Rubber-Toughened Plastics, Copyright, Advances in Chemistry Series

Downloaded by 24.46.80.12 on May 22, 2014 | http://pubs.acs.org Publication Date: May 5, 1989 | doi: 10.1021/ba-1989-0222.fw001

Rubber-Toughened Plastics

In Rubber-Toughened Plastics; Riew, C.; Advances in Chemistry; American Chemical Society: Washington, DC, 1989.



ADVANCES

IN

CHEMISTRY

SERIES

Rubber-Toughened Plastics C. Keith Riew,

EDITOR


BF Goodrich Company

Developed from a symposium sponsored by the Division of Polymeric Materials: Science and Engineering of the American Chemical Society, at the 194th National Meeting of the American Chemical Society, New Orleans, Louisiana August 30-September 4, 1987

American Chemical Society, Washington, DC 1989


222

Library of Congress Cataloging-in-Publication Data Rubber-toughened plastics. (Advances in chemistry series, ISSN 0065-2393) "Developed from a symposium sponsored by the Division of Polymeric Materials: Science and Engineering of the American Chemical Society, New Orleans, Louisiana, August 30-September 4, 1987."


Bibliography: p. Includes indexes. 1. Plastics—Additives—Congresses. 2. Rubber— Congresses. I. Riew, C. Keith. II. American Chemical Society. Division of Polymeric Materials: Science and Engineering. III. American Chemical Society. Meeting (194th: 1987: New Orleans, La.). IV. Series. QD1.A355

no. 222

ISBN 0-8412-1488-3

[TP1142]

540s

89-14938

[668.4'22]

Copyright © 1989 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, M A 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means— graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission, to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. P R I N T E D IN THE UNITED STATES OF AMERICA


Advances in Chemistry Series M. Joan Comstock, Series Editor


1989 ACS Books Advisory Board P a u l S. A n d e r s o n Merck Sharp & Dohme Research Laboratories

M a r y A . Kaiser Ε. I. du Pont de Nemours and Company

A l e x i s T. Bell University of California—Berkeley

Michael R. Ladisch Purdue University

H a r v e y W. B l a n c h University of California—Berkeley M a l c o l m H. C h i s h o l m Indiana University Alan Elzerman Clemson University J o h n W. F i n l e y Nabisco Brands, Inc. N a t a l i e Foster Lehigh University M a r y e A n n e Fox The University of Texas—Austin G . Wayne Ivie U.S. Department of Agriculture, Agricultural Research Service

J o h n L. M a s s i n g i l l Dow Chemical Company D a n i e l M. Q u i n n University of Iowa James C . R a n d a l l Exxon Chemical Company Elsa Reichmanis A T & T Bell Laboratories C . M. R o l a n d U.S. Naval Research Laboratory S t e p h e n A. S z a b o Conoco Inc. W e n d y A. W a r r Imperial Chemical Industries R o b e r t A. Weiss University of Connecticut


FOREWORD


The

A D V A N C E S I N C H E M I S T R Y S E R I E S was

founded in 1949

by

the American Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that w o u l d otherwise be fragmented because their papers w o u l d be distributed among several journals or not published at all. Papers are reviewed critically according to A C S editorial standards and receive the careful attention and processing characteristic of A C S publications. Volumes in the A D V A N C E S I N C H E M I S T R Y S E R I E S maintain the

integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.


A B O U T THE E D I T O R


C . KEITH RiEW received his M . S . and

Ph.D.

degrees in organic chemistry from Wayne State University, Detroit, Michigan, and his B.S. degree in chemistry from Seoul National University, Seoul, Korea. H e is an R & D Fel low at the B F Goodrich Company, Research and Development Center, Brecksville, Ohio. H e has served as research scientist or R & D manager for N e w Products Research and Development, B F Goodrich Company, for more than 21 years. H e has presented more than 20 technical papers and owns more than 20 patents on the synthesis and application of telechelic poly mers, including rubber-toughened or rubber-modified thermosets and hydrophilic polymers. His latest research is in the synthesis, characteriza tion, engineering, and performance evaluation of impact modifiers for thermosets and engineering thermoplastics. His research interests include correlating dynamic thermomechanical properties to the failure mechanisms of impact-modified thermosets and thermoplastics. In 1983 he coorganized the first international symposium on "Rubber-Modified Thermoset Resins" at the 186th National Meeting of the American Chemical Society, Division of Polymeric Materials: Science and Engineering, Washington, D C , August 28-September 2, 1983. In 1984 he coedited Rubber-Modified Thermoset Resins, Advances in Chemistry Series, Volume 208, American Chemical Society, Washington, D C . In 1987 he organized the second international symposium on "RubberToughened Plastics" at the 194th National Meeting of the American Chemical Society, Division of Polymeric Materials: Science and Engineer ing, N e w Orleans, Louisiana, August 31-September 4,1987.

vii




Dedication


A Tribute to JohnA.Manson 1928-1988 Following his education at McMaster Univer sity and the University of Michigan and an industrial position with the A i r Reduction Company, John Manson joined the faculty of Lehigh University i n 1967. There he enjoyed an incredibly rich technical career. H e authored more than 160 scientific papers i n diverse fields that involved interactions with faculty from four different academic depart ments and two research centers at Lehigh University. In 1983 he was corecipient of Lehigh U n i versity's L i b s e h A w a r d for outstanding research achievement. H i s interactions with international colleagues from England, France, Italy, Columbia, Czecho slovakia, and his homeland, Canada, are truly impressive. John Manson coauthored two books, several critical reviews, and numerous encyclope dia articles that represent seminal contributions to the fields of polymer composites, acid-base interactions, polymer fatigue, polymer blends and composites, and polymer concrete. A day with John Manson may be likened to a stroll through a grove of giant redwoods. The air was always fresh and clear from his extraordi nary intellectual honesty and respect for the views of his students and colleagues. His logic and thought processes were as strong and true as the trunks of these great specimens of nature. John's tree will grow no more, but its growth rings will bear permanent witness to his many contributions to so many of us. It will serve us well to periodically review his record as w e rededicate our efforts to train the minds of our students and push back the frontiers of the unknown. R.W. Hertzberg Department of Materials Science and Engineering Lehigh University Bethlehem, PA 18015-3195 ix


Professor Manson fought hard against his cancer. H e was writing an article entitled "Fatigue Crack Propagation in Rubber-Modified Epoxies and Polyacetal" for this book when he passed away. I truly regret that I could not include Professor Manson s chapter in this book.


C. Keith Riew

χ


Rubber-Toughened Plastics, Copyright, Advances in Chemistry Series

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