Recent Reviews. 56 - The Journal of Organic Chemistry (ACS

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the sco...
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J. Org. Chem. 2000, 65, 2267-2276

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Recent Reviews. 56 compiled by Veronica M. Cornel Department of Chemistry, Reedley College, 339 West Carpenter Avenue, Reedley, California 93654

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index. Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted. This installment of Recent Reviews covers principally the latter part of the 1999 literature. Previous installment: J. Org. Chem. 2000, 65(1), 267-74. Supporting Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in rtf format is available free of charge via the Internet at http://pubs.acs.org.

Regularly Issued Journals and Series Volumes Accounts of Chemical Research 1. Arduengo, A. J., III. Looking for Stable Carbenes: The Difficulty in Starting Anew. 1999, 32(11), 913-21. 2. Wiberg, K. B. The Interaction of Carbonyl Groups with Substituents. 1999, 32(11), 922-9. 3. Paradisi, C.; Scorrano, G. From Tars to Products: How to Disentangle the Reactions of Nitrobenzenes with Nucleophiles. 1999, 32(11), 958-68. 4. Moss, R. A. The Fragmentation of Alkoxyhalocarbenes. 1999, 32(11), 969-74. 5. Caulder, D. L.; Raymond, K. N. Supermolecules by Design. 1999, 32(11), 975-82. 6. Goodman, L.; Pophristic, V.; Weinhold, F. Origin of Methyl Internal Rotation Barriers. 1999, 32(12), 98393. Acta Chemica Scandinavica 7. Langstrom, B.; Kihlberg, T.; Bergstrom, M.; Antoni, G.; Bjorkman, M.; Forngren, B. H.; Forngren, T.; Hartvig, P.; Markides, K.; Yngve, U.; Ogren, M. Compounds Labeled with Short-Lived β+-Emitting Radionuclides and Some Applications in Life Sciences. The Importance of Time as a Parameter. 1999, 53(9), 651-69. 8. Evans, D. H.; Lehmann, M. W. Two-Electron Reactions in Organic and Organometallic Electrochemistry. 1999, 53(10), 765-74. 9. Senning, A.; Hawata, M. A. The Synthetic Chemistry of Carbon Monosulfide. 1999, 53(10), 775-80. Advances in Heterocyclic Chemistry 10. Friedrischsen, W. Recent Advances in the Chemistry of Benzo[c]furans and Related Compounds. 1999, 73, 1-96. 11. Groundwater, P.; Nyerges, M. 1,7-Electrocyclizations of R,β; γ,δ-Unsaturated 1,3-Dipoles. 1999, 73, 97129.

12. Shaban, M. A. E.; Morgann, A. E. A. The Chemistry of 1,2,4-Triazolopyrimidines I: 1,2,4-Triazolo[4,3-a]pyrimidines. 1999, 73, 131-76. 13. Hermecz, I. Chemistry of Benzologs of Pyrido[1,2a]pyrimidines: Part V of Series on Pyrido-Oxazines, -Diazines, and -Thiazines. 1999, 73, 177-274. 14. Hashem, A. I.; Senning, A. Reactions of 2(3H)Furanones. 1999, 73, 275-93. 15. Belenkii, L. I.; Kruchkovskaya, N. D.; Gramenitskaya, V. N. Literature of Heterocyclic Chemistry, Part VI, 1994-1997. 1999, 73, 295-395. 16. van der Plas, H. C. Degenerate Ring Transformations of Heterocyclic Compounds 1999, 74, 1-253. Advances in Organometallic Chemistry 17. Twamley, B.; Haubrich, S. T.; Power, P. P. Element Derivatives of Sterically Encumbering Terphenyl Ligands. 1999, 44, 1-65. Aldrichimica Acta 18. Hudlicky, T.; Gonzalez, D.; Gibson, D. T. Enzymatic Dihydroxylation of Aromatics in Enantioselective Synthesis: Expanding Asymmetric Methodology. 1999, 32(2), 35-62. Angewandte Chemie, International Edition in English 19. Podlech, J. New Insight into the Source of Biomolecular Homochirality: an Extraterrestrial Origin for Molecules of Life? 1999, 38(4), 477-8. 20. Shaik, S.; Shurki, A. Valence Bond Diagrams and Chemical Reactivity. 1999, 38(5), 587-625. 21. Beuck, M. Nonsteroidal Antiinflammatory Drugs: A New Generation of Cyclooxygenase Inhibitors. 1999, 38(5), 631-3. 22. Zhang, A. J.; Burgess, K. Total Syntheses of Vancomycin. 1999, 38(5), 634-6.

10.1021/jo004001l CCC: $19.00 © 2000 American Chemical Society Published on Web 03/16/2000

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23. Dalko, P. I.; Sinay, P. Recent Advances in the Conversion of Carbohydrate Furanosides and Pyranosides into Carbocycles. 1999, 38(6), 773-7. 24. Rybtchinski, B.; Milstein, D. Metal Insertion into C-C Bonds in Solution. 1999, 38(7), 871-83. 25. Fischer, M.; Vogtle, F. Dendrimers: From Design to Application - A Progress Report. 1999, 38(7), 885905. 26. Bolm, C.; Beckmann, O.; Dabard, O. A. G. The Search for New Environmentally Friendly Chemical Processes. 1999, 38(7), 907-9. 27. MacGillivray, L. R.; Atwood, J. L. Structural Classification and General Principles for the Design of Spherical Molecular Hosts. 1999, 38(8), 1018-33. 28. Abbenhuis, H. C. L. Heterogenization of Metallocene Catalysts for Alkene Polymerization. 1999, 38(8), 1058-60. 29. Martin, R. E.; Diederich, F. Linear Monodisperse π-Conjugated Oligomers: Model Compounds for Polymers and More. 1999, 38(10), 1351-77. 30. Schroder, P. N.; Giannis, A. From Substrate to Transition State Analogues: The First Potent Inhibitor of Sialyltransferases. 1999, 38(10), 1379-80. 31. Kolter, T.; Sandhoff, K. Sphingolipids - Their Metabolic Pathways and the Pathobiochemistry of Neurodegenerative Diseases. 1999, 38(11), 1532-68. 32. Vogl, E. M.; Groger, H.; Shibasaki, M. Towards Perfect Asymmetric Catalysis: Additives and Cocatalysts. 1999, 38(11), 1570-7. 33. Tor, Y. RNA and the Small Molecule World. 1999, 38(11), 1579-82. 34. Nelson, A. Asymmetric Phase-Transfer Catalysis. 1999, 38(11), 1583-5. 35. Dyker, G. Transition Metal Catalyzed Coupling Reactions under C-H Activation. 1999, 38(12), 1699712. 36. Watson, C. Polymer-Supported Synthesis of Non-Oligomeric Natural Products. 1999, 38(13/14), 19038. 37. Nicolaou, K. C.; Boddy, C. N. C.; Brase, S.; Winssinger, N. Chemistry, Biology, and Medicine of the Glycopeptide Antibiotics. 1999, 38(15), 2097-152. 38. Lindner, E.; Schneller, T.; Auer, F.; Mayer, H. A. Chemistry in Interphases-A New Approach to Organometallic Syntheses and Catalysis. 1999, 38(15), 215574. 39. Tenaglia, A.; Heumann, A. Palladium-Catalyzed Enantioselective Organic Transformations. 1999, 38(15), 2180-4. 40. Sears, P.; Wong, C.-H. Carbohydrate Mimetics: A New Strategy for Tackling the Problem of CarbohydrateMediated Biological Recognition. 1999, 38(16), 2301-24. 41. Batey, R. T.; Rambo, R. P.; Doudna, J. A. Tertiary Motifs in RNA Structure and Folding. 1999, 38(16), 2327-43. 42. Theil, F. Synthesis of Diaryl Ethers: A LongStanding Problem has been Solved. 1999, 38(16), 23457. 43. Heinz, D. W. A Phospholipase with a Novel Catalytic Triad. 1999, 38(16), 2348-51. 44. Lottspeich, F. Proteome Analysis: A Pathway to the Functional Analysis of Proteins. 1999, 38(17), 247692. 45. Wilming, M.; Johnsson, K. Spontaneous Formation of the Bioactive Form of the Tuberculosis Drug Isoniazid. 1999, 38(17), 2588-90.

Recent Reviews

46. Woggon, W.-D. Improving the Yield of R-Tocopherol from Natural Sources - Chemistry Versus Molecular Biology. 1999, 38(18), 2715-9. 47. Arend, M. Asymmetric Catalytic Aminoalkylations: New Powerful Methods for the Enantioselective Synthesis of Amino Acid Derivatives, Mannich Bases, and Homoallylic Amines. 1999, 38(19), 2873-4. 48. Davis, A. P.; Wareham, R. S. Carbohydrate Recognition through Noncovalent Interactions: A Challenge for Biomimetic and Supramolecular Chemistry. 1999, 38(20), 2979-96. 49. Broll, D.; Kaul, C.; Kramer, A.; Krammer, P.; Richter, T.; Jung, M.; Vogel, H.; Zehner, P. Chemistry in Supercritical Water. 1999, 38(20), 2999-3014. 50. Cardenas, D. J. Towards Efficient and Wide-Scope Metal-Catalyzed Alkyl-Alkyl Cross-Coupling Reactions. 1999, 38(20), 3018-20. Australian Journal of Chemistry 51. Lynch, D. E.; Cooper, C. J.; Chauhan, V.; Smith, G.; Healy, P.; Parsons, S. Conformational Comparisons between Phenoxyacetic Acid Derivatives in Adducts and in the Free Form. 1999, 52(7), 695-703. Canadian Journal of Chemistry 52. Bohme, D. K. 1998 J. C. Polanyi Award Lecture. Fullerene Ions in the Gas Phase: Chemistry as a Function of Charge State. 1999, 77(9), 1453-64. Chemical Reviews 53. Youngs, W. J.; Tessier, C. A.; Bradshaw, J. D. Ortho-Arene Cyclynes, Related Heterocyclynes, and their Metal Chemistry. 1999, 99(11), 3153-80. 54. Segura, J. L.; Martin, N. o-Quinodimethanes: Efficient Intermediates in Organic Synthesis. 1999, 99(11), 3199-246. 55. Eilbracht, P.; Baerfacker, L.; Buss, C.; Hollmann, C.; Kitsos-Rzychon, B. E.; Kranemann, C. L.; Rische, T.; Roggenbuck, R.; Schmidt, A. Tandem Reaction Sequences under Hydroformylation Conditions: New Synthetic Applications of Transition Metal Catalysis. 1999, 99(11), 3329-65. 56. Beletskaya, I.; Moberg, C. Element-Element Addition to Alkynes Catalyzed by the Group 10 Metals. 1999, 99(12), 3435-61. 57. Castro, E. A. Kinetics and Mechanisms of Reactions of Thiol, Thiono, and Dithio Analogues of Carboxylic Esters with Nucleophiles. 1999, 99(12), 3505-24. Chemical Society Reviews 58. Erker, G. Using Bent Metallocenes for Stabilizing Unusual Coordination Geometries at Carbon. 1999, 28(5), 307-14. 59. Liu, S.-T.; Rajender Reddy, K. Carbene Transfer Reactions between Transition-Metal Ions. 1999, 28(5), 315-22. 60. Gribble, G. W. The Diversity of Naturally Occurring Organobromine Compounds. 1999, 28(5), 335-46. Chemistry and Industry 61. Holmes, A. B.; Stephenson, G. R. Organic Chemistry. 1999(18), 713-5.

Recent Reviews

62. Burgess, K. Organometallic Chemistry. 1999(18), 716-7. Chemistry - A Europian Journal 63. Alsina, J.; Jensen, K. J.; Albericio, F.; Barany, G. Solid-Phase Synthesis with Tris(alkoxy)benzyl Backbone Amide Linkage (BAL). 1999, 5(10), 2787-95. Chemistry of Heterocyclic Compounds 64. Frasinyuk, M. S.; Khilya, V. P. Preparation and Reactions of Isoflavone Heteroanalogues. 1999, 35(1), 3-22. 65. Fisyuk, A. S.; Bundel, Y. G. 5,6-Dihydropyridin2(1H)-ones and 5,6-Dihydropyridine-2(1H)-thiones. 1999, 35(2), 125-45. 66. Shantare, D.; Gudriniece, E.; Yure, M. Synthesis and Properties of 2-Oxooxazolopyridines. 1999, 35(2), 146-60. 67. Yurovskaya, M. A.; Mit’kin, O. D. Functionalization of Pyridines. 3. Reactions Forming a Carbon-Heteroatom Bond with Group IV, V, and VI Elements. 1999, 35(4), 383-435. CHEMTRACTS: Organic Chemistry 68. Rotella, D. P. Photoaffinity Labeling of Oxidosqualene Cyclase and Squalene Cyclase by a Benzophenone-Containing Inhibitor. 1999, 12(7), 483-6. 69. Kresge, A. J. Aspirin-Like Molecules that Covalently Inactivate Cyclooxygenase-2. 1999, 12(7), 489-91. 70. Bergbreiter, D. E. Very Active, Selective Chiral Phosphane/Diamine Catalysts for Ketone Reduction. 1999, 12(7), 494-7. 71. Wender, P. A.; Love, J. A. Organic Synthesis Delivers on Another Medicinal Lead: Total Syntheses of Dysidiolide. 1999, 12(7), 512-21. 72. Thompson, A.; Dolphin, D. Synthesis and Properties of Ring-Deactivated Deuterated (Hydroxymethyl)pyrroles. 1999, 12(7), 534-8. 73. Vlcek, A., Jr. Substrates for Rapid Delivery of Electrons and Holes to Buried Active Sites in Proteins. 1999, 12(8), 565-9. 74. Yu, B.; Dai, L.-X. Glycosyl Triflates are Intermediates that Lead to an Efficient Protocol for β-Mannopyranoside Formation from Thioglycosides. 1999, 12(9), 629-34. 75. Poli, G.; Scolastico, C. Phosphapalladacycles: New Efficient Catalysts. 1999, 12(9), 643-55. 76. Jarvis, B. B. Combinatorial Chemistry in Insects: A Library of Defensive Macrocyclic Polyamines. 1999, 12(9), 662-6. 77. Sahasrabudhe, K.; Aube, J. The Family Approach to the Resolution of Racemates. 1999, 12(9), 672-4. 78. Walters, M. A. Chameleon Catches in Combinatorial Chemistry: Tebbe Olefination of Polymer Supported Esters and the Synthesis of Amines, Cyclohexanones, Enones, Methyl Ketones and Thiazoles. 1999, 12(9), 67983. 79. Pirrung, M. C. Novel RNA Synthesis Method using 5′-O-Silyl-2′-O-orthoester Protecting Groups. 1999, 12(9), 684-6. 80. Casiraghi, G.; Zanardi, F.; Appendino, G. Convergent Synthesis of the Amphotericin Polyol Subunit Employing Asymmetric Dienolate Addition Reactions. 1999, 12(9), 695-702.

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81. Asao, N.; Yamamoto, Y. Catalytic Carbon-Carbon Bond Activation of Unstrained Ketone by Soluble Transition-Metal Complex. 1999, 12(11), 808-12. 82. Keh, C. C. K.; Li, C.-J. Indium-Mediated Organometallic Reactions in Aqueous Media: The Nature of the Allylindium Intermediate. 1999, 12(11), 813-6. 83. Hoffman, R. V. Isolation and X-ray Structure of Chloroarenium Cations as Wheland Intermediates in Electrophilic Aromatic Chlorination. 1999, 12(11), 81721. 84. Poli, G.; Scolastico, C. New Modes of Regiocontrol in Palladium-Catalyzed Allylic Alkylations. 1999, 12(11), 822-36. 85. Poli, G.; Scolastico, C. Memory Effects in PdCatalyzed Allylic Alkylations. 1999, 12(11), 837-45. 86. Hoffman, R. V. Chemical and Spectroscopic Studies Related to the Lewis Acidity of Lithium Perchlorate in Diethyl Ether. 1999, 12(11), 846-9. Coordination Chemistry Reviews 87. Shapiro, P. J. The Syntheses, Structures, Bonding, and Reactivity of Cyclopentadienylaluminum(III) Derivatives. 1999, 189, 1-17. 88. du Mont, W. W.; Ruthe, F. Iodophosphonium Salt Structures: Homonuclear Cation-Anion Interactions Leading to Supramolecular Assemblies. 1999, 189, 10133. 89. Rawson, J. M.; McManus, G. D. Benzo-fused Dithiazolyl Radicals: From Chemical Curiosities to Materials Chemistry. 1999, 189, 135-68. 90. Andrews, P. C.; Hardie, M. J.; Raston, C. L. Supramolecular Assemblies of Globular Main Group Cage Species. 1999, 189, 169-98. 91. Wilson, L. J.; Cagle, D. W.; Thrash, T. P.; Kennel, S. J.; Mirzadeh, S.; Alford, J. M.; Ehrhardt, G. J. Metallofullerene Drug Design. 1999, 190-2, 199-207. 92. Nicolau, M.; Cabezo, B.; Torres, T. Triazolephthalocyanines: Synthesis, Supramolecular Organization and Physical Properties. 1999, 190-2, 231-43. 93. Trzeciak, A. M.; Ziolkowski, J. J. Perspectives of Rhodium Organometallic catalysis. Fundamental and Applied Aspects of Hydroformylation. 1999, 190-2, 883900. 94. Joynal Abedin, M.; Bergman, B.; Holmquist, R.; Smith, R.; Rosenberg, E.; Ciurash, J.; Hardcastle, K.; Roe, J.; Vazquez, V.; Roe, C.; Kabir, S.; Roy, B.; Alam, S.; Azam, K. A. Electron Deficient Bonding of Benzoheterocycles to Triosmium Clusters: Synthesis and Applications to Organic Chemistry. 1999, 190-2, 975-1002. 95. Chen, J. T. Addition Reactions of Mononuclear 3Allenyl/Propargyl Transition Metal Complexes: A New Class of Potent Organometallic Carbon Electrophiles. 1999, 190-2, 1143-68. 96. Antinolo, A.; Carrillo-Hermosilla, F.; Fajardo, M.; Fernandez-Baeza, J.; Garcia-Yuste, S.; Otero, A. Advances in the Chemistry of Bis-Cyclopentadienyl Hydride Derivatives of Niobium and Tantalum. 1999, 193-5, 4372. 97. Cuenca, T.; Royo, P. Transition Metal Complexes with Functionalized Silyl-Substituted Cyclopentadienyl and Related Ligands: Synthesis and Reactivity. 1999, 193-5, 447-98.

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98. Esteruelas, M. A.; Oro, L. A. Iridium and Rhodium Complexes with Tetrafluorobenzobarrelene Diolefins. 1999, 193-5, 557-618. Current Medicinal Chemistry 99. Ding, Q.; Chichak, K.; Lown, J. W. Pyrroloquinoline and Pyridoacridine Alkaloids from Marine Sources. 1999, 6(1), 1-27. 100. Pindur, U.; Kim, Y.-S.; Mehrabani, F. Advances in Indolo[2,3-a]carbazole Chemistry: Design and Synthesis of Protein Kinase C and Topoisomerase I Inhibitors. 1999, 6(1), 29-69. 101. Steinhilber, D. 5-Lipoxygenase: A Target for Antiinflammatory Drugs Revisited. 1999, 6(1), 71-85. 102. Elhalabi, J. M.; Rice, K. G. Synthesis and Applications for Unnatural Sugar Nucleotides. 1999, 6(2), 93-116. 103. Janczuk, A.; Li, J.; Zhang, W.; Chen, X.; Chen, Y.; Fang, J.; Wang, J.; Wang, P. G. R-Gal Oligosaccharides: Chemistry and Potential Biomedical Application. 1999, 6(2), 155-64. 104. Witczak, Z. J. Thio Sugars: Biological Relevance as Potential New Therapeutics. 1999, 6(2), 165-78. 105. Xia, Y.; Yang, Z.-Y.; Morris-Natschke, S. L.; Lee, K.-H. Recent Advances in the Discovery and Development of Quinolones and Analogs as Antitumor Agents. 1999, 6(3), 179-94. 106. Kidwai, M.; Sapra, P.; Bhushan, K. R. Synthetic Strategies and Medicinal Properties of β-Lactams. 1999, 6(3), 195-215. 107. Dax, S. L.; McNally, J. J.; Youngman, M. A. MultiComponent Methodologies in Solid-Phase Organic Synthesis. 1999, 6(3), 255-70. 108. Soriente, A.; De Rosa, M.; Scettri, A.; Sodano, G.; Terencio, M. C.; Paya, M.; Alcaraz, M. J. Manoalide. 1999, 6(5), 415-31. 109. Minakawa, N.; Matsuda, A. Mechanism-Based Design of Inosine 5′-Monophosphate Dehydrogenase Inhibitors: Synthesis and Biological Activities of 5-Ethynyl-1-β-D-Ribofuranosylimidazole-4-Carboxamide (EICAR) and Its Derivatives. 1999, 6(7), 615-28. 110. Seltzman, H. H. Structure and Receptor Activity for Classical Cannabinoids. 1999, 6(8), 685-704. 111. Huffman, J. W. Cannabimimetic Indoles, Pyrroles and Indenes. 1999, 6(8), 705-20. 112. Barth, F.; Rinaldi-Carmona, M. The Development of Cannabinoid Antagonists. 1999, 6(8), 745-55. 113. Gademann, K.; Hintermann, T.; Schreiber, J. V. β-Peptides: Twisting and Turning. 1999, 6(10), 905-25. 114. Ojima, I.; Lin, S.; Wang, T. Recent Advances in the Medicinal Chemistry of Taxoids with Novel β-Amino Acid Side Chains. 1999, 6(10), 927-54. 115. Abdel-Magid, A. F.; Cohen, J. H.; Maryanoff, C. A. Chemical Process Synthesis of β-Amino Acids and Esters. 1999, 6(10), 955-70. 116. Scarborough, R. M. Structure-Activity Relationships of β-Amino Acid-Containing Integrin Antagonists. 1999, 6(10), 971-81. 117. Juaristi, E.; Lopez-Ruiz, H. Recent Advances in the Enantioselective Synthesis of β-Amino Acids. 1999, 6(10), 983-1004. 118. Gozes, I.; Fridkin, M.; Hill, J. M.; Brenneman, D. E. Pharmaceutical VIP: Prospects and Problems. 1999, 6(11), 1019-34.

Recent Reviews

119. Bratoeff, E.; Ramirez, E.; Murillo, E.; Flores, G.; Cabeza, M. Steroidal Antiandrogens and 5R-Reductase Inhibitors. 1999, 6(12), 1107-23. 120. Dimmock, J. R.; Elias, D. W.; Beazely, M. A.; Kandepu, N. M. Bioactivities of Chalcones. 1999, 6(12), 1125-49. 121. Ablordeppey, S. Y.; Fan, P.; Ablordeppey, J. H.; Mardenborough, L. Systemic Antifungal Agents Against AIDS-Related Opportunistic Infections: Current Status and Emerging Drugs in Development. 1999, 6(12), 115195. 122. Gagliardi, S.; Rees, M.; Farina, C. Chemistry and Structure Activity Relationships of Bafilomycin A1, A Potent and Selective Inhibitor of the Vacuolar H+ATPase. 1999, 6(12), 1197-212. Current Organic Chemistry 123. Rose-Munch, F.; Rose, E. Application of (6-Arene) Chromium Tricarbonyl Complexes in Organic Synthesis: Nucleophilic Aromatic Substitution and Lithiation. 1999, 3(5), 445-67. 124. Banik, B. K. Tributyltin Hydride Induced Intramolecular Aryl Radical Cyclizations: Synthesis of Biologically Interesting Organic Compounds. 1999, 3(5), 469-96. 125. Kingsbury, C. L.; Mehrman, S. J.; Takacs, J. M. A Comprehensive Review of the Applications of Transition Metal-Catalyzed Reactions to Solid-Phase Synthesis. 1999, 3(5), 497-555. Enantiomer 126. Solladie-Cavallo, A. Effect of Countercations on Aggregation and Chiral Discrimination: Application to Highly Diastereo- and Enantioselective Syntheses. 1999, 4(3-4), 173-82. 127. Solladie, G. Applications of Chiral Sulfoxides in Enantioselective Synthesis of Diols and Total Synthesis of Natural Products. 1999, 4(3-4), 183-93. 128. Jager, V.; Ohrlein, R.; Wehner, V.; Poggendore, P.; Steuer, B.; Raczko, J.; Griesser, H.; Kiess, F.-M.; Menzel, A. Nitro Compounds. 7. The Nitro-Aldol Route Towards Nitro-, Amino-, and Imino-Polyols. Prerequisites for Efficient Addition with High Diastereoselectivity. 1999, 4(3-4), 205-28. European Journal of Organic Chemistry 129. Mitchell, R. H. The Metacyclophanediene-Dihydropyrene Photochromic π Switch. 1999(11), 2695-703. 130. Brown, R. F. C. Some Developments in the HighTemperature Gas-Phase Chemistry of Alkynes, Arynes, and Aryl Radicals. 1999(12), 3211-22. 131. Palomo, C.; Aizpurua, J. M.; Ganboa, I.; Oiarbide, M. Asymmetric Synthesis of β-Lactams by Staudinger Ketene-Imine Cycloaddition Reaction. 1999(12), 322335. Heteroatom Chemistry 132. Schmidpeter, A. Molecules that We Made: An Essay on Phosphorus Chemistry. 1999, 10(7), 529-37. Heterocycles 133. Fujii, T.; Itaya, T. Nx-Oxygenated Adenines: Their Chemistry, Physicochemical Properties, and Biological Activities. 1999, 51(8), 1971-2000.

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134. Fujii, T.; Itaya, T. Systematic Tables of Mono- and Poly-N-methylated Adenines: Acid Dissociation Constants and UV and NMR Spectral Data. 1999, 51(9), 2255-77. 135. Trofimov, B. A.; Mal’kina, A. G. Acetylene-based Functionalized Dihydrofuranones and Related Biomimetic Assemblies. 1999, 51(10), 2485-522. Journal of Combinatorial Chemistry 136. Hudson, D. Matrix Assisted Synthetic Transformations: A Mosaic of Diverse Contributions. II. The Pattern Is Completed. 1999, 1(6), 403-57. Journal of Heterocyclic Chemistry 137. Bavetsias, V. Heterocyclic Templates and Nonpolyglutamatable Inhibitors of Thymidylate Synthase as Potential Antitumor Agents: A Chemical Perspective. 1999, 36(4), 827-35. Natural Product Reports 138. Seto, H.; Kuzuyama, T.; Seto, H.; Kuzuyama, T. Bioactive Natural Products with Carbon-Phosphorus Bonds and Their Biosynthesis. 1999, 16(5), 589-96. 139. Fleming, F. F. Nitrile-Containing Natural Products. 1999, 16(5), 597-606. 140. Hanson, J. R. Steroids: Reactions and Partial Synthesis. 1999, 16(5), 607-17. 141. Rahman, A.-U.; Choudhary, M. I. Diterpenoid and Steroidal Alkaloids. 1999, 16(5), 619-35. Organic Preparations and Procedures International 142. Abele, E.; Lukevics, E. Reactions of Carbon Tetrachloride and Carbon Tetrabromide with Anions and Carbanions. A Review. 1999, 31(4), 359-77. 143. Lamberth, C. The Chemistry of 4′,5′-Unsaturated Nucleosides. A Review. 1999, 31(4), 379-97. Photochemistry 144. Horspool, W. M. Photolysis of Carbonyl Compounds. 1999, 30, 59-77. 145. Horspool, W. M. Enone Cycloadditions and Rearrangements: Photoreactions of Dienones and Quinones. 1999, 30, 78-118. 146. Horspool, W. M. Photochemistry of Alkenes, Alkynes and Related Compounds. 1999, 30, 119-48. 147. Cox, A. Photochemistry of Aromatic Compounds. 1999, 30, 149-87. 148. Cox, A. Photoreduction and -Oxidation. 1999, 30, 188-229. 149. Pratt, A. C. Photoreactions of Compounds Containing Heteroatoms other than Oxygen. 1999, 30, 23095. 150. Dunkin, I. R. Photoelimination. 1999, 30, 296328. Pure and Applied Chemistry 151. Michael, J. P.; De Koning, C. B.; Gravestock, D.; Hosken, G. D.; Howard, A. S.; Jungmann, C. M.; Krause, R. W. M.; Parsons, A. S.; Pelly, S. C.; Stanbury, T. V. Enaminones: Versatile Intermediates for Natural Product Synthesis. 1999, 71(6), 979-88.

152. Nicolaou, K. C.; Hepworth, D.; King, N. P.; Finlay, M. R. V. Chemistry, Biology and Medicine of Selected Tubulin Polymerizing Agents. 1999, 71(6), 989-97. 153. Dai, L.-X.; Lin, Y.-R.; Hou, X.-L.; Zhou, Y.-G. Stereoselective Reactions with Imines. 1999, 71(6), 103340. 154. Backvall, J.-E. Synthesis of Natural Products via Stereocontrolled Palladium-Catalyzed Reaction. 1999, 71(6), 1065-70. 155. Chorghade, M. S.; Gurjar, M. K.; Adhikari, S.; Sadalapure, K.; Lalitha, S. V. S.; Murugaiah, A. M. S.; Krishna, P. R. Synthesis of (2S, 5S)-Trans-5-[(4-fluorophenoxy)methyl]-2-[4-(N- hydroxyureido)-1-butynyl]tetrahydrofuran (CMI-977). 1999, 71(6), 1071-4. 156. Winterfeldt, E. Marine Natural Products - Synthetic Exercises and Biological Activity. 1999, 71(6), 1095-9. Russian Chemical Reviews 157. Prokof’ev, A. I. Radical Pairs in Redox Reactions Involving Sterically Hindered Quinones and Phenols. 1999, 68(9), 727-36. 158. Litvinov, V. P. Cyanoacetamides and Their Thioand Selenocarbonyl Analogues as Promising Reagents for Fine Organic Synthesis. 1999, 68(9), 737-63. 159. Kaberdin, R. V.; Potkin, V. I.; Zapol’skii, V. A. Synthesis and Reactions of Mixed Halogenobuta-1,3dienes. 1999, 68(9), 765-79. 160. Syromyatnikov, V. G.; Paskal’, L. P.; Savchenko, I. A. Aryl (Meth)Acrylates and Polymers Based on Them. 1999, 68(9), 781-99. 161. Kochervinskii, V. V. Ferroelectricity of Polymers Based on Vinylidene Fluoride. 1999, 68(10), 821-57. 162. Shevchenko, V. P.; Nagaev, I. Y.; Myasoedov, N. F. Methods for the Synthesis of Tritium-Labeled Fatty Acids and Their Derivatives, Oxylipins and Steroids. 1999, 68(10), 859-79. 163. Shumyantseva, V. V.; Bulko, T. V.; Archakov, A. I. Regulation of Cytochrome P450 Activity by Physicochemical Methods. 1999, 68(10), 881-87. 164. Karaulova, E. N.; Bagrii, E. I. Fullerenes: Functionalisation and Prospects for the Use of Derivatives. 1999, 68(11), 889-907. 165. Sadekov, I. D.; Zakharov, A. V. Stable Tellurols and Their Metal Derivatives. 1999, 68(11), 909-23. 166. Demin, V. A.; Shereshovets, V. V.; Monakov, J. B. Reactivity of Lignin and Problems of Its Oxidative Destruction with Peroxy Reagents. 1999, 68(11), 93756. 167. Usov, A. I. Alginic Acids and Alginates: Analytical Methods Used for Their Estimation and Characterisation of Composition and Primary Structure. 1999, 68(11), 957-66. 168. Dobrikov, M. I. Site-Specific Photosensitised Modification of Nucleic Acids with Biradical and Electrophilic Reagents. 1999, 68(11), 967-82. 169. Moiseev, I. K.; Makarova, N. V.; Zemtsova, M. N. Reactions of Adamantane in Electrophilic Media. 1999, 68(12), 1102-21. 170. Azatyan, V. V. Non-Isothermic Regimes of Branched Chain Processes and Their Chemical Control. 1999, 68(12), 1122-41. 171. Evtugyn, G. A.; Budnikov, H. C.; Nikolskaya, E. B. Biosensors for the Determination of Environmental Inhibitors of Enzymes. 1999, 68(12), 1142-67.

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172. Voronkov, M. G.; Deryagina, E. N. Thermal Transformations of Organic Compounds of Divalent Sulfur. 2000, 69(1), 90-104. Russian Journal of Organic Chemistry 173. Koval, I. V. N-Halo Reagents. Preparation of Chlorosulfonamide Sodium Salts and Their Application to Organic Synthesis. 1999, 35(4), 475-99. 174. Kas’yan, L. I. Steric Strain and Reactivity of Epoxynorbornanes (3- Oxatricyclo[3.2.1.02, 4]octanes). 1999, 35(5), 635-65. 175. Savelova, V. A.; Popov, A. F. Nucleophilic Reactions of Imidoyl Halides. Kinetics, Reactivity, Mechanisms. 1999, 35(6), 797-828. Synlett 176. Coxon, J. M.; Froese, R. D. J.; Ganguly, B.; Marchand, A. P.; Morokuma, K. On the Origins of Diastereofacial Selectivity in Diels-Alder Cycloadditions. 1999, (11), 1681-703. 177. Lo Sterzo, C. The Wonder of Palladium Catalysis. From Carbon-Carbon to Metal-Carbon Bond Formation. An Opportunity of Getting Astonishment from Reality. 1999, (11), 1704-22. 178. Vollmer, H. R. (4-Tolylsulfonyl)hydrazones. 1999, (11), 1844. 179. Kodokawa, J.; Tagaya, H.; Chiba, K. Novel Approaches to Glycopolymer Syntheses from the Viewpoint of Polymerization Chemistry. 1999, (12), 1845-56. 180. Paquette, L. A.; O’Neil, S. V.; Guillo, N.; Zeng, Q.; Young, D. G. The Need for an Incisive Analysis of the Regioselectivity Associated with the Deprotonation of R-Alkoxy and R-Acyloxy Ketones. 1999, (12), 185766. 181. Hasserodt, J. Organic Synthesis Supported by Antibody Catalysis. 1999, (12), 2007-22. 182. Longbottom, D. Scandium Triflate. 1999, (12), 2023. Synthesis-Stuttgart 183. Ziessel, R. Making New Supermolecules for the Next Century. Multipurpose Reagents from EthynylGrafted Oligopyridines. 1999, (11), 1839-65. 184. Ferraz, H. M. C.; Silva, L. F., Jr.; Vieira, T. D. O. Thallium(III) in Organic Synthesis. 1999, (12), 200123.

Tetrahedron 185. Andrews, M. J. I.; Tabor, A. B. Forming Stable Helical Peptides Using Natural and Artificial Amino Acids. 1999, 55(40), 11711-43. 186. Zhou, W.-S.; Lu, Z.-H.; Xu, Y.-M.; Liao, L.-X.; Wang, Z.-M. Synthesis of Optically Active R-Furfurylamine Derivatives and Application to the Asymmetric Syntheses. 1999, 55(41), 11959-83. 187. Fields, S. C. Synthesis of Natural Products Containing a C-P Bond. 1999, 55(42), 12237-73. 188. Taylor, S. D.; Kotoris, C. C.; Hum, G. Recent Advances in Electrophilic Fluorination. 1999, 55(43), 12431-77. 189. Sen, S. E.; Smith, S. M.; Sullivan, K. A. Organic Transformations using Zeolites and Zeotype Materials. 1999, 55(44), 12657-98. 190. Eymery, F.; Iorga, B.; Savignac, P. Synthesis of Phosphonates by Nucleophilic Substitution at Phosphorus: The SN P(V) Reaction. 1999, 55(46), 13109-50. Tetrahedron: Asymmetry 191. Arsequell, G.; Valencia, G. Recent Advances in the Synthesis of Complex N-Glycopeptides. 1999, 10(16), 3045-94. Topics in Organometallic Chemistry 192. Molander, G. A.; Dowdy, E. D. Lanthanide- and Group 3 Metallocene Catalysis in Small Molecule Synthesis. 1999, 2(Lanthanides), 119-54. 193. Shibasaki, M.; Groger, H. Chiral Heterobimetallic Lanthanoid Complexes: Highly Efficient Multifunctional Catalysts for the Asymmetric Formation of CC, CO, and CP bonds. 1999, 2(Lanthanides), 199-232. 194. Hou, Z.; Wakatsuki, Y. Reactions of Ketones with Low-Valent Lanthanides: Isolation and Reactivity of Lanthanide Ketyl and Ketone Dianion Complexes. 1999, 2(Lanthanides), 233-53. 195. Hidai, M.; Mizobe, Y. Activation of the NN triple Bond in Molecular Nitrogen: Toward Its Chemical Transformation into Organo-Nitrogen Compounds. 1999, 3(Activation of Unreactive Bonds and Organic Synthesis), 227-41. 196. Richmond, T. G. Metal Reagents for Activation and Functionalization of Carbon-Fluorine Bonds. 1999, 3(Activation of Unreactive Bonds and Organic Synthesis), 243-69.

Contributed Volumes Advances in Molecular Structure Research. Volume 5. Hargittai, M., Hargittai, I., Eds. JAI: Stamford, Connecticut, 1999. 197. Charton, M. The Quantification of Structural Effects in Stereochemistry by Correlation Analysis. 198. Glaser, R.; Shiftan, D. The Stereochemistry and Interconversion of Nine-Membered Rings Containing one Strong Torsional Constraint. 199. Chesnut, D. B.; Quin, L. D. The Theoretical Determination of Phosphorus NMR Chemical Shielding.

Rodd’s Chemistry of Carbon Compounds, 2nd ed. Volume 4. Part F/Part G (partial). Sainsbury, M., Ed. Elsevier: Amsterdam, The Netherlands, 1998. 200. Plunkett, O.; Sainsbury, M. Pyridine and Piperidine Alkaloids. 201. Michael, J. P. The Quinoline Alkaloids. 202. Michael, J. P. The Acridine Alkaloids. 203. Bentley, K. W. The Isoquinoline Alkaloids.

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Monographs 204. Abraham, M. A., Hesketh, R. B., Eds. Reaction Engineering for Pollution Prevention. Elsevier: Amsterdam, The Netherlands, 2000. 205. Barcelo, D., Giro, J., Eds. Sample Handling and Trace Analysis of Pollutants: Techniques, Applications and Quality Assurance. Elsevier: Amsterdam, The Netherlands, 1999. 206. Brook, M. A. Silicon in Organic, Organometallic, and Polymer Chemistry. Wiley-Interscience: New York, 1999. 207. Brown, D. J. Pyridazines, Supplement 1. WileyInterscience: New York, 1999. 208. Claridge, T. High-Resolution NMR Techniques in Organic Chemistry. Elsevier Science: Amsterdam, The Netherlands, 1999. 209. Cornils, B., Hermann, W. A., Eds. Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Two Volumes. Wiley: New York, 2000. 210. Davies, G., Ghabbour, E. A., Eds. Understanding Humic Substances. The Royal Society of Chemistry: Cambridge, U.K., 1999. 211. Diederichsen, U., Lindhorst, T. K., Westermann, B., Eds. New Aspects in Bioorganic Chemistry. Wiley: New York, 1999. 212. Durig, J. R., Ed. Vibrational Spectra and Structure - Equilibrium Structural Parameters. Vol. 24. Elsevier Science: Amsterdam, The Netherlands, 1999. 213. Ehrat, M., Townshend, A., Eds. Reviews on Analytical Chemistry - Euroanalysis 10. Elsevier Science: Amsterdam, The Netherlands, 1999. 214. Gawronski, J.; Gawronska, K. Tartaric and Malic Acids in Synthesis: A Source Book of Building Blocks, Ligands, Auxiliaries, and Resolving Agents. Wiley-Interscience: New York, 1999. 215. Gru¨nanger, P.; Vita-Finzi, P. Isoxazoles. Vol. 49(2). Wiley-Interscience: New York, 1999.

216. Ho, T.-L. Stereoselectivity in Synthesis. WileyInterscience: New York, 1999. 217. Ju¨ng, G., Ed. Combinatorial Chemistry. Wiley: New York, 2000. 218. Kastner, M., Ed. Protein Liquid Chromatography. Elsevier Science: Amsterdam, The Netherlands, 1999. 219. Larock, R. C. Comprehensive Organic Transformations: A Guide to Functional Group Preparations, 2nd ed. Wiley-VCH: New York, 1999. 220. Lightner, D. A.; Gurst, J., E. Organic Conformational Analysis and Stereochemistry from Circular Dichroism. Wiley-VCH: New York, 2000. 221. Quevauviller, P., Ed. Special Issue: Metrology in Chemistry. [In TrAC, Trends Anal. Chem. 1999; 18(9 + 10)]. Elsevier: Amsterdam, The Netherlands, 1999. 222. Quin, L. A Guide to Organophosphorus Chemistry. Wiley: New York, 2000. 223. Ru¨ck-Braun, K.; Kunz, H. Chiral Auxiliaries in Cycloadditions. Wiley: New York, 1999. 224. Suzuki, H.; Ogawa, T.; Matano, Y.; Murafuji, T.; Ikegami, T.; Komatsu, N. Organobismuth Chemistry. Elsevier: Amsterdam, The Netherlands, 2000. 225. Toshiaki, K.; Atsushi, I.; Weihau, Q. Hydrodesulfurization and Hydrodenitrogenation: Chemistry and Engineering. Wiley: New York, 2000. 226. Volman, D. H., Hammond, G. S., Gollnick, K., Eds. Advances in Photochemistry. Vol. 24. Wiley-Interscience: New York, 1998. 227. Volman, D. H., Hammond, G. S., Gollnick, K., Eds. Advances in Photochemistry. Vol. 25. Wiley-Interscience: New York, 1999. 228. Ward, R. S. Selectivity in Organic Synthesis. Wiley: New York, 1999. 229. Wuts, P. G. M.; Greene, T. W. Protective Groups in Organic Synthesis. 3rd ed. John Wiley & Sons: New York, 1999.

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Index Acosamine stereoselective addition, 128 Adamantanes, reactions, 169 Adenines, methyl spectroscopy, 134 methyl, acid-dissociation constants, 134 oxygenated, chemical properties, 133 Adipic acid, synthesis, 26 AIDS infections, fungicides, 121 Alginates, 167 Alginic acids, 167 Alkaloids, acridine, 202 enaminones, synthesis, 151 indolocarbazole, 100 isoquinoline, book, 203 marine, pyridoacridine, 99 marine, pyrroloquinoline, 99 piperidine, book, 200 pyridine, book, 200 quinoline, 201 Alkenes, polymerization, 28 hydroformylation, 93 photochemical rearrangement, 146 Alkoxyhalocarbenes, fragmentation, 4 Alkylation, allylic, regioselective, 84 allylic, memory effect, 85 allylic, Pd catalyzed, 85 Alkynes, addition, 56 photochemical rearrangement, 146 reactions at high temp, 130 Allylic alkylation, palladium catalyst, 84 Allylindium intermediate, 82 Amides, in solid-phase synthesis, 63 Amines, combinatorial synthesis, 78 furfuryl, optically active, 186 homoallylic, preparation, 47 Amino acids, β-, enantioselective synthesis, 117 β-, large scale synthesis, 115 homochirality, evolution, 19 resolution, large scale, 115 taxoid containing, 114 Aminodiphenylamine, synthesis, 26 Aminotrideoxyhexose preparation, 128 Amphotericin preparation, 80 Analgesics, manoalide, 108 Analysis, trace, book, 205 Antiandrogens, 119 Antibiotics, bafilomycin A1, 122 glycopeptide, 37 quinolones, 105 Antibodies, in organic synthesis, 181 Anticancer agents, indolocarbazoles, 100 Antifungal agents, AIDS-related infections, 121 Anti-inflammatory agents, 111 lipoxygenases, 101 manoalide, 108 nonsteroidal, 21 Antimicrobial agents, chalcones, 120 Antithrombotic agents, 116 Antitumor agents, 109, 137 antibiotics, anisomycin, 128 chalcones, 120 quinolone antibiotics, 105 taxoid, 114 Antiviral agents, 109 Aromatics, chlorination, 83 dihydroxylation, enantioselective, 18 isomerization, photochemical, 147 rearrangement, photochemical, 147 Aryl radicals, at high temperature, 130 intramolecular cyclization, 124

Arylation, catalyzed, 75 Arynes, reactions at high temperature, 130 Aspirin analogs, 69 Asymmetric catalysis, 32 Azaheterocycles, 16 Azines, 16 Benzimidazole, triosmium cluster, 94 Benzofurans, 10 Benzoheterocycles, osmium clusters, 94 Benzopyridopyrimidines, 13 Benzoquinoline, triosmium cluster, 94 Benzothiazole, triosmium cluster, 94 Benzotriazole, triosmium cluster, 94 Biomimetics, carbohydrate recognition, 48 Bioorganic chemistry, book, 211 Biosensors, book, 205 enzyme inhibitors, 171 Biphenols, chlorinated, analysis, book, 205 Branching-chain reaction, 170 Cannabimimetic indenes, 111 Cannabimimetic indoles, 111 Cannabimimetic pyrroles, 111 Cannabinoid antagonists, 112 Cannabinoids, 111 receptors, 110 Carbene transfer, between transition metals, 59 Carbenes, stable, 1 Carbocycles, from glycosides, 23 Carbohydrates, 63 mimetics, 40 recognition, 48 thio, drugs, 104 Carbon electrophiles, allenyl complexes, 95 propargyl complexes, 95 Carbon monosulfide, 9 Carbon tetrabromide, reaction with anions, 142 reaction with carbanions, 142 Carbon tetrachloride, reaction with anions, 142 reaction with carbanions, 142 Carbon-carbon bond, metal insertion, 24 Carbon-fluorine bonds, activation, 196 Carbon-phosphorus bonds, 138 asymmetric, 193 Carbonyl group, interaction with substituents, 2 Carbonyls, photolysis, 144 Carboranes, 90 Carboxylic esters, analogs, reaction with nuclephiles, 57 thio analogs, 57 Catalysis, homogeneous, book, 209 Catalysts, reduction, ruthenium, 70 antibodies, 181 asymmetric phase transfer, 34 heterobimetallic lanthanoids, 193 palladium, 39, 84, 154, 177, phosphapalladacycles, 75 reduction, diamine, 70 reduction, phosphane, 70 rhodium, 93 rhodium, hydroformylation, book, 204 scandium triflate, 182 tributyltin hydride, aryl cyclization, 124 zeolites, 189 C-H activation, coupling reactions, 35

Recent Reviews Chemometrics, book, 213 Chiral molecules, stereochemistry, book, 220 Chirality, book, 216 Chloroarenium cations, 83 Chlorosulfonamide sodium salts, 173 Circular dichroism, book, 220 Clathrates, 27 Combinatorial chemistry, 63, 78, 107, 136 book, 213, 217 Combinatorial libraries, insect polyamines, 76 Combinatorial resolution, racemates, 77 Combinatorial synthesis, acyanoacetamides, 158 Combustion, chain thermal explosion, 170 Computational chemistry, book, 212 Correlation analysis, book, 197 Countercation effect, aggregation, 126 Coupling reactions, transition metal catalyst, 35 Cross-coupling reactions, alkyl-alkyl, 50 Cyanoacetamides, 158 Cyanoselenoacetamides, 158 Cyanothioacetimides, 158 Cyclization, catalyzed, 75 Cycloadditions, chiral auxiliaries, book, 223 intramolecular, 61 Cyclooxygenase inhibitors, 21 aspirin analogs, 69 Cyclopentadienyl complexes, 87 Cyclynes, ortho-arene, 53 Cytochrome P450, 73, 163 Cytotoxic agents, 109 Dendrimers, 25 Diamine, chiral, reduction catalysts, 70 Diarylpyrazoles, cannabinoid antagoists, 112 Diels-Alder cycloaddition, diastereofacial selectivity, 176 Dienes, photochemical rearrangement, 146 Dienolate addition, asymmetric, 80 Dienones, 145 Dihydrofuranones, acetylene based, 135 Dihydropyridinethione preparation, 65 Dihydropyridinones, preparation, 65 Diols, enantioselective synthesis, 127 Diradicals, localized triplets, book, 226 Dithiazoles, benzo-fused, 89 Drug design, carbohydrate mimetics, 40 thio sugar, 104 VIP-based, 118 Drug development, isotope indicators, 7 Dysidiolide, synthesis, 71 Electrochemistry, oxidation, 8 reduction, 8 Electrocyclization, unsaturated dipoles, 11 Electron diffraction technique, book, 212 Electrophoresis, book, 213 Enamines, enantiomeric, reduction, 115 Enaminones, synthesis, 151 Enantiomers, book, 216 identification, book, 220 Enantioselective synthesis, 126 with palladium, 39 Environmentally friendly synthesis, 26 Enzyme inhibitors, biosensors, 171 Enzymes, dihydroxylation of aromatics, 18 Epoxynorbornanes, steric strain, 174

Recent Reviews Esters, large scale synthesis, 115 polymer supported, olefination, 78 Ethers, diaryl, preparation, 42 Fatty acids, labelled, 162 Ferritin, characterisation, book, 213 Fluorination, electrophilic, 188 Fullerenes, 164 gaseous ions, 52 Functional groups, book, 219 Furanones, 14 Furanosides, conversion into carbocycles, 23 Furfuryl amines, R-, 186 Glycopeptides, antibiotics, 37 synthesis, 191 Glycopolymers, synthesis, 179 Glycosyltriflates, 74 Glycosyltransferases, 102 Halogenobuta-1,3-dienes, 159 Hemoproteins, catalysts, 163 Heteroatoms, non oxygen, photochemistry, 149 Heterocycles, 15 benzo, osmium cluster, 94 dithiazoles, 89, 91 nine membered rings, interconversion, 198 organobismuth, book, 224 pyridazines, book, 207 ring transformations, 16 Heterocyclynes, ortho-arene, 53 Humic acids, book, 210 Hydrodenintrogenation, book, 225 Hydrodesulfurization, book, 225 Hydroformulation, tandem reactions, 55 with rhodium, book, 204 transition metal catalysis, 55 Imidazolylidenes, 1 Imidoyl halides, nucleophilic reactions, 175 Imines, aminoalkylation, 47 metal enolate addition, 115 stereoselective aldol reaction, 153 stereoselective allylation, 153 stereoselective aziridination, 153 Iminodihydrofuran preparation, 135 Iminopolyols, stereoselective addition, 128 Insecticides, chalcones, 120 Integrins, antagonists, 116 Isoflavone, heteroanalogs, 64 hetarylchromone analogs, 64 Isoquinoline alkaloids, book, 203 Isoserines, 114 Isoxazoles, heterocyclic chemistry, book, 215 Ketene-imine cycloaddition, 131 Ketones, alcyloxy, deprotonation, 180 alkoxy, deprotonation, 180 C-C bond activation, 81 enamino, synthesis, 151 methyl, combinatorial synthesis, 78 reduction, 70 lanthanide complex, 194 Lactams, β-, 106 asymmetric synthesis, 131 Lanthanides, metallocenes, 192 Lanthanoids, heterobimetallic complexes, 193 Leukotrienes, biosynthesis, 101 Lewis acids, lithium perchlorate, 86 Lignin, oxidation, 166 Macrolides, antibiotics, 122 Malic acid, in synthesis, book, 214 Mannich base preparation, 47

J. Org. Chem., Vol. 65, No. 7, 2000 2275 Mannopyranosides, from glycosyl triflates, 74 from thioglycoside, 74 Manoalide, 108 Metacyclophanedienes, to hydropyrene, 129 Metallocenes, bent, coordination stabilization, 58 group 3, 192 heterogenization, 28 lanthanide, 192 Metallofullerenes, lanthanides, radiotracers, 91 Methacrylates, 160 Methyl group, rotation barrier, 6 Metrology, book, 221 Michael addition, large scale, 115 Molecular hosts, spherical, 27 Molecular recognition, 34 carbohydrates, 40 Monoradicals, benzyl-type, book, 226 Mutagens, chalcones, 120 Natural products, ephalostatin, 156 from enaminones, 151 library, 36 marine, 156 nitrile containing, 139 organobromine, 60 phosphorus, biosynthesis, 138 polymer supported, 36 ritterazine, 156 synthesis, with palladium, 154 synthesis, with sulfoxides, 127 tocopherol, 46 with carbon-phosphorus bond, 187 Niobocene hydrides, 96 Nitroaldol reaction, hexose preparation, 128 Nitrobenzenes, reaction with alkoxides, 3 reaction with nucleophiles, 3 Nitrogen, triple bond transformation, 195 Nitropolyol sugars, amino, 128 imino, 128 NMR, high resolution, book, 208 Nuclear overhauser effect, book, 208 Nucleic acid, photomodification, 168 Nucleosides, unsaturated, preparation, 143 Nucleotides, unnatural sugar, 102 Nuclides, radiolabeled, 7 Olefins, hydroformylation, 93 polymerization, 28 Oligomers, linear monodisperse conjugated, 29 Oligopyridines, 183 Oligosaccharides, galactose, 103 unnatural, 102 Organobismuth compounds, book, 224 Organobromine compounds, natural, 60 Organochromium complexes, arenes, 123 tricarbonyl, 123 Organoiridium, diolefin complexes, 98 Organometallic catalysis, interphase chemistry, 38 Organometallic chemistry, 62 Organonitrogen compounds, 195 Organophosphorus compounds, 132 book, 222 NMR, 199 Organorhodium catalysts, 93 Organorhodium, diolefin complexes, 98 Organosilicon compounds, book, 206 Organosulfur reagents, divalent, thermal reactions, 172

Oxazolopyridinones, preparation, 66 Oxylipins, labelled, 162 Palladium catalysts, metal-carbon bonds, 177 Peptides, β, syntheis, 113 helical, 185 Peptidomimetics, 113 Phenols, redox reactions with quinones, 157 trace analysis, book, 205 Phenoxyacetic acid derivatives, conformation, 51 Phosphanes, chiral, reduction catalysts, 70 Phospholipase, active site, 43 Phospholipids, labelled, 162 Phosphonate preparation, 190 Photoaffinity labeling, oxidosqualene cyclases, 68 squalene cyclases, 68 Photochemistry, alkenes, 146 alkynes, 146 aromatics, 147 book, 226-7 elimination, 150 non oxygen heteroatoms, 149 oxidation, 148 phenol radicals, 157 quinones, 145, 157 reduction, 148 Photochromic switch, 129 Photoelimination, 150 Photolysis, carbonyl compounds, 144 Polyamines, from insects, 76 Polyarylmethacrylates, 160 Polycyclic aromatics, preparation, 130 Polymerization, alkenes, 28 Polymers, glycogen, 179 Polysaccharides, alginates, 167 Polyvinylidene fluoride, 161 Progesterone derivatives, 119 Progestogens, 119 Protecting groups, book, 229 RNA synthesis, 79 Proteins, liquid chromatography, book, 218 proteome analysis, 44 redox reactions, 73 Proteome analysis, proteins, 44 Protozoacides, chalcones, 120 Pyranosides, conversion into carbocycles, 23 Pyridazines, book, 207 Pyridines, ethynyl grafted oligomeric, 183 organometallic compounds, 67 with heteroatoms, 67 Pyridopyrimidines, benzologs, 13 Pyrimidines, pyrido, 13 Pyrroles, hydroxymethyl, 72 Quinodimethanes, intermediates, 54 Quinones, dienones, 145 redox reactions with phenols, 157 Quinoxaline, triosmium cluster, 94 Racemates, resolution, 77 Radionuclides, 7 Resin linkers, 78 Resolving agent, 77 RNA, 33 folding, 41 structure, 41 synthesis, protecting groups, 79 Sarcodictyin, 152 Selectivity, book, 228

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Sensors, book, 213 Serine, catalytic triad, 43 Sesterterpene, manaolide, 108 Sialic acid glycoconjugates, 30 Sialyltransferase inhibitors, 30 Silylcyclopentadiene transition metal complex, 97 Solid-phase synthesis, 63, 107, 136 backbone amide linker, 63 metal catalyzed, 125 Solid-state chemistry, 78 Solvents, supercritical water, 49 Sphingolipids, labelled, 162 metabolic pathways, 31 Stereochemistry, structural effects quantification, 197 Stereoselectivity, book, 216 Steroids, diterpenoid, 141 labelled, 162 partial synthesis, 140 reactions, 140 Sulfinimines, metal enolate addition, 115

Sulfoxides, chiral, 127 Supramolecules, carbohydrate recognition, 48 from iodophosphonium salts, 88 globular main group cage, 90 molecular design, 5 oligopyridines, 183 triazolophthalocyanine, 92 Tandem reactions, hydroformulation, 55 Tantalocene hydrides, 96 Tartaric acid, in synthesis, book, 214 Taxanes, 114 Taxol, 152 Tellurols, 165 Terphenyl ligands, 17 Tetrafluorobenzobarrelene, iridium complexes, 98 rhodium complexes, 98 Tetrahydrofuran, enantiomers, 155 fluorophenoxymethyl hydroxyureidobutynyl, 155 Thallium, oxidant, 184 Thiazoles, combinatorial synthesis, 78

Recent Reviews Thioglycosides, 74 Thymidylate synthase inhibitor, 137 Tolylsulfonylhydrazones, 178 Toxic organics, treatment, book, 204 Triazoles, phthalocyanine, 92 Triazolophthalocyanine, preparation, 92 Triazolopyrimidines, 12 Trienes, photochemical rearrangement, 146 Triflides, simpler preparation, 62 Tuberculostatic isoniazid, 45 Tubulin polymerizing agents, 152 Valence bond theory, reactivity, 20 Vancomycin synthesis, 22 Vancomycin, 37 Vasoactive intestinal peptide, 118 Vibrational spectroscopy, book, 212 Vinylation, catalyzed, 75 Wheland intermediate, 83 Zeolites, 189 JO004001L