APPLICATIONS Stereospecific Polyolefin Catalysts: Intermediates in the manufacture of catalysts for the production of polypropylene, polyethylene, polybutadiene, polyisoprene and other olefin polymers. Straight-chain Alcohols and Alpha Olefins: Intermediates for making primary straight-chain compounds. Pyrophoric Fuels: Efficient self-igniting fuels gaining acceptance for use in rockets and missiles. Gas Plating of Aluminum: As a source of aluminum in a versatile new chemical vapor deposition process for making aluminum coatings on a variety of materials.
ROUND-UP OF FACTS ABOUT ALUMINUM ALKYLS
Chemical Intermediates: These versatile new metal-organics present interesting possibilities for use in growth reactions, olefin displacement, oxidation and hydrolysis, formation of complex salts, as alkylation agents and reducing agents. n U I Y l U L U u D — T h e r e are various homologs of the commercial and development Aluminum Alkyls that can be prepared in research quantities upon special request. Inquiries for specific Aluminum Alkyls are welcome for discussion on availability, purity and price.
• M i l H I X—Special safety and handling techniques have been developed to minimize hazards involved in the use of Aluminum Alkyls. TEXAS ALKYLS, INC. is pleased to offer technical and engineering consultation at the customer's request and to make appointments for you to see our facilities.
LITERATURE-A
new 150-page Data Book "Aluminum Alkyls, Specifications, Physical Properties and Analytical Procedures" has been published by TEXAS ALKYLS, INC. The coupon below facilitates your request for valuable information in publications or for the use of 30-minute safety film.
TEXAS ALKYLS, INC.
PASADENA, TEXAS
Please send me:
(Name)
U Brochure: "Organoaluminum Products: Glamor Petrochemicals"
(Company)
•
Brochure: "Safety and Handling: Aluminum Alkyls" (Street)
U Data Book: 150 pages, described above. •
(Title)
Safety Film: We are interested in a showing about (date)
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These Compounds Available for Immediate Shipment in Commercial Quantities ALUMINUM ALKYL
T f Al
Tri thylaluminum
TNPRAL
Tri-n-propylaluminuw
TNBAL
ri-n-butylafuminum r s
u
a um num
T I B A L ^ '' °^ *y' ' ' I M I W I II |}I||I\I-H
D'>s°butylaluminumhydride
ISOPRENYL
,s
r n ,a ym
°P e y ' 'nu'«
|1
FORMULA
1 11
11
(C2Hs)3 Al
1
(n-C3H7)3 Al
1
11
1
(n-C4H9)3 Al
11
I1
(iso-C4H9)3 Al
11
1 11
(i$o-C4H9)2 Al H
11
Unknown
1
FORMULA WT.
1 1 STATE & APPEARANCE | I | AT25°C J1
DENSITY 1 1 FREEZING 1 GR./ML 1 | PT..°C J
H4J66
1
Clear Liquid
—52.5
1
156.238
1 1
Clear to Yellowish Liquid
1 1 1 0.8272*
—107
1
198.328
1 1
Clear to Yellowish Liquid
1 1
0.8232(>
—26.7
1
4
1
0.827"
I
198,328
1
Clear Liquid
1
0.78592*
142.21
1 1
Clear to Grayish Liquid
1 1
0.7752*
—80
1
1 1
Clear to Bright Yellow Liquid
1 1
0.81023
—26.3
1
1
r A n r
Monoethylaluminumdichloride
11
(C2H5) Al Cl2
1
126.96
1
Clear Liquid
1
1.23225
22
1
QtAC
Oiethylaluminumchloride
11
(C2H0)2 Al CI
1
120.56
I
Clear Liquid
1
0.95825
—74
1
247.52
1 1
Clear to Yellowish Liquid
1 1
1.09225
1
—20
1
1
—29.8
1
0.9088 > 1
—39.5
1
FASC
Ethylafuminumsesquichloride a,um numcjich,oricie
MONIBAC DIBA C
'
Diisobut ,a,uminijmch,oride
y
(C2H5)3 AI2CI3
j
11 11
(1SO-C4H9) Al CI2 (iso-C4H9) Al CI
1 1 1
155.00
11
176.66
1 1
20
Clear Liquid
1
1.1218
Clear to Yellowish Liquid
1 1
2,
1 The Following Compounds Are Available in Development Quantities TNHEXYL
Tri-n-hexylaluminum
TRIISOHEXYL 5 2 M 2 L TNOCTYL TNDECYL Mf\SC Q[f\B QEAF
DLAI
Tri-n-octylaluminum T
"'»*"-decylaluminum
Methylaluminumsesquichloride Diethylaluminumbromide Diethylaluminumfluoride
^'e^y'a^moc''^e
11 1
11 11
1
(n-C6Hi3)3 Al (iS0-C6Hl3)3 A l
(n-CsHnhAI (n-CioH2i)3 Al
1
1 1
282.47
1
Colorless Liquid
11
0.82623
-77.3
1
282.47
I I
Clear to Yellowish Liquid
1 11
0.78922
—°°
1
366.63
I 1
Clear to Yellowish Liquid
1 11
0.825«-8
—66.0
I
450.77
1 1
Clear to Yellowish Liquid
1 ] 1 0.82537-8
-38.3
1
1 I
Clear Viscous Liquid
1 11
1.1629
22.8
1
25
11
(CH3)3 AI2CI3
1
205.43
11
(C2H5)2 Al Br
1
165.02
1
Clear Liquid
11
0.7558
—94.5
1
104.10
1 1
Clear-Extremely Viscous Liquid
1 11
0.7691*
—97.8*
I
11
11
(C 2 H 5 ) 2 AIF
(C2H5)2 Al I
1
J1
212.02
J1
Clear Liquid
1[
1.6091
J
569
1 ^- J
s 50fo Bolution in n hcpta
•
^iSB
TFMAIKYIS INC. Exclusive Sales A g e n t
STAUFFER CHEMICAL COMPANY ANDERSON CHEMICAL D I V I S I O N — W E S T O N , M I C H I G A N OFFICES: P.O. Box 9 8 8 — P a s a d e n a , Texas 3 8 0 M a d i s o n A v e . , N e w York 17, N.Y. 5 0 0 S. V i r g i l A v e . , Los Angeles 5 , Col.
Statements concerning the possible use of these products are not intended as recommendations to use them in the infringement of any patent. Certain of these uses involve processes which arc covered by patents and pending applications of Karl Ziegler of Muelheim. Germany; purchase of these materials does not include the right to practice under such patents or patent applications.
