P(VDF-HFP) Core-Shell-Matrix

Core-shell-matrix, Energy storage density, Multiple interfaces, Internal barrier layer .... P(VDF-HFP) polymer matrix to form nanocomposited films. As...
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Multiple Interfacial Fe3O4@BaTiO3/P(VDF-HFP) CoreShell-Matrix Films with Internal Barrier Layer Capacitor (IBLC) Effects and High Energy Storage Density Ling Zhou, Qiuyun Fu, Fei Xue, Xiahui Tang, Dongxiang Zhou, Yahui Tian, Geng Wang, Chaohong Wang, Haibo Gou, and Lei Xu ACS Appl. Mater. Interfaces, Just Accepted Manuscript • DOI: 10.1021/acsami.7b10923 • Publication Date (Web): 01 Nov 2017 Downloaded from http://pubs.acs.org on November 2, 2017

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ACS Applied Materials & Interfaces

Multiple Interfacial Fe3O4@BaTiO3/P(VDF-HFP) Core-Shell-Matrix Films with Internal Barrier Layer Capacitor (IBLC) Effects and High Energy Storage Density Ling Zhou†‡, Qiuyun Fu†‡,*, Fei Xue§, Xiahui Tang†, Dongxiang Zhou†‡, Yahui Tian†‡, Geng Wang†‡, Chaohong Wang †‡, Haibo Gou †‡ and Lei Xu †,ǁ †

School of Optical and Electronic Information, ‡Engineering Research Center for

Functional Ceramics of the Ministry of Education, Huazhong University of Science and Technology, Wuhan 430074, P. R. China. §

Center of Collaboration and Innovation, Jiangxi University of Technology, Nanchang, Jiangxi, 330098, P. R. China ǁ

Institute of Huazhong University of Science and Technology, 9 Yuexingsandao, Nanshan District, Shenzhen 518000, China

Key words Core-shell-matrix, Energy storage density, Multiple interfaces, Internal barrier layer capacitor effect, Maxwell–Wagner capacitor model.

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Abstract Flexible nanocomposites composed of high dielectric constant fillers and polymer matrix have shown great potential for electrostatic capacitors and energy storage applications. To obtain the composited material with high dielectric constant and high breakdown strength, multi-interfacial composited particles, which composed of conductive cores and insulating shells and possessed the internal barrier layer capacitor (IBLC) effect, were adopted as fillers. Thus, Fe3O4@BaTiO3 core-shell particles

were

prepared

and

loaded

into

the

poly-(vinylidene

fluoride-co-hexafluoropropylene) (P(VDF-HFP)) polymer matrix. As the mass fraction of core-shell fillers increased from 2.5 wt.% to 30 wt.%, the dielectric constant of the films increased, while the loss tangent remained at a low level (