BOOKREVIEWS
July 5, 1962
words, the fraction of the book devoted t o ideas developed since 1959 is very small T h e style of writing IS clear, concise and very readable. I t would make a n excellent text-book. T h e printing and paper are of high quality, and i t is essentially- free from errors. There is a definite, but justifiable, lean t o the British work and apparatus, which does not make i t any less useful t o the American reader. It is highly recommended t o the beginning chromatographer or t h e technician who needs more background. DEPARTMEST OF CHEMISTRY ROBERTL. PECSOK UXIVERSITY OF CALIFORNIA L o s ANGELES24, CALIFORNIA Separation of Heavy Metals. B y ANIL I;. DE, D. Phil., Reader in Chemistry, Jadavpur University, Calcutta, India. Pergamon Press Ltd., Headington Hill Hall, Oxford, England. 1961. 308 pp. 16 X 2 3 . 5 cm. Price $9.00. The opening sentence on the inside of the dust jacket is: “This book, the first of its kind, is devoted t o liquid-liquid extraction and deals with the theory and practice of this valuable tool for separation of heavy metals.” However, it is by no means devoted exclusively t o this separations technique, the 91-page section on liquid-liquid extraction being followed by %-page, 37-page and 27-page sections, respectively, on ion-exchange, analytical procedures (classical) and radiochemical separations procedures. Of course this diversity of treatment is not, in itself, bad; b u t the lack of a unifying philosophy of presentation renders the book difficult to read. T h e resultant disjointed effect is heightened by the presence of a n irritatingly large number of “typographical” errors: 0, for Ox ( p . 3 0 ) , making the theoretical treatment difficult indeed; H Q E H P for H D E H P ( p . 66); Szilard-Chalmer’s for SzilardChalmers (consistently); misspelling of the names of prominent workers in the field such a s Hindman ( p p . 106, 189), Maddock(p. 95,96), Dyrssen (pp. 105, 176), etc. The theoretical sections on liquid-liquid extraction and ion-exchange are so sketchy a s t o be of doubtful value; and the “applied” discussions are, in many instances, deficient in detail. For example, pp. 213-219, if the T B P , (nC,HeO)aPO, has not been freed from acidic phosphates (almost certain to be present in the sample as received), the stripping procedure will be totally ineffectual. Nevertheless, the major criticisms may be summarized by saying t h a t too much has been attempted in too few pages. With the exception t h a t exceedingly sparse attention has been given t o amine “liquid ion exchange” systems, the book constitutes a good survey of both liquid-liquid extraction and ion-exchange in the field of metals separations. It‘hereas it will be of limited value t o the separations specialist, it should prove of very real worth to the research worker wishing t o use these techniques as tools and t o the analytical chemist faced with unusual separatiiitis problems. CHEMISTRY DIVISION ARGOXNE NATIONAL LABORATORYDOSALDF. PEPPARD .\RGOSSE, ILLISOIS I
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chemistry. I t s coverage includes chapters on homolytic oxidation processes, hydroxylation of phenols, dextran, diterpenoids and finally tropylium and related compounds. The last of these chapters, written by Professor Sozoe, appeared to me to be of outstanding merit. However, some of the others hardly seemed suitable for inclusion in a series dedicated t o “the policy of presenting critical reviews of some of the major topics of organic Chemistry which are of present interest.” If the chapters do not blend to one man’s punch, it is as much due to the unevenness and lack of care in the treatment as to the variety of topics. The book is not inexpensive. DEPARTMENT OF CHEMISTRY H ARVARD Us IVERSITY CAMBRIDGE 38, MASSACHCSBTTS
E . J . COREY
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Molecular Sieves. B y CHARLESI;. HERSH,Senior Engineering, Xrmour Research Foundxtion of Illinois Institute of Technology, Chicago, Illinois. Reinhold Publishing Corporation, 430 Park Avenue, S e w Ycirk 22, S . Y. 1961. vii 129 pp. 10: X 23 cni. Price, $6.50. This well-printed but brief volume on the so-called “molecular sieves” will serve a useful purpose, because of the growing importance of the synthetic zeolites in industrial and technical processes such as the drying of gases a t both OW and high temperatures, gas separations, ion-eschange and gas chromatograph>-. I t is the only book on the subject wherein M coherent picture of the applications of molecular sieves can be found in a single source. The priiicipal difficulty with this book is its briefness. However, the reviewer stronglJ- recommends this volume to libraries and to individuals interested in the subject, especially those desiring an introductory approach. The brief historial introduction is well-presented aiid accurate. However, the second and fourth chapters on the physical chemistry of adsorption will be or little interest to those familiar with the theory of adsorption or informative t o others. Chapters five to seven represent the heart of the book, and justify its publication, The lack of specific references to the original literature will limit its usefulness to the initiated. but may be justified on the grounds that the book is priniarily directed to the novice. The price is high, cimsidering the number rif pages. Despite some of the obvious short-comings of this book, the reviewer believes that it will serve a useful purpose in stimulating interest in the application of rnolecular sieves to technical problems, and it is recommended on that basis.
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DEPARTMEST OF CHEMISTRY MARSH R I C E I T S I V E R S I T Y HovsTos; TEXAS
\vILLIAM
if.. 0. MILLIGAN
The Chemical and Biological Action of Radiations. \‘iiluiiie 5 . Edited b>- hf. HAISSINSKY. I . Llechanisiu of thc Kadiolysis of \Vater b y Gamma Rays or Electrons. By A. 0. .ILLES.11. ;\ction des Ra>-onsAlpha sur le5 Solutions Aqueuses. By J . PUCHEAULT. 111. Diffusion Kinetics in Radiation Chemistry. By A , LUPProgress in Organic Chemistry. 5. Joint Editors, J. \V. PERWANS. IT.. Mass Spectrometry and Radiation COOK,D. Sc., F.R.S. T%e-Chancellor, University of Exeter. Chemistry. By D. P. STEVENSOS and D. 0. SCHISSLER Fellow of University College, London, and \V. CARAcademic Press, Inc., (London) Ltd., 17 Old Queen Street, RUTHERS, P h . D . , M . R . C . Carcinogenic Substance ReLondon, S.Ll‘. 1, England. 1961. si ‘778 pp. 16.5 X search Unit, Li’ashington Singer Laboratories, Exeter. 24.,5cm. Price, $3.00. Butterworth Inc., 723*5 \\’isconsin Avenue, Lvashington The book is prefaced by a seven page introduction by the 11, D.C. 1961. viii 17% pp. 15 X 21.3 cm. Price, editor which itself provides an excellent review of the book. $9.00. H e discusses unresolved problems and differences of opinioii Most books which gather together an extensive literature in a manner not feasible for the individual authors. on one or more topics in the field of organic chemistrJ- are S o one is better qualified than A . 0. Allen to discuss the useful and valuable even if they leave something to be dedevelopment of the theories used to explain the action of sired. However, at a time when chemists depend so gamma rays or electrons on aqueous systems and to point heavily on the review a s an indispensable instrument for out the areas where research work remains t o be done. This broadening their grasp of the ever-changing and proliferat- he does in an interesting and concise manner in the 20 ing fields of chemical science, one hopes for an emphasis on pages of P a r t I. quality, for a logical selection of topics t o be reviewed a n d In P a r t 11, 53 pages, Pucheault reviews experimental for expert and well-reasoned presentation. T h e latest in the information on the effects in aqueous systems of heavy series of volumes on “Progress in Organic Chemistry,” particles ranging in L . E . T . from high energy protons to low in my opinion, is at best of average quality relative to the energy alpha particles. He also introduces some new various reviews which are currently available in organic ideas to explain and correlate the yields observed in various
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solutions. H e proposes t h a t t h e reactions O H H202, OH HPan,d H Hz02 occur in the neighborhood of the tracks t o a significant extent which varies with nature and concentration of solute and must be considered along with the formation of H , OH, HPand H20~in correlating yields. In the 81 pages of P a r t 111, Kuppermann gives a comprehensive treatment of the application of diffusion kinetics in explaining the action of ionizing radiation in liquid systems. Since the primary chemical entities formed by the radiation are not homogeneously distributed, both time and space variables must be considered in explaining or predicting the reactions of these entities with each other, with solutes present initially and with stable products. Kuppermann and other workers in the field have made much progress in t h e past few years with the help of electronic computers. T h e applicability of diffusion kinetics is shown by comparison of calculations with experimental values. The author suggests that in the future a knowledge of track parameters, diffusion coefficients and rate constants will furnish a complete space-time history of the radiolytic process. In P a r t I V , 100 pages, Stevenson and Schissler present a n excellent discussion of the fundamentals of mass spectrometry with emphasis on information which is useful to radiation chemists. T h e authors treat in detail the processes of ion formation, unimolecular dissociation of ions and ionmolecule reactions in the mass spectrometer. They are careful to point out the limitations in extrapolating from mass spectrometer d a t a t o the effects of ionizing radiation o n gases a t higher pressures. Kadiation chemistry and the chemical aspects of radiobiology are rapidly moving fields of research in which no one author can become familiar with all of the work appearing in the literature. T h e Haissinsky series provides a n important medium wherein experts in specific areas of radiation chemistry and radiobiology summarize the status of their particular areas. T h e present volume maintains the high standards of previous volumes and will be especially welcomed by English-speaking readers since all escept the contribution by Pucheault is in English.
Vol. 84
HERBERT C. BROWS. “Hydroboration.” \V. A. Benjamin, Inc., 2465 Broadway, New York 25, S. Y . 1962. 290 pp. $10.00. HARRISBUSCH. “Xn Introduction t o the Biochemistry of the Cancer Cell.” Xcadetnic Press, Inc., 111 Fifth Avenue, S e w York 3, N.E’. 1962. 424 pp. $13.50. G. CHARLOT,J . BADOZ-LAMBLING A N D B. TREMILLON. “Electrochemical Reactions. The Electrochemicil Methods of .Analysis.” .hierican Elsevier Poblishing Company, Inc,, 52 Vanderbilt Avenue, S e w York 17, S.1’. 196%. 376 pp. $15.03. E. G. D. COHES, Compiled by. “Fundamental Problems in Statistical Mechanics. Proceedings of the S U F F I C International Summer Course in Science a t Sijenrode Castle, The Setherlands, August 1961.” Interscience Division, John Wile)- and Sons, Inc., 440 Park Avenue South, S e w York 16, S. Y. 196%. 249 pp. $7.50. A. S. DAVYDOV.Translated from the First Russian Edition by MICHAELKASHAASD M A XOPPESHEIMER,J R . “Theory of Molecular Excitations.” McGraw-Hill Book Company, Inc., 330 \Yest 42nd Street, S e w York 36, S.I-. 1962. 174 pp. $7.95. ERSEST L. ELIEL. “Stereochemistry of Carbon Compounds.” McGraw-Hill Book Company, Inc , 330 \Vest 42nd Street, S e w Tork 30, S. Y. 1962. 486 pp. $15.00. HIROSHIFUJITA.“Mathematical Theory of Sedimentation Analysis.” Academic Press, Inc., 111 Fifth Avenue, S e w York 3 , N.Y. 1962. 315 pp. $11.00. M. F.JAYLE. Avec la Collaboration de E . E. B A ~ ~ I E0. U, A N D S. H. WEINMAS. Analyse CROP\,, J . POLONOVSKI des Stkroides Hormonauz.” Tome I. “M6thodes Ge+ 6rales.” Masson et Cie., 120, Boulevard Saint-Gerimin, Paris 0, France. 1961. 275 pp. Cartonnetoile de>nisouple, 45 SF. M .F. JAYLE. Xvec la Collaboration de E. E. BAULIEU,0. “AnC R ~ P YP., DESGREZ,K. H E N R YE T K.SCHOLLER. PARMA RESEARCHLABORATORY alyse des StCroides Hormonaus.” Tome 11. “Methodes UNIONCARBIDECORPORATIOS JOHX A. GHORMLEY de Dosage.” Masson et Cie., 120, Boulevard SttintPARMA 30, OHIO Germain, Paris 6, France. 1962. 497 pp. Cartonrlk toile dexni-souple, 80 SF. GEORG KARAGOUNIS.F. c. SACHOD, Translated and Edited by. “Introductory Organic Quantum Chemistr]-.” Academic Press, Inc., 111 Fifth Avenue, Tew York 3, S . E’. 1962. 20-1 pp. 36.50. PAUL. PASCAL, Edited by. “Souveau Trait6 de Chiiiiie Min6rale.” Tome L’. “Zinc- Cadmium-Mercure.” hlasson et Cie., 120, Boulevard Skint-Gerinaih, Paris fi, France. 1962. 966 pp. Rroch6, 170 SF.; Cartonti6 toile, 182 SF. BOOKS RECEIVED PAULPASCAL,Edited by. “Souveau Trait6 de Chiinie M a y 10, 1962-June If), 1962 Minerale.” Tome \.I. “Bore-Xlumi~~utt~-Galliu~~~.I. C. XLLISOS, B. B. BRODIE,F. LYSES, A . I . OPARINA N D Indium-Thalliuin.” hlass(in et Cie , 120, Boulevard E’. ZOTTERMAN,Regional Editors. “Life Sciences.” Sttint-Germaih. Paris 0, France. 1961. 10:N pi^. Surnber 1. January 1962. Pergatnon Press, Ltd., Broch6, 160 SF.; Cartonne toile, 172 SF. Headington Hill Hall, Oxford, England. 1962. 34 pp. Subscription rates: 530.00 (libraries); $10.00 (private I
