Effects of Metal-Centered Reduction on the Structural, Electronic, and

Am. Chem. Soc. 1994,. 116, 6019-6020], Yoshinori Yamamoto,* Mohammad. Al-Masum, and Naoki Asao. Page 6019,Table 1, entry 5: thestructure of 8c should ...
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J. Am. Chem. SOC., Vol. 117, No. 8, 1995 2379

Additions and Corrections

Additions and Corrections Palladium Catalyzed Addition of Activated Methylene and Methyne Compounds to Allenes [J.Am. Chem. SOC. 1994, 116, 6019-60201. YOSHINORI YAMAMOTO,*MOHAMMAD AL-MASUM,AND NAOKIASAO Page 6019, Table 1, entry 5: the structure of 8c should be as follows (8e-1 and 8e-2).

8e-1

8e -2

The ratio of 7e:8e was 57:43, and the ratio of 8e-Me-2 was 76:24. JA955000R

Effects of Metal-Centered Reduction on the Structural, Electronic, and Coordination Properties of Nickel and Copper Octaethylisobacteriochlorins [J.Am. Chem. SOC.1995, 117, 293-3001, MARKW. F&NNER,*LARS R. FURENLID,* AND ALANM. STOLZENBERG Page 298: Due to a production error, Figures 10 and 11 were published incorrectly. The following figures are the corrected versions. 0.50

0.40

a./

0.30 0.20 0.10 0.00 0.00

0.05

0.10

0.15 AR (A)

0.20

0.25

0.30 2

Figure 10. Goodness-of-fit indices for fits with two shells at fixed distance differences for Ni"(0EiBC) (0)and Ni'(0EiBC)- (0). Fits AR. Free parameters were carried out with N2 = N , and Rz = Rl were N , , R I , q2,and m2.

+

JA955002B

4

6

a

Wavevector k (A')

10

12

Figure 11. Fourier-filtered second-shell EXAFS oscillations (-) and nonlinear least squares fits (-0) of Cu'(0EiBC)- without crown ether 2 Na at 2.89 A, 8 C at 3.09 A, and 4 C at 3.34 A.