Elementary Reaction Mechanism for Benzene ... - ACS Publications

benzene combustion mechanism and submechanisms describing the oxidation of key intermediate ... For example, the model predicts the benzene reaction t...
1 downloads 0 Views 125KB Size
10576

J. Phys. Chem. A 2000, 104, 10576-10586

Elementary Reaction Mechanism for Benzene Oxidation in Supercritical Water† Joanna L. DiNaro,‡ Jack B. Howard,§ William H. Green,| Jefferson W. Tester,*,‡ and Joseph W. Bozzelli⊥ Department of Chemical Engineering and Energy Laboratory, Massachusetts Institute of Technology, 77 Massachusetts AVenue, Cambridge, Massachusetts 02139, and Chemistry and Chemical Engineering Department, New Jersey Institute of Technology, Newark, New Jersey ReceiVed: April 13, 2000; In Final Form: August 31, 2000

Supercritical water (SCW) benzene oxidation data were modeled using a published, low-pressure (