Structure and bonding in thiazyl fluorides - Inorganic Chemistry (ACS

Jan 1, 1984 - Structure and bonding in thiazyl fluorides. Constantin Zirz, Reinhart Ahlrichs. Inorg. ... Peter Gersdorf. The Journal of Physical Chemi...
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Inorg. Chem. 1984, 23, 26-31

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but experimental evidence does exist for facile rotation about the MoMo triple bond in some systems. Recent work from Chisholm's laboratory12 suggests a wide range of values for metal-metal rotation barriers: