4568
Organometallics 2002, 21, 4568
Additions and Corrections 2002, Volume 21 Bogdan Marciniec* Ireneusz Kownacki, and Maciej Kubicki: Synthesis, Structure, and Reactivity of [{Ir(cod)(µ-OSiMe3)}2] with Styrene and Vinylsilanes: Catalytic Activation of the Vinylic dC-H Bond. Page 3266. Table 3 and eq 3 should appear as shown. Table 3. Silylative Coupling vs Hydrovinylation (Co-dimerization) of Styrene with Vinyltrisubstituted Silanes Catalyzed by [{Ir(cod)(µ-OSiMe3)}2]a
yield (%) compd
conversion (%)
(1)
(2)
(3)
50 90 59b 7c 70 30b 2c 60 75d 9b 44 65d 46 65d 7b 39
45 84 55 7 60 29 traces 51 64 6 44 61 traces traces 0 0
2 6 4 0 4 traces 0 6 7 0 0 0 0 0 traces 0
0 0 0 0 0 0 0 3 4 3 0 4 42 60 7 39
CH2dCHSiMe3 CH2dCHSi(OEt)3 CH2dCHSiMe2Ph CH2dCHSiMe2OSiMe3 CH2dCHSiMe(OSiMe3)2 CH2dCHSi(OSiMe3)3 CH2dCHSi(OSiMe3)3 CH2dCHSi(OtBu)3
a Reaction conditions: [Ir]:[CH dCHSit]:[styrene], 10-2:1:10; 2 argon; 100 °C; 24 h, ampules. b 80 °C, 24 h. c [{Ir(cod)(µ-Cl)}2]. d 100 °C, 48 h.
OM020617K 10.1021/om020617k Published on Web 09/07/2002
Hwimin Seo, Si-Guen Lee, Dong Mok Shin, Bog Ki Hong, Sungu Hwang, Doo Soo Chung, and Young Keun Chung*: Studies on the Chemistry of Manganese Tricarbonyl Cations of Phenol and Cresols. Page 3417. Reference 2 should have included citation of the following papers by Amouri et al., which report the iridium-mediated functionalization of phenols and related molecules: (k) Le Bras, J.; Vaissermann, J.; Amouri, H. Organometallics 1996, 15, 5706. (l) Le Bras, J.; Vaissermann, J.; Amouri, H. Organometallics 1998, 17, 1116. (m) Le Bras, J.; Vaissermann, J.; Amouri, H. Inorg. Chem. 1998, 37, 5056. (n) Le Bras, J.; Vaissermann, J.; Amouri, H. Organometallics 1998, 17, 5850. (o) Le Bras, J.; Rager, M. N.; Besace, Y.; Vaissermann, J.; Amouri, H. Organometallics 1997, 16, 1765. (p) Le Bras, J.; Vaissermann, J.; Amouri, H. J. Organomet. Chem. 1998, 567, 57. OM020707P 10.1021/om020707p Published on Web 09/13/2002
