Electrocrystallizing C60: synthesis, single crystal x-ray structure, and

Nov 1, 1993 - Alain Penicaud, Aaron Perez-Benitez, R. Gleason V., E. Munoz P., R. Escudero ... Patrick Batail, Kamal Boubekeur, Marc Fourmigu , and ...
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10392

J. Am. Chem. SOC.1993,115, 10392-10393

Electrocrystallizing Cm: Synthesis, Single Crystal X-ray Structure, and Magnetic (ESR, SQUID) Characterization of [(C&IS)~P]Z[C,][I]~ Alain PCnicaud,'*tJ Aar6n PerCz-Benitez,? R. Gleason V.,J E. Muiloz P..i and R. Escuderos Instituto de Quimica, Instituto de Fisica, and Instituto de Investigaciones en Materiales Universidad Nacional Autonoma de Mgxico Coyoachn, C.P. 04510, M&.xicoD.F., Mgxico Received July 14, I993

Despite the explosion of research' on C602Jmostly due to its novel chemical nature and the discovery of superconductivity4 and ferromagnetism5 in fulleride salts, there still exist only a few families of well-characterized &based materials. We report here on the synthesis by electrocrystallization of high quality single crystals of volume up to 1 mm3 of a salt of formula [(C6H5)4P]2[C6~] [IIx (0 < x