Effects of Chloride and Sulfate Salts on the Inhibition or Promotion of

Nov 28, 2017 - The effects of salts on the stability of amorphous sucrose and its crystallization in different environments were investigated. Chlorid...
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Effects of chloride and sulfate salts on the inhibition or promotion of sucrose crystallization in initially amorphous sucrose-salt blends Alpana Ankush Thorat, Laurent Forny, Vincent Meunier, Lynne S. Taylor, and Lisa J. Mauer J. Agric. Food Chem., Just Accepted Manuscript • DOI: 10.1021/acs.jafc.7b04746 • Publication Date (Web): 28 Nov 2017 Downloaded from http://pubs.acs.org on November 29, 2017

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Journal of Agricultural and Food Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.

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Journal of Agricultural and Food Chemistry

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Effects of chloride and sulfate salts on the inhibition or promotion of sucrose crystallization

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in initially amorphous sucrose-salt blends

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Alpana A. Thorat1,2, Laurent Forny3, Vincent Meunier3, Lynne S. Taylor2, Lisa J. Mauer1 1

Department of Food Science, Purdue University, 745 Agriculture Mall Drive, West Lafayette, 9 Indiana 47907, United States

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Department of Industrial and Physical Pharmacy, Purdue University, 575 Stadium Mall Drive, West Lafayette, Indiana 47907, United States

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Nestlé Research Center, Vers-chez-les-Blanc, Route du Jorat, 1005 Lausanne, Switzerland

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1 ACS Paragon Plus Environment

Journal of Agricultural and Food Chemistry

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ABSTRACT

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The effects of salts on the stability of amorphous sucrose and its crystallization in different

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environments were investigated. Chloride (LiCl, NaCl, KCl, MgCl2, CaCl2, CuCl2, FeCl2, FeCl3,

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and AlCl3) and sulfate salts with the same cations (Na2SO4, K2SO4, MgSO4, CuSO4, Fe(II)SO4,

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and Fe(III)SO4) were studied. Samples (sucrose controls and sucrose:salt 1:0.1 molar ratios)

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were lyophilized, stored in controlled temperature and relative humidity (RH) conditions, and

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monitored for one month using X-ray diffraction. Samples were also analyzed by differential

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scanning calorimetry, microscopy, and moisture sorption techniques. All lyophiles were initially

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amorphous, but during storage the presence of a salt had a variable impact on sucrose

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crystallization. While all samples remained amorphous when stored at 11 and 23%RH at 25°C,

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increasing the RH to 33 and 40%RH resulted in variations in crystallization onset times. The

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recrystallization time generally followed the order: monovalent cations