This unique new source of aldehyde groups gives you an infinite

Nov 6, 2010 - DOI: 10.1021/cen-v037n039.p033. Publication Date: September 28, 1959. Copyright © 1959 AMERICAN CHEMICAL SOCIETY. ACS Chem...
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SUMSTART First commercially available polymeric

dialdeiiyde

H-CH I CHO

1 CH2OH

This unique new source of aldehyde groups gives you an infinite range of cross-linking possibilities SUMSTAR is our tradename for the first poly­ meric dialdehyde ever offered commercially. S U M S T A R opens up limitless possibilities for new products and modifications of your present products. A wide variety of materials, both syn­ thetic and natural, can be cross-linked to varying degrees using SUMSTAR. Originally developed by She U.S.D.A.'s Northern Utilization Research and Development Division, the process has been adapted for manu­ facture by Miles Chemical Company. SUMSTAR can be described as a polymeric dialdehyde produced by the oxidation of corn­ starch. The highly specific periodate ion breaks the carbon-to-carbon bond between C2 and Ο of the anhydroglucose units of the starch molecule forming two aldehyde groups. The extent of oxi­ dation is carefully controlled. Currently we offer three grades as indicated below. SUMSTAR is a fine powder, nonvolatile, and virtually odorless. Its acute toxicity is only a small fraction of that of other commercially available aldehydes. Here are the specifications: S U M S T A R - S . . . over 90% oxidized S U M S T A R - R. . . 75-80% oxidized S U M S T A R - J . . . 50% oxidized W a t e r Content: Less than 10%

SUMNER

A

Heavy Metals: Average less than 10 p.p.m. S u l f a t e d Ash: l % - 2 % B u l k Density: 45 to 55 ml./oz.

Unusually versatile SUMSTAR is so new that the full range of its usefulness is still being deter­ mined. However, work in progress indicates ex­ cellent possibilities in: a d h e s i v e s — for laminates l e a t h e r — tanning

t e x t i l e s — crease resistance and waterproofing p l a s t i c s — n e w polymers p a p e r — increase in wet strength

Current information on S U M S T A R is now available in our bulletin No. 6-129 which we will be pleased to send you. Samples are available upon request, and production in pilot plant quantities is now under way. Full-scale commer­ cial p r o d u c t i o n will, of c o u r s e , p e r m i t price reductions which will make SUMSTAR a re­ markably low-cost polymer with high aldehyde content. Coming soon: bisulfite, urea, and meiamine derivatives. Bulletin and samples For Miles bulletin No. 6-129 and sample quanti­ ties, write, wire, or call us.

Miles Clieixiicol Company CHEMICALS

DIVISION O F M I L E S L A B O R A T O R I E S , INC., E L K H A R T , I N D I A N A General S a l e s O f f i c e : E l k h a r t , I n d i a n a , T e l e p h o n e J A c k s o n 3 - 1 1 3 0 or C l i f t o n , N e w J e r s e y — P R e s c o t t 9 - 4 7 7 6 o r New Y o r k - M U r r a y Hill 2 - 7 9 2 0 W e s t C o a s t A g e n t : B. W H o l m e s , L a C a n a d a , C a l i f o r n i a — M U r r a y 1 - 5 7 2 3