Reactions of [Au (acac) PPh3] with diphosphine derivatives: different

Reactions of [Au(acac)PPh3] with diphosphine derivatives: different coordination modes of gold to the ligand systems. X-ray structure of ...
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Organometallics 1994,13, 1538

1993,Volume 12 M. Concepci6n Gimeno, Antonio Laguna,' Mariano Laguna, Federico Sanmartin, and Peter G. Jones: Reactions of [Au(acac)PPhal with Diphosphine Derivatives: Different CoordinationModes of Gold to the Ligand Systems. X-ray Structure of [SPPhlC(AuPPh~)~PPh~CH(AuPPh~)COOMelClO~ and [Aus-

(C6F5)t(SPPhz)zC)z(PPha)j. Page 3984. In the Introduction the first sentenceshould be changed as follows: Acetylacetonate complexes of palladium and platinum1*and mainly of goldlb have been used as useful deprotonating agents of organophosphorus compounds to allow the synthesis of new compounds of these metals. We have recently reported the preparation of methanide or methanediide complexes by a similar procedure,starting from [A~(CsFs)2t(PPh2)2CH2))3ClO4.~~ (1) (a) Hasimoto, H.; Nakamura, Y.; Okeya, S. Znorg. Chim. Acta 1986, 120, L25. (b) Vicente, J.; Chicote, M. T.; Saura-Llamas, 1.; Turpiu, J.;

Fernandez-Baeza, J. J. Organomet. Chem. 1987,333, 129. Vicente, J.; Chi~te,M.T.;Saura-Llamas,I.;Jones,P.G.;Meyer-BHse,K.;Erdb~er, C. F. Organometallics 1988, 7, 997. Vicente, J.; Chicote, M. T.; SawnLlamas, I. J. Chem. SOC., Dalton Trans. 1990,1941. Vicente, J.; Chicote, M. T.;Lagunas, M. C. Znorg. Chem. 1993,32,3748. (c) Femhdez, E. J.; Gimeno, M. C.; Jones, P. G.; Laguna, A.; Laguna, M.; L6pez de Luzuriaga, J. M. J. Chem. Soe., Dalton Trans. 1992,3365.

0276-7333/94/2313-1538$04.60/0 Q 1994 American Chemical Society