Subscriber access provided by UB + Fachbibliothek Chemie | (FU-Bibliothekssystem)
Article
Ecological network analysis for a virtual water network - a case study of the Heihe River Basin Delin Fang, and Bin Chen Environ. Sci. Technol., Just Accepted Manuscript • DOI: 10.1021/es505388n • Publication Date (Web): 04 May 2015 Downloaded from http://pubs.acs.org on May 13, 2015
Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.
Environmental Science & Technology is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.
Page 1 of 35
Environmental Science & Technology
Ecological network analysis for a virtual water network - a case study of the Heihe River Basin Delin Fanga, Bin Chena,*,§ a
State Key Joint Laboratory of Environmental Simulation and Pollution Control, School of Environment, Beijing Normal University, Beijing 100875, P R China
1 2
ABSTRACT
3
The notions of virtual water flows provide important indicators to manifest the water
4
consumption and allocation between different sectors via product transactions. However, the
5
configuration of virtual water network (VWN) still needs further investigation to identify the
6
water interdependency among different sectors as well as the network efficiency and stability in a
7
socio-economic system. Ecological network analysis is chosen as a useful tool to examine the
8
structure and function of VWN and the interactions among its sectors. A balance analysis of
9
efficiency and redundancy is also conducted to describe the robustness ( RVWN ) of VWN. Then,
10
network control analysis and network utility analysis are performed to investigate the dominant
11
sectors and pathways for virtual water circulation and the mutual relationships between pairwise
12
sectors. A case study of the Heihe River Basin in China shows that the balance between efficiency
13
and redundancy is situated on the left side of the robustness curve with less efficiency and higher
14
redundancy. The forestation, herding and fishing sectors and industrial sectors are found to be the
15
main controllers. The network tends to be more mutualistic and synergic, though some
16
competitive relationships that weaken the virtual water circulation still exist.
17
Keywords: Network analysis, Robustness, Virtual water network, Heihe River Basin
ACS Paragon Plus Environment
Environmental Science & Technology
18
1. INTRODUCTION
19
Unreasonable water circulation has escalated water exploitation and exhaustion and even
20
intensified the irrational water wastage in socio-economic systems.1,2 It is necessary to explore the
21
efficient and stable management of the socio-economic water system to meet the increasing water
22
demand for the rapid economic growth, population explosion and urbanization, particularly for
23
regions or countries prone to severe droughts.3-6
24
The notion of virtual water flows has been introduced to provide a useful indicator to
25
investigate the water allocation and circulation in a socio-economic system.7-9 Allan (1993)
26
initially proposed the concept of virtual water to evaluate the total volume of water required
27
during a commodity or service production process, in order to ameliorate the water deficit
28
problem in the Middle East.10,11 The methods for the evaluation of virtual water flows can be
29
sorted into two categories including bottom-up approach based on the detailed information about
30
the water footprint calculation,7,12,13 and top-down approach based on input-output table.14-16 The
31
bottom-up method evaluates the virtual water via accounting the water used throughout the
32
production of a good and the related international trade.17-19 Because of the merits of
33
comparatively reliable data collection, this approach has been employed in several researches.20,21
34
Nevertheless, such bottom-up approach does not trace the virtual water flows through the supply
35
chain in the trade network, which is critical to allocate the responsibility to the intermediate and
36
final users.14 Environmental input-output analysis (EIOA) as a top-down approach may describe
37
the supply chain effects in a comprehensive perspective and distinguish the responsibilities of
38
final users and promote to discover the driving forces.22,23 Furthermore, it can investigate the
ACS Paragon Plus Environment
Page 2 of 35
Page 3 of 35
Environmental Science & Technology
39
virtual water circulation through sectoral, regional, national and global supply chain to identify the
40
water importer or exporter, and further to facilitate the redistribution of water.22,24-29 The
41
discriminations of water scarcities in different regions can also be taken into consideration via
42
EIOA.15,30-37
43
There are still few studies on stability issues of the virtual water flows from the perspective
44
of the systematic configuration,38,39 which should be further explored to describe the network
45
structures of inner interactions and distribution of water resources throughout the socio-economic
46
system. Ecological network analysis (ENA), introduced by Hannon in 1973, aims to investigate
47
the interdependence of species and functional groups and determine the distribution of both direct
48
and indirect ecological flows in an ecosystem, thus providing a powerful tool for investigating the
49
internal structure of the virtual water flows.40 Ulanowicz introduced information theory into
50
ecological network analysis and presented a uniform way to quantify system’s effective
51
performance (efficiency) and reserve capacity (redundancy) with a robustness metric to signify the
52
tradeoff allotment.41-44 Bodini et al employed information-based ENA to evaluate water exchanges
53
between different sectors and investigate the sustainability of water resources by measuring the
54
system efficiency and flexibility.45,46 Li et al. used information-based ENA to analyze the water
55
system’s structures and the intensity of synthesized water use intensity and to investigate the
56
sustainable systems based on the optimal balance between network efficiency and resilience with
57
consideration of complex socio-economic characters.47,48 Furthermore, Kharrazi et al. applied this
58
approach to quantify the robustness of economic resource trade flow networks including virtual
59
water, oil, world commodities and so on, incorporating both intensity and extensive dimensions of
ACS Paragon Plus Environment
Environmental Science & Technology
60
sustainability.49 Meanwhile, Patten et al. and Finn developed a line of flow-based ecological
61
network analysis,50,51 which has been successful in evaluating the direct, indirect and cycling
62
flows of an ecosystem’s energy and materials and the mutual relationships between compartments
63
from a whole system perspective. 52-56 The flow-based ENA, including network control analysis
64
(NCA) and network utility analysis (NUA), has also been employed in the water system analysis
65
to investigate the network’s structure and function via water circulation and mutual relationship
66
analyses to show the interdependence and interactions between different sectors.57-59 Yang et al.
67
also adopted NCA and NUA to identify the quantitative control or dependency relations, describe
68
the mutual relation and distinguish the beneficiary and the contributor regions/countries in the
69
global virtual water network based on agricultural and livestock production trade.58
70
A virtual water network (VWN), shaped by virtual water flows circulating in the
71
socio-economic system, needs to maintain itself in the long term under varying conditions, which
72
can be assessed in terms of the network flows between compartments.48,60-63 The tracking of
73
virtual water fluxes and pathways within the system will facilitate the regulation of virtual water
74
circulation and the adjustment of the sectors’ responsibilities. Moreover, the identification of
75
systematic configuration is critical to keep the balance of the efficiency and redundancy of VWN.
76
The efficiency of VWN represents the capacity to perform within a sufficiently organized structure
77
to maintain its integrity over time. However, the most efficient flow structure, one that has no
78
option for parallel pathways, sometimes puts the VWN into a brittle situation when facing with
79
perturbations. For instance, with the disappearance of nodes, the VWN will show little ability to
80
sustain its original function. Conversely, virtual water systems featuring more parallel circulation
ACS Paragon Plus Environment
Page 4 of 35
Page 5 of 35
Environmental Science & Technology
81
pathways, including some weaker pathways (transferring flows with less amount of virtual water),
82
will have a flexible reserve as redundancy to cope with internal and external changes, though
83
sacrificing efficiency.49,60,61 The whole system is dominated by relatively few strong flows with a
84
multitude of weak connections providing the safety margin for efficient virtual water circulation.62
85
Information-based ENA can highlight the balance between both efficiency and redundancy on a
86
system level and achieve a sustainable VWN. Furthermore, the flow-based ENA method can also
87
penetrate deeply into the sector and pathway level via NCA and NUA to investigate the control
88
and dependent sectors, dominant and weaker pathways, and pairwise relations.55,58,56-66 It is
89
therefore useful to combine two lines of ENA with a system-based view to deepen the
90
understanding of VWN.
91
This paper is organized as follows: Section 2 emphasizes the methodology, including the
92
ENA model, system robustness analysis covering efficiency and redundancy facets, network
93
control and utility analysis. Section 3 illustrates the analysis results of the Heihe River Basin, such
94
as the calculations of system robustness, and the control and utility conditions of VWN. The last
95
section offers discussion of a range of model results.
96
2. MATERIALS AND METHODS
97
2.1 Construction of the VWN model
98
A steady state model of the VWN is developed to illustrate the inter-compartmental flows,
99
mutual relationships and network configuration from the perspective of ENA. Water resources IO
100
model is established based on the basic economic IO model framework via incorporating with
ACS Paragon Plus Environment
Environmental Science & Technology
Page 6 of 35
101
statistical data about water consumption of each sectors (see Sec. 2.6 of SI). The intermediate
102
input/use matrix of water resources IO model shows a clear image of virtual water trade. The
103
VWN is established based on this intermediate input/use matrix, which reflects the virtual water
104
trade hidden in the production transactions in the socio-economic system. A steady-state system
105
meets the requirement that, for each sector of the system, the total inputs equal the total outputs
106
including both inter-sector flows and boundary flows, 66 i.e.,: n
107
i 1
n
fij y j f ji z j
(1)
i 1
108
In the VWN model (Fig. 1b), fij stands for the virtual water trade flows (m3 yr-1)
109
originating from compartment j to compartment i, i.e., virtual water flows produced by
110
compartment i and consumed by compartment j. fij only contains direct virtual water flows
111
among sectors with the direction from the production side (matrix column) to others on the
112
consumption side (matrix row). z k represents the boundary inputs of compartment k (fresh
113
water), while yk is the boundary outputs (virtual water of net exports).
114
2.2 Information-based ENA
115
The indicators of information-based ENA can show a system’s efficiency and
116
redundancy.49,60-62,67,68 The ascendency, which stands for VWN efficiency, shows how well
117
organized these water flows are. For example, a VWN with larger water flows along fewer
118
pathways will have a higher ascendency. The redundancy shows the ability of a system to
119
withstand perturbations. For example, a VWN where all water flows are equally distributed along
120
all pathways will have a higher redundancy. The efficiency and redundancy are mutual
121
complements of system robustness. The indicator of robustness is used to identify the balance
ACS Paragon Plus Environment
Page 7 of 35
Environmental Science & Technology
122
between the system’s efficiency and redundancy, which is essential for a system’s vitality. Below
123
is a brief explanation of this method. A more detailed description of the method is provided in the
124
Supplementary Information (SI).
125
2.2.1 Efficiency analysis for network organization
126
The average mutual information (AMI) of a system shows the network’s capacity to perform
127
in an efficient and well-organized way to keep its integrity over the long term, which is adopted to
128
indicate the efficiency of a system from the structural perspective. AMI measures how much
129
knowing one of these variables reduces the uncertainty about the other. In a VWN, it stands for the
130
efficient end-to-end virtual water flows, which is crucial to catalyze the system’s operation and
131
progression. The total system throughput of virtual water resources ( T.. ) includes the first order
132
virtual water flows (m3 yr -1) transported among all sectors (only direct flows), i.e., the sum over all
133
combinations of fij . T. j stands for the flows originating from sector j, and Ti. represents the
134
T. j T flows flowing into sector i. r b j = and r ai = i. are the ratio of flows originating T.. T..
135
from sector j to total system throughput and the ratio of flows streaming into sector i to total
136
f system throughput, respectively. r (ai , b j )= ij is the ratio of flows originating from sector j T..
137
to sector i to total system throughput. AMI is defined as follows:
138
r (ai , b j ) AMI K r (ai , b j ) log r (a )r (b ) i, j j i fij fijT.. K log T T i , j T.. i. . j
139
where T.. fij , Ti. fij , T. j fij , and K is the scale coefficient. j
(2)
i
ACS Paragon Plus Environment
Environmental Science & Technology
Page 8 of 35
140
The non-scaled AMI (i.e., K = 1) stands for the system’s authentic efficiency only from the
141
structural perspective, which is not correlated with the size of the system, i.e., the amount of
142
virtual water circulation. A VWN with high AMI value means that the flows within the network
143
are more concentrated with fewer dispersion pathways, indicating it is better organized with
144
higher efficiency. AMI scaled by T.. covers not only the intrinsic structure character of the system,
145
but also the dimension of the system. To clearly describe the diversification of the intrinsic
146
structure character, scaled AMI is not mentioned in the main text but used as gauge for system
147
efficiency in the Sec.2.2 of Supporting Information to address the size issues.
148
2.2.2 Redundancy analysis for network organization
149
The residual uncertainty stands for the unorganized part of the VWN, which is used to
150
evaluate the redundancy of the network. The high diversity and connectivity of a VWN guarantees
151
that the system will reserve diverse actions when encountered with the disruption of notes or
152
linkages. When faced with internal and external changes, the inefficient and indeterminate part of
153
the virtual water flow structure is insurance for the VWN to reduce the chance of collapse (see Sec.
154
2.1 of SI). The redundant pathways show the unconfirmed virtual water flows in the system,
155
which provide excess options to dissipate weak throughput via various inefficient sectors. In
156
information-based network analysis, the virtual water system residual uncertainty H c is defined
157
as follows:
158
1 H c K r (ai , b j ) log r (a )r (b ) i, j j i 2 fij fij K log T T i , j T.. i. . j
ACS Paragon Plus Environment
(3)
Page 9 of 35
Environmental Science & Technology
159
Similar to AMI and ascendency, H c shows the residual uncertainty only from the authentic
160
structural perspective with the scale coefficient K = 1. Redundancy displays the amount of wasted
161
“space” used to transmit certain water flows in a VWN. However, too many parallel pathways
162
make the VWN inefficient and cause some virtual water to flow along less efficient pathways. The
163
scaled H c covering with system dimension conceals the intrinsic alternation of system structure,
164
so it is not chosen as the chief indicator. The explanation of scaled H c is given in Sec. 2.3 of SI.
165
2.2.3 Virtual water network robustness ( RVWN )
166
The system robustness is concerned with the balance between a system’s efficiency and
167
redundancy, measuring both how streamlined and articulated the system is and the possibility for
168
alternate flow paths, which are useful in case of internal and external changes.61,62 The virtual
169
water network robustness ( RVWN ) measurement can be derived from the indicators of efficiency
170
and redundancy as follows. A relative measurement of the organized power flowing within the
171
VWN, namely, the proportion of development capacity accounted for by the order degree (a, i.e.,
172
relative efficiency), is denoted by the following formula:
173
a AMI / ( AMI H c )
(4)
174
The RVWN depends on both the order and disorder of the system. The order part can be
175
derived from the relative order (i.e., a), and the disorder part can be measured by the Boltzmann
176
formulation (i.e., k log(a ) ). Based on this result, the VWN interprets the balance between
177
efficiency (AMI) and redundancy ( H c ) as a single metric to show the degree of constraint and
178
degree of freedom in the system. 41,49 The RVWN is defined as follows:
179
RVWN -a log(a)
(5)
ACS Paragon Plus Environment
Environmental Science & Technology
Page 10 of 35
180
The curve of RVWN is shown in Fig. S1 to illustrate the trade-off relationship between
181
system efficiency and redundancy (see Sec. 2.2 of SI). The x axis shows the ascendency portion of
182
the development capacity. If the indicator lies on the left side of the curve, the VWN is stagnant
183
with less efficiency and more redundancy. If the indicator lies on the right side of the curve, the
184
VWN is brittle and easily collapses in the face of internal or external changes because too much
185
efficiency sacrifices the redundancy of the VWN.
186
2.3 Network control analysis (NCA)
187
Network control analysis (NCA) is adapted to evaluate the dominance of one sector over
188
another via pairwise environs. The distributed control matrix is defined to explain the influence of
189
one sector exerted on another within the overall system configuration, which is featured by the
190
integral flow. 55,56,56,69 The integral flow matrix is defined as N and N’, which includes both the
191
direct and indirect flows through the system:66
192
N [nij ] (I G)1 N' [nij1 ] (I G' )1
193
where G [ gij ] , gij fij / T. j ; G' [ gij' ] , and gij' fij / Ti. . Based on this equation, the control
194
difference matrix (CD) and dimensionless control ratio matrix (CR) can be defined to facilitate
195
the explanation of pairwise individual comparisons of the fractional transfer water values
196
considering both the direct and indirect effects:56
197
CD [cdij ] [nij n ji ]
(7)
198
nij n ji ] nij n ji 0, crij [ max(nij , n ji ) CR [crij ] n n 0, cr 0 ji ij ij
(8)
199
where cdij and crij indicate the control influence of compartment j on compartment i via the
ACS Paragon Plus Environment
(6)
Page 11 of 35
Environmental Science & Technology
200
integral system flows. If the CD value is positive, it stands for the control intensity; otherwise, it
201
shows the dependent intensity. CR is a non-dimensional matrix with a value between 0 and 1. If
202
the value is closer to 1, this pairwise relationship has a definite direction; otherwise, the control
203
pairwise relationship is weaker. Accordingly, the stronger or weaker control relations will be
204
reflected on the pathways. Thus, if the crij is closer to 1, the pairwise pathway can be defined as
205
a stronger pathway with definite direction. On the contrary, if the value is closer to 0, the pathway
206
can be described as a weaker pathway with uncertain directions as the two directions have
207
relatively equal strength. Furthermore, the mean value of positive crij (μ = Mean ( crij ), crij >0))
208
and standard deviation of positive crij (σ = Standard Deviation ( crij ), crij >0)) can be used to
209
identify the control power condition of the system.
210
Because the magnitude of the control difference values are additive, the sector magnitude of
211
control weighing can be evaluated by summing the rows of the CD matrix.56 The system control
212
vector matrix (SC) can thus be given as follows:
213
SC [sc j ] [ cdkj ]
n
(9)
k 1
214
where the subscript j represents the specific donor compartment. If the value of sc j is positive,
215
the focal sector j controls the system; otherwise, it is controlled by the system. Supported by the
216
NCA, the dominant sectors and strong linkages along with the dependent sectors and weaker
217
linkages can be identified.
218
2.4 Network utility analysis (NUA)
219
Network utility analysis (NUA) is used to evaluate the mutual relationships between different
220
sectors in the VWN. The mutual benefit between compartments is evaluated via a matrix of
ACS Paragon Plus Environment
Environmental Science & Technology
Page 12 of 35
221
mutualism.70,71 The direct mutualism evaluates the direct relationship between compartments with
222
a direct utility matrix D:
223
D dij [
224
where dij is the inter-compartmental flow utility and Ti is the sum of flows in or out of sector i
225
when the system is at steady state. The integral mutualism considers both direct and indirect
226
effects encompassing the integral effects hidden in the system, interpreted via the integral utility
227
matrix U:
228
U D0 D1 D2
229
where D0 stands for the initial flows, D1 for the direct utility relation, and Dn for the direct
230
utility relationships realized by the extended flow pathways.
fij f ji Ti
]
(10)
Dn
(I - D)1
(11)
231
The relationships between different economic sectors can be identified through the
232
positive/negative signs of the mutualism index. In terms of the two opposite directions, there are
233
always two signs for each pair of compartments in the D and U matrices. The sign matrix of D and
234
U, i.e., SignD and SignU, facilitates the interpretation of the inner relationships between pair
235
compartments. In the two sign combinations of pair sectors, (+,+) stands for a mutualistic
236
relationship, (+,–) for an exploitative relationship, (–,+) for an exploited relationship, and (–,–) for
237
a competitive relationship (more information is shown in Sec. 2.4 of SI).70 Because U matrix
238
shows the integrated mutual relationships including both direct and indirect influences, only U
239
matrix is chosen to exhibit the system mutual utility condition.
240 241
From a systematic perspective, the network mutualism index (NM) and network synergism index (SI) can be used to determine the fitness of the current VWN:65,70
ACS Paragon Plus Environment
Page 13 of 35
Environmental Science & Technology
242
NM SignU () / SignU ()
243
SI uij
n
(12)
n
(13)
j 1 i 1
244
where the NM is the ratio of the number of positive signs over the number of negative signs in U.
245
SI assesses the magnitude of the positive and negative relationships of a system. If the positive
246
signs are in the dominant position, (i.e., NM > 1 and SI > 0), the system is mutualistic. If not, some
247
negative or problematic pathways should be modified or mitigated.58,65
248
2.5 Study site and data
249
The Heihe River Basin is the second largest inland river basin in the arid region of northwest
250
China, covering an area of approximately 128,000 km2 with an altitude of 4300 m and annual
251
normal runoff of 1.58×109 m3. The location of the Heihe River Basin is illustrated in Fig. 1a. With
252
rapid socio-economic development and increasing population density, the unreasonable water
253
utilization structure in the middle regions of the Heihe River Basin leads to an extensive
254
exploitation of water resources. The Ganzhou District, which is chosen as a case study, is one of
255
the most developed regions in the middle region of the Heihe River Basin, with intensive
256
agricultural activities as the main economic contributor. The VWN is established on EIOA model
257
based on the data from Gansu Statistical Yearbook 2012, Zhangye Statistical Yearbook 2012 and
258
the work of Zhang (more information about data sources are shown in Sec. 2.6 of SI).72-74 In this
259
paper, the VWN of the Ganzhou District is aggregated into six economic sectors, each of which
260
consists of a block of sectors with similar water use habits, to manifest the virtual water
261
circulation (see Fig. 1b). This aggregation of sectors allows us to distinguish the pairwise
262
relationship between similar sectors as a block and the other remaining blocks, without having to
ACS Paragon Plus Environment
Environmental Science & Technology
Page 14 of 35
263
aggregate more than is required by the available data. 30 The sectors include (1) Farming (Far), (2)
264
Livestock (Liv), (3) Forestation, Herding and Fishing and related activities (FHF), (4) Industrial
265
(Ind), (5) Construction (Con) and (6) Services (Ser). The investigation time ranges from 2002 to
266
2010.
z1
y1
1 Far f61 z6
y6
f12 f16
f34
f62 6 Ser
f65 f64
2 Liv f24
f32
f23
f41 f14 f53
5 Con
z5
y2
f42
f36 f46
y5
z2
f21
f26 f63
f56
f43
f54
3 FHF f43
f45
f34
y3
z3
4 Ind y4
z4
267 268
(a)
(b)
269 270
Fig. 1 Virtual water network model for Ganzhou District in the Heihe River Basin.
271
Notes: fij : Virtual water flows from j to i. yk : Boundary outputs for k. zk : Boundary inputs for
272 273
k.
274
3. RESULTS
275
3.1 Calculation of RVWN
276
3.1.1 Average Mutual Information (AMI)
(a) Study site, (b) Virtual water network model
277
The results of AMI representing the system efficiency are shown in Fig. S3. The AMI reaches
278
a peak value of 0.053 in 2007, implying that the virtual water flows are highly concentrated with
ACS Paragon Plus Environment
Page 15 of 35
Environmental Science & Technology
279
clear directions and the system efficiency is at its highest; however, in 2002, the AMI value is at its
280
lowest with a value of 0.031 because the virtual water flows are relatively evenly distributed,
281
providing less room for specialization and indicating that the flow distribution along the pathways
282
between different sectors influences the AMI of the VWN. The results of scaled AMI are shown in
283
Sec. 3.2 of SI.
284
3.1.2 Residual uncertainty ( H c )
285
The values of H c representing the redundancy during 2002-2010 (see Fig. S5) range
286
between 0.2 and 0.4; H c declines to its lowest value in 2005 and increases to its highest value of
287
0.391 in 2008. The even distribution of virtual water flows means the network system has more
288
options to deliver water flows, which improves the system’s capacity to keep stable when faced
289
with internal or external changes. The results of scaled H c are shown in Sec. 3.3 of SI.
290
3.1.3 Degree of order (a) and RVWN
0.4 0.35 0.3
RVWN
0.25 0.2 0.15 0.1 0.05 0
291 292
Redundancy 0
0.1
0.2
0.3
Efficiency 0.4
0.5
0.6
0.7
0.8
0.9
a Fig. 2 The relationship between a and RVWN in the VWN
ACS Paragon Plus Environment
1
Environmental Science & Technology
Page 16 of 35
293 294
The calculation results of a are shown in Fig. S7, which is affected by the combination of
295
AMI and H c . The relationship between a and RVWN is depicted in Fig. 2. From 2005 to 2007, the
296
VWN has the highest a and RVWN values, indicating that the VWN is well organized with more
297
regularity and orderliness compared with the VWN in other phases. All of the RVWN dots are
298
scattered on the left side of the robustness curve, demonstrating that the VWN is characterized by
299
higher redundancy and lower efficiency.
300
3.2 NCA for the VWN
Control and Dependence Intensity
8.0E-5
Far Liv FHF Ind Con Ser
6.0E-5 4.0E-5 2.0E-5 0.0 -2.0E-5 -4.0E-5 -6.0E-5 2002
2003
2004
2005
2006
2007
2008
2009
2010
Year
301 302 303 304 305
Notes: Dots above the horizon line (the dotted line) mean the sector is the controller of the system;
306
The system control or dependence intensity of each sector is shown in Fig. 3 based on the
307
results of the SC matrix. Before 2008, the control intensity of each sector is spread in a large scale,
308
while the distribution trend significantly converges afterward. This observation indicates that the
Fig. 3 The system control or dependence intensity of each sector otherwise, the sector is dominated by other sectors.
ACS Paragon Plus Environment
Page 17 of 35
Environmental Science & Technology
309
control powers of all of the sectors are comparatively equally distributed, and the system is not
310
controlled by single or minor sectors.
311
From 2002 to 2004, Ind is the largest controller of the VWN. However, the situation changes
312
from 2005 to 2007, when the dominant sector became FHF. From 2008 to 2010, Ind becomes the
313
controller again. As for the dependents, the value of Con is always below the horizon line in a
314
large scale, especially from 2002 to 2007, which indicates that Con is the major dependent in the
315
VWN. The variation curves of FHF, Ind and Ser shows sudden changes from 2005 to 2007.
316
During this period, FHF becomes the dominant controller. Meanwhile, Ind loses its position of
317
major controller in the VWN, as it is before and after this period. Ser turns into a dependent that
318
received virtual water from other sectors, and then becomes a controller again from 2008 to 2010.
319
The change tendencies of the dependence of Con and Liv are similar, where the dependence
320
intensity on other sectors declines. Far’s dependence strength declines from 2002 to 2007, and it
321
becomes a controller from 2008 to 2009. μ = 0.704
σ = 0.266
μ = 0.763
σ = 0.253 1
Far
0.9
Far
0.8 Liv
0.7 0.6
FHF
0.8 Liv FHF
0.6
Ind
0.4
0.5 Ind
0.4 0.3
Con
Con 0.2 0.1
Ser Far
Liv
FHF
Ind
Con
Ser
0.2 Ser Far
Liv
FHF
Ind
(b) 2003,2004
(a) 2002
ACS Paragon Plus Environment
Con
Ser
0
Environmental Science & Technology
μ = 0.887
σ = 0.166
Page 18 of 35
μ = 0.808
σ = 0.231
1
Far
Far
0.9 0.8
0.8
Liv
Liv
0.7 FHF
0.6
FHF
Ind
0.4
Ind
0.6 0.5 0.4 0.3
Con
Con
0.2
0.2
0.1
Ser
Ser Far
Liv
FHF
Ind
Con
(c) 2005,2006,2007
Ser
0
Far
Liv
FHF
Ind
Con
Ser
0
(d) 2008,2009,2010
322 323 324 325 326
Notes: The control/dependence relationships between sectors are presented from the production
327
Fig. 4 shows the control ratio condition of each sector. In 2002, Ind and Ser are the two main
328
dominators of the system. Liv and Con depend on other virtual water suppliers (i.e., Far, FHF, Ind
329
and Ser). From 2003 to 2004, FHF is the major virtual water resources supplier, and every control
330
power on other sectors is above 80%. Liv still significantly depends on other sectors, which are all
331
above 50%. During the stage from 2005 to 2007, this situation is intensified. The control power of
332
FHF on others is above 95% on average. The reliance of Liv on other sectors is nearly 99%,
333
indicating that the virtual water resources of Liv seriously rely on imports from others and rarely
334
exports to other sectors. From 2008 to 2010, the system’s control state changes obviously so that
335
Ind became the major controller, and FHF and Con become the largest dependents with average
336
values above 80%.
Fig. 4 Pairwise control relationship between each sector of the VWN derived from the results of the control ratio matrix (CR) side (matrix column) to others on the consumption side (matrix row).
337
In addition to the dominant sectors, the stronger and weaker pathways can also be identified.
338
Strong linkages exist between the following pairwise sectors: Far – Liv, FHF – Liv, Ser – Liv,
339
FHF – Con and Ind – Con. The pairwise relationship with control intensity lower than 50% can be
ACS Paragon Plus Environment
Page 19 of 35
Environmental Science & Technology
340
defined as weaker control relation. The weaker pathways include Liv – Con, Ind – Ser and Ser –
341
Con.
342
Regarding the statistic indicators in Fig. 4, it can be seen that the system’s control strength
343
from 2005 to 2007 is the most powerful with an average control ratio value (μ) of 0.887.
344
Furthermore, the standard deviation value of the control ratio (σ) is comparatively lower,
345
indicating that the control power is more centralized to such a high level.
346
3.3 NUA for the VWN Far
+
Liv
+ -
+
FHF
+ -
- +
+
Ind
- +
- +
- +
+
Con
- -
- -
+ -
+ -
+
Ser
- +
- +
- +
- -
- +
+
Far
Liv
FHF
Ind
Con
Ser
NM = 1.00 SI = 5.68
Far
+
Liv
+ -
FHF - +
- +
+
Ind
- +
- +
+ -
+
Con
- -
- -
+ -
+ -
+
Ser
- +
- +
+ -
+ -
- +
+
Far
Liv
FHF
Ind
Con
Ser
(a) 2002
(b) 2003,2004
Far
+
Liv
+ -
+
FHF
+ +
+ +
+
Ind
- +
- +
+ -
+
Con
+ -
+ -
+ -
- -
+
Ser
- +
- +
+ -
- +
- -
+
Far
Liv
FHF
Ind
Con
Ser
NM = 1.40 SI = 5.91
(c) 2005,2006,2007
347 348 349 350 351 352 353
NM = 1.12 SI = 5.48
+
Far
+
Liv
+ -
NM = 1.12 SI = 6.07
+
FHF + -
- -
+
Ind
- +
- +
- +
+
Con
+ +
- -
+ -
+ -
+
Ser
- -
- +
- +
+ -
+ -
+
Far
Liv
FHF
Ind
Con
Ser
(d) 2008,2009,2010
+ + Mutualistic relation
- + Exploited relation
+ - Exploitation relation
- - Competition relation
Fig. 5 Integral mutual relationship for the VWN Notes: The integral utility relationships between sectors are presented from the production side (matrix column) to others on the consumption side (matrix row). The block with dark blue shadow means that the mutual relationship of these two sectors differs from the one of the previous phase. NM (network mutualism index): ratio of the number of positive signs over the number of negative signs in utility matrix. SI (network synergism index): summation of all elements of the utility
ACS Paragon Plus Environment
Environmental Science & Technology
354
matrix to assess the magnitude of the positive and negative relationships of a system.
355
Fig. 5 shows the integral relationships (in the integral utility sign matrix, SignU) between
356
pairwise social-economic sectors in the VWN. In 2002, there are only two types of relationships,
357
exploitative and competitive. The competitive relationships account for 25% of the total
358
relationships, including the pairwise sectors of Far – Con, Liv – Con, and Ind – Ser, which
359
indicates that the Con water requirement puts stress on the irrigation and livestock water supply
360
and the local industrialization sacrifices the public services’ water supply. The Ind and Ser sectors
361
are the largest contributors during the water trade interactions, as they are under the exploitation of
362
4 other sectors. Liv is the largest water beneficiary because it exploits the Far, FHF, Ind and Ser
363
sectors. From 2003 to 2004, four relationships change. One competitive relationship changes to an
364
exploitative relationship (Ind – Ser). The directions of three exploitative relationships shift, which
365
are all correlated with FHF, including Far – FHF, FHF – Ind, and FHF – Ser. Afterward, FHF
366
become the largest contributor as it is exploited by every other sector, while Far and Liv turns into
367
the major exploiters of the FHF, Ind, Con and Ser sectors. From 2005 to 2007, a mutualistic
368
relationship occurs in the pairwise relations of Far – FHF and Liv – FHF, indicating that the inner
369
relationships among the three agricultural sectors are prone to the synergism. Two competitive
370
relationships change to exploitative relationships (Far – Con, Liv – Con), and two exploitative
371
relationships alter to competitive relationships (Ind – Con, Con – Ser). All of them are correlated
372
with Con as the largest exploiter. The largest contributor is FHF, as it owns positive utility
373
relationships with all other sectors, transferring virtual water to the other sectors. From 2008 to
374
2010, Liv is the most competitive one, as it competes with FHF and Con and is exploited by Far,
375
Ind and Ser. Ind delivers profits through water transactions to other sectors, as it is the contributor
ACS Paragon Plus Environment
Page 20 of 35
Page 21 of 35
Environmental Science & Technology
376
to other five sectors. During the whole period (2002–2010), two pairwise relationships
377
continuously change, i.e., FHF – Far ((+,–) → (–,+) → (+,+) → (+,–)) and Ser – Ind ((–,–) → (+,–)
378
→ (–,+) → (+,–)).
379
The exploitative relationship is the dominating one among the pairwise relations throughout
380
the study period, with proportions above 67.7% and as high as 83.3%. The competitive
381
relationship always exists, indicating that the virtual water transaction structure of VWN inclines
382
to a relationship of competition between sectors.
383
4. DISCUSSION
384
Unlike fresh water management strategies, which mainly focus on the efficiency of the target
385
production processes of water utilization, the VWN provides an integral view via the link of
386
virtual water flows with different socio-economic activities. ENA is a powerful tool considering
387
its detailed pathway-focused analysis based on the network configuration and nodes’ interactions.
388
It uncovers the indirect flows and influences hidden in the network systems from a whole
389
systematic perspective, which contributes greatly to the formation of a system’s structure and
390
function. Different from the accounting methods that only focus on the efficiency aspect, ENA can
391
evaluate the stability of the whole system from the balance between efficiency and redundancy,
392
which is vital for the system’s stability long-term sustainability. In addition, the anatomy of the
393
network can be characterized by NCA and NUA based on how the virtual water flows are
394
distributed within a network at the sectoral and pathway levels. The network’s control and
395
dependence intensity and the mutual relationships between pairwise sectors display another facet
396
of the VWN that might be helpful to water resources management, i.e., it uncovers the dominators
ACS Paragon Plus Environment
Environmental Science & Technology
397
and dependents along with the beneficiaries and contributors of the system. As such, ENA
398
highlights the pathways of flows and interactions between sectors, thus manifesting the
399
sector-level dynamics and system-wide conditions for reasonable water resources allocation in the
400
VWN.
401
The case study of Ganzhou District in the Heihe River Basin based on ENA shows that, the
402
agricultural sector is the major local economic sector with high-intensity water consumption. The
403
current policies for water management emphasize the control of the total amount of water
404
consumption in this region, ignoring the balance between efficiency and redundancy for virtual
405
water circulation within the socio-economic system. Although the total fresh water consumption
406
declines (see Sec. 3.1 of SI), the efficiency of VWN is still low. Compared to the previous studies
407
(see Sec. 2.2 of SI),49,60,61 it can be seen that the robustness of VWN remains on the left-side of the
408
ideal robustness curve, implying that the VWN has a higher redundancy level due to stable
409
circulation among various sectors but lower system efficiency, which is contrary to the intuition
410
that human-designed networks should be more efficient. This occurs because except for the
411
freshwater flowing through specific supply chains, the water hidden in the products or services is
412
circulating within diverse sectors with more exchanges along various pathways, which results in
413
higher redundancy.
414
The stronger control pathways are identified based on NCA as Far – Liv, Ser – Liv and FHF
415
– Con, indicating that there are clear water flow directions from Farming to Livestock, Services to
416
Livestock, and Forestation, Herding and Fishing to Construction sectors. The weaker pathways,
417
including Ind – Ser and Ser – Con, mean that the water flows between the pairwise sectors are not
ACS Paragon Plus Environment
Page 22 of 35
Page 23 of 35
Environmental Science & Technology
418
totally controlled by one side, i.e., the virtual water flow directions from the Industry to Services
419
and Services to Construction sectors are not obvious. From the sectoral perspective, the
420
controlling effects of Ind as the largest controller of Far and Liv are notable, indicating that the
421
agricultural activities need great inputs from industrial products associated with huge water
422
consumption, e.g., farm machinery or irrigation systems. Although the farming sector is the largest
423
water consumer in this region, the major controller is industrial sector instead of farming sector.
424
This is because that most of the agricultural products are exported to other regions instead of
425
consumed in local area, while the industrial products are usually consumed locally to support
426
economic production activities, which is critical for the local virtual water circulation. Although
427
farming sector consumes large amount of water resources directly, it still exploits water resources
428
from local industry sector indirectly. From the network perspective, it is significant to improve
429
water utilization efficiencies of both agricultural and industrial sectors because agricultural sector
430
is the main direct consumer while industry sector contributes virtual water to agricultural activities
431
in an indirect manner.
432
The NUA results show that the NM indicator (positive/negative signs) in the matrix during
433
the study period is higher than or equal to 1, implying that the system has more positive utility
434
relationships and is in a better mutualism shape. In particular, the NM reaches its highest value
435
from 2005 to 2007, indicating that the system is under the most mutualistic conditions. Although
436
the NM declined from 2008 to 2010, the SI indicator reaches its highest value, demonstrating that
437
the system has an increasing synergism. Moreover, the diagonal elements of SignU are all positive,
438
showing that all of the sectors have an active utility impact on each other. However, it should be
ACS Paragon Plus Environment
Environmental Science & Technology
439
noted that although the system shows a good performance of mutualism and synergism, there are
440
still some competitive relationships that may cause potential risk for the water security in the
441
current configuration of VWN.
442
There are various water management policies aiming to mitigate the contradiction between
443
water supply and water demand in the Heihe River Basin, which are mainly about the reduction of
444
total water inputs.13,15,75 This study aims to add an accurate investigation of virtual water flow
445
network, which uses ecological network analysis to cover both direct and indirect flows and
446
describe the water system structure and sectoral characteristics via virtual water transaction. The
447
results show that the efficiency of VWN is still low, indicating that it needs more virtual water
448
flows to pass through stronger pathways with higher virtual water intensity. It can be seen from
449
NCA and NUA that Con – Liv, Ser – Ind and Ser – Con are weaker pathways with unclear
450
pairwise relations, i.e., Con – Liv: (–,–) → (+,–) → (–,–), Ser – Ind: (–,–) → (+,–) → (–,+)
451
→ (+,–), Ser – Con: (–,+) → (–,–) → (+,–). Thus, strengthening the virtual water trade between
452
Con – Liv, Ser – Ind and Ser – Con might improve the VWN structure and promote the systematic
453
efficiency. Meanwhile, from the sectoral perspective, farming sector is the major direct water user
454
and imports net virtual water from industry sector indirectly. The indirect water consumption
455
correlated with industrial activities should therefore be considered to coordinately reduce the
456
virtual water consumption of farming activities, e.g., improving the production technology of local
457
industries or importing industrial products from other regions outside the Heihe River Basin.
458 ACKNOWLEDGEMENTS
ACS Paragon Plus Environment
Page 24 of 35
Page 25 of 35
Environmental Science & Technology
This work was supported by the Fund for Creative Research Groups of the National Natural Science Foundation of China (No. 51121003), Major Research Plan of the National Natural Science Foundation of China (No. 91325302), National Natural Science Foundation of China (No. 41271543), and Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20130003110027).
ASSOCIATED CONTENT Supporting Information Available The explanatory details of ENA methodology and calculation details of VWN are presented in the Supporting Information. This information is available free of charge via the Internet at http://pubs.acs.org/.
459
AUTHOR INFORMATION 460
Corresponding author
461
**Tel.: +86−10−58807368; fax: +86−10−58807368; e−mail:
[email protected] (Bin Chen).
462
Affiliation: State Key Joint Laboratory of Environmental Simulation and Pollution Control,
463
School of Environment, Beijing Normal University, Beijing 100875, China
464 465
Author Contributions
466 467 468
§Both authors have equal contribution as the first author.
469
The authors declare no competing financial interest.
Notes
470
ACS Paragon Plus Environment
Environmental Science & Technology
471
REFERENCES
472
(1) Oki, T.; Kanae, S. Global hydrological cycles and world water resources. Science 2006, 313,
473 474 475
1068-1072. (2) Vörösmarty, C. J.; Green, P.; Salisbury, J.; Lammers, R. B. Global water resources: vulnerability from climate change and population growth. Science 2000, 289, 284-288.
476
(3) Flörke, M.; Kynast, E.; Bärlund, I.; Eisner, S.; Wimmer, F.; Alcamo, J. Domestic and
477
industrial water uses of the past 60 years as a mirror of socio-economic development: A
478
global simulation study. Global Environ. Chang. 2013, 23, 144-156.
479 480
(4) Postel, S. L.; Daily, G. C.; Ehrlich, P. R. Human appropriation of renewable fresh water. Science-AAAS-Weekly Paper Edition 1996, 271, 785-787.
481
(5) Vörösmarty, C. J.; McIntyre, P. B.; Gessner, M. O.; Dudgeon, D.; Prusevich, A.; Green, P.;
482
Glidden, S.; Bunn, S. E.; Sullivan, C. A.; Liermann, C. R. Global threats to human water
483
security and river biodiversity. Nature 2010, 467, 555-561.
484
(6) Willis, R. M.; Stewart, R. A.; Panuwatwanich, K.; Williams, P. R.; Hollingsworth, A. L.
485
Quantifying the influence of environmental and water conservation attitudes on household
486
end use water consumption. J. Environ. Manage. 2011, 92, 1996-2009.
487 488
(7) Hoekstra, A. Y.; Mekonnen, M. M. The water footprint of humanity. P. Natl. Acad. Sci. USA. 2012, 109, 3232 -3237.
489
(8) Liu, J.; Yang, W. Water sustainability for China and beyond. Science 2012, 337, 649-650.
490
(9) Liu, J.; Savenije, H. Time to break the silence around virtual-water imports. Nature 2008,
491
453, 587-587.
ACS Paragon Plus Environment
Page 26 of 35
Page 27 of 35
492 493
Environmental Science & Technology
(10) Allan, J. A. Virtual water: A strategic resource global solutions to regional deficits. Groundwater 1998, 36, 545-546.
494
(11) Allan, T. Fortunately there are substitutes for water: otherwise our hydropolitical futures
495
would be impossible. In ODA, Priorities for Water Resources Allocation and Management;
496
London, 1993; pp. 13–26.
497
(12) Hoekstra, A. Y.; Chapagain, A. K.; Aldaya, M. M.; Mekonnen, M. M. Water Footprint
498
Manual – State of the Art 2009; Water Footprint Network: Enschede, Netherlands, 2009.
499
(13) Zeng, Z.; Liu, J.; Koeneman, P. H.; Zarate, E.; Hoekstra, A. Y. Assessing water footprint at
500
river basin level: a case study for the Heihe River Basin in northwest China. Hydrol. Earth
501
Syst. Sc. 2012, 16, 2771-2781.
502
(14) Feng, K.; Chapagain, A.; Suh, S.; Pfister, S.; Hubacek, K. Comparison of bottom-up and
503
top-down approaches to calculating the water footprints of nations. Economic Systems
504
Research 2011, 23, 371-385.
505 506 507 508 509 510 511 512
(15) Feng, K.; Hubacek, K.; Pfister, S.; Yu, Y.; Sun, L. Virtual scarce water in China. Environ. Sci. Technol. 2014, 48, 7704-7713. (16) Shao, L.; Chen, G. Q. Water footprint assessment for wastewater treatment: method, indicator, and application. Environ. Sci. Technol. 2013, 47, 7787-7794. (17) Hoekstra, A. Y.; Hung, P. Q. Globalisation of water resources: international virtual water flows in relation to crop trade. Global Environ. Chang. 2005, 15, 45-56. (18) Liu, J.; Lundqvist, J.; Weinberg, J.; Gustafsson, J. Food losses and waste in China and their implication for water and land. Environ. Sci. Technol. 2013, 47, 10137-10144.
ACS Paragon Plus Environment
Environmental Science & Technology
513 514 515 516
(19) Liu, J.; Savenije, H. H. Food consumption patterns and their effect on water requirement in China. Hydrol. Earth Syst. Sc. 2008, 12, 887-898. (20) Zhao, C.; Chen, B. Driving force analysis of the agricultural water footprint in China based on the LMDI method. Environ. Sci. Technol. 2014,.
517
(21) Zhao, C.; Chen, B.; Hayat, T.; Alsaedi, A.; Ahmad, B. Driving force analysis of water
518
footprint change based on extended STIRPAT model: Evidence from the Chinese agricultural
519
sector. Ecol. Indic. 2014,.
520
(22) Feng, K.; Siu, Y. L.; Guan, D.; Hubacek, K. Assessing regional virtual water flows and water
521
footprints in the Yellow River Basin, China: A consumption based approach. Appl. Geogr.
522
2011, 32, 691-701.
523 524 525 526 527 528
(23) Guan, D.; Hubacek, K.; Tillotson, M.; Zhao, H.; Liu, W.; Liu, Z.; Liang, S. Lifting China’s water spell. Environ. Sci. Technol. 2014,. (24) Dong, H.; Geng, Y.; Sarkis, J.; Fujita, T.; Okadera, T.; Xue, B. Regional water footprint evaluation in China: a case of Liaoning. Sci. Total Environ. 2013, 442, 215-224. (25) Guan, D.; Hubacek, K. Assessment of regional trade and virtual water flows in China. Ecol. Econ. 2007, 61, 159-170.
529
(26) Zhao, X.; Yang, H.; Yang, Z.; Chen, B.; Qin, Y. Applying the input-output method to
530
account for water footprint and virtual water trade in the Haihe River basin in China. Environ.
531
Sci. Technol. 2010, 44, 9150-9156.
532
(27) Pfister, S.; Bayer, P.; Koehler, A.; Hellweg, S. Environmental impacts of water use in global
533
crop production: hotspots and trade-Offs with land use. Environ. Sci. Technol. 2011, 45,
ACS Paragon Plus Environment
Page 28 of 35
Page 29 of 35
534 535 536
Environmental Science & Technology
5761-5768. (28) Pfister, S.; Koehler, A.; Hellweg, S. Assessing the environmental impacts of freshwater consumption in LCA. Environ. Sci. Technol. 2009, 43, 4098-4104.
537
(29) Ridoutt, B. G.; Pfister, S. A revised approach to water footprinting to make transparent the
538
impacts of consumption and production on global freshwater scarcity. Global Environ.
539
Chang. 2010, 20, 113-120.
540 541
(30) Duarte, R.; Sanchez-Choliz, J.; Bielsa, J., Water use in the Spanish economy: an input–output approach. Ecol. Econ. 2002, 43: 71-85.
542
(31) Sánchez-Chóliz, J.; Duarte, R., Analysing pollution by way of vertically integrated
543
coefficients, with an application to the water sector in Aragon. Cambridge J. Econ. 2003, 27,
544
433-448.
545
(32) Cazcarro, I.; Duarte, R.; Sánchez-Chóliz, J., Water flows in the Spanish economy: Agri-food
546
sectors, trade and households diets in an input-output framework. Environ. Sci. Technol.
547
2012, 46: 6530-6538.
548 549
(33) Cazcarro, I.; Duarte, R.; Sánchez-Chóliz, J., Multiregional input–output model for the evaluation of Spanish water flows. Environ. Sci. Technol. 2013, 47, 12275-12283.
550
(34) Cazcarro, I.; Duarte, R.; Sánchez-Chóliz, J., Economic growth and the evolution of water
551
consumption in Spain: A structural decomposition analysis. Ecol. Econ. 2013, 96, 51-61.
552
(35) Cazcarro, I.; Duarte, R.; Sánchez-Chóliz, J.; Sarasa C.; Serrano A.,
Environmental
553
footprints and scenario analysis for assessing the impacts of the agri‐food industry on a
554
regional economy. J. Ind. Ecol. 2014, DOI: 10.1111/jiec.12209.
ACS Paragon Plus Environment
Environmental Science & Technology
555
(36) Deng, X. Z.; Zhang, F.; Wang, Z.; Li, X.; Zhang, T., An extended input output table compiled
556
for analyzing water demand and consumption at county level in China. Sustainability 2014, 6,
557
3301-3320.
558 559 560 561
(37) Lenzen, M.; Moran, D.; Bhaduri, A.; Kanemoto, K.; Bekchanov, M.; Geschke, A.; Foran, B., International trade of scarce water. Ecol. Econ. 2013, 94, 78-85. (38) Fang, D.; Fath, B. D.; Chen, B.; Scharler, U. M. Network environ analysis for socio-economic water system. Ecol. Ind. 2014, 47, 80-88.
562
(39) Hubacek, K.; Guan, D.; Barrett, J.; Wiedmann, T. Environmental implications of
563
urbanization and lifestyle change in China: Ecological and water footprints. J. Clean. Prod.
564
2009, 17, 1241-1248.
565
(40) Hannon, B. The structure of ecosystems. J. Theor. Biol. 1973, 41, 535-546.
566
(41) Ulanowicz, R.E. Quantitative methods for ecological network analysis and its application to
567
coastal ecosystems. In Treatise on Estuarine and Coastal Science Vol 9. Waltham; Wolanski,
568
E., McLusky, D.S., Eds.; Academic Press: New York, 2011; pp 35-57.
569 570 571 572 573 574 575
(42) Ulanowicz, R. E. Growth and Development: Ecosystems Phenomenology; Springer-Verlag: New York, 1986. (43) Ulanowicz, R. E. Ecology, the Ascendent Perspective; Columbia University Press: New York 1997. (44) Ulanowicz, R. E. Quantitative methods for ecological network analysis. Comput. Biol. Chem. 2004, 28, 321-339. (45) Bodini, A.; Bondavalli, C. Towards a sustainable use of water resourcess: a whole-ecosystem
ACS Paragon Plus Environment
Page 30 of 35
Page 31 of 35
576 577 578 579 580
Environmental Science & Technology
approach using network analysis. Int. J. Environ. Pollut. 2002, 18, 463-485. (46) Bodini, A.; Bondavalli, C.; Allesina, S. Cities as ecosystems: Growth, development and implications for sustainability. Ecol. Model. 2012, 245, 185-198. (47) Li, Y.; Chen, B.; Yang, Z. F. Ecological network analysis for water use systems—a case study of the Yellow River Basin. Ecol. Model. 2009, 220, 3163-3173.
581
(48) Li, Y.; Yang, Z. F. Quantifying the sustainability of water use systems: Calculating the
582
balance between network efficiency and resilience. Ecol. Model. 2011, 222, 1771-1780.
583
(49) Kharrazi, A.; Rovenskaya, E.; Fath, B. D.; Yarime, M.; Kraines, S. Quantifying the
584
sustainability of economic resource networks: An ecological information-based approach.
585
Ecol. Econ. 2013, 90, 177-186.
586 587 588 589 590 591 592 593
(50) Finn, J. T. Measures of ecosystem structure and function derived from analysis of flows. J. Theor. Biol. 1976, 56, 363-380. (51) Patten, B. C.; Bosserman, R. W.; Finn, J. T.; Cale, W. G. Propagation of cause in ecosystems. Syst. Anal. Sim. Ecol. 1976, 4, 457-579. (52) Baird, D.; Ulanowicz, R. E. The seasonal dynamics of the Chesapeake Bay ecosystem. Ecol. Monogr. 1989, 59, 329-364. (53) Borrett, S. R.; Moody, J.; Edelmann, A. The rise of Network Ecology: Maps of the topic diversity and scientific collaboration. Ecol. Model. 2014, 293, 111-127.
594
(54) Scharler, U. M.; Baird, D. A comparison of selected ecosystem attributes of three South
595
African estuaries with different freshwater inflow regimes, using network analysis. J. Marine
596
Syst. 2005, 56, 283-308.
ACS Paragon Plus Environment
Environmental Science & Technology
597
(55) Schramski, J. R.; Gattie, D. K.; Patten, B. C.; Borrett, S. R.; Fath, B. D.; Whipple, S. J.
598
Indirect effects and distributed control in ecosystems: Distributed control in the environ
599
networks of a seven-compartment model of nitrogen flow in the Neuse River Estuary,
600
USA—Time series analysis. Ecol. Model. 2007, 206, 18-30.
601
(56) Schramski, J. R.; Gattie, D. K.; Patten, B. C.; Borrett, S. R.; Fath, B. D.; Thomas, C. R.;
602
Whipple, S. J. Indirect effects and distributed control in ecosystems:: Distributed control in
603
the environ networks of a seven-compartment model of nitrogen flow in the Neuse River
604
Estuary, USA—Steady-state analysis. Ecol. Model. 2006, 194, 189-201.
605 606 607 608
(57) Mao, X.; Yang, Z. Ecological network analysis for virtual water trade system: A case study for the Baiyangdian Basin in Northern China. Ecol. Inform. 2012, 10, 17-24. (58) Yang, Z.; Mao, X.; Zhao, X.; Chen, B. Ecological network analysis on global virtual water trade. Environ. Sci. Technol. 2012, 46, 1796-1803.
609
(59) Zhang, Y.; Zheng, H.; Fath, B. D.; Liu, H.; Yang, Z.; Liu, G.; Su, M. Ecological network
610
analysis of an urban metabolic system based on input–output tables: Model development and
611
case study for Beijing. Sci. Total Environ. 2014, 468, 642-653.
612
(60) Goerner, S. J.; Lietaer, B.; Ulanowicz, R. E. Quantifying economic sustainability:
613
Implications for free-enterprise theory, policy and practice. Ecol. Econ. 2009, 69, 76-81.
614
(61) Ulanowicz, R. E.; Goerner, S. J.; Lietaer, B.; Gomez, R. Quantifying sustainability: resilience,
615 616 617
efficiency and the return of information theory. Ecol. Complex. 2009, 6, 27-36. (62) Ulanowicz, R. E.; Holt, R. D.; Barfield, M. Limits on ecosystem trophic complexity: insights from ecological network analysis. Ecol. Lett. 2014, 17, 127-136.
ACS Paragon Plus Environment
Page 32 of 35
Page 33 of 35
618 619
Environmental Science & Technology
(63) Zorach, A. C.; Ulanowicz, R. E. Quantifying the complexity of flow networks: how many roles are there? Complex. 2003, 8, 68-76.
620
(64) Borrett, S. R.; Whipple, S. J.; Patten, B. C.; Christian, R. R. Indirect effects and distributed
621
control in ecosystems: Temporal variation of indirect effects in a seven-compartment model
622
of nitrogen flow in the Neuse River Estuary, USA—Time series analysis. Ecol. Model. 2006,
623
194, 178-188.
624
(65) Chen, S. Q.; Chen, B. Network environ perspective for urban metabolism and carbon
625
emissions: a case study of Vienna, Austria. Environ. Sci. Technol. 2012, 46, 4498-4506.
626
(66) Fath, B. D.; Patten, B. C. Review of the foundations of network environ analysis. Ecosystems
627
1999, 2, 167-179.
628
(67) Huang, J.; Ulanowicz, R. E. Ecological network analysis for economic systems: Growth and
629
development and implications for sustainable development. PLoS ONE 2014, 9, e100923
630
(68) Scharler, U. M. Ecological network analysis, Ascendency. In Encyclopedia of Ecology;
631
Jorgensen, S.E., Fath, B., Eds.; Elsevier: New York, 2008; pp 1064-1071.
632
(69) Gattie, D. K.; Schramski, J. R.; Borrett, S. R.; Patten, B. C.; Bata, S. A.; Whipple, S. J.
633
Indirect effects and distributed control in ecosystems: Network environ analysis of a
634
seven-compartment model of nitrogen flow in the Neuse River Estuary, USA—Steady-state
635
analysis. Ecol. Model. 2006, 194, 162-177.
636 637 638
(70) Fath, B. D. Network mutualism: Positive community-level relations in ecosystems. Ecol. Model. 2007, 208, 56-67. (71) Fath, B. D.; Borrett, S. R. A MATLAB® function for Network Environ Analysis. Environ.
ACS Paragon Plus Environment
Environmental Science & Technology
639 640 641
Modell. Softw. 2006, 21, 375-405. (72) Statistical Bureau of Gansu Province. Gansu Development Yearbook 2013; China Statistics Press: Beijing, China, 2013.
642
(73) Statistics Bureau of Zhangye. Zhangye Statistical Yearbook 2012; Zhangye, China.
643
(74) Zhang, X. J. A Study on Water Cycle in Social-economic System: A Case study of Ganzhou
644
District at the Middle Reaches of Heihe River Basin. M.S. Thesis, Northwest Normal
645
University, Gansu, China, 2013 (In Chinese).
646
(75) Chen, Y.; Zhang, D.; Sun, Y.; Liu, X.; Wang, N.; Savenije, H. H. G., Water demand
647
management: A case study of the Heihe River Basin in China. Phys. Chem. Earth 2005, 30,
648
(6-7), 408-419.
649
ACS Paragon Plus Environment
Page 34 of 35
Page 35 of 35
Environmental Science & Technology
88x50mm (300 x 300 DPI)
ACS Paragon Plus Environment