SEW nooKs

SEW nooKs. shape of the nucleus is only one of the methods of indicating the vibra- tion or oscillation which was first proposed by Kekul6 for the ben...
0 downloads 0 Views 66KB Size
t322

SEW

nooKs.

shape of the nucleus is only one of the methods of indicating the vibration or oscillation which was first proposed by Kekul6 for the benzene structure, a n d is of interest now in another connection. These formulas represent all the possible structures produced b y the making and breaking of bonds, each make and break causing a definite absorption band. This conception of make arid break hi,tuwn the atoms in the molecule being responsible for the a1)sorption l ~ a n t l sis not lar removed from the physicist’s conception of tlie tnotion of tlie electron within tlie a t o m or molecule being responsible for the optical phenotnena. In Appendix A , the R e h t ion., o j . V / m ~ o c h i ~i)si/ir j , io Ijhj~.riologyare discussed briefly, and in Appendix 13, directions ;ire given for tlie construction of stereochemical models. This book is fully up t o the best of the other volumes of the series, a n d is indispensable to every organic cliemist. Exception may be taken t o the statement on page 41 t h a t the solid racemic compound possesses a molecular weight double t h a t of one active component, \vhen as a rnatter of fact, practically nothing is known of the molecular weight of any substance in the solid state. The proof-reading has been well done, very few misprints being noticeable, the most serious being on page 14, where t h e length of t h e liquid layer for the specific rotation is given a s centimeters instcad of deciiiietc.rs. The expression is given correctly in the foot-note on page 1 2 - 7 . I