648
Macromolecules 1983, 16, 648-657
lower AT or at a much earlier stage. Registry No. PS, 9003-53-6; PVME, 9003-09-2.
References and Notes See, for example: Kwei, T. K.; Wang, T. T. In “Polymer Blends”; Paul, D. R., Newman, S., Eds.; Academic Press: New York, 1978; Vol. 1, Chapter 4. Cahn, J. W. Trans. Metall. SOC. AZME 1968, 242, 166. See, for example: Paul, D. R., ref 1, Chapter 1. Krause, S., ref 1, Chapter 2. Sanchez, I. C., ref 1, Chapter 3. Hashimoto, T.; Kumaki, J.; Kawai, H. Macromolecules, part 2 of this series, submitted for publication. Nishi, T.; Wang, T. T.; Kwei, T. K. Macromolecules 1975,8, 227.
Cahn, J. W. J. Chem. Phys. 1965,42,93. de Gennes, P.-G. J. Chem. Phys. 1980, 72, 4756. Cahn, J. W.; Hilliard, J. E. J. Chem. Phys. 1958, 29, 258. Cahn, J. W.; Hilliard, J. E. J. Chem. Phys. 1959, 31, 688. Flory, P. “Principles of Polymer Chemistry”; Cornel1University Press: Ithaca, NY, 1971; Chapter XII. Huggins, M. J. Am. Chem. SOC. 1942,64, 1712. Debye, P. J. Chem. Phys. 1959,31, 650. Helfand, E.; Sapse, A. J. Chem. Phys. 1975, 62, 1327. de Gennes, P.-G. J. Chem. Phys. 1971,55,572. Doi, M.; Edwards, S. F. J. Chem. SOC.,Faraday Trans. 2 1978, 74, 1789. Bank, M.; Leffingwell, J.; Thies, C. Macromolecules 1971, 4, 43; J. Polym. Sci., Polym. Phys. Ed. 1972, 10, 1097. Nishi, T.; Kwei, T. K. Polymer 1975, 16, 285. Saijo, K.; Tanaka, K.; Suehiro, S.; Hashimoto, T.; Kawai, H., to be submitted for publication.
(18) Lifshitz, -I. M.; Slyozov, V. V. J. Phys. Chem. Solids 1961,19, 35.
(19) Cahn, J. W. Acta Metall. 1966, 14, 685. (20) Langer, J. S. Ann. Phys. (N.Y.)1971,65,53;Acta Metall. 1973, 21, 1649. (21) Langer, J. S.; Bar-on, M.; Miller, H. S. Phys. Reu. A 1975,11, 1417. (22) Hashimoto, T.; Tanaka, K.; Kawai, H., to be submitted for
publication.
(23) Hashimoto, T.; Sasaki, K.; Kawai, H., to be submitted for
publication.
(24) Binder. K.: Stauffer. D. Phvs. Reu. Lett. 1974. 33. 1006. (25) Nojima, S.; Tsutsumi, K.; Nose, T. Polym. J.’1982, 14, 225. (26) For larger q limit where qRo >> 1, de Gennes’ theory predicts
that the Onsager coefficient has a q dependence different from eq 11-14, The theory has been corrected and extended by Pin~us.~’ However our light-scattering data are obviously associated with the fluctuations occurring at a distance scale much larger than the coil size Ro (Le., A >> Ro),hence satisfying qRo
