Enzyme electrodes mediated by a thermoshrinking redox polymer

Apr 1, 1994 - Modification of Ferrocene-Containing Redox Gel Sensor Performance by Copolymerization of Charged Monomers. Hai-zhi Bu, Ann M. English, ...
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Anal. Chem. 1994,66,1002-1006

Enzyme Electrodes Mediated by a Thermoshrinking Redox Polymer Tetsu Tatsuma, Ken-ichi Saito, and Noboru Oyama' Depadment of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and Technolugy, Naka-cho, Koganei, Tokyo 184, Japan

Reagentless glucose oxidase electrodes for glucose were fabricated by the use of poly (N-isopropylacrylamide-ce vinylferrocene) (PAF) which acts both as a charge transfer mediator and as an enzyme support. PAF is a redox polymer which is soluble in water at 28 O C . Glucose oxidase and PAF are well mixed in water at