OCTOBER 1, 1993 VOLUME 65 NUMBER 19 The ANCHAM Audit 65(19) 815A-866A/2553-2712 (1993) ""'"" ISSN 0003-2700
Analytical® CHEMISTRY
Registered in U.S. Patent and Trademark Office; ©Copyright 1993 by the American Chemical Society EDITOR: ROYCE W. MURRAY, University of North Carolina ASSOCIATE EDITORS: Catherine C. Fenselau, University of Maryland Baltimore County, William S. Hancock, Genentech, James W. Jorgenson, University of North Carolina, Robert A. Osteryoung, North Carolina State University, Edward S. Yeung, Iowa State University/Ames Laboratory Editorial Headquarters, research section Department of Chemistry Venabie and Kenan Laboratories University of North Carolina Chapel Hill, NC 27599-3290 Phone:919-962-2541 Fax:919-962-2542 E-mail: Murray @ uncvxl .oit.unc.edu Editorial Headquarters, A-page section 1155 Sixteenth St., N.W. Washington, DC 20036 Phone:202-872-4570 Fax: 202-872-4574 E-mail: rmh96 @ acs.org Managing Editor: Mary Warner Senior Editor: Louise Voress Associate Editor: Grace K. Lee Assistant Editor: Felicia Wach Editorial Assistant: Deborah Noble Contributing Editor: Marcia Vogel Head, Graphics and Production: Leroy L. Corcoran Art Director:AlanKahan Designers: Sarah Chung, Peggy Corrigan Production Editor: Elizabeth Wood Electronic Composition: Wanda R. Gordon Circulation: David Schulbaum LabGuide Managing Editor of Directories and Databases: Kathleen Strum Associate Editor: Joanne Mullican Assistant Editor: Susan Barclay Journals Dept., Columbus, Ohio Editorial Office Manager: Mary E. Scanlan Journals Editing Managers: Kathleen E. Duffy, Anne C. O'Melia, Joseph E. Yurvati Associate Editor: Lorraine Gibb Assistant Editor: Brenda S. Wooten Advisory Board: Michelle V. Buchanan, Bruce Chase, M. Bonner Denton, Joseph G. Gordon, David M. Haaland, Joel M. Harris, Timothy D. Harris, Franz Hillenkamp, Kiyokatsu Jinno, Dennis C. Johnson, Richard A. Keller, Philip D. LaFleur, Gary E. Maciel, Geraldine Richmond, Ralph Riggin, Michael Thompson Ex Officio: Joseph L. Glajch
REPORT
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Nonlinear multivariate calib r a t i o n m e t h o d s . The data explosion created by t h e increased resolving power of analytical ins t r u m e n t s h a s placed more e m p h a s i s on d a t a a n a l y s i s . Sonja Sekulic, Bruce Kowalski, and cow o r k e r s a t t h e U n i v e r s i t y of Washington present an overview of multivariate calibration methods a n d apply t h e m to six d a t a sets from different spheres of analytical chemistry
ANALYTICAL APPROACH
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On the cover. A q u e s t for o l e a n d r i n . In 1985 a young funeral parlor owner died from what was t h e n reported as cardiac a r r e s t ; t h e case w a s r e o p e n e d in 1991 when an informant suggested that death h a d been caused by intentional poisoning. Jack Henion and co-workers at Cornell University describe t h e LC/MS protocol developed to determine whether oleandrin was present in the decomposed tissue samples
Cover .photo by Lee Anderson. Reproduction of A Family Business cover courtesy of St. Martin's Press, Inc. Newspaper article by John Johnson, staff writer, © 1990 Los Angeles Times, reprinted by permission.
UPCOMING RESEARCH
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EDITORIAL
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The ubiquitous laser: or, let all spectroscopists enjoy t h e radiance. Lasers have played a pervasive role in the development of, and remain a frontier of, analytical chemistry. Lasers are clearly a bright spot in our discipline's future, both basic and applied, and it will be fascinating to watch analytical laser spectroscopy grow
NEWS
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1994 ACS a w a r d s will go to Edward S. Yeung, Barbara J. G a r r i s o n , Adam Heller, Paul Kebarle, William H. Pirkle, Philip C. Wankat, and George M. Whitesides. · ASA a n d P e r k i n Elmer awards for outstanding technical papers. · Golay award presented to Konrad Grob
FOCUS
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Instrumentation Advisory Panel: Anna Brajter-Toth, Raymond E. Clement, Therese M. Cotton, Norman J. Dovichi, Jack D. Henion, Mary Ellen P. McNally, John W. Olesik, Dallas L. Rabenstein, J. Michael Ramsey
C a p i l l a r y c h r o m a t o g r a p h y h a s been t r a d i t i o n a l l y associated with terms such as high resolution, speed, and low detection limits. Wolfgang Bertsch of the University of Alabama reports on the 15th International Symposium on Capillary Chromatography, held in Riva del Garda, Italy, in May
Publications Division Director: Robert H. Marks Head, Special Publications: Anthony Durniak Head, Journals: Charles R. Bertsch
NEW PRODUCTS AND MANUFACTURERS' LITERATURE
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ANALYTICAL CHEMISTRY, VOL. 65, NO. 19, OCTOBER 1, 1993 · 819 A
Analytical® CHEMISTRY
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Articles Piezoelectric pH Sensors: AT-Cut Quartz Resonators with Amphoteric Polymer Films 2553 Juan Wang, Michael D. Ward *, Richard C. Ebersole *, and Robert P. Foss Analytical Applications of Catalytic Properties of Modified Cyclodextrins Ellen Tuanying Chen and Harry L. Pardue *
2563
Piezoelectric Detection of Water with A Separated Electrode 2568 WenhongZhu, Wanzhi Wei, ZhihongMo, Lihua Nie, and Shouzhuo Yao * Schiff Base Complexes of Cobalt(II) as Neutral Carriers for Highly Selective Iodide Electrodes 2572 Ruo Yaun, Ya-Qin Chai, Dong Liu, De Gao, Jun-Zhong Li, andRu-Qin Yu * High-Frequency Generation of Electrochemiluminescence at Microelectrodes Maryanne M. Collinson andR. Mark Wightman *
2576
Behavior and Calibration of the Copper (II) Ion-Selective Electrode in High Chloride Media and Marine Waters Stuart L Belli * and Alberto Zirino
2583
High-Performance Flow Flame Atomic Absorption Spectrometry for Automated On-Line Separation and Determination of Cr(III)/Cr(VI) and Preconcentration of Cr (VI) 2590 JozsefPosta, Harald Berndt *, Shen-Kay Luo, and Gerhard Schaldach Helium Microwave Induced Plasma Atomic Emission Detection for Liquid Chromatography Utilizing a Moving Band Interface Peter B. Mason, Liming Zhang, Jon W. Carnahan*, and Randall E. Winans*
2596
Solid-Matrix and Solution Luminescence Photophysical Parameters and Analytical Aspects of the Tetrols of Benzo[a]pyrene-DNA Adducts 2601 Johannes Corley and Robert J. Hurtubise* Liquid Mixtures for Matrix-Assisted Laser Desorption D. Shannon Cornett, Michael A. Duncan, and I. Jonathan Amster*
2608
Detection of Electrospray Ionization Using a Quadrupole Ion Trap Storage/Reflectron Time-of-Flight Mass Spectrometer Steven M. Michael, Benjamin M. Chien, and David M. Lubman *
2614
Ultrahigh Resolution Matrix-Assisted Laser Desorption/Ionization of Small Proteins by Fourier Transform Mass Spectrometry 2621 John A. Castoro and Charles L. Wilkins * On-Line Fermentation Process Monitoring of Carbohydrates and Ethanol Using Tangential Flow Filtration and Column Liquid Chromatography TorbjornA. Buttler*, Kristina A. J. Johansson, Lo G. O. Gordon, and GyorgyA. Marko-Varga
*Corresponding author
continued
2628
on p. 823 A
ACS membership information: Lorraine Bowiin (202-872-4567)
ANALYTICAL CHEMISTRY, V O L 65, NO. 19, OCTOBER 1, 1993 · 821 A
Analytical® CHEMISTRY
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Glass Chips for High-Speed Capillary Electrophoresis Separations with Submicrometer Plate Heights Carlo S. Effenhauser*, Andreas Manz, andH. Michael Widmer
2637
New Parameters for the Characterization of Relationship between Gas Chromatographic Retention and Temperature M. deFrutosJ. Sam*, I. Martinez-Castro, andM. I.Jiménez
2643
Separation and Identification of Higher Molecular Weight Fullerenes by High-Performance Liquid Chromatography with Monomeric and Polymeric Octadecylsilica Bonded Phases Kiyokatsu Jinno *, Takashi Uemura, Hatasuichi Ohta, Hideo Nagashima, and Kenji Itoh
2650
Mathematical Treatment of Electrophoretically Mediated Microanalysis Bryan J. Harmon, DaleH. Patterson, and Fred E. Régnier*
2655
Axial Thermal Gradient Microbore Liquid Chromatography by Flow Programming Leslie K. Moore and Robert E. Synovec *
2663
Affinity of Antifluorescein Antibodies Encapsulated within a Transparent Sol-Gel Glass Run Wang, UpvanNarang, Paras N. Prasad*, and Frank V. Bright*
2671
Engineering Protein Orientation at Surfaces To Control Macromolecular Recognition Events Mark A. McLean, Patrick S. Stayton, and Stephen G. Sligar*
2676
Purification and Analysis of Drug Residues in Urine Samples by On-Line Immunoaffinity Chromatography/High-Performance Liquid Chromatography/Continuous-Flow Fast Atom Bombardment Mass Spectrometry 2679 Enrico Davoli, Roberto Fanelli, and Renzo Bagnati *
Correspondence Molecular Basis of Peak Width in Capillary Gas Chromatography under High Column Pressure Drop Leonid M. Blumberg* and Terry A. Berger
2686
Ascorbic Acid Interferences in Hydrogen Peroxide Detecting Biosensors Based on Electrochemically Immobilized Enzymes Francesco Palmisano and Pier G. Zambonin *
2690
Technical Notes On-Line Peptide Mapping by Capillary Zone Electrophoresis Lawrence N. Amankawa and Werner G. Kuhr*
2693
In Situ Elimination of Metal Inhibitory Effects Using Ligand- Containing Carbon Paste Enzyme Electrodes Joseph Wang* and Qiang Chen
2698
Radiochemical Determination of Low-Level Lead-210 in Environmental Water Samples Dominic To
2701
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continued on p. 825 A
ANALYTICAL CHEMISTRY, VOL. 65, NO. 19, OCTOBER 1, 1993 · 823 A
Analytical® CHEMISTRY
LabGuide The LabGuide is published as the August 15 issue of ANALYTICAL CHEMISTRY. Begun 38 years ago by the JOURNAL, the annual LabGuide edition is designed to be the ultimate buyers' resource for chemists. Its comprehensive coverage includes 2250 categories of laboratory products and services from more than 1700 companies. The 1994 edition featured -40,000 informative listings detailing manufacturers and distributors of each product and service. Each listing includes the company's phone number for fast action; a more complete listing of the company's address and branch offices is located in a separate section at the back of the book. Sections include Chromatography; Spectroscopy; Instruments and Accessories; Equipment and Supplies; Chemicals and Standards; and Research, Analytical, Consulting, Education, and Training Services. Putting together such a comprehensive and useful guide would be impossible without the suggestions and guidance of our advisory board. Current members include Duane Bartak (University of North Iowa), Bob Hoesly (Mettler Toledo), Paul Preidecker (Gilson), K. C. Warawa (K. C. Associates), Anne Cerino (Anne Cerino Marketing Communications), H. M. Kingston (Duquesne University), Tim Heil (Radian), Susan Olesik (Ohio State University), Rodger Stringham (Merck), Bob Wright (Battelle Pacific Northwest Laboratories), and Sherman Hamel (Parr Instruments).
Instrumentation in Analytical 1988-1991
Lithium Ion Selective Optical Sensor Based on a Novel Neutral Ionophore and a Lipophilic Anionic Dye Kazuhiko Watanabe, Rieko Nakagawa, Hiroyuki Yamada, Hideaki Hisamoto, and Koji Suzuki *
2704
Correction Analysis of Diffusional Broadening of Vesicular Packets of Catecholamines Released from Biological Cells during Exocytosis Timothy}. Schroeder, Jeffrey A. Jankowski, Kirk T. Kawagoe, R. Mark Wightman *, Christine Lefrou, and Christian Amatore
2711
Author Index
2712
Chemistry
This recently published book continues a series begun as Instrumentation in Analytical Chemistry in 1973 by Alan J. Senzel, and continued by Stuart A. Borman in the 1980s as Instrumentation in Analytical Chemistry: Volume 2 and Instrumentation in Analytical Chemistry: 1982-86. Like its predecessors, Instrumentation in Analytical Chemistry 1988-1991 is designed to provide readers with updated overviews of analytical techniques and instrumentation drawn from articles originally published in ANALYTICAL CHEMISTRY'S A pages. The volume begins with an introduction by Royce Murray designed to help readers put into perspective the methodological and instrumental developments that have occurred during the period. The book is divided into six topical areas: Robotics, Computers, and Laboratory Data Management; Atomic and Molecular Spectroscopy; Electroanalytical Chemistry and Chemical Sensors; Separations; Mass Spectrometry; and Surface Analysis. Each section begins with a short introduction designed to provide a context for interpreting the articles that follow and to answer questions such as "What are recent changes in this field?" and "Why are these techniques important?". Copies of Instrumentation in Analytical Chemistry 1988-1991 are available in clothbound ($44.95), paperbound ($28.95), and student ($16.95) editions from the ACS Distribution Office, Dept. 390, 1155 16th St., N.W., Washington, DC 20036 (800-ACS-5558).
ANALYTICAL CHEMISTRY, VOL. 65, NO. 19, OCTOBER 1, 1993 · 825 A
