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Tunable Electrochemistry via Controlling Lattice Water in Layered Oxides of Sodium-ion Batteries Kai Zhu, Shaohua Guo, Qi Li, Yingjin Wei, Gang Chen, and Haoshen Zhou ACS Appl. Mater. Interfaces, Just Accepted Manuscript • DOI: 10.1021/acsami.7b09658 • Publication Date (Web): 22 Sep 2017 Downloaded from http://pubs.acs.org on September 23, 2017
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ACS Applied Materials & Interfaces
Tunable Electrochemistry via Controlling Lattice Water in Layered Oxides of Sodium-ion Batteries Kai Zhu,
a,c
Shaohua Guo, a,b* Qi Li,b Yingjin Wei,c Gang Chen,c and Haoshen Zhou
a,b*
a, National Laboratory of Solid State Microstructures & Department of Energy Science, Nanjing University. E-mail:
[email protected];
[email protected]; b, Energy Technology Research Institute, Institution National Institute of Advanced Industrial Science and Technology (AIST) c, Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University. Abstract Layered oxides based on abundant elements have been extensively studied as cathodes of sodium-ion batteries. Among them, Birnessite-type sodium manganese oxide containing lattice water meets the low-cost and high-performance requirement for stationary batteries. Herein, we for the first time present the controllable states of lattice water via adjusting the cut-off voltages, effectively enhancing the reversible capacity, cycling stability and rate ability of the materials. The current investigation not only highlights the significance of intercalated lattice water for reversible Na-(de)insertion of Birnessite as well as other similar compounds, but also opens up new opportunities for advanced cathode materials for sodium storage.
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ACS Applied Materials & Interfaces
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Introduction Lithium-ion batteries (LIBs) have become the essential to the development of portable electronic devices such as smart phone, laptop and the (hybrid) electric vehicles.1 Moreover, they have been integrated into large-scale energy storage system (LESS) for the renewable and clean energy sources such as wind and solar. However, considering the increasing market of the portable electronic devices and the limited availability of lithium, the growing price of LIBs makes them less suitable for the application of LESS. Recently, sodium-ion batteries (SIBs) have attracted lots of attention due to the advantages of natural abundance of sodium and low cost.2-5 Meanwhile, sodium owns the similar chemical properties with lithium, which leads to the identical fundamental principles of SIBs and LIBs. Thus SIBs are considered as a smart and promising choice for the LESS and exploring capable electrode materials become the key issue of the development of the SIBs.6 So far, transition metal oxides NaxMeO2 (0
