Exo Stereoselectivity of Intramolecular Diels−Alder

On the Endo/Exo Stereoselectivity of Intramolecular Diels−Alder Reactions of Hexadienylacrylates: An Interesting Failure of Density Functional Theor...
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ORGANIC LETTERS 2005 Vol. 7, No. 20 4547

Additions and Corrections

Volume 4, 2002

Garth A. Jones, Michael N. Paddon-Row,* Michael S. Sherburn,* and Craig I. Turner On the Endo/Exo Stereoselectivity of Intramolecular DielsAlder Reactions of Hexadienylacrylates: An Interesting Failure of Density Functional Theory. Page 3790. In Table 1, entry 5, the correct experimental endo:exo ratio should be 27:73 and not 73:27, as reported. This experimental error led to incorrect conclusions being drawn from our study, i.e., that DFT is inferior to MP theory and that DFT failed in this case. A full paper containing a complete study of this system will be submitted shortly. OL052028R 10.1021/ol052028r Published on Web 08/30/2005