Emorganics - C&EN Global Enterprise (ACS Publications)

Nov 6, 2010 - Publication Date: October 31, 1966. Copyright © 1966 AMERICAN CHEMICAL SOCIETY. ACS Chem. Eng. News Archives. First Page Image...
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Emorganics Can you see the big difference between these polyesters ? Probably not, in this illustration. The reflectometer, however, shows the Yellow Index* for the dimethyl terephthalate/ethylene glycol polyester incorporating new Emerox® 1144 Azelaic Acid to be 8 units lower than for the similar polyester modified with sebacic acid shown at left. (See accompanying table for comparison of color and color stability of Emerox 1144, adipic, and sebacic acids.) It's the superior color, color stability, and extremely low monobasic content of Emerox 1144 that allow greater control over the color and molecular weight of end products. These outstanding characteristics are indicative of its purity and quality, so essential in the preparation and modification of high molecular weight condensation polymers, such as polyesters and nylons. Typical composition of Emerox 1144, as % methyl esters by gas chromatography, is as follows: Cg dibasic, 92.00; Cio dibasic, 1.20; C n dibasic, 5.60; other dibasics, 1.16; monobasics, 0.04. *Yellow Index determined on a Gardner Multi-Purpose Reflectometer. The lower the number, the less yellow the sample appears to the eye. Polyester slab stocks were used in this test.

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The odd-carbon (C9) structure of Emerox Azelaic Acid usually improves low-temperature impact strength with no sacrifice in high-temperature performance. Emerox 1144 is now available in commercial quantities. Use coupon to request evaluation sample and descriptive brochure. TYPICAL COLOR AND COLOR STABILITY Emerox Adipic 1144 Acid Sebacic Acid C.P. Purified Grade Grade Color (% Transmission a t 440/550 mmu on 97/99 94/98 74/86 45/80 molten material) 72/93 26/59 75/95 14/48 Color Stability 1 40 40 75 175 Ester Color Test 2 1 % Transmission at 440/550 mmu after holding for 2 hrs. a t 205°C in a test tube open to the air. 2 Determined by preparation of the dioctyl ester under controlled conditions and measurement of the APHA color.

Significant

developments from Emery oleochemical

research

New plasticizer for drycleanable vinyls A new, high molecular weight polymeric plasticizer, spe­ cially developed for use in compounding drycleanable polyvinyl chloride constructions, has just been introduced by Emery. Emery 3745-D, the latest addition to Emery's com­ prehensive line of specialty plasticizers, is highly resistant to perchlorethylene extraction. It also has excellent re­ sistance to extraction by other organic or hydrocarbon solvents. Light color, superior low temperature performance, and good humidity aging are other advantages offered by Emery 3745-D. Excellent efficiency, compatibility, and heat stability contribute to processing ease and economy. Check coupon for performance data and evaluation sample.

Now -- Emerez® Polyamide Resin warehouse facilities in 11 cities Now you can arrange for overnight delivery of any Emerez Polyamide Resin. Emery has warehouse facilities throughout the U.S. and Canada, which, if local area LCL demands warrant, can be stocked for prompt shipment of Emerez Polyamide Resins 1530, 1540,1532, 1535 and 1538. Eleven strategic locations: Boston, Newark, Phila­ delphia, Cincinnati, Cleveland, Chicago, Dallas, Atlanta,, Greenville (S.C.), Los Angeles... London, Ontario, Cana­ da, too! Why pay for storage space when you can count on prompt shipment from the nearest Emery warehouse?

£lKW| INDUSTRIES, INC. Organic Chemicals Division Dept. 116, Carew Tower Cincinnati, Ohio 45202

Please send: Emerox 1144 brochure Π and evaluation sample Π Western Operations, Emery 3745-D data sheet • Santa Fe Springs, California and evaluation sample D Emery Industries (Canada) Ltd., Emerez Polyamide London, Ontario Unilever-Emery N.V., Gouda, The Netherlands brochure Q Export Division, Cincinnati Name Company Address City

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