T. M. Wilson, M. R. Wasielewski, J. Phys. Chem. C 113, 11936-11942 (2009). Efficient Charge Transport in DNA Diblock Oligomers, J. Vura-Weis, M. R. Wasielewski, A. K. Thazhathveetil, and F. D. Lewis, J. Am. Chem. Soc. 131, 9722-9727 (2009). Photoinitiated Charge Transport through π-Stacked Electron Conduits in Supramolecular Ordered Assemblies of Donor-Acceptor Triads, J. E. Bullock, R. Carmieli, S. M. Mickley, J. Vura-Weis, and M. R. Wasielewski, J. Am. Chem. Soc. 131, 11919-11929 (2009). Synthesis and Photophysical Properties of an AlkyneBridged Bis(Zinc Porphyrin)-Perylene Diimide Derivative, S. A. Odom, R. F. Kelley, S. Ohira, T. Ensley, C. Huang, L. A. Padilha, S. Webster, V. Coropceanu, S. Barlow, D. J. Hagan, E. W. Van Stryland, J.-L

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