CH ι CH3-Cι CH
CH:
CH3 1
CH 3 -C
C-NH 2
I
CH
1
CH3
t-Bufylamine and t-Octylamine MOLECULAR WEIGHT BOILING RANGE (760 mm.) COLOR SOLUBILITY
f-BUTYLAMINE 73
f-OCTYLAMINE
44-50°C. 15 (APHA) Miscible in all propor tions with water and a l c o h o l . Soluble in common organic solvents. Development quantities
129 137-143°C. 1- (Varnish) Insoluble in water. Water is soluble in t-oetvlamine — 3 5 % by weight (2° C ) , 7 % by weight (85° C.) Commercial quantities
REACTIONS — These amines have normal basic strength and undergo the usual reactions for primary amines. Reactivity is somewhat modified by steric hindrance. Reactions ivith aliphatic aldehydes^ to give stable, monomeric aldimines^ and xoith cyanogen chloride to give stable t-alhyl cyanamides are unique.
RNH* + (R = f-butyl or *-octyl)
I
R'-CHO CICN R'X
-^R-N=CHRI -^R-NH-CN •^R-NH-R"
/°\
CH2-CH2—*-R~NH-CH2CH2OH CH2=CHCN-^R-NH-CH2CH2CN
SUGGESTED USES — Synthesis of rubber chemicals, in secticides, bactericides, oil additives, photographic chemi cals, pharmaceuticals, surface active agents, corrosion inhibitors, dyestuifs. For samples and technical literature describing reactions in detail, write Dept. SP.
1 CHEMICALS
FOR INDUSTRY
R O H M £• HAAS cores P A N Y WASHINGTON SQUARE, PHILADELPHIA 5, PA. Representatives in principal foreign countries
