Organometallics 1995, 14,5454
5454
Additions and Corrections 1995,Volume 14 Matti Haukka, Jari Kiviaho, Markku Ahlgren, and Tapani k Pakkanen*:Studies on Catalytically Active Ruthenium Carbonyl Bipyridine Systems. Synthesis and Structural Characterization of [Ru(bpy)OCH~)I, (CO)2C121, [ R U ( ~ ~ ~ ) ( C O ) ~ C ~ ( C ( ~ > [Ru(bpy)(C0)2C112, and [Ru(bpy)(CO)zClHI (bpy = 2,2’-Bipyridine).
Page 832. Entries in Tables 7 and 8 were placed in the wrong columns. The correct versions of these tables appear below.
Table 7. Selected Bond Lengths (A) for cis-(CO),cis-(C1)-[Ru(bpy)(CO)~C1~1 (la), ~ ~ ~ ~ ( C O ) , ~ ~ ~ - ( C ~ ) - [ R U(lb), (~~~~~CO~~C~~~.CH~C~Z [Ru(~~~)(CO)ZC~(COOCHS)I (2), [R~(bp~)(CO)zC~lz (31, and [Ru(bpy)(CO)~ClHl(4) la lb 2 3 Ru-Cl(1) Ru-C1(2Ia Ru-N(l) Ru-N(2) Ru-C(l1) Ru-C(l2) Ru-C(31) C(ll)-O(11) C(12)-0(12) C(31)-0(31) C(31)-0(32) 0(32)-C(32) Ru-RU
4
2.439(3) 2.411(4) 2.117(8) 2.090(8) 1.899(11)
2.391(5) 2.496(3) 2.512(1) 2.524(2) 2.390(5) 2.112(12) 2.117(8) 2.040(6) 2.118(4) 2.102(9) 2.179(7) 2.120(5) 1.835(17) 1.859(13) 1.953(8) 1.874(6) 1.841(16) 1.817(8) 1.860(8) 1.938(10) 2.041(12) 1.115(14) 1.133(22) 1.161(16) 1.148(10) 1.142(8) 1.123(20) 1.159(11) 1.130(10) 1.012(15) 1.175(18) 1.299(20) 1.397(17) 2.860(1)
Cl(2) = Cl(3) for lb.
Table 8. Selected Bond Angles (deg) for cis-(CO),cis-(Cl)-[Ru(bpy)(CO~~Cl~l (la), cis-(CO),trune-(C1)-[Ru(bpy~(C0)~Cl~l.CH~C1~ (lb), [R~(bpy)(CO)zCl(C00CHs)3(2), [R~(bp~)(CO)zCllz (31, and [Ru(bpy)(CO)~ClHl(4) la Cl(l)-Ru-C1(2)* Cl(l)-RU-N(l) Cl(l)-Ru-N(2) Cl(l)-Ru-C(ll) Cl(l)-Ru-C(12) CKl)-Ru-C(31) N(1)-Ru-C1(2Ib N(l)-Ru-N(2P N(l)-Ru-C(ll) N(l)-Ru-C(12P N(l)-Ru-C(31) N(2)-Ru-Cl(2lb N(2)-Ru-C(11) N(2)-Ru-C(12) N(2)-Ru-C(31) C(ll)-R~-C1(2)~ C( 11)-Ru- C( 12P C(ll)-Ru-C(31) R~-C(ll)-O(ll) Ru-C(12)-0(12) Ru-C(31)-0(31) Ru-C(31)-0(32) C(31)-0(32)-C(32) Ru-Ru(A)-Cl( 1)
lb
92.1(1) 176.3(1) 86.5(2) 89.4(4) 89.1(2) 87.3(3) 88.5(3) 91.0(6)
2
86.1(2) 94.0(3)
3
86.0(1) 84.6(1) 94.8(2) 95.0(2)
4
86.6(1) 87.3(1) 97.9(2) 98.4(2)
178.8(3) 175.2(5) 96.0(2) 88.9(4) 77.6(3) 77.2(4) 76.6(5) 78.2(2) 77.0(2) 174.1(4) 174.8(6) 174.3(5) 172.3(3) 172.5(2) 95.0(6) 97.7(5) 101.9(3) 97.5(2) 94.0(4) 90.1(4) 89.1(2) 89.2(3) 99.3(4) 97.6(6) 94.3(3) 97.2(3) 172.1(6) 179.6(2) 171.9(2) 92.1(4) 88.5(3) 90.2(7) 88.0(8) 85.6(3) 87.8(3) 91.0(5) 89.5(4) 174.5(10) 178.6(15) 179.7(8) 179.6(8) 176.7(7) 177.9(13) 177.0(6) 176.7(7) 171.1(11) 129.N111 113.2(10) 117.0(11) 177.0(1)
N(2) = N(1a) and C(12) = C(1la) for 2. Cl(2) = Cl(3) for lb.
OM950576A
