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Organometallics 1996, 15, 2418
Additions and Corrections 1995, Volume 14 Kiyonari Hashidzume, Hiromi Tobita,* and Hiroshi Ogino*: Electrochemistry of Octamethyl[3]ruthenocenophane: Synthesis and Structure of the First Dicationic Derivative of Ruthenocene, [{η5:η5C5Me4(CH2)3C5Me4}Ru(NCMe)](PF6)2. Page 1189. The data listed in Table 2 were found to be incorrect. The corrected version of Table 2 appears below. A mistake was made in generating the published table from the computer data, so that there is no change in the structural data. Table 2. Final Atomic Coordinates (×104) and Equivalent Isotropic Temperature Factors for {η5:η5-C5Me4(CH2)3C5Me4}Ru (1) atom
x
y
z
Beq,a Å2
Ru C(0) C(1) C(2) C(3) C(4) C(5) C(6) C(7) C(8) C(9) C(10) C(11) C(12) C(13) C(14) C(15) C(16) C(17) C(18) C(19) C(20A)b C(20B)b
2753.5(2) 2017(3) 2053(3) 2973(3) 3514(3) 2921(3) 1982(3) 2016(3) 2937(3) 3472(3) 2887(3) 1201(4) 1274(4) 3320(5) 4501(4) 3209(5) 1182(5) 1248(4) 3289(4) 4456(4) 3154(4) 713(10) 814(9)
551.1(3) -973(4) -25(5) 132(5) -673(4) -1356(4) 1166(4) 2102(4) 2448(4) 1735(4) 947(4) -1443(8) 647(6) 973(7) -823(6) -2347(5) 521(6) 2628(7) 3434(5) 1842(6) 118(6) -325(13) 1547(12)
2559.8(3) 1699(4) 782(4) 708(4) 1573(4) 2169(4) 3883(4) 2970(4) 3077(4) 4026(4) 4541(4) 2101(7) 15(8) -171(5) 1726(6) 3095(6) 4154(9) 2081(6) 2354(6) 4504(6) 5598(5) 2780(13) 1109(12)
2.8 3.5 3.7 3.5 3.3 3.4 3.6 3.5 3.5 3.3 3.4 6.9 6.6 5.5 5.1 5.3 6.6 5.8 5.1 5.3 5.1 4.6(0.3) 6.0(0.3)
a The equivalent isotropic temperature factors for non-hydrogen atoms were computed using the following expression: Beq ) 4/ (B a2 + B b2 + B c2 + B ac (cos β)). The B ’s are defined by 3 11 22 33 13 ij exp[-(h2B11 + k2B22 + l2B33 + 2hkB12 + 2hlB13 + 2klB23)]. b These atoms were refined isotropically.
We are grateful to Mrs. S. Barrett in Cambridge at the Crystallographic Data Centre for her comments. Michael Knorr,* Pierre Braunstein,* Antonio Tiripicchio, and Franco Ugozzoli: Novel CO-Induced Silyl Migration in Heterobimetallic Iron-Palladium Methyl Complexes Leading to µ-Siloxycarbene Complexes. Crystal Structures of the Metallasiloxanes [(OC)3Fe{µ-Si(OSiMe3)2(OSiMe3)}(µ-dppm)PdCl] and [(OC)3{(Me3SiO)3Si}Fe(µ-dppm)Pt(η3-C3H5)]. Page 4919. The correct values for the 31P{1H} NMR spectrum of the complex [(OC)3{(Me3OSi)3Si}Fe(µdppm)Pt(CtNtBu)(η1-C3H5)] (6b) should read as follows. 31P{1H} NMR (81.02 MHz, CDCl ): δ 18.4 (d, P(Pt), 3 2+3J(P-P) ) 85, 1J(P-Pt) ) 3414 Hz), 63.7 (d, P(Fe), 2+3J(P-P) ) 85 Hz, 2J(P-Pt) not observed). S0276-7333(96)00009-X CCC: $12.00
© 1996 American Chemical Society
