Thiolate-Induced Structural Reconstruction of Gold Clusters Probed by

We investigated the structures of a series of glutathionate-protected gold clusters, Aun(SG)m with n = 10−45, using 197Au Mössbauer spectroscopy, w...
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Published on Web 05/17/2007

Thiolate-Induced Structural Reconstruction of Gold Clusters Probed by Mo1 ssbauer Spectroscopy

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Kazuhiro Ikeda,† Yasuhiro Kobayashi,‡ Yuichi Negishi,§ Makoto Seto,‡ Takeshi Iwasa,§ Katsuyuki Nobusada,§ Tatsuya Tsukuda,*,§ and Norimichi Kojima*,§,† Graduate School of Arts and Sciences, The UniVersity of Tokyo, Tokyo 153-8902, Japan, Research Reactor Institute, Kyoto UniVersity, Kumatori, Osaka 590-0494, Japan, and Institute for Molecular Science, Myodaiji, Okazaki 444-8585, Japan Received March 14, 2007; E-mail: [email protected]; [email protected]

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