Rubber-Modified Thermoset Resins, Copyright, Advances in

Downloaded by UNIV OF GUELPH LIBRARY on February 3, 2015 | http://pubs.acs.org Publication Date: December 5, 1984 | doi: 10.1021/ba-1984-0208.fw001

Rubber-Modified Thermoset Resins

In Rubber-Modified Thermoset Resins; Riew, C., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1984.



ADVANCES IN CHEMISTRY SERIES 208


Rubber-Modified Thermoset Resins C.

Keith

Riew,

EDITOR

The BFGoodrich Company John K. Gillham, EDITOR

Princeton University

Based on a symposium sponsored by the Division of Polymeric Materials Science and Engineering at the 186th Meeting of the American Chemical Society, Washington, D.C., August 28-September 2, 1983

American Chemical Society, Washington, D.C. 1984



Library of Congress Cataloging in Publication Data Rubber-modified thermoset resins. (Advances in chemistry series, ISSN 0065-2393; 208) Bibliography: p. Includes indexes. 1. Thermosetting plastics—Additives—Congresses. 2. Rubber—Congresses. I. Riew, C. Keith. II. Gillham, John K. III. American Chemical Society. Division of Polymeric Materials Science and Engineering. IV. American Chemical Society. Meeting (186th: 1983: Washington, D.C.) V. Series. QD1.A355 no. 208 540 s [668.4'22] 84-21566 [TP1180.T55] ISBN 0-8412-0828-X

Copyright ©1984 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per copy fee through the Copyright Clearance Center, Inc., 21 Confess Street, Salem, MA 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means— graphic or electronic—for any other purpose, such as for general distribution, for advertis ing or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specifica tion, chemical process, or other data be regarded as a license or as a conveyance of any right or permission, to the holder, reader, or any other person or corporation, to manufac ture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law.


Advances in Chemistry Series M. Joan Comstock,

Series Editor


Advisory Board Robert Baker

Geoffrey D.Parfitt

U.S. Geological Survey

Carnegie-Mellon University

Martin L. Gorbaty

Theodore Provder

Exxon Research and Engineering Co.

Glidden Coatings and Resins

Herbert D. Kaesz

James C. Randall

University of California—Los Angeles

Rudolph J. Marcus

Phillips Petroleum Company

Charles N. Satterfield

Office of Naval Research

Massachusetts Institute of Technology

Marvin Margoshes

Dennis Schuetzle

Technicon Instruments Corporation

Donald E. Moreland USDA, Agricultural Research Service

W. H. Norton J. T. Baker Chemical Company

Robert Ory

USDA, Southern Regional Research Center

Ford Motor Company Research Laboratory

Davis L. Temple, Jr. Mead Johnson

Charles S. Tuesday General Motors Research Laboratory

C. Grant Willson IBM Research Department



FOREWORD A D V A N C E S I N C H E M I S T R Y S E R I E S was

founded in 1 9 4 9 by

the

American Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would otherwise be fragmented, their papers distributed among several journals or not pub lished at all. Papers are reviewed critically according to A C S editorial standards and receive the careful attention and pro cessing characteristic of A C S publications. Volumes in the A D V A N C E S I N C H E M I S T R Y S E R I E S maintain the integrity of the

symposia on which they are based; however, verbatim repro ductions of previously published papers are not accepted. Papers may include reports of research as well as reviews since symposia may embrace both types of presentation.


ABOUT THE EDITORS


C . KEITH RlEW is an R & D Fellow at The

BFGoodrieh Company, Research and Development Center, Brecksville, Ohio. H e received his M . S . and P h . D . in or ganic chemistry from Wayne State Uni versity, Detroit, Michigan, and his B.S. in Chemistry from Seoul National Univer sity, Seoul, Korea. H e served as research scientist or manager for the N e w Prod ucts' R & D , Chemical Group, The BFGoodrieh Company for more than 15 years. H e has presented more than 30 technical papers and owns 15 patents on the synthesis and application of telechelic polymers, including rubber-toughened or -modified thermosets, hydrophilic polymers, and latexes. His latest research is in the synthesis, characterization, compound ing, and performance evaluation of polymeric additives, especially i m pact modifiers for engineering thermoplastics. His research interests include correlating polymer chemistry and physics, morphology, process ing, and static and dynamic thermomechanical properties to the failure mechanisms of impact-modified thermosets and thermoplastics. JOHN K . GlLLHAM received a B . A . from Cambridge University, England, and a P h . D . in Chemistry from M c G i l l Univer sity, Canada. H e is a professor in the Polymer Materials Program of the De partment of Chemical Engineering at Princeton University. His research with polymers includes thermosetting sys tems, transitions, spiral fractures in com posite materials, and pyrolysis. H e was the recipient of the 1978 Borden Award of the American Chemical Society in the Chemistry of Plastics and Coatings, the 1978 Mettler Award of the North American Thermal Analy sis Society, and corecipient of the Doolittle Award for the best paper presented in 1979 to the American Chemical Society Division of Organic Coatings and Plastics Chemistry. H e has served on National Materials Advisory Board Committees on "Characterization of Organic Matrix



Composites" and "High-Performance, Low-Energy-Curing Resins". In 1983 he was chairman of the Gordon Research Conference on Ther mosets, was corecipient of the First Prize in the Roon Foundation Awards Competition of the Federation of Societies for Coatings Technologies for the best technical paper, and presented a series of lectures in Japan sponsored by the Japan Society for the Promotion of Science. In 1984 he presented a series of lectures in the People's Republic of China at the invitation of the Chinese Academy of Sciences. H e is the developer of the torsion braid analysis (TBA) technique and the Time-Temperature-Trans formation (TTT) cure diagram for thermosetting systems.


Rubber-Modified Thermoset Resins, Copyright, Advances in

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