T'hs Journal of
,.
ORGANIC CHEMISTRY March 1961, Vol. 26, No. 3
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087
Tables of Contents of ACS PUBLICATIONS A Thermodynamic Study of the System Am11. The Solid monium Fluoride-Water. Solution of Ammonium Fluoride in Ice. Leonard C. Labowitz and Edgar F. Westrum, J r . . . . .
408
971
Kinetics of Hydrogen Oxidation Downstream of Lean Propane and Hydrogen Flames. Burton Fine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
414
Reduction of 3-Cholestanone with Lithium Aluminum Hydride-Aluminum Chloride. JeanClaude Richer and Ernest L. Eliel. . . . . . . . . . . . 972
Hydrocarbon Synthesis on Pure Iron. P . B. Weisz and W. P. K e r n . . . . . . . . . . . . . . . . . . . . . .
417
Preparation of Substituted Thiamorpholine 1,lDioxides. V. Baliah and T . Rangarajan. . . . . . 969 Synthesis of 3,5-Diaryl-1,4-thiazine, 1,l-Dioxides. V. Baliah and T. Rangarajan.. . . . . . . . . . . . . . . 970 Poly(methy1ene Sulfide). Joginder L a l . . . . . . . . .
Fluorinated Steroids 111. The Synthesis of 16rFluorotestosterone. Henry M . Kissman, Arlene M . Small, and Martin J . W e i s s . . . . . . . . 6p-Hydroxylation of Sa-Fluorohydrocortisone. Leland L. Smith, Joseph J. Goodman, Harold Mendelsohn, John P. Dusza, and Seymour Bernstein. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Chloromethylation: A Novel Route t o 4-Methylsteroids. John H. Fried, Anthony N . Nutile, and Glen E . Arth . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
973
974
976
Structure of Rhein. Hayao Nawa, Masao Uchibayashi, and Toshiro Matsuoka. . . . . . . . . . . . . . 979 Structures of Carotol and Daucol. Leon H. Zalkow, E . J . Eisenbraun, and J . N . Shoolery. . . . . Generation of Nitroethylene in situ for Use in Diels-Alder Reactions. Ralph B. Kaplan and Harold Shechter.. . . . . . . . . . . . . . . . . . . . . . . . . . . Racemization during Chromatography of Some Optically Active Halides. Donald B. Denney and Roland DiLeone.. . . . . . . . . . . . . . . . . . . . . . .
The Dipole Moments of Cyclohexanethiol, aToluenethiol and Benzenethiol. Simao Mathias, Eurico de Carvalho Filho and Renato G. Cecchini.
425
Partial Specific .Volumes and Refractive Index Increments in Multicomponent Systems. Edward F. Casassa and Henryk Eisenberg. . . . .
427
Countercurrent Distribution of Chemically Reacting Systems. I. Polymerization. J . L . Bethune and Gerson Kegeles . . . . . . . . . . . . . . . . . 431
981
The Computation of the Path Difference Function for the Calculation of Diffusion Coefficients by the Gouy Method. W. J . Thomas and I . A . Furzer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
982
The Fluoride Complexing of Yttrium(II1) in Aqueous Solution. Armine D. Paul, Linda S. Gallo and Jean B . V a n C a m p . . . . . . . . . . . . . . . . 441
984
Infrared Extinction Coefficients of Ketones Adsorbed on Ca-Montmorillonite in Relation t o Surface Coverage (Clay-organic Studies, Part IV). Reinhard W. H o f f m a nand G. W . Brindley
443
Synergistic Surface Tension Effects from Mixtures of Fluorinated Alcohols with Conventional Wetting Agents. Marianne K . Bernett and W . A. Z i s m a n . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
448
Species of Cobalt(I1) in Acetic Acid. I. Cobaltous Acetate in the Presence of Water and of Sodium Acetate. P . J. Proll, L. H. Sutclife and J . Walkley.. . . . . . . . . . . . . . . . . . . . . . . . . . . .
455
Communications A New Aromatic Rearrangement. The Migration of Substituted Sulfamyl Groups. Francis L. Scott, Charles W. Schaumann, and James P. King . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
A Vapor Phase Equilibrator for Activity Coefficient Determinations. Leo Brewer, Thomas R. Simonson and Lee Karl J . T o n g . . . . . . . . . . . 420
985
Steroids and Related Natural Products. 111. 4Oxasteroids. George R. Pettit and T. R. Kasturi. 986
438
Complex Ions in Fused Salts. Silver Halides. F. D. Duke and H . M . Garfinkel. . . . . . . . . . . . . 461 Hydrolysis of Alkyl Acetates in a PhosphateBuffered Aqueous Medium. John M . Holland and John G. Miller.. . . . . . . . . . . . . . . . . . . . . . . .
463
The Thermal Decomposition of n-Propylcyclobutane. S. M . E. Kellner and W . D. Walters. ,
466
The Thermal Decomposition of Anhydrous Uranyl Nitrate and Uranyl Nitrate Dihydrate. R . S. Ondrejcin and T. P . Garrett, Jr.. . . . . . . .
470
March 1961, Vol. 65, No. 3
Diffusion to a Plane with Lagmuirian Adsorption. W. H . Reinmuth.. . . . . . . . . . . . . . . . . . . . . . . . . .
473
Dimensions and Hydrodynamic Properties of Cellulosic Molecules in Dilute Solutions. H . J . Marrinan and J. J . Hermans. . . . . . . . . . . . . . . . 385
Heats of Combustion, Formation, and Hydrogenation of Fourteen Cyclomonoolefin Hydrocarbons. Abbas Labbauf and Frederick D . Rossini . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
476
Kinetics and Mechanism for the Electrochemical Reduction of Benzophenone in Acidic Media. Makoto Suzuki and Philip J . Elving.. . . . . . . . .
391
The Configuration of Adsorbed Alkyl Methacrylate Polymers by Infrared and Sedimentation Studies. B . J . Fontana and J . R. Thomas. . . .
480
398
Effects of Short Range Surface-Segment Forces on the Configuration of a n Adsorbed Flexible Chain Polymer. W. I . Higuchi. . . . . . . . . . . . . . 487
The Journal of
PHYSICAL CHEMISTRY
The Thermal Decomposition of Plutonium Hexafluoride. L. E. Trevorrow, W. E . Shinn and R . K . Steunenberg . . . . . . . . . . . . . . . . . . . . . . . . . . . .
A Thermodynamic Study of the System Ammonium Fluoridewater. I. The Heat Capacity and Thermodynamic Functions of Ammonium Fluoride Monohydrate. Leonard C. Labowitz and Edgar F. Westrum, J r . . . . . . . . . . . 403
A Nuclear Magnetic Resonance Study of syn-anti Isomerism in Ketoximes. Ernest Lustig . . . . . . .
491
Low Temperature Thermodynamic Properties of Six Isomeric Heptanes. H . M . Huffman, M . E. Gross, D. W. Scott and J . P . McCullough. . . . .
495
VOL. 53, NO. 5
M A Y 1961
111 A
Tables of Contents of ACS PUBLICATIONS The Kinetics of Dissociation of a Diatomic Gas. H . 0. Pritchard.. . . . . . . . . . . . . . . . . . . . . . . . . . . The Palladium-Chlorine System a t High Temperature. Wayne E . Bell, Ulrich Merten and M . Tagami . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
504
510
Thermodynamic Properties of Gaseous Ruthenium Chlorides at High Temperatures. Wayne E . Bell, M . C. Garrison and Ulrich Merten. . , . 517
+
The Rate of Thermal Decomposition of Dimethyl 2,2’-Azo-bis-iso-butyrate. Horace A . Ory. . . . .
571
The Effect of Analine and its Derivatives on Oxanilic Acid. Louis Watts Clark. . . . . . . . . . .
572
Heat of Neutralization of Strong Acids by Strong Bases in Mixed Water-Dioxane Solutions. Hidehiko Kid0 and W . Conrad Fernelius.. . . . .
574
Solubility and Thermodynamic Functions of Ethylene in Diethyl Sulfate. A . M . Truchard, H. G. Harris and D . M . Himmelblau. . . . . . . . . . 575
The Equilibrium: 2/3Bi(lj, 1/3BiI, (g) = BiI (g). Daniel Cubicciotti . . . . . . . . . . . . . . . . . .
521
Heat of Solution of Orthophosphoric Acid. Edward P. Egan, Jr., and Basil B. L u f f . . . . . . .
523
C o m m u n i c a t i o n to the Editor
527
Specific Refractive Increment of Polypropylene in a-Chloronaphthalene. N. E. Weston and F. W . Billmeyer, Jr.. . . . . . . . . . . . . . . . . . . . . . . .
Hydrogen Atom Excesses in Some Propane Flames. Robert Reid and Robert Wheeler. . . . . . The Kinetics of the Reactions of Aromatic Hydrocarbons in Sulfuric Acid. 11. Toluene, Pseudocumene and Hemimellitene. Martin Kilpatrick and Max W . Meyer. . . . . . . . . . . . . .
530
The Rate of Reaction of Hydrogen with Nitrogen Dioxide. W . A . Rosser, Jr., and H . W i s e . . . . . .
532
Journal of
Viscoelastic Properties of Polyethylene Oxide in the Rubber-like State. Theodore P. Yin, Stuart E . Love11 and John D . F e r r y . . . . . . . . . . .
534
An Infrared and Isopiestic Investigation of the Interaction between Tri-n-butyl Phosphate and Mono- (2-ethylhexylj-phosphori R. Ferraro and D. F. Peppard. . . . .
539 Symposium: Chemistry 542
Dietary Butyl Ether: Strain Energy and Physical Properties. E . J . Smutny and A . Bondi High Temperature Thermodynamics of the Iron Oxide System. Oliver N . Salmon. . . . . . . . . . . .
160
546
Oxidation-Reduction Mechanisms. Frederick R . Duke . . . . . . . . . . . . . . . . . .
161
550
Crystal Field Theory and Substitution Reactions of Metal Ions. Ralph G. Pearson . . . . . .
164
Notes 560
Interpretation of the Magnetic Resonance Spectrum of the Methylene Group in Certain Unsymmetrically Substituted Compounds. J . S. Waugh and F. A . Cotton.. . . . . . . . . . . . . . . . .
562
D,O Isotope Effects in the Catalytic Activation of Molecular Hydrogen by Metal Ions. J . F. Harrod and J . Halpern. ..........
563
Polarographic and Coulometric Investigations on the Reduction Rate of Cobalt(I1) Ions in.the Presence of Cystine. Emilian B. Weronskz . . .
564
Secondary Processes in Gas Phase Radi Hydrocarbons. Jean H. Futrell . . . . . .
565
567
The Heat Stabilities of Bisacetylacetoneethylenediimine and its Metal Chelates. Robert G. 568 Charles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1 12 A
INDUSTRIAL AND ENGINEERING CHEMISTRY
Introduction.
R . W . Parry
New Selective Reducing Agents. Herbert C. B r o w n . . . . . . . . . . . . . . . . . . 173 Recent Developments in N-F Charles B . Colbc-n. . . . . .
Chemistry.
. . . . . . . 180
Recent Advances in Solid State Inorganic Materials. Otto L. Forchheimer and Terry F. Newkirk.. . . . . . . . . . . . . . . . . .
183
Recent Developments in Metal Carbonyl Syn., thesis. Harold E. Podall . . . . . . . . . 187
Remarks on the Archibald Method of Molecular Weight Determination in the Ultracentrifuge. James M . Peterson and Robert M . Mazo. . . . . . . 566
Reactions of Tritium Atoms with Frozen Hydrocarbons. R. D . Shores and H . C. Moser. . . . . . .
R e c e n t Advances I n Inorganic
. . . . . . . . .
Kinetics of the Reaction between Hydrogen Peroxide and Aquo-(ethylenediaminetetraacetoj cobalt (11)and Evidence for the Formation of a Peroxodicobalt (111,111) Complex. Rachard 556 G. Yalman . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Self-Diffusion of Liquid Meyer . . . . . . . . . . . . . . . .
CHEMICAL EDUCATION April 1961, Vol. 38, No. 4
Potassium Hexafluorophosphate-an Associated Electrolyte. R. A . Robinson, J . M . Stokes and R. H. Stokes.. . . . . . . . . . . . . . . . . . . . . . . . . .
Ice VIII-An Acetone Hydrate? Aruin S. Quist and Henry S . F r a n k . , . . . . . . . . . . . . . . . . . . . . . .
576
570
The Structure and Spectra of Nickel(I1j and Copper(I1) Complexes. W . Manch and W . Conard Fernelius . , , , , . , , . , , . ,
192
Inorganic Infrared Spectroscopy. John R. Ferr a r o . . . . . . . . . . . . . . . . . . . 201 Disposable Plastic Mounts for Radioactive Samples. T . E , Burgess, J . T . Looby, and W . C. Orr . . . . . . . . . . . . . . . . . . . 208 The National Science Fair-International and the ACS Chemistry Awards. Robert M . Brooker and Richard T . Rapala . . . . . . . . . .
209
Division of Chemical Education: Condensed Norms: ACS Cooperative Examinations . . .
210
Proceedings of the California Association of Chemistry Teachers: Gas Chromatography. Robert L. Pecsok . . . . . . . . . . . . . 212 Report of the New England Association of Chemistry Teachers: Ribonucleic Acid and Protein Synthesis. J a y S.Roth. . . . . . . . . . . 217
