6A Chemical Reviews, 1999, Vol. 99, No. 4
To Appear in CHEMICAL REVIEWS, Vol. 99, No. 5 Nature of the Electronic Factor Governing Diastereofacial Selectivity in Some Reactions of Rigid Saturated Model SubstratessWilliam Adcock and Neil A. Trout, The Flinders University of South Australia. Inductive and Resonance Effects of Substituents on π-Face SelectionsAndrzej Stanislaw Cieplak, Yale University, and State University of New York at Stony Brook. Using Perturbation and Frontier Molecular Orbital Theory to Predict Diastereofacial SelectivitysJ. J. Dannenberg, City University of New York. Structure Distortions in Heteroatom-Substituted Cyclohexanones, Adamantanones, and Adamantanes: Origin of Diastereofacial SelectivitysBenjamin W. Gung, Miami University. Face Selection in Addition and Elimination in Sterically Unbiased SystemssMira Kaselj, Wen-Sheng Chung, and William J. le Noble, State University of New York at Stony Brook, and National Chiao Tung University. The Concept of Transient Chirality in the Stereoselective Synthesis of Functionalized Cycloalkenes Applying the Retro-DielssAlder MethodologysAntonius J. H. Klunder, Jie Zhu, and Binne Zwanenburg, University of Nijmegen. Catalytic Entantioselective Addition to IminessShu Kobayashi and Haruro Ishitani, The University of Tokyo. Diastereoselection in Lewis-Acid-Mediated Aldol AdditionssRainer Mahrwald, Humboldt Universita¨t. Electronic Control of Facial Selection in Additions to Sterically Unbiased Ketones and OlefinssGoverdhan Mehta and Jayaraman Chandrasekhar, University of Hyderabad, Indian Institute of Science, and Jawaharlal Nehru Centre for Advanced Scientific Research. Around and beyond Cram’s RulesAnne Mengel and Oliver Reiser, Universita¨t Regensburg. Orbital-Controlled Stereoselections in Sterically Unbiased Cyclic SystemssTomohiko Ohwada, Nagoya City University, and The University of Tokyo. Synthesis and Diastereoselective Reactions of N,N-Dibenzylamino Aldehydes and Related CompoundssManfred T. Reetz, Max-Planck-Institut fu¨r Kohlenforschung. The Exterior Frontier Orbital Extension ModelsShuji Tomoda, The University of Tokyo Neucleophilic Additions to 4,4-Disubstituted 2,5-Cyclohexadienones: Can Dipole-Effects Control Facial Selectivity?sPeter Wipf and Jae-Kyu Jung, University of Pittsburgh.