Stereochemistry and ultraviolet spectra of simple nitrate esters

Experimental Section. Reactions involving benzoyl nitrate were carried out using freshly prepared stock solutions in acetonitrile as described else-...
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J . Org. Chem., Vol. 38,N o . 13, 1973 2281

SIMPLE NITRATEESTERS TABLE V

CYCLOHEXENE TRAPPING REACTIONS~ Produots

f f

Cyclohexen-3-01 acetate 1,2-Dichlorocyolohexaneh 1-Nitrocyclohexene 2-Chlorocyclohexyl acetate ZChloro-1-nitrocyclohexane

Retention timeb

CeHsCONOs

+ LiClc

mu m MQ M m M M m

4.0

4.3 6.6 7 . 8 8.8

+

NOzCld

CsHsCOaCl'

m m M

m m M