Superelastic and Superhydrophobic Nanofiber-Assembled Cellular

Apr 8, 2015 - Functionalization of Biodegradable PLA Nonwoven Fabric as Superoleophilic and Superhydrophobic Material for Efficient Oil Absorption and...
0 downloads 4 Views 4MB Size
ARTICLE

Superelastic and Superhydrophobic Nanofiber-Assembled Cellular Aerogels for Effective Separation of Oil/Water Emulsions Yang Si,†,‡ Qiuxia Fu,† Xueqin Wang,‡ Jie Zhu,† Jianyong Yu,†,§ Gang Sun,†,§ and Bin Ding*,†,‡ †

Key Laboratory of Textile Science & Technology, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China, ‡State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China, and § Nanomaterials Research Center, Modern Textile Institute, Donghua University, Shanghai 200051, China

ABSTRACT Many applications proposed for functional nanofibers require their assembly

into a monolithic cellular structure. The ability to maintain structural integrity upon large deformation is essential to ensure a macroscopic cellular material that functions reliably. However, it remains a great challenge to achieve high elasticity in three-dimensional (3D) nanofibrous networks. Here, we report a strategy to create fibrous, isotropically bonded elastic reconstructed (FIBER) aerogels with a hierarchical cellular structure and superelasticity by combining electrospun nanofibers and the freeze-shaping technique. Our approach allows the intrinsically lamellar deposited electrospun nanofibers to assemble into elastic bulk aerogels with tunable porous structure and wettability on a large scale. The resulting FIBER aerogels exhibit the integrated properties of ultralow density (