Facts & Figures for the chemical industry - C&EN Global Enterprise

But earnings fell for the second year in a row for the 30 major chemical ... With no turnaround yet in major & chemicals markets, more plants coming o...
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Facts

&Fieii

for the chemical industry No expansion lasts forever, and, as the data graphed and tabulated o n t h e f o l l o w i n g p a g e s of C&EN's annual Facts & Figures issue show, 1990 clearly marked the end of the strong growth the U.S. chemical industry enjoyed through much of the late 1980s. Still, by some measures, 1990 was not a bad year for chemical makers, more of a lackluster one. Sales continued to rise, as they have every year since 1981, though not enough to offset rising raw materials costs. Production posted its second year of only modest expansion, thanks to softening in most important enduse markets for chemicals, particularly housing construction and automobiles. But earnings fell for the second year in a row for the 30 major chemical makers C&EN regularly surveys—22% in 1990. And the outlook is for more of the same before things get better. With no turnaround yet in major

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28

June 24, 1991 C&EN

chemicals markets, more plants coming on stream at a time when capacity utilization is already soft, and the prospect of continuing tightness in raw materials supplies, thanks to events in the Middle East, 1991 isn't shaping up as a turnaround year. The data presented on the following pages illustrate statistically the overall health of the chemical industry both in the U.S. and, to a lesser extent, in several other important chemical-producing nations. The data pulled together here come from a variety of sources, such as government agencies, trade associations, and international organizations, as well as the individual companies that comprise the chemical industry. In many cases, these raw data have been used by C&EN's staff to develop analytical measures and comparisons that help put the industry's recent results into better perspective.

At a glance Section O n e : P r o d u c t i o n

Section F o u r : M a r k e t s

The U.S. chemical industry raised output last year 3%, making 1990 the second year in a row of only modest p r o d u c t i o n increases. Most major sectors of the industry held fairly steady for the year; only plastics, led by 15% increases in output for both polypropylene and low-density polyethylene, showed significant gains. The biggest volume commodity chemicals generally posted gains for the year. Page 30

Chemical markets, like the U.S. economy as a whole, were soft in 1990. As the overall economy moved into a recession at year's end, key markets for chemicals— such as new housing and automobiles—were posting only the latest of several poor years. Agriculture, on the other hand, did well in 1990. Page 62

Section T w o : F i n a n c e s A l t h o u g h sales c o n t i n u e d to climb, setting yet another all-time high in 1990, rising raw materials costs and softening capacity utilization ate into profits and profitability for chemical makers. Overall, earnings dropped 22% among the 30 companies C&EN tracks. Capital spending, however, remained strong, and R&D expenditures increased. Page 39 Section T h r e e : E m p l o y m e n t The number of people working in the chemical industry was essentially unchanged last year at nearly 1.09 million. Scientists and engineers among that number rose to 78,400 in January 1990, 1% higher than their level a year earlier. Women were 30% of the chemical work force in 1989, compared with 33% for manufacturing workers generally. Among the larger chemical companies, overall employment declined 2% in 1990. Page 58

Section Five: F o r e i g n T r a d e U.S. firms exported almost $39 billion in chemicals last year, setting a record high chemical trade surplus of $16.5 billion. Chemical trade worldwide was strong, up 12% when measured in U.S. dollars, though trade volume grew somewhat less. Germany, long the world's largest exporter and importer of chemicals, strengthened its lead in both categories, thanks to unification. Page 64 Section Six: F o r e i g n C h e m i c a l Industries Slowdown was evident in the chemical industry throughout the world in 1990. In Western Europe, drugmakers boosted earnings, but more purely chemical makers did not. Although Japanese production grew for many chemicals, s h a r p rises in oil costs took their toll in company earnings. Recession cut volume and prices for many Canadian chemicals. And Eastern Europe and the Soviet U n i o n posted their worst year in more than four decades. Page 66

June 24, 1991 C&EN

29

Production by the U.S. Chemical Industry

Little change in chemical output last year Production by U.S. chemical makers held steady in 1990. The softening of growth that was evident in most sectors of the chemical industry by the end of 1989 never quite became an actual decline in production during 1990. Instead, by most measures, production changed little last year. According to the Federal Reserve Board, production of chemicals and allied products rose a modest 2% overall in 1990, somewhat less than the 3% gain made in 1989, and right in line with the 2% average annual performance for the group over the past 10 years. The largest volume chemicals, C&EN's Top 50, didn't perform as well, posting a 1.4% gain in 1990 after an annual gain of only 0.8% in 1989. Output for the major organic chemicals rose 1% in 1990, while inorganic production was up 1.6%. Though only inching upward, production for these 50 largest volume chemicals has set new all-time highs each year for the past three. Plastics had the best year of the major chemical sectors, with overall production up 9% in 1990, according to Federal Reserve Board data, and 8% as measured by the Society of the Plastics Industry. But other synthetic materials fared less well. Synthetic rubber production was off 4% for the year as were man-made fibers, including cellulosics. Fertilizers, too, had a moderately good year, with all three major nutrients posting production gains of 5 to 8% for the 1990 crop year, which ended June 30. Some of the biggest losses in production were among large-volume inorganic chemicals. Although the group as a whole rose 1.6% for the year, hydrochloric acid fell 26%, calcium chloride fell 28%, and ammonium nitrate fell 10%. In contrast, sodium hydroxide rose 11% and ammonia rose 4%. As mandated by t h e Montreal protocol, production of chlorofluorocarbons fell sharply in 1990. 30

June 24, 1991 C&EN

Plastics only chemical sector to show much growth in 1990 Production, % running annual growth rate 3

Inorganics Organics i Plastics Fibers Total - 1 0 1

i 11 i i i

M

i i r l i i i 11 i i i i i i 11 i i i i i i i i i i I i i i i i i i i i i i I

1986

1987

1988

1989

M

i i i i i i i >

1990

a Average running annual growth rates in production of major plastics, inorganic and organic chemicals, and all chemicals, and in shipments of man-made fibers. Sources: International Trade Commission, Bureau of the Census, Society of the Plastics Industry, Textile Economics Bureau

I Chemicals hold on to production gains of late 1980s Production index, 3 1987 = 100 Basic chemicals

Chemicals and allied products

9 0 1

i i I i

1986

M

i i

M

11 i 11

1987

i i i i i i 11 11 i 11 i i i i 11 i i i i i 11 11 i i I i i i i 11 i 11 i i I

1988

a Seasonally adjusted. Source: Federal Reserve Board

1989

1990

1991

3

50 CHEMICALS: Very modest growth last year for both organics and inorganics Rank

1990

Billions of lb 1989a

1990

1989

Sulfuric acid Nitrogen Oxygen Ethylene Limec

88.56 57.32 38.99 37.48 34.80

Common unitsb 1990

1989

86.60 53.91 37.42 34.99 34.36

44,281 tt 791 bcf 471 bcf 37,480 mp 17,400 tt

43,301 tt 744bcf 452bcf 34,994 mp 17,178tt

Average annual growth 1989-90

1988-89

2.3% 2.8% 6.3 3.0 4.2 0 7.1 -5.9 1.3 0.7

1985-90

1980-90

1 2 3 4 5

1 2 3 4 5

6 7 8 9 10

6 7 9 10 8

Ammonia Phosphoric acid Sodium hydroxide Propylene Chlorine

33.92 24.35 23.38 22.12 21.88

32.72 23.47 20.98 20.58 22.83

16,958tt 12,175tt 11,688tt 22,117mp 10,942tt

16,362tt 11,735tt 10,492tt 20,575mp 11,413tt

3.6 3.7 11.4 7.5 -4.1

-2.7 0.5 -0.3 -3.1 1.4

-0.4 3.0 1.4 8.2 1.0

-1.5 1.2 0.1 4.9 -0.4

11 12 13 14 15

11 13 12 14 15

Sodium carbonated Ureae Nitric acid Ammonium nitrate' Ethylene dichloride

19.85 15.81 15.50 14.21 13.30

19.83 15.93 16.70 15.74 13.39

9,925tt 7,905tt 7,749tt 7,107tt 13,301 mp

9,915tt 7,963tt 8,349tt 7,871tt 13,385mp

0.1 -0.7 -7.2 -9.7 -0.6

2.9 0.6 4.5 4.9 2.7

3.1 3.4 1.0 1.0 1.9

1.8 0.1 -1.7 -2.5 1.8

16 17 18 19 20

16 17 18 19 21

Benzene Carbon dioxide9 Vinyl chloride Ethylbenzene Styrene

11.86 10.98 10.65 8.99 8.02

11.94 10.68 10.14 9.24 8.34

1,610mg 5,491tt 10,652mp 8,988 mp 8,018 mp

1,621 mg 5,339tt 10,137mp 9,238 mp 8,338 mp

-0.7 2.8 5.1 -2.7 -3.8

1.8 5.6 11.9 -7.0 -7.2

4.8 1.9 2.4 4.0 1.0

-2.2 6.2 5.1 1.6 1.6

21 22 23 24 25

22 20 23 30 25

Methanol Terephthallc acidh Formaldehyde' Methyl ferf-butyl ether* Toluenek

7.99 7.69 6.41 6.30 6.10

8.17 8.43 5.89 8.23 5.81

7,987mp 7,692mp 6,413mp 6,302 mp 841 mg

8,168mp 8,427mp 5,894mp 8,229 mp 801 mg

2.2 -8.7 8.8 -23.4 5.0

0.3 -17.7 -6.1 44.9 -8.5

9.8 3.5 2.7 27.2 3.8

1.1 2.4 1.4 na -1.9

26 27 28 29 30

26 29 28 27 31

Xylene Ethylene oxide p-Xylene Ethylene glycol Ammonium sulfate

5.70 5.58 5.20 5.03 4.99

5.80 5.03 5.35 5.46 4.69

791 mg 5,581 mp 5,201 mp 5,028 mp 2,495tt

805 mg 5,032mp 5,345mp 5,462 mp 2,347tt

-1.7 10.9 -2.7 -7.9 6.3

5.8 -15.5 -4.6 -1.0 0.6

1.4 0.6 1.7 3.8 3.6

-1.4 0.7 2.1 1.4 1.6

31 32 33 34 35

24 32 34 35 33

Hydrochloric acid Cumene Acetic acid Potash1 Phenol"1

4.68 4.31 3.76 3.62 3.51

6.35 4.43 3.29 3.52 3.81

2,341 tt 4,312 mp 3,756mp 1,640tmt 3,512mp

3,177tt 4,427 mp 3,294mp 1,595tmt 3,807mp

-26.3 -2.6 14.0 2.8 -7.7

20.3 -0.6 4.3 4.9 6.9

-3.5 5.2 5.3 4.8 4.8

-2.1 2.2 2.4 -3.1 3.2

36 37 38 39 40

36 37 39 38 42

Propylene oxide Butadiene" Acrylonttrile Carbon black Vinyl acetate

3.20 3.16 3.03 2.87 2.55

3.20 3.12 2.36 2.91 2.55

3,200mp 3,156mp 3,029 mp 2,868mp 2,546 mp

3,200mp 3,122mp 2,363 mp 2,913mp 2,553 mp

0 1.1 28.2 -1.5 -0.3

2.9 -1.5 -9.4 -0.1 -0.3

5.9 6.2 5.2 2.2 3.8

6.1 1.2 5.2 1.2 2.8

41 42 43 44 45

43 41 40 44 46

Cyclohexane Aluminum sulfate Acetone Titanium dioxide Sodium silicate

2.47 2.42 2.22 2.16 1.76

2.27 2.49 2.53 2.20 1.67

2,468mp 1,208tt 2,221 mp 1,079tt 878tt

2,274mp 1,244tt 2,525mp 1,101tt 834tt

8.5 -2.9 -12.0 -2.0 5.3

-1.0 1.0 9.6 7.7 2.7

8.3 -1.0 4.4 4.6 4.9

2.3 -0.6 0.7 4.2 0.9

46 47 Adipicacid 47 48 Sodium sulfate0 48 45 Calcium chloride" 48 49 Isopropyl alcohol 48 50 Caprolactam TOTAL ORGANICS TOTAL INORGANICS GRAND TOTAL

1.64 1.47 1.38 1.38 1.38 216.82 409.07 625.89

1.64 1.51 1.92 1.47 1.31 214.68 402.51 617.19

1,640mp 733tt 690 tt 1,380mp 1,380mp

1,640mp 755tt 962 tt 1,474mp 1,308mp

0 -2.9 -28.3 -6.4 5.2 1.0% 1.6% 1.4%

2.5 -7.6 32.0 6.1 4.0 -1.4% 2.0% 0.8%

2.5 -2.4 -2.9 2.2 5.0 4.6% 2.1% 2.9%

1.1 -4.3 -3.5 -2.8 4.3 2.1% 0.5% 1.0%

.

2.1% 0 % 3.8 5.1 3.7 0.9 4.7 2.7 1.9 -0.9

a Revised, b tt = thousands of tons, bcf = billions of cubic feet, mp = millions of pounds, mg = millions of gallons, tmt = thousands of metric tons, c Except refractory dolomite, d Natural and synthetic, e 100% basis, f Original solution, g Liquid and solid only, h Includes both acid and ester without double counting, i 37% by weight, j Production data for earlier years unavailable. k All grades. I K 2 0 basis, m Synthetic only, η Rubber grade, ο High and low purity, ρ Solid and liquid, na = not available.

June 24, 1991 C&EN 31

PRODUCTION: Like manufacturing as a whole, most chemicals rose only slightly in 1990 Annual change

Industrial production indexes, 1987 = 100

1990

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

1989-90

1980-90

Total index Manufacturing, total Nondurable manufacturing Chemicals and products Chemicals and synthetic materials

109.2 109.9 107.8 110.3 107.2

108.1 108.9 106.4 108.5 106.5

105.4 105.8 103.6 105.4 102.5

100.0 100.0 100.0 100.0 100.0

95.3 94.3 94.9 94.6 93.9

94.4 91.6 91.5 91.4 92.2

92.8 89.3 90.8 91.4 92.8

84.9 80.9 87.0 87.5 88.6

81.9 76.6 82.5 81.8 79.4

85.7 80.3 84.5 89.2 91.2

84.1 78.8 83.1 87.8 86.3

Basic chemicals Alkalies and chlorine Industrial gases Inorganic pigments Inorganic chemicals, nee

108.6 99.5 109.2 104.3 110.1

106.6 103.2 108.0 111.0 105.7

98.3 96.0 104.1 102.6 96.4

100.0 100.0 100.0 100.0 100.0

95.1 92.1 98.8 96.2 94.7

96.1 93.6 92.8 95.1 97.2

96.9 95.3 97.5 89.0 98.0

92.1 87.9 85.9 87.3 94.3

86.5 82.1 80.1 79.1 89.2

96.9 94.6 91.2 90.7 98.7

96.5 101.5 91.5 90.6 96.8

Industrial organic chemicals

107.1

109.2

103.1

100.0

95.1

94.1

93.4

89.9

81.0

97.0

92.8

Synthetic materials Plastics materials Synthetic rubber Man-made fibers

106.5 115.8 88.6 92.7

103.1 106.7 92.4 98.7

104.4 106.8 105.0 99.5

100.0 100.0 100.0 100.0

91.6 88.2 109.3 93.7

86.9 84.1 114.4 86.6

88.9 81.1 132.8 93.3

84.3 74.4 124.1 92.3

71.8 64.4 110.5 76.4

79.5 68.3 114.5 91.7

71.2 64.2 110.8 74.9

Chemical products Drugs and medicines Soaps and toiletries Paints

113.3 114.0 112.3 99.5

110.1 108.1 111.1 104.8

107.5 107.2 107.9 103.9

100.0 100.0 100.0 100.0

95.9 96.7 96.7 97.5

90.2 88.5 91.3 95.7

89.0 86.9 90.6 91.8

86.6 86.1 91.4 84.6

83.0 82.7 89.2 78.8

85.4 80.9 97.7 84.1

87.6 80.2 103.5 87.0

Agricultural chemicals

105.1

108.2

107.2

100.0

88.5

96.1

102.0

87.5

88.8

102.3

97.2

-3

1

Petroleum products

108.2

106.1

103.4

100.0

98.9

92.6

92.8

89.6

89.3

94.1

99.0

2

1

Rubber and plastics products

110.2

108.9

105.9

100.0

90.8

85.8

83.8

74.3

65.9

66.6

61.7

1

6

3% 3 3 2 2

1% 1 1 2 1

-2

nee = not elsewhere classified. Source: Federal Reserve Board

Only potash, which is largely imported, showed strong growth in 1990 Annual change 1990a

Thousands of tons b

1989

1988

1987

1984

1986

1983

1982

1981

1980

1989-90

1980-90

a

180

168

155

160

193

185

200

189

189

a

731

658

780

940

1,036

912

853

917

811

-14

-2

17,178 16,658 15,733 14,474 15,690 15,922 14,867 14,075 18,890 19,037

1

-1

-8 -11

-2 -7

2,468 5,481 6,999

3 22 15

-3 -2 -2

Salt, productionh Evaporated' Rock' Salt in brine1

39,400d 39,278 39,170 36,943 37,282 39,217 39,181 32,973 37,665 38,899 40,396 6,700d 7,070 7,203 6,896 6,316 6,162 6,334 5,276 5,273 6,206 6,358 14,200d 14,140 12,750 12,230 13,333 13,990 13,653 11,870 12,806 11,866 11,806 18,500d 18,068 19,218 17,817 17,633 19,065 19,195 15,827 19,586 20,826 22,231

0 -5 0 2

nc nc nc nc

Sodium carbonate, production*

10,098

8,275

2

2

Sulfur, production1" Apparent consumption1 Frasch, production Recovered elemental, production Other, production

12,484 14,082 3,968 7,110

12,778 11,845 11,616 12,221 12,797 11,742 10,240 10,788 13,388 13,080 13,983 14,012 12,481 11,669 13,192 13,976 12,112 11,088 14,093 15,056 4,286 3,499 3,530 4,457 5,524 4,622 3,530 4,641 6,997 7,044 7,176 7,103 6,791 6,411 5,857 5,747 5,462 4,855 4,695 4,490

-2 1 -7 -1

0 -1 -6 5

7

-3

Bromine, sold or used

Calcium chloride, production

193 cd

Lime, sold or used0 Lithium, consumption

690 17,400 3.0

Phosphate rock Marketable production Exports

50,700 7,700

Potash (K 2 0 equivalent)9 Production Imports Apparent consumption

1,810 4,590 5,680

1,405

193 801

3.0

3.0

2.7

2.6

2.5

3.2

2.2

2.0

3.2

9,915

1,316

1,677 4,648 5,803

9,632

1,243

1,391 4,490 5,609

8,891

1,296

1,325 4,643 5,338

8,438

1,354

1,429 5,063 5,893

8,511

1,416

1,724 5,323 6,638

8,511

1,372

1,575 4,894 6,231

8,467

1,249

1,967 4,253 5,647

7,819

1,293

2,377 5,287 6,849

8,281

1,695

0%

3.0

54,913 50,000 45,145 44,445 56,035 54,230 46,928 41,241 59,110 59,982 8,644 8,920 9,319 8,651 10,071 12,707 13,239 10,849 11,458 15,737 1,758 3,759 4,960

0%

1,547

a Preliminary, b Elemental bromine sold as such or used in preparation of bromine compounds by primary producers, c 75% CaCI2 equivalent, d Estimated, e Includes Puerto Rican production, f Lithium content basis, g Includes muriate and sulfate of potash, potassium magnesium sulfate, and parent salts; excludes other chemical compounds containing potassium. h Figures for 1980 are total obtained by all recovery methods that was sold or used by domestic producers (slightly different from U.S. production); figures for 1980-81 include Puerto Rican production. I Sold or used as such, j Natural and synthetic for 1980-86, natural only in 1987-90. k Sulfur content basis. I Calculated from shipments plus imports minus exports (sulfur content basis), nc = not comparable. Sources: Bureau of Mines, Bureau of the Census

32

June 24, 1991 C&EN

1

Production by the U.S. Chemical Industry

U.S Biggest volume organics generally did well in otherwise mixed field ORGANIC CHEMICALS: Annual c;hange

Production

Millions of lb unless otherwise noted

1990a

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

Acetic acid, synthetic Acetone Acrylonitrile Aniline Benzene, mg bc

3,755 2,221 3,029 947 1,615

3,294 2,524 2,362 1,016 1,631

3,159 2,303 2,609 1,029 1,608

3,246 1,846 2,452 829 1,575

2,728 1,910 2,182 824 1,362

2,897 1,788 2,349 716 1,283

2,619 1,862 2,219 786 1,318

2,807 1,859 2,146 663 1,232

2,748 1,694 2,035 557 1,052

2,705 2,144 1,997 634 1,308

2,977 2,076 1,830 659 1,534

14% -12 28 -7 -1

Bisphenol A 1,3-Butadiened 1-Butanol Caprolactam Carbon tetrachloride

1,141 3,155 1,269 1,379 271

1,241 3,121 1,751 1,307 na

1,340 3,169 1,194a 1,261 761

1,000 2,931 1,155 1,156 672

956 2,546 881 1,109 627

949 2,340 716 1,089 646

762 2,452 908 1,027 713

643 2,353 833 977 573

480 1,915 730 793 587

555 2,986 809 928 726

530 2,799 790 905 710

-8 1 -28 5



8 1 5 4 -9

Chloroform Cumene Cyclohexane Dioctyl phthalate Ethanol, synthetic

497 4,311 2,467 302 na

588 4,426 2,273 306 549

524 4,455 2,297 344 562

462 4,105 2,276 343 574

422 3,745 2,070 296 529

275 2,627 1,657 275 649

405 3,754 1,994 301 1,060

362 3,345 1,656 300 1,077

299 2,743 1,275 266 1,023

405 3,309 1,820 304 1,317

273 3,459 1,964 353 1,451

-15 -3 9 -1

6 2 2 -2





376 429 667 679 416 468 504 627 608 537 543 7,642 8,987 9,235 7,876 6,656 7,813 7,562 9,346 9,929 9,020 7,386 396 324 162 339 282 152 na 290 171 155 164 37,474 34,988 37,204 34,951 32,859 29,847 31,383 28,680 24,501 29,418 28,667 9,974 11,108 7,619 13,299 13,383 13,028 12,197 12,940 12,101 10,710 11,506

2 -3

6 2





7 -1

3 2

Ethanolamines Ethylbenzene Ethyl chloride Ethylene Ethylene dichloride

1989-90

1980-90

2% 1 5 4 1

Ethylene glycol Ethylene oxide 2-Ethylhexanol Formaldehyde, 37% f Isobutylene

5,027 5,580 596 6,412 1,145

5,461 5,031 612 5,893 1,193

5,517 5,953 743 6,280 1,244

5,183 4,785 662 5,733 1,035

4,771 5,430 571 5,549 1,124

4,178 5,430 536 5,606 na

4,823 5,699 541 5,815 883

4,425 5,534 387 5,465 760

4,309 4,987 325 4,817 741

4,143 4,937 389 5,721 1,035

4,386 5,220 367 5,555 1,052

-8 11 -3 9 -4

1 1 5 1 1

Isopropyl alcohol Maleic anhydride Methanol, synthetic Methyl chloride Methyl ethyl ketone

1,380 418 7,986 498 473

1,474 475 8,167 461 450

1,389 448 8,142 597 482

1,371 382 7,537 373 672

1,301 359 7,205 605 600

1,235 394 5,003 410 537

1,394 359 8,186 482 543

1,209 299 7,982 409 531

1,380 260 7,555 366 468

1,669 293 8,577 405 614

1,836 304 7,153 362 692

-6 -12 -2 8 5

-3 3 1 3 -4

Methyl methacrylate Methylchloroform Methylene chloride Perchloroethylene Phenol, synthetic9

1,207 785 471 384 3,512

1,161 783 482 481 3,806

1,100 724 504 498 3,562

1,029 694 516 473 3,351

943 652 566 414 3,115

858 869 467 678 2,841

917 675 607 573 2,889

844 586 584 547 2,638

721 595 532 585 2,023

592 611 891 691 2,578

564 587 780 765 2,568

4 0 -2 -20 -8

8 3 -5 -7 3

Phthalic anhydride Propyleneh Propylene glycol Styrene, monomer Terephthalic acid, dimethyl ester1

941 917 999 22,113 20,571 21,224 805 800 840 8,017 8,337 8,984

1,035 19,019 747 8,014

863 16,522 573 7,888

820 14,887 500 7,622

870 15,559 462 7,709

838 13,959 484 6,802

684 12,535 400 5,942

870 13,482 473 6,679

818 13,676 488 6,856

3 8 -1 -4

1 5 5 2

7,690

8,426

10,234

7,601

6,257

6,490

5,912

5,626

4,843

6,235

6,054

-9

2

Toluene, mgbj Vinyl acetate Vinyl chloride o-Xylene p-Xylene

843 2,545 10,650 943 5,200

806 2,552 10,135 983 5,344

892 2,561 9,058 971 5,601

967 1,813 8,402 940 5,155

611 1,710 8,439 788 5,035

698 2,112 9,463 675 4,779

728 2,024 6,084 688 4,264

780 1,963 6,875 781 4,114

714 1,876 4,902 802 3,391

852 1,936 6,874 918 4,532

1,010 1,922 6,466 995 4,238

5 0 5 -4 -3

-2 3 5 -1 2

Note: mg = millions of gallons, a Preliminary, b Tar distillers and coke-oven operators not included, c Specification grades, d Rubber grade, e Mono-, di-, and triethanolamines. f By weight. g Does not include data for coke ovens and gas-retort ovens, h All grades, i Includes both acid and dimethyl ester (DMT), without double counting, j High-purity toluene, includes material used in blending motor fuel, na = not available. Source: International Trade Commission

June 24, 1991 C&EN 33

INORGANICS: Mixed results mark production for both the year and the decade Annual change

Production

Thousands of tons unless otherwise noted

1990a

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

1,208 16,958 7,107 2,495

1,243 16,362 7,871 2,347

1,237 16,821 7,504 2,333

1,227 16,098 6,547 2,189

1,222 14,487 6,091 2,080

1,268 17,319 7,149 2,093

1,129 16,692 7,146 2,067

1,119 14,072 6,240 1,956

1,154 15,801 7,091 1,768

1,294 19,044 8,861 2,185

10,943

11,413

11,257

11,078

10,436

10,402

10,700

9,960

9,176

2,341 188 204

3,177 208 204

3,228 177 168

2,996 173 153

2,413 136 152

2,807 121 144

2,732 109 139

2,468 103 117

7,749 791 471

8,349 744 452

7,991 722 452

7,225 685 405

6,734 677 383

7,631 665 393

7,726 661 375

12,175

11,737

11,659

10,599

9,578

10,607

Phosphorusm Sodium chlorate, 100% Sodium hydroxide, 100% Sodium phosphate"

356 353 308 290 11,688 10,491 568° 610°

343 267 10,533 549

344 289 11,553 586

364 267 10,691 617

359 259 10,811 625

Sodium silicate' Sodium sulfate, 100% q Sulfuric acid, 100% r Titanium dioxide, 100% s Urea

3

Aluminum sulfate* Ammonia, 100% c d Ammonium nitrate, 100% e Ammonium sulfate, 100% d f Chlorine gas9 h

Hydrochloric acid, 100% Hydrogen, bcf, 100% IJ Hydrogen peroxide, 100%k Nitric acid, 100% k Nitrogen gas, bcf, 100% u Oxygen, bcf, 100% u Phosphoric acid, 100% r

2v5

1989-90

1980-90

1,286 19,653 9,128 2,136

-3% 4 -10 6

-1% -1 -2 2

10,763

11,421

-4

0

2,450 88 108

2,574 105 111

2,888 107 116

-26 -10 0

-2 6 6

6,768 560 346

7,390 483 349

9,093 490 431

9,231 479 431

-7 6 4

-2 5 1

11,370

9,767

8,253

9,958

10,848

4

1

386 295 10,914 675

366 323 10,039 669

361 291 9,385 651

426 297 10,621 696

432 312 11,625 727

1 6 11 -7

-2 0 0 -2

771 878 664 812 833 805 710 685 952 791 692 733 864 819 755 1,140 1,111 914 901 837 799 1,203 44,281 43,301 42,580 39,256 35,993 39,890 41,802 36,583 33,233 40,742 44,158 1,022 1,079 727 660 761 1,101 760 835 931 968 860 7,905 7,963 7,914 7,433 6,264 6,975 7,433 6,137 6,470 8,062 7,830

5 -3 2 -2 -1

1 -4 0 4 0

Note: bcf = billions of cubic feet, a Preliminary, b Commercial, 17% Al 2 0 3 ; includes municipalities, c Synthetic anhydrous, d Excludes by-product ammonia liquor and ammonium sulfate, e Original solution, f Synthetic and noncoke by-product, g Includes quantities liquefied for use, storage, or shipment, h Includes anhydrous hydrochloric acid production, i High- and low-purity gas. J Liquid and gas; excludes amounts vented and used as fuel, and amounts produced in petroleum refineries for captive use. k Includes unspecified amounts produced but not withdrawn from the system. I Excludes amounts produced and consumed in making synthetic ammonia or ammonia derivatives, m Elemental, white (yellow), and red. n Tripolyphosphate (100% Na5P3O10). o Includes tetrabasic (pyro) phosphate, p Soluble silicate glass (water glass), solid and liquid (anhydrous); excludes amounts produced and consumed in making meta-, ortho-, and sesquisilicates. q Anhydrous, high and low purity, and Glauber's salt, r Gross (new and fortified), s Composite and pure. Sources: Department of Commerce, International Trade Commission

Synthetic noncellulosic fibers output Billions of lb 9

SYNTHETIC FIBERS Production declines for all fibers except polyolefins 1980 81 82 83 84 85 86 87 88 89 90 Annual change Millions of lb

1990

NONCELLlILOSIC FIBIERS Acrylic3 506 2662 Nylonb 1822 Olefin0 Polyester 3195 CELLULOSIC FIBERS Acetated 505 Rayon TOTAL 8690

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

1989-90

1980-90

543 2740 1639 3594

588 2669 1588 3681

592 2689 1494 3541

616 2514 1393 3305

631 2343 1249 3341

671 2412 997 3392

671 2419 906 3544

624 1927 723 3196

691 2332 785 4176

779 2358 748 3989

-7% -3 11 -11

-4% 1 9 -2

580

614

605

619

558

9096

9140

8921

8447

8122

f 199 \421 8092

229 401 8168

196 388 7027

261 509 8754

316 \ 490} 8680

~13 -4%

"5 0%

a Includes modacrylic. b Excludes aramid in 1983-87. c Includes olefin yarn and monofilaments and olefin and vinyon staple, tow, and fiberfill. d Includes diacetate and triacetate; excludes production for cigarette filters. Source: Fiber Economics Bureau

34 June 24, 1991 C&EN

1

Production by the U.S. Chemical Industry

SYNTHETIC RUBBER: Output decline, which began in 1989, accelerated in 1990 Annual change

Production Thousands of metric tons

Ethylene-propylene Nitrile Polybutadiene Styrene-butadiene rubber Other3 TOTAL

1990

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

256 56 403 853 546 2114

260 69 411 874 647 2261

263 76 407 909 679 2335

254 69 371 850 638 2182

230 59 336 792 596 2013

215 53 330 735 505 1838

215 67 359 958 556 2155

175 55 333 904 468 1935

123 45 288 876 498 1830

178 66 342 1032 404 2022

144 63 311 1074 423 2015

1989-90

-2% -19 -2 -2 -16 -7%

1980-90

6% -1 3 -2 3 0%

a Includes butyl, polychloroprene, polyisoprene, silicone, and other synthetic elastomers. Some values are estimated. Source: Rubber Manufacturers Association

Plastics production Billions of lb 60

PLASTICS: Production of major resins moved ahead last year

40 20 0 1—i i i i i 1980 81 82 83 84 85 86

i i i 87 88 89 90

Annual change Millions of lba

1990

1989

1988

1987

1986

1985

1984

1983

1982

THERMOSETTING RESINS Epoxyb Melamine Phenolic6 Polyester6 Urea TOTAL

499 202 2,946d 1,221 1,496 6,364

509 222 2,879d 1,319 1,477 6,408

486 207 3,066d 1,404 1,425 6,588

433 212 2,869d 1,367 1,382 6,263

398 173 2,735d 1,271 1,271 5,848

385 192 2,621d 1,223 1,210 5,631

406 210 2,502d 1,232 1,199 5,549

334 180 2,477d 1,084 1,172 5,247

336 286 179 158 2,006d 2,333d 997 865 1,165 998 5,010 4,313

THERMOPLASTIC RESINS. Polyethylene Low density' High density9 Polypropylene Styrene polymers Polystyrene Styrene-acrylonitrile Acrylonitrlle-butadienestyrene and other styrene polymersh Polyamlde, nylon type Vinyl resins Polyvinyl chloride and copolymers Other vinyl resins' Thermoplastic polyester TOTAL

1981

1989-90

1980-90

315 167 1,499 947 1,165 4,093

-2% -9 2 -7 1 ~1%

5% 2 nc 3 3 nc%

1980

11,176 8.334 8,318

9,695 8,102 7,238

10,397 8,400 7,274

9,599 7,995 6,647

8,903 7,182 5,812

8,889 6,671 5,139

8,413 6,085 4,940

8,041 5,689 4,433

7,503 4,928 3,477

7,693 4,695 3,955

7,291 4,405 3,648

15 3 15

4 7 9

5,012 134 2.335

5,104 113 2,394

5,187 148 2,418

4,780 126 2,254

4,470 92 2,196

4,054 87 2,036

3,838 99 2,127

3,570 93 1,889

3,191 91 1,380

3,621 107 1,745

3,521 111 1,705

-2 19 -2

4 2 3

556

569

566

507

465

399

396

321

228

312

274

-2

7

9,088

8,478

8,350

7,971

7,256

6,772

6,760

6,067

5,326

5,707

5,470

7

5

226 1,879

220 1,630

222 1,652

212 1,394

195 1,175

190 965

187 899

186 778

177 648

208 609

196 na

3 15

1

47,058

43,543

44,614

41,485

37,746

35,202 33,744

31,067

26,949

28,652

26,621

8%

6%

Note: Totals are for those products listed and exclude some small-volume plastics, a Dry-weight basis unless otherwise specified, b Unmodified, c Includes other tar acid resins, d Grossweight basis, e Unsaturated, f Density 0.940 and below, g Density above 0.940. h Includes styrene-butadiene copolymers and other styrene-based polymers, i Includes polyvinyl butyral, polyvinyl formal, and polyvinylidene-chloride. na = not available, nc = not comparable. Source: Society of the Plastics Industry

June 24, 1991 C&EN 35

1

Production by the U.S. Chemical Industry

Fertilizer consumption Millions of tons 30 Total 20

FERTILIZERS: All major nutrients had increased use in 1990 crop year

Potash (K 2 0) Phosphates (P 2 0 5 ) llllllllilllllllsi

10

\ 0 1980

Nitrogen (N) I 81

l_ 82

I 83

L 84

1—--- i 85 86

i 87

i 88

i

l 90

89

Note: Years ending June 30. Sources: Department of Agriculture, Fertilizer Institute

Annua change

Consumption

Nitrogen (N) Phosphates (P205) Potash (K20) TOTAL

1989-90

1990

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

11,076 4,345 5,203 20,624

10,593 4,117 4,838 19,548

10,512 4,129 4,973 19,614

10,210 4,008 4,837 19,055

10,424 4,178 5,053 19,655

11,493 4,658 5,553 21,704

11,092 4,901 5,797 21,790

9,127 4,138 4,831 18,096

10,983 4,814 5,631 21,428

11,924 5,434 6,320 23,678

11,407 5,432 6,245 23,084

Thousands of tons

5% 6 8 6%

1980-90

0% -2 -2 -1%

Note: Years ending June 30. Source: Fertilizer Institute

ION: Phosphate rock declined, ammonia and potash showed little change FERTILIZER PRODUCTION: Annual change Thousands of tons

1989-90

1983-90

1990

1989

1988

1987

1986

1985

1984

1983

14,167 2,579 2,395 4,231 4,750

14,192 2,528 2,327 4,253 5,644

14,136 2,765 2,260 4,501 6,999

13,357 2,472 2,153 4,253 5,988

12,565 2,250 2,058 3,564 5,945

16,594 3,178 2,343 3,975 7,928

16,613 3,365 2,078 4,889 7,999

13,361 3,232 1,969 4,112 6,385

0% 2 3 -1 -16

1% -2 2 0 -3

13,860 2,252 1,998 44,311 11,344

13,507 1,991 1,777 47,676 10,962

11,575 1,818 2,032 42,220 10,234

9,537 1,679 2,049 39,330 8,903

7,492 1,416 2,127 36,227 8,085

10,800 1,641 2,570 49,348 9,837

12,358 1,654 2,404 47,465 10,899

10,264 1,423 2,684 40,664 9,182

3 13 12 -7 3

4

2,350

2,316

2,243

1,810

1,715

1,713

2,168

1,928

NITROGEN PRODUCTS Ammonia Ammonium nitrate Ammonium sulfate Urea Nitrogen solutions PHOSPHATE PRODUCTS Dlammonium phosphate Monoammonium phosphate Concentrated superphosphate Phosphate rock Phosphoric acid (P205) POTASH PRODUCTS Potassium chloride

Note: Figures are based on Fertilizer Institute surveys and may not represent the entire industry. Source: Fertilizer Institute

36

June 24, 1991 C&EN

6 -3 1 3

PESTICIDES: Strong growth in 1989 helps insecticides recover from declines of early 1980s Annual change

Production Millions of lb 3

Herbicides Insecticides*3 Fungicides0 TOTAL

1989

1988

1987

1986

1985

1984

1983

1982

1981

1980

1979

697 424 111 1232

702 352 110 1164

556 379 105 1040

725 342 113 1180

756 370 109 1235

716 350 123 1189

604 306 106 1017

623 379 111 1113

839 448 143 1430

806 506 156 1468

657 617 155 1429

1988-89

1979-89

-1% 20 1 6%

1% -4 -3 -1%

a Includes plant growth regulators, b Includes rodenticides, soil conditioners, and fumigants. c Includes dithiocarbamates. Source: International Trade Commission

Paints and coatings shipments Millions of gal 1100

1000

COATINGS: Decline in major uses drops overall volume below 1989 level

1980 81 82 83 84 85 86 87 88 89 90 Annua1 change

Shipments Millions of gal

1990a

1989a

1988

1987

1986

1985

1984

1983

1982

1981

1980

1989-90

Architectural Product5 Special purpose TOTAL

517 324 161 1002

552 358 159 1069

536 366 154 1056

527 340 145 1013

501 350 136 987

477 317 145 939

457 336 145 938

433 294 130 857

374 280 129 783

417 312 129 858

439 316 135 890

-6% 10 1 -6%

1980-90

2% 0 2 1%

a Preliminary, b For original equipment manufacturers. Source: Department of Commerce

AEROSOLS: Production growth of 1980s has stalled Annual change

Production 1981

1980

1989-90

Millions of units

1990

1989

1988

Personal products Household products Automotive and industrial products Paints and finishes Insect sprays Food products Animal products Miscellaneous TOTAL

1050 680 415

1015 680 475

1100 650 440

964 640 379

952 635 375

879 630 342

832 603 337

747 586 303

628 556 286

645 575 302

637 580 310

3% 0 -13

350 190 175 8 15 2883

350 197 175 8 12 2912

331 190 157 8 31 2907

307 190 140 22 80 2722

297 193 136 22 18 2628

290 190 140 15 23 2509

307 184 138 16 15 2432

300 180 132 19 15 2282

295 166 131 19 13 2094

313 173 145 14 28 2195

310 150 130 15 30 2162

0 -4 0 0 25 -1%

1989-90

1987

1986

1984

1985

1982

1983

1980-90

5% 2 3 1 2 3 -6 -7 3%

Source: Chemical Specialties Manufacturers Association

CHLOROFLUOROCARBONS: Production for all major types falls sharply Annual change

Production Millions of lb

1990a

Chlorodifluoromethane (F-22) Dlchlorodlfluoromethane (F-12) Trichlorofluoromethane (F-11) All other ffluorinated hydrocarbons'5 TOTAL

306 209 135 na

343 392 192 385

333 414 249 379

275 335 198 354

271 322 202 344

235 302 176 306

254 337 185 337

na

1312

1374

1162

1139

1019

1113

1989

1988

1987

1986

1985

1984

1980-90

1982

1981

1980

236 290 215 279

174 258 140 na

252 325 163 na

227 296 158 na

-11% -47 -30

3% -3 -2





1020

na

na





1983

a Preliminary, b Includes other fluorohalogenated hydrocarbons, na = not available. Source: International Trade Commission

June 24, 1991 C&EN 37

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^

I Finances of the U.S. Chemical Industry

Chemical earnings, profitability decline Last year brought few surprises for the chemical industry. It was expected that 1990 would be a continuation of the lackluster second half of 1989, and that is just what it turned out to be, although there were some extras that perhaps made the year somewhat worse than some industry observers predicted. Chief among these was perhaps the r u n u p in raw materials costs brought on by the Middle East situation. This was coupled with already w e a k e n i n g capacity u t i l i z a t i o n caused by softening in such end-use markets as housing construction and automobiles and other durable goods, and by new plants coming on stream. The result was increased pressure on profits in the chemical industry and a classic cost-price squeeze. Combined earnings for the 30 major chemical companies regularly surveyed by C&EN dropped 22% in 1990 from the year-earlier level. This is the fourth earnings contraction since 1980, with the others occurring in 1981, 1985, and the small drop-off registered in 1989. But the 22% drop is the largest since earnings fell about 35% in 1981. Spurred in part by exports and by price increases, sales at the 30 companies held up, however. Sales in 1990 rose about 7% from their 1989 levels, making it yet another record year. Naturally, 1990 profitability followed earnings on the downward course. Return on year-end stockholders' equity fell to 14.0% in 1990 from 20.2% in 1989. And the average profit margin for the 30 chemical firms dropped to 6.3% last year from 8.6% the year before. This, however, is not quite so bad as it seems since both measures are still reasonably good on a historical basis. Although during the past few years the industry has gotten fairly spoiled by high returns, profitability in 1990 was still higher than any

year during the past decade (except for 1987 through 1989). Thus far, the current year is a continuation of 1990. Earnings are continuing on their downward slide from year-earlier levels, causing profitability also to continue downward. Chemical producers are hoping for an upturn in the second half of this year and, indeed, there are some signs that this may be more than wishful thinking. First-quarter earnings and profitability were both

higher than they had been in the fourth quarter of 1990, showing some increased business activity. And some markets, such as residential construction, have in the past couple of months shown some signs of strengthening. Others, however, are still in the doldrums. However, even if producers are correct in forecasting a better second half, the best they can hope for is that 1991 will be flat when compared with the previous 12 months. June 24, 1991 C&EN

39

TOP 100 CHEMICAL PRODUCERS; Profits fall substantially for many of the largest firms Chemical Change sales 1990 from ($ millions) 1989

Rank 1990 1989

1 2 3 4 5

1 2 3 4 5

6 7 8 9 10

6 8 7 9 10

Hoechst Celanese General Electric Occidental Petroleum BASF Amoco

5,499 5,167d 5,040 4,366 4,087

-2.8 4.8 -2.4 -2.1 -4.4

11 12 13 14 15

11 12 13 15 14

Mobil Shell Oil Eastman Kodak W. R. Grace Chevron

4,084 3,718 3,588 3,570 3,325

Arco Chemical Rohm & Haas Allied-Signal Air Products6 Bayer USA

2,830 2,824 2,786 2,614 2,380

Du Pont Dow Chemical Exxon Union Carbide Monsanto

Chemical sales as % of total sales

$15,571 2.1% 38.9% 14,690 3.6 74.3 11,153 5.6 9.6 7,621d - 0 . 4 100.0 5,711 - 1 . 2 63.5

Industry classification

Chemical operating Change profits3 from ($ millions) 1989

- 2 8 . 9 % 40.1% -45.7 68.3 -54.1 8.1 -17.0 100.0 68.6 -32.8

12.6% $13,788 13,604 13.1 8,548 6.6 13.6 7,613 10.9 4,831

36.2% 14.3% 56.8 14.2 9.7 8.6 87.2 13.6 52.3 12.9

105.4 13.2 23.4 na 6.4

7.8 19.7 12.6 na 6.2

na 7,973 5,494 na 3,646

na 5.2 27.8 na 11.5

na 12.8 11.6 na 6.9

-47.1 -44.8 -6.4 6.9 -91.7

7.6 26.6 21.2 77.9 0.9

9.7 14.0 16.8 12.1 1.3

3,265 3,952 3,952 2,756 2,622

7.8 13.9 16.4 44.3 7.5

12.2 13.1 15.2 15.6 1.7

469 351 287 441 91 f

-19.1 22.3 -19.2 3.6 -24.9

100.0 100.0 39.3 108.0 61.2

16.6 12.4 10.3 16.9 3.8f

3,739 100.0 2,414 100.0 1,896 18.1 3,132 80.3 na na

12.5 14.5 15.1 14.1 na

Specialty chemicals Basic chemicals Petroleum Basic chemicals Petroleum

na 195 70 167 448

na -15.0 -45.3 22.8 -31.3

na 62.2 21.1 69.0 21.3

na 8.7 3.1 7.6 21.1

na 1,832 856 1,860 1,797

na 36.0 16.7 50.3 14.8

na 10.7 8.2 9.0 24.9

52.0 73.8 79.7 100.0 29.1

Specialty chemicals Basic chemicals Basic chemicals Basic chemicals Petroleum products

na 242 129 152 na

na -42.7 -50.4 11.6 na

na 95.1 85.2 100.0 na

na 12.4 6.7 8.0 na

na 2,235 1,521 na na

na 69.4 64.3 na na

na 10.8 8.5 na na

Diversified Basic chemicals Petroleum Basic chemicals Basic chemicals

$1968 1925 737 1033 624

93.5 8.8 23.2 81.1 12.9

Basic chemicals Diversified Petroleum Basic chemicals Petroleum

427 1017 636 na 252

-25.9 -3.8 -39.8 na -66.1

1.1 -3.0 1.9 10.8 9.1

7.7 15.2 19.0 52.9 8.0

Petroleum Petroleum Photo equipment Specialty chemicals Petroleum

397 519 602 431 44

6.3 6.1 -6.9 5.3 3.6

100.0 100.0 22.6 90.3 40.0

Basic chemicals Basic chemicals Diversified Basic chemicals Diversified chemicals

21 32 Rhone-Poulenc 22 22 American Cyanamid 6 23 23 Ashland Oil 24 30 Hercules 25 20 Phillips Petroleum

2,278 42.4 2,255 0.6 0.7 2,245 2,193 3.6 2,120 -13.4

100.0 49.3 25.0 68.5 15.6

26 42 Ciba-Geigy 27 24 Quantum Chemical 28 25 B. F. Goodrich 29 31 Akzo 30 26 Lyondell Petrochemical

1,976 1,959 1,940 1,893 1,889

10.0 -6.9 -1.9 1.0 19.6

16 17 17 18 18 16 19 19 20 21

Chemical Chemical operating Identifiable assets Operating profits as Operating chemical as % of return on % of total profit assets total chemical profits marginb ($ millions) assets assets0

31 32 33 34 35

29 27 33 34 35

Alcoa Texaco Dow Corning National Starch FMC

1,842d 5.7 1,723 - 5 . 2 1,718 9.1 6.4 1,670 1,624 5.4

17.2 4.1 100.0 100.0 43.6

Nonferrous metals Petroleum Specialty chemicals Specialty chemicals Machinery

1319 60 171f 254 192

11.5 -85.0 5.1 12.3 -15.1

121.3 2.5 100.0 100.0 45.4

71.6 3.5 10.0f 15.2 11.8

2,855 25.0 1,308 5.0 na na 1,448 100.0 1,469 49.6

46.2 4.6 na 17.6 13.0

36 37 38 39 40

36 28 56 45 42

Ethyl Atochem Degussa Lubrizol Huntsman Chemical

4.7 1,591 1,540 -13.4 1,435 61.9 1,335 18.8 1,300 8.3

100.0 100.0 75.3 91.9 100.0

Basic chemicals Basic chemicals Specialty chemicals Specialty chemicals Basic chemicals

308 na na 398 na

9.0 na na 24.1 na

100.0 na na 90.8 na

19.4 na na 29.8 na

1,383 100.0 na na na na 887 79.5 na na

22.3 na na 44.9 na

41 42 43 44 45

40 38 39 48 44

Tenneco Olln Unocal Nalco Chemical PPG Industries

1,298 1,269 1,236 1,212 1,150

6.0 -1.2 -3.1 13.2 -2.1

8.9 49.0 10.5 100.0 19.1

Diversified Basic chemicals Petroleum Specialty chemicals Glass products

167 45 115 211 231

40.3 -74.1 -47.0 16.3 -10.1

11.5 30.6 23.7 100.0 25.4

12.9 3.5 9.3 17.4 20.1

1,409 7.5 945 50.6 671 6.9 1,037 100.0 1,076 17.6

11.9 4.8 17.1 20.3 21.5

46 47 48 49 50

52 41 61 67 54

Cabot6 IMC Fertilizer9 Great Lakes Chemical Imcera Group9 Morton International9

1,107 1,106 1,066 1,025 1,021

16.3 -9.5 34.6 54.7 9.2

66.2 100.0 100.0 71.9 62.3

Basic chemicals Agrochemicals Specialty chemicals Specialty chemicals Specialty chemicals

147 171 290 104 140

32.1 -33.5 43.7 99.2 -3.4

89.6 100.0 100.0 92.5 58.0

13.3 15.5 27.2 10.2 13.7

1,100 63.5 1,585 100.0 1,406 100.0 1,090 51.1 na na

13.4 10.8 20.6 9.6 na

40 June 24, 1991 C&EN

Chemical Change sales 1990 from ($ millions) 1989

Rank 1990 1989

Chemical sales as % of total sales

Industry classification

Chemical operating Change from profits3 ($ millions) 1989

Chemicali Chemical Identifiable assets Operating operating profits as Operating chemical as % of return on % of total profit assets total chemical profits margin" ($ millions) assets assets0

na na na na na na 8.7% $412 25.3 1129

na na na na na na 30.4% 20.4% 100.0 21.5

na 100.0 100.0 100.0 17.2

pa 24.5 27.7 5.4 6.3

na 457 1967 801 880

na 100.0 100.0 100.0 24.5

na 50.1 12.8 6.1 5.9

15.7 2.4 3.8 12.8 363.7

61.8 100.0 71.0 100.0 66.9

19.7 13.4 12.4 6.6 10.7

523 1178 874 490 477

18.4 100.0 66.2 100.0 40.5

30.6 9.2 11.4 10.6 17.2

151 123 104 48 68

-32.7 -1.6 19.0 17.0 14.5

100.0 33.8 100.0 100.0 2.6

20.9 19.2 17.4 8.6 12.3

na 658 427 489 510

na 18.9 100.0 100.0 6.4

na 18.7 24.4 9.7 13.3

Drugs Specialty materials Basic chemicals Drugs Basic chemicals

29 10 88 na -17

-26.2 -48.2 -43.4 na def

2.5 14.5 100.0 na 100.0

5.3 2.0 17.5 na def

418 288 352 na 221

4.6 42.0 100.0 na 100.0

6.9 3.5 25.1 na def

3.7 52.2 100.0 16.2 83.2

Petroleum Specialty chemicals Specialty chemicals Diversified Specialty chemicals

na 164 na 22 104

na -4.4 na 66.2 14.3

na 88.8 na 6.1 94.1

na 34.0 na 4.9 23.5

na na na 352 485

na na na 8.0 88.7

na na na 6.4 21.4

-0.1 -9.7 -4.9 12.5 10.7

48.3 100.0 37.0 100.0 79.7

Specialty chemicals Basic chemicals Nonmetallic minerals Specialty chemicals Specialty chemicals

38 68 72 21 43

23.3 -29.1 -16.2 83.1 19.6

90.7 100.0 39.3 100.0 72.2

8.7 16.1 17.7 5.5 13.9

280 544 na 247 239

36.7 100.0 na 100.0 84.5

13.7 12.4 na 8.7 18.1

295 285 283 275 253

-4.1 12.4 2.9 -0.9 21.1

59.3 100.0 94.2 45.9 100.0

Agrochemicals Basic chemicals Specialty chemicals Specialty chemicals Farm cooperative

23 62 17 23 5

-14.8 10.1 -9.4 -38.6 -89.6

97.4 100.0 93.3 56.3 100.0

7.8 21.9 5.9 8.5 1.9

173 285 209 139 289

33.9 100.0 82.8 42.4 100.0

13.3 21.9 8.0 16.9 1.7

Georgia-Pacific Quaker Chemical Sequa Corp. Sherex Lawter International

247 201 201 177 150

-2.4 10.9 42.4 -5.9 10.3

2.0 100.0 10.8 100.0 100.0

Wood products Specialty chemicals Diversified Specialty chemicals Specialty chemicals

na 22 30 na 28

na 17.6 54.4 na 23.0

na 100.0 20.2 na 100.0

na 10.7 14.7 na 18.5

na 152 112 na 154

na 100.0 5.9 na 100.0

na 14.1 26.5 na 18.0

LeaRonal1 Cambrex Corp. Eagle-Picher Aceto9 Sybron

141 134 123 122 120

-10.5 2.0 -19.4 8.1 na

100.0 100.0 17.5 100.0 100.0

Specialty chemicals Specialty chemicals Diversified Specialty chemicals Specialty chemicals

14 4 16 7 na

-10.4 -32.3 7.4 -2.4 na

100.0 100.0 33.3 100.0 na

10.0 3.3 13.0 5.4 na

81 na 76 68 na

100.0 na 18.2 100.0 na

17.3 na 21.1 9.6 na

na na na na na na - 7 . 0 % 52.5% 11.8 100.0

Specialty chemicals Basic chemicals Basic chemicals Agricultural supplies Specialty chemicals

na na na $84 243

100.0 100.0 100.0 100.0 52.2

Agrochemicals Basic chemicals Basic chemicals Agrochemicals Agrochemicals

na 229 251 49 52

na -23.6 -18.6 78.5 -52.3

22.8 0.4 -0.7 5.2 0.4

21.1 100.0 27.4 100.0 47.1

Petroleum Specialty chemicals Diversified Specialty chemicals Specialty chemicals

160 108 100 52 82

719 642 597 555 551

-7.7 8.4 15.5 17.2 11.9

100.0 17.4 100.0 100.0 7.2

Basic chemicals Petroleum Specialty chemicals Specialty chemicals Drugs

Pfizer Ferro Sterling Chemical6 Hoffmann-La Roche Nova

548 513 506 500 489

7.5 5.5 -12.9 0 -27.9

8.5 45.6 100.0 20.8 100.0

73 68 — 83 84

Sun Co. GAF Huls Union Camp Sigma-Aldrich

486 481 465 460 440

-4.6 -19.8 3.6 12.8 22.6

81 82 83 84 85

81 78 82 85 87

Dexter Borden Chemicals Vulcan Materials Stepan Crompton & Knowles

438 421 409 390 311

86 87 88 89 90

86 90 89 88 92

First Mississippi9 Calgon Carbon Petrolftek Chemed Mississippi Chemical9

91 92 93 94 95

90 94 — 93 98

96 97 98 99 100

95 99 97 — —

51 52 53 54 55

— 50 51 55 57

Reichhold Chemicals Solvay America Aristech Farmland Industries'1 International Flavors

56 57 58 59 60

53 47 49 58 46

Terra Chemicals Georgia Gulf NL Industries CF Industries Freeport-McMoRan

961 932 907 903 825

1.3 -15.6 -9.4 5.5 -25.3

61 62 63 64 65

66 60 59 65 64

American Petrofina Uniroyal Chemical Engelhard H. B. Fuller' Witco

813 808 807 792 769j

66 67 68 69 70

62 69 72 79 76

Vista Chemical6 Kerr-McGee Betz Laboratories Loctite Merck

71 72 73 74 75

74 77 70 75 63

76 77 78 79 80

$1000 997 974 965 963

na 100.0% 0%100.0 - 2 . 2 100.0 9.2 28.6 10.7 100.0

a Operating income is sales less administrative expenses and cost of sales, b Chemical operating profit as a percentage of sales, c Chemical operating profit as a percentage of identifiable chemical assets, d Chemical sales include significant amounts of nonchemical products, e Fiscal year ended Sept. 30. f Chemical net income, g Fiscal year ended June 30. h Fiscal year ended Aug. 31. i Fiscal year ended Nov. 30. j Does not include all chemical sales, k Fiscal year ended Oct. 31.1 Fiscal year ended Feb. 28, 1990. na = not available, def = deficit.

June 24, 1991 C&EN

41

FINANCIAL ANALYSIS: Decline evident in many chemical company performance measures

Profit margin3

Return on investment"

Debt as % of debt plus equity

% total sales abroad0

% total assets abroadd

Sales per employee6

Dividends as % of net income

CAPITAL SPENDING' as % as% of of net plant sales

R&D as % of sales

Sales as % of assets

Net plant as % of gross plant

SALES OVER $1 BILLION Air Products9

1990 1989

7.9% 8.4

3.9% 4.3

36.1% 37.1

24.5% 23.6

35.5% $207 187 30.8

American Cyanamid

1990 1989

2.4 6.1

1.7 5.0

13.1 16.5

39.6 38.6

27.2 24.6

143 136

118.9 41.1

8.2 8.2

19.7 22.6

10.1 8.4

89.8 97.1

51.5 51.4

Cabot9

1990 1989

4.2 0.9

3.4 1.0

45.7 44.1

41.8 32.8

36.0 12.7

279 352

41.8 166.1

10.4 9.9

19.9 25.9

2.1 1.8

96.6 136.7

57.3 56.1

Dow Chemical

1990 1989

7.0 14.1

5.1 10.1

37.4 32.6

52.0 54.1

45.4 44.9

318 283

51.4 23.2

10.7 9.6

25.7 22.2

5.7 5.0

82.5 79.4

43.1 44.1

Ethyl

1990 1989

9.2 14.4

12.5 13.2

39.5 35.6

21.2 31.3

4.9 3.8

441 276

108.0 26.3

6.0 7.8

22.4 20.5

2.6 4.0

37.6 27.0

50.8 48.8

B. F. Goodrich

1990 1989

4.8 7.1

4.3 6.3

13.2 18.5

24.7 26.7

18.6 18.6

165 203

53.8 34.6

10.0 9.9

21.9 24.2

3.0 2.7

102.8 106.4

60.3 59.6

W. R. Grace

1990 1989

3.0 4.2

2.8 3.9

50.7 48.6

36.9 34.8

34.1 31.0

138 132

59.5 46.6

7.6 7.9

20.9 21.8

2.2 2.0

108.5 108.8

50.2 49.6

Great Lakes Chemical

1990 1989

13.2 15.5

11.5 13.2

9.2 16.1

53.1 40.1

42.7 49.6

na na

11.5 11.1

4.6 5.1

13.3 14.7

2.7 3.4

75.8 72.2

59.5 56.6

Hercules

1990 1989

3.0 def

2.4 def

23.6 23.3

27.8 25.4

18.6 17.0

161 133

109.4 def

8.5 9.5

18.8 20.7

2.9 2.5

86.5 84.6

47.3 48.4

Imcera Group

1990 1989

4.1 11.2

3.7 7.1

47.8 44.5

34.4 25.8

17.0 27.3

133 148

def 43.8

9.5 6.0

20.7 14.6

2.5 5.3

84.6 66.9

48.4 69.2

Lubrizol

1990 1989

13.2 7.7

12.2 6.9

6.8 7.4

56.8 52.4

43.7 40.3

280 230

27.5 54.8

5.4 5.3

21.9 20.4

5.2 5.7

129.6 127.1

39.0 39.0

Monsanto

1990 1989

6.1 7.8

4.9 6.7

28.8 27.2

36.8 35.6

32.4 28.5

219 206

44.3 32.5

8.3 7.0

21.5 19.1

7.7 6.9

97.4 100.9

45.8 45.7

Morton International*1

1990 1989

8.2 6.9

7.4 6.5

20.6 4.6

30.4 31.1

25.6 26.4

169 167

30.7 na

6.8 9.4

17.2 23.8

2.9 2.7

90.4 103.1

59.7 59.7

Nalco Chemical

1990 1989

10.8 11.2

10.5 10.8

38.3 32.5

28.2 27.1

20.4 19.4

207 195

48.2 47.9

9.5 8.1

27.4 24.6

3.7 3.8

116.9 114.1

49.9 48.7

Olin

1990 1989

3.2 4.9

2.8 4.2

39.5 36.1

7.8 7.2

10.9 9.3

171 163

58.3 34.7

7.2 5.7

22.6 18.2

2.5 2.6

138.9 131.8

36.1 36.0

PPG Industries

1990 1989

7.9 8.1

5.8 6.2

31.1 33.3

34.3 30.9

33.5 29.7

172 162

37.0 35.6

6.9 9.4

12.8 17.9

3.6 4.1

98.6 101.6

54.3 55.2

Quantum

1990 1989

0.8 4.3

0.6 3.4

104.2 107.9

na na

na na

na na

0 1121.1

17.3 21.8

22.7 33.2

1.8 1.7

82.4 88.9

69.5 70.0

Rohm & Haas

1990 1989

7.3 6.6

5.5 5.2

32.7 21.5

43.7 43.2

32.4 32.1

219 204

38.2 43.8

14.6 14.5

29.6 33.5

6.3 6.6

104.5 108.4

50.2 47.9

Union Carbide

1990 1989

4.0 6.6

2.6 4.7

49.6 46.6

36.4 33.7

32.3 40.7

202 190

44.8 24.4

9.8 9.0

17.2 17.1

2.5 2.1

87.3 102.3

48.5 48.1

Wltco

1990 1989

4.2 2.2

4.4 2.3

28.2 29.2

19.8 18.9

20.2 16.4

225 216

56.4 103.3

5.6 4.4

19.3 16.9

1.6 1.6

138.4 139.4

48.8 48.3

5.5% 7.0

4.4% 5.7

34.4% 32.6

34.4% 31.3

32.3% $205 193 26.4

8.3% 8.7

20.4% 20.6

2.9% 93.5% 50.2% 102.0 49.2 3.1

MEDIAN 1990 MEDIAN 1989 42

June 24, 1991 C&EN

33.4% 16.2% 15.7 31.2

44.6% 34.7

18.8% 18.7

2.5% 2.7

74.2% 49.6% 49.9 78.5

Finances of the U.S. Chemical Industry

Profit margin3

Return on investment6

Debt as % of debt plus equity

% total sales abroad"

% total assets abroadd

Sales per employee6

Dividends as % of net income

CAPITAL SPENDING' as % as% of of net plant sales

R&D as % of sales

Sales as % of assets

Net plant as % of gross plant

SALES LESS THAN $1 BILLION. Betz Laboratories

1990 1989

11.0% 10.8

11.3% 12.1

Calgon Carbon

1990 1989

13.9 13.9

12.4 13.3

Chemed

1990 1989

3.1 4.9

Crompton & Knowles

1990 1989

First Mississippi*1

56.2% 55.4

9.6% 10.2

24.6% 30.7

3.9% 3.7

139.7% 57.9% 54.6 139.9

190 191

15.4 12.5

16.7 10.4

33.0 25.8

2.0 1.9

99.9 108.4

76.4 75.5

13.7 11.8

87 93

122.4 70.6

2.5 2.7

19.7 21.4

0.6 0.6

161.7 158.1

55.2 56.5

18.7 17.3

19.2 21.5

218 212

31.2 27.9

4.2 3.8

21.3 26.4

2.2 2.2

138.0 163.3

62.1 56.1

39.7 30.6

24.0 17.7

na na

na na

135.0 34.6

13.0 24.7

20.8 38.2

na na

97.2 90.8

45.0 44.8

3.7 3.1

30.9 35.1

46.3 44.9

54.2 50.8

142 140

25.7 34.9

4.0 5.4

15.6 21.9

2.0 2.1

161.9 165.5

61.3 63.5

10.2 17.4

17.9 35.3

263.9 66.1

na na

na na

868 818

0 12.5

6.2 4.9

27.1 25.9

na na

204.1 233.5

68.0 69.7

1990 1989

16.3 15.9

11.4 11.9

0.0 0.0

70.1 69.2

46.6 47.0

230 206

52.5 52.6

4.3 3.8

15.5 14.1

6.0 6.0

85.3 89.7

51.7 53.1

Loctite

1990 1989h

12.1 11.9

13.0 14.0

9.8 13.8

55.0 57.9

65.5 62.0

151 130

31.2 26.4

5.1 3.5

27.4 22.8

3.9 3.8

113.5 126.1

55.6 53.7

Petrolite1

1990 1989

4.4 2.4

3.4 2.0

2.3 1.1

31.3 30.5

37.5 35.0

na na

96.7 178.1

5.8 6.5

14.8 18.0

4.1 4.1

118.9 121.5

44.5 44.0

Quaker

1990 1989

7.0 7.1

8.4 8.9

5.2 5.9

41.1 43.4

35.0 32.1

187 185

30.5 29.8

6.3 4.2

27.3 20.7

na na

132.2 138.2

55.3 53.0

Sigma-Aldrich

1990 1989

13.5 14.5

11.3 12.0

16.1 17.1

28.1 21.9

29.0 26.4

129 116

14.3 14.3

6.1 11.7

16.9 29.3

na na

96.9 93.4

66.2 71.3

Stepan

1990 1989

3.7 2.3

3.8 2.3

48.3 49.2

11.7 na

13.6 na

297 301

22.0 37.2

9.8 9.8

26.8 27.8

3.4 2.9

157.7 160.8

49.6 48.7

Sterling Chemical9

1990 1989

11.7 17.9

14.8 28.6

37.1 37.6

35.4 35.0

na na

na na

93.6 42.5

3.9 9.9

9.2 26.6

na na

143.8 176.5

78.8 84.7

10.2% 10.8

10.4% 11.2

16.1% 29.4

33.4% 35.0

31.2% 34.9

5.8% 5.4

21.3% 25.8

3.0% 2.8

132.2% 55.6% 138.2 54.6

19.0% 17.8

22.0% $162 151 18.9

5.3 9.9

39.2 37.3

43.5 30.7

6.3 9.8

42.2 41.5

12.2 11.0

7.7 6.9

10.4 11.2

37.4 29.4

1990 1989

0.9 3.8

0.5 2.1

H. B. Fuller'

1990 1989

2.7 2.1

Georgia Gulf

1990 1989

International Flavors

MEDIAN 1990 MEDIAN 1989

31.0% 35.2

33.6% $189 188 32.1

Note: Net income is from continuing operations, excluding extraordinary and nonrecurring items where possible, a Net income as a percentage of sales, b Net income as a percentage of current assets plus gross plant, c Consolidated sales only, d Foreign identifiable assets as a percentage of total assets, e Thousands of dollars, f Actual spending on construction of new facilities and purchase of land and new equipment in consolidated businesses, g Fiscal year ended Sept. 30. h Fiscal year ended June 30. i Fiscal year ended Nov. 30. j Fiscal year ended Oct. 31. na = not available, def = deficit.

June 24, 1991 C&EN

43

2

Finances of the U.S. Chemical Industry

Chemical capital spending continues to rise Capital spending by U.S. chemical producers continued to rise in 1990. In a year when earnings and profitability were both down, the 25 major chemical firms that C&EN tracks still increased their capital spending budgets a healthy 12% over already respectable 1989 spending levels. The 1990 hike is much lower than the 23% increase in capital spending that these companies posted in 1989 or the 29% hike of 1988. Nevertheless, it's a good deal higher than the 4%o annual compound growth rate

during the past 10 years for the companies whose plant outlays are tabulated by C&EN. As a percentage of sales, capital spending by the 25 companies continued to rise in 1990, reaching 10.6% and making 1990 the first year since 1982 when this figure topped 10%. Capital spending as a percentage of sales in 1989 was 9.9%. For much of the mid-1980s this value hovered around 8%. The Department of Commerce's much wider survey of the chemical

industry found a similar rise in capital expenditures in 1990. Their measure was up 11%. And, as of the first quarter of 1991, chemical companies planned to continue increasing capital spending in 1991, according to Commerce Department data. Plans for 1991 called for a 5% increase in capital outlays to reach $21.6 billion this year. A separate survey by the Conference Board, meanwhile, shows that the backlog of unspent funds ticketed for plant expansions by chemical

INDUSTRY CAPITAL SPENDING: Holding steady for 1991 following three years of big gains $ Billions

1990

1983

Chemicals Iron and steel Nonferrous metals Paper

$ 21.63 7.20 2.88 13.10

$ 20.54 7.81 2.88 16.72

$ 18.47 7.87 2.64 15.58

$ 19.25 6.16 2.77 11.23

$ 16.42 4.69 2.16 9.01

$ 16.81 3.32 1.93 8.77

$ 16.44 4.12 1.88 8.59

$ 15.32 3.54 2.13 7.21

$ 12.96 3.25 1.74 5.92

$ 12.66 3.78 1.90 5.60

$ 13.11 3.48 2.51 6.11

Petroleum Rubber Stone, clay, glass All manufacturing

38.45 3.44 3.19 193.39

34.46 3.48 3.31 192.78

30.08 3.79 4.00 183.80

19.93 3.86 3.59 165.70

17.12 3.52 3.37 145.90

17.92 3.89 3.14 142.69

26.71 3.86 3.40 153.48

25.53 3.11 3.09 138.82

23.14 2.46 2.77 116.20

26.39 2.16 2.90 120.68

25.98 2.15 3.41 126.54

a Estimate. Source: Department of Commerce

Chemicals and petroleum sectors lead industry in unspent capital appropriations $ Billions

1990

1984

1983

1981

1980

Chemicals Iron and steel Nonferrous metals Paper

$ 12.6 2.4 2.1 14.6

$ 11.9 2.9 2.3 17.4

$ 10.6 2.7 1.6 12.3

$ 7.0 1.4 1.7 6.3

$ 6.2 0.5 1.6 4.4

$ 8.0 1.1 2.3 4.3

$ 7.8 2.1 2.5 5.9

$ 7.5 2.2 3.2 4.0

$ 7.4 2.7 3.2 5.1

$ 9.4 5.4 3.7 5;1

$ 9.8 3.9 3.7 4.0

Petroleum Rubber Stone, clay, glass All manufacturing

23.4 3.9 2.5 106.3

17.1 3.5 2.7 114.2

14.6 2.8 2.8 101.7

15.2 1.7 2.4 76.8

16.7 1.9 1.8 69.7

26.2 3.1 2.0 95.0

24.7 1.6 2.2 94.4

22.3 1.1 1.5 73.7

22.9 1.0 1.6 70.8

29.7 0.9 1.9 92.7

26.7 1.0 2.0 91.9

$ 2.4 1.0 14.1 13.6

$ 2.3 0.9 15.9 13.6

$ 2.8 0.9 19.7 16.8

$ 3.0 0.8 15.8 19.2

Note: Figures are for fourth quarter of each year. Source: Conference Board

Capital spending by chemical firms abroad continues to rise strongly $ Billions3

Chemicals and allied products Metals, primary and fabricated Petroleum All manufacturing

$ 6.6 1.3 18.6 29.8

$ 6.2 2.1 1.56 27.4

$ 5.3 1.5 14.4 23.4

$ 4.7 1.1 13.3 20.8

a By majority-owned affiliates of U.S. companies, b Planned. Source: Department of Commerce

44

June 24, 1991 C&EN

$ 3.7 0.8 9.8 17.2

1986

1985

$ 3.1 0.9 9.6 16.4

$ 2.7 0.9 13.7 14.9

Chemical capital spending has more than doubled since 1983, and continues to grow faster than sales $ Billions3 121

Capital spending as % of sales3

121

io[

J 1980 81 82

L 83 84

J 85

86

I

I

8

I

6

I

h

Ol

L

87 88 89 90

1980 81 82 83 84 85 86 87 88 89 90

producers was 6% higher at the end of 1990 than a year earlier, rising to nearly $13 billion. The hectic rate of increase in capital spending abroad by U.S. chemical companies continued in 1990, though Commerce Department data suggest the pace will slow in 1991. Overseas affiliates of U.S. chemical producers increased their outlays 17% in 1990, compared with a 13% rise in 1989. For 1991, they plan only a 6% rise in overseas expenditures.

a Worldwide data for 25 major chemical producers. Source: Company data

CHEMICAL CAPITAL SPENDING: Tops $11 billion in third straight year of strong growth $ Millions

1981

1980

$ 347

$ 323

$ 364

171 152 4 3

181 194 4 7

196 137 4 10

630

829

1276

1300

1176 1420

1184 1297

85 115 353

92 144 560

141 205 657

156 184 658

29 218 10 30 614

20 168 9 25 560

29 174 9 52 673

47 167 11 75 668

21 229 14 92 781

60 154 452 24 6

53 165 315 11 4

41 123 450 9 2

56 129 452 24 2

59 186 376 15 1

35 172 401 17 5

102 179 14 466 60

76 159 19 649 76

116 124 12 670 85

71 72 10 761 55

126 16 1179 54

44 182 12 1186 83

49 93 9 1129 73

$5923

$6374

$6172

$5333

$6643

$7420

$7310

1985

1984

1983

$ 367

$ 392

$ 263

$ 246

263 80 9 4

203 184 7 3

200 505 9 3

165 80 5 2

1989

1988

1987

468

$ 414

$ 409

$ 323

376 298 13 16

398 233 14 13

374 214 15 7

268 83 9 4

2,119 3,142

1756 2563

1264 2029

995

890

806

781

1674

1587

1515

1319

Ethyl B. F. Goodrich W . R. Grace

166 243 514

119 240 485

151 181 418

139 143 243

134 144 199

90 202 348

103 153 380

Great Lakes Chemical Hercules Loctlte Lubrizol Monsanto

49 273 29 77 750

40 293 24 65 607

47 251 15 55 590

35 205 17 42 505

18 257 11 41 520

21 234 9 40 645

Nalco Chemical Olin P P G Industries PetroIKe Quaker Chemical

115 187 415 18 13

86 142 537 19 8

62 147 410 20 5

57 115 426 19 4

64 128 356 25 5

Quantum Chemical Rohm & Haas Stepan Union Carbide Witco

459 412 38 744 91

589 385 34 726 70

334 338 20 608 72

154 222 26 452 69

$11,025

$9860

$8036 29 S

$6229

Air Products American Cyanamid Cabot a Chemed Crompton & Knowles

D o w Chemical

Du Pontb

TOTAL ANNUAL CHANGE

1990

$

12%

23%

16%

-20% -10%

2%

25%

Note: Figures are for worldwide spending on construction, equipment, and land in consolidated businesses. Where possible, acquisition costs and investments in nonconsolidated businesses are excluded, a Includes acquisitions and investments, b Excludes Conoco. Source: Company data

June 24, 1991 C&EN 45

Finances of the U.S. Chemical Industry SHIPMENTS: Like all manufacturing, chemical products make modest gains in 1990 Annual change $ Billions

1990

All manufacturing industries Chemicals and allied products Industrial chemicals3 Drugs, soap, and toiletries Petroleum and coal products Rubber and plastic products Paper and allied products

1989

1988

1987

1986

1985

1984

1982

1983

1981

1980

1989-90

$2860.3 $2781.4 $2611.6 $2390.0 $2260.3 2279.1 $2254.4 $2054.9 $1960.2 $2017.5 $1852.7

1980-90

3%

4%

265.7

255.5

240.5

212.7

197.1

197.3

198.2

183.2

170.7

180.5

162.5

4

5

70.4 87.3

68.9 82.0

67.8 73.1

59.5 67.1

54.1 65.8

59.6 60.9

61.5 57.5

56.6 54.4

53.2 50.7

62.7 46.9

57.3 41.9

2 6

2 8

169.6

138.5

124.2

124.5

124.9

179.1

189.0

192.6

208.9

224.1

198.7

22

-2

90.1

95.8

91.1

80.5

73.4

71.3

69.5

60.3

55.4

53.2

47.3

-6

7

131.2

130.4

124.2

110.3

97.9

93.4

94.8

84.6

79.9

80.2

72.8

1

1981

1980

1989-90

6

a Excluding pigments. Source: Department of Commerce

PRICES Chemical products stagnated while other commodities rose last year Annua I average

Annual change

1990

1989

1988

1987

1986

1985

1984

1983

1982

All commodities

116.3

112.2

106.9

102.8

100.2

103.1

103.7

101.3

100.0

98.0

89.8

4%

3%

Industrial commodities

115.8

111.6

106.3

102.6

99.9

103.7

103.3

101.1

100.0

97.4

88.0

4

3

Finished goods

119.2

113.6

108.0

105.4

103.2

104.7

103.7

101.6

100.0

96.1

88.0

5

3

Chemicals and allied products Industrial chemicals Prepared paint Paint materials Drugs and pharmaceuticals Fats and oils, inedible Agricultural chemicals and chemical products Plastic resins and materials Other chemicals and allied products

123.6 113.2 124.8 136.3 170.8 88.1 107.4

123.0 114.8 119.5 129.1 160.0 95.5 108.7

116.3 106.8 112.2 115.7 148.4 110.9 104.5

106.4 95.5 108.1 107.3 139.1 92.7 96.4

102.5 91.5 107.0 104.4 129.9 80.5 94.2

103.7 96.0 105.3 109.5 122.2 110.6 96.2

102.9 96.8 103.7 108.2 114.2 139.1 97.4

100.2 97.3 100.7 100.3 107.7 106.2 96.0

100.0 100.0 100.0 100.0 100.0 100.0 100.0

98.4 103.0 95.0 98.5 92.1 110.7 97.5

89.1 91.9 89.5 89.9 83.1 111.6 87.9

0 -1 4 6 7 -8 -1

3 2 3 4 7 -2 2

124.1 118.9

133.4 117.3

132.4 111.9

110.3 107.0

104.4 105.8

107.5 105.2

108.9 102.7

102.4 101.3

100.0 100.0

102.0 94.1

98.5 83.1

-7 1

2 4

Rubber and plastic products

113.6

112.6

109.3

103.0

101.9

101.9

102.2

100.8

100.0

96.4

90.1

Producer price indexes, 1982 = 100

1980-90

Source: Department of Labor

Chemical shares have partially recovered from deep plunge in mid-1990 Stock price index, 1954 = 100' 700 k- 1

600

ft

1 High 1- Close

J_

1 Low

500

T^|rK:

1 rft 1

400

300

200

LfLL r | rr

L 'r ' T

HJ »-Lr L. ~

;Hfcr

r

1h

h •

100 1980

1981

1982

1983

1984

1985

1986

1987

1988

1989

1990

a C&EN stock price index of American Cyanamid, Dow Chemical, W. R. Grace, Hercules, Monsanto, Rohm & Haas, and Union Carbide, weighted according to number of shares outstanding for each company.

46

June 24, 1991 C&EN

1991

R&D spending made healthy rise in 1990 in real terms and as a percentage of company sales $ Billions1 4

1980

81

R&D spending as % of 5

82

83

84

85

86

87

88

89

90

1980 81

87

82

88

89

90

a R&D spending by 15 major chemical producers. Sources: Company data, Battelle Columbus Laboratories

R&D SPENDING: Most companies made significant increases in 1990 $ Millions

1990

1989

1988

1987

1984

1985

1986

1982

1983

1980

1981

CHEMICAL COMPANIES Air Products8 American Cyanamid Dow Chemical Ethyl W. R. Grace

$

72 460 1136 65b 148

$

71 406 873 61 b 125

$

72 365 772 59b 119

$

57 314 670 50 107

$

61 278 605 47 94

$

51 251 547 47 92

$

44 232 507 40 81

$

40 208 492 39 73

$

37 185 460 39 64

$

32 166 404 37 57

$

30 148 314 34 45

Hercules International Flavors Lubrizol Monsanto Nalco

92 57 74 612 45

79 52 70 598 41

74 50 65 648 37

74 45 62 615 35

71 39 51 596 33

76 34 44 470 32

72 32 33 370 32

74 32 37 290 30

74 31 36 264 33

65 30 33 233 30

57 29 28 208 28

Olln Petroltte PPG Industries Rohm & Hass Union Carbide

66 12 218 178 191

66 12 233 175 181

58 12 232 156 159

62 12 227 142 159

56 12 204 133 148

53 12 176 124 275

52 12 150 109 265

49 13 127 100 245

45 10 127 92 240

38 8 119 77 207

31 7 103 67 166

$3426 13%

$3043 6%

$2867 9%

$2631 8%

$2428 6%

$2284 12%

$2031 10%

$1849 6%

$1737 13%

$1536 19%

$1295 17%

TOTAL ANNUAL CHANGE

PHARMACEUTICAL & DIVE:RSIFIED C()MPANIES. Allled-Slgnalc Du Pont Eastman Kodak Eli Lilly FMC Merck & Co. Morton International0 d Pfizer Upjohn TOTAL ANNUAL CHANGE

$ 721 1428 1329 703 158

$ 603 1387 1253 605 150

$ 647 1319 1147 512 144

$ 667 1223 992 466 132

$ 734 1156 1059 427 146

$ 470 1144 976 370 149

$ 389 1097 838 341 121

$ 383 966 746 294 102

$ 177 879 710 267 105

$ 152 718 615 235 94

$ 105 591 520 201 81

854 48 640 427

751 38 531 407

669 35 473 380

566 31 401 356

480 29 336 314

426 34 287 284

393 28 255 247

356 21 230 218

320 7 199 185

274 6 179 162

234 6 162 139

$6308 10%

$5725 7%

$5326 10%

$4834 3%

$4681 13%

$4140 12%

$3709 12%

$3316 16%

$2849 17%

$2435 19%

$2039 17%

Note: Prior years not restated to reflect company revisions, a For fiscal year ending Sept. 30. b Adjusted to reflect spin-off of Tredegar Industries, c Includes all company-financed R&D but excludes contract R&D. d Fiscal year ends June 30; data for Morton Thiokol prior to 1985. Source: Company data

June 24, 1991 C&EN

47

The Last Three Generations Ifour Lab Has Three Weeks ' O U R TESTING H A S T O BE D O N E QUICKLY. A N D ACCURATELY. A N D IT H A S T O BE R I G H T THE FIRST TIME. XX — Dan

Vollmer

J K V a n Vollmer is the lab ^ ^ ^ ^ ^ ^ ^ d i r e c t o r for Waste Stream Technology in Buffalo, New York. Vollmer and his team support Waste Stream's remediation operation by performing critical point-in-time analysis on soil samples from prospective remediation projects. Old industrial sites and landfills contaminated by crude oil, coal tar, benzene, and other volatile aromatics. Waste that has been ^"fc, buried — and often ^ ^ reburied — for decades. "When we remediate a site, we don't just haul it away," Vollmer says. "We eliminate it. And the method we

use means that we just can't afford downtime. Ever." Testing is done with PerkinElmer gas chromatographs. Waste Stream performs the remediation by spraying the site with bacteria which use the contaminant as their carbon source. The bacteria "eat" the contaminant. "But some 'bugs' work better than others," Vollmer explains. "So first, we do a treatability study. We introduce different bacteria to soil samples, and test the samples at seven-day intervals for three weeks. Then we compare those data to see what kind of degradation rates we're getting. Data handling is the crux of the matter." Data handling is done with a PE Nelson data station. In a sample treated with bacteria, the contaminant concentration changes constantly.

Testing complex soil samples for aromatic hydrocarbons contributes to a heavy sample schedule.

Timing is critical. You can't stop the bugs.

Have Buried The Problem. To Uncover The Solution,

%: Chemical exports

5

n 1980

i

i

i

i

i

81

82

83

84

85

i

i

i

i

87

88

89

90

Source: Ministry of International Trade & Industry

INDUSTRY TRENDS: Plastics lead growth Production index, 1985 = 100

All manufacturing All chemicals Inorganic chemicals and pigments Alkalies and chlorine Organic chemicals Petrochemicals Aromatics Cyclic intermediates and dyes Plastics Synthetic fibers Synthetic rubber Fertilizer Textile materials Medicinals and drugs

1989

1988

1987

125.6 134.4 114.3

120.0 128.7 114.4

113.1 120.4 108.4

103.2 111.1 100.9

5% 4 0

120.9 131.7 136.7 137.3 143.2

114.7 128.1 129.1 133.2 135.3

110.5 115.9 118.1 115.9 121.2

103.6 105.4 107.6 107.1 110.9

5 3 6 3 6

139.6 101.2 123.1 85.2 126.8 154.8

130.7 97.5 116.7 86.6 118.7 147.3

120.6 95.4 112.2 88.5 117.8 136.2

109.9 94.6 102.9 91.6 110.7 123.1

7 4 6 -2 7 5

Source: Ministry of International Trade & Industry 74

June 24, 1991 C&EN

Change 1989-90

1990

Acetaldehyde Acetic acid Acetone Acrylonitrile Benzene3 Butadiene Butanol Caprolactam Cyclohexane Dioctyl phthalate Ethylene Ethylene dichloride Ethylene glycol Ethylene oxide Methanol Octanol Phenol Phthalic anhydride8 Propylene Propylene glycol Styrene Terephthalic acid Toluene Toluene diisocyanate Urea Xylene PLASTICS

a 'Petroleum-based product only. Source: Ministry of International Trade & Industry

Despite strong sales increase, profitability is declining for Japanese chemical firms Sales index, 1980 = 100 130 I First half Second half

Net income index, 1980 = 100 350

Net income as % of sales 5

ouu

4

120

-r

250 3 110

200 2 150

100 1

100

1986

1987

1988

1989

1990

50

1986

1987

1988

1989

1990

0

i

1 .

1986

1987

1988

1989

1990

Note: Based on results of 12 leading Japanese chemical companies: Asahi Chemical, Dainippon Ink & Chemicals, Hitachi Chemical, Mitsubishi Kasei, Mitsubishi Petrochemical, Mitsui Toatsu Chemicals, Sekisui Chemical, Showa Denko, Sumitomo Chemical, Takeda Chemical Industries, Teijin, and Toray Industries. The fiscal year for most, but not all, of these companies ends March 31. Source: Toyo Keizai Shinposha

COMPANY RESULTS: Earnings drop for many Japanese chemical companies $ Millions

Net sales

Net income

Asahi Chemical Industry5 $262.4 1990 $6699 1989 6377 241.0 1988 6384 219.4 1987 5357 141.0 Mitsubishi Kaseic 1990 $5321 1989 5307 1988 6132 1987 4360

Profit margin3

3.9% 3.8 3.4 2.6

Total assets

Employees (thousands)

$6895 6468 6410 5241

15.3 15.1 15.4 15.6

Employees (thousands)

2.0% 2.6 1.9 1.3

$5439 4455 4299 3881

5.3 5.1 5.1 5.0

1.6% 1.8 1.8 1.5

$4052 3999 4074 3366

7.2 6.9 6.7 6.6

69.1 87.3 83.5 43.5

2.3% 2.9 2.7 1.7

$4301 3963 3936 3004

5.5 5.4 5.4 5.6

Mitsubishi Petrochemic a l 5 $178.5 1990 $3000 227.8 2795 1989 160.0 2654 1988 64.7 2022 1987

6.0% 8.2 6.0 3.2

$4220 4376 3493 2843

3.3 3.0 2.9 2.8

Teijin5 1990 1989 1988 1987

Net sales

Showa Deii k o d $3934 1990 3811 1989 3679 1988 2908 1987

Net income

$ 78.2 97.1 71.3 38.8

Profit margin3

5

$128.1 130.8 124.9 90.4

2.4% 2.5 2.0 2.1

$6851 6621 6973 6002

9.1 8.9 8.8 8.9

Dainippon Ink & ChenHeals $ 57.3 1990 $3489 62.4 3407 1989 62.2 3440 1988 43.7 2923 1987 Mitsui Toatsu Chemic als $ 1990 $3039 2997 1989 3082 1988 2543 1987

5

Sumitomo Chemical1 _ 1990 $4950 $114.5 145.7 1989 4363 1988 4341 116.4 1987 3609 78.6

2.3% 3.3 2.7 2.2

$5587 5730 5806 4615

7.8 7.7 7.7 7.7

Takeda Chemical Industries5 1990 $3833 $265.9 1989 4262 271.7 1988 4567 269.4 1987 3777 219.6

6.9% 6.4 5.9 5.8

$5020 5280 5358 4628

11.0 10.9 10.8 10.8

Sekisui Chemical5 1990 $4144 1989 4018 1988 3936 1987 3089

4.3% 4.3 3.6 2.7

$4238 3414 2919 2555

5.6 5.4 5.2 5.3

Toray Industries5 1990 $4040 1989 3982 1988 4317 1987 3789

Total assets

$ Millions

$179.6 171.6 141.4 84.6 $193.4 227.7 134.7 113.5

4.8% 5.7 3.1 3.0

$5189 5362 5528 4854

10.3 9.6 10.0 10.6

$2279 2217 2438 2167

$138.1 154.9 136.5 109.3

6.1% 7.0 5.6 5.0

$4023 4015 3823 3391

5.7 5.7 5.8 6.2

Hitachi Ch smical5 $2099 1990 2052 1989 2158 1988 1748 1987

$ 30.7 31.7 28.2 20.7

1.5% 1.5 1.3 1.2

$1394 1279 1261 1056

5.3 5.1 5.0 4.9

Note: Monetary statistics are converted from yen to U.S. dollars on the basis of $1.00 equals: 1990, 144.8 Y; 1989, 137.9 Y; 1988, 128.1 Y; 1987, 142.9 Y. Year-to-year changes in sales, net income, and assets are affected by these fluctuations in the currency exchange rate, a Net income as a percentage of sales, b Fiscal year ends March 31. c Fiscal year ends March 31 for 1990, 1989, and 1988, Jan. 31 for 1987. d Fiscal year ends Dec 31. Sources: Toyo Keizai Shinposha, Nihon Keizai Shimbon America

June 24, 1991 C&EN

75

6

Foreign Chemical Industries -— C a n a d a

Sales and profits of Canadian chemical companies slipped last year as the country's recession ate into volume, and prices for many chemicals dropped. Inorganics were especially hard hit. Some of the trouble spots included chemicals that move into the fertilizer, pulp and paper, and construction markets. But it could have been worse. These rough spots were more than offset by advances in petrochemical and plastics production. In some cases, the advances were substantial. Total polyethylene output, for instance, was up a healthy 14%, while high-density polyethylene production registered a strong 20% gain. New capacity that came on stream last year explains some of the increase in production. But only some. Strong export markets are the other explanation. Canadian chemical exports increased 7.7% (in Canadian dollars) last year to $6.6 billion (U.S.). Chemical shipments to the U.S., which account for almost 70% of Canadian chemical exports, were especially strong. They were up 13% (in Canadian dollars) to $4.6 billion (U.S.).

Note on currency conversion: Monetary statistics in this section have been converted from Canadian dollars to U.S. dollars on the basis of $1.00 U.S. equals: 1990, $1,667 Canadian; 1989, $1,184 Canadian; 1988, $1,231 Canadian; 1987, $1,322 Canadian; 1986, $1,391 Canadian; 1985, $1,362 Canadian.

COMPANY RESULTS: Most profits dip $ Millions (U.S.)

Celanese Canada. $ 1990 1989 1988 1987

Sales

Net income3

Profit margin"

Capital Employees expenditures (thousands)

11.3% $ 20.7 14.5 12.2 19.9 12.0 16.1 8.1

312.5 335.0 330.8 265.5

$ 35.4 40.8 39.7 21.5

Du Pont Canada. $1209.4 1990 1196.9 1989 1119.6 1988 1021.4 1987

$ 53.5 66.4 81.2 68.5

4.4% 5.6 7.3 6.7

$154.6 91.3 86.6 47.9

4.3 4.1 4.0 4.2

Nova Corp. of Alberta 1990 $4059.2 1989 4088.3 1988 3202,1 1987 1755.4

$158.7 157.1 321.8 170.1

3.9% 3.8 10.0 9.7

$822.8 621.7 356.7 151.2

9.5 13.0 11.3 7.0

Union Carbide Canada 1990 $ 419.1 1989 436.0 461.3 1988 318.4 1987

$-4.0 36.0 34.3 19.4

na 8.3% 7.4 6.1

$ 56.5 41.7 45.0 26.2

2.5 2.6 2.8 2.3

1.8 1.9 2.1 2.1

a Excludes extraordinary gains and losses, b Net income as a percentage of sales. na = not available.

76 June 24, 1991 C&EN

Chemical output barely inches upward Production index, 1986 = 100 140

120

100

1981

82

83

Source: Statistics Canada

PRODUCTION: Inorganics weak, plastics do well Thousands of metric tons

1988

1987

Change 1989-90

INORGANIC CHEMICALS Ammonia Ammonium nitrate Ammonium phosphate Carbon black Chlorine Hydrochloric acid Nitric acid Phosphoric acid, 100% P205 Sodium chlorate Sodium hydroxide Sulfuric acid Zinc oxide

3602 1031 803 178 1542 187 965 402 658 1651 3311 31

4054 1056 952 190 1592 180 1027 470 593 1679 3560 41

4012 990 986 181 1664 180 919 475 503 1720 3805 62

3512 844 941 249 1635 164 900 464 432 1770 3437 44

-11.2% -2.3 -15.6 -6.0 -3.1 3.8 -6.0 -14.4 11.0 -1.7 -7.0 -24.4

ORGANIC CHEMICALS. Benzene Butadiene Butylene Ethylene Formaldehyde Methanol Propylene Toluene Urea Xylenes

765 192 176 2425 106 1884 766 427 2490 514

670 175 151 2317 112 2015 719 397 2402 432

695 182 148 2346 123 2101 672 417 2372 399

720 167 156 2140 122 1627 628 396 2142 345

14.3 9.8 16.7 4.7 -4.8 -6.5 6.6 7.6 3.7 18.8

PLASTICS Polyesters, unsaturated Polyethylene, high density Polyethylene, low density Polystyrene3

36 364 1167 215

37 303 1039 196

43 311 1105 216

47 269 1021 197

-1.3 20.4 12.3 9.4

a Includes acrylonitrile-butadiene-styrene resins. Source: Statistics Canada

SHIPMENTS: Chemical shipments were weak last year, particularly for inorganics $ Millions (U.S.)

All manufacturing Chemicals and chemical products Industrial chemicals, inorganic Industrial chemicals, organic Plastics and synthetic resins Pharmaceuticals and medicinals Adhesives Paint and varnish Soaps and cleansers Toilet preparations Printing ink Synthetic fibers Plastic products

Change 1989-90a

1990

1989

1988

1987

1986

$252,188 19,650 1,998 4,589 2,648 3,161 178 1,265 1,413 957 216 907 4,975

$256,099 19,471 2,064 4,446 2,547 3,022 177 1,313 1,401 994 238 853 5,175

$234,446 17,808 1,949 4,869 2,034 2,528 168 1,220 1,239 863 208 791 4,401

$203,013 15,020 1,780 3,676 1,681 2,121 150 1,061 1,111 759 182 700 3,686

$182,154 13,401 1,570 3,128 1,488 1,790 136 894 1,084 679 192 610 3,149

$182,526 13,409 1,605 3,456 1,445 1,637 95 885 1,002 644 177 572 2,834

-3% -1 -5 2 3 3 -1 -5 -1 -5 -11 5 -5

a In Canadian dollars. Source: Statistics Canada

TRADE BALANCE: Back to a surplus . . .

CHEMICAL IMPORTS: Post a sliqht qain $ Millions (U.S.)

Inorganic chemicals Organic chemicals Fertilizers and fertilizer materials Synthetic and reclaimed rubber Plastic materials Plastic film and sheet Other plastic shapes and forms Dyes, except dyeing intermediates Pigments, lakes, and toners Paints and related products Other chemical products TOTAL Imports from U.S. U.S. share

1990

1989

1988

1987

$1122 1781 189

$1190 1646 156

$ 910 1559 197

$ 396 1270 158

241

232

228

202

1299 435 421

1238 427 425

1094 392 430

831 372 261

93

96

86

71

115

117

115

115

254

233

195

176

1148 1155 951 857 $7096 $6878 $6158 $4708 $5335 $5060 $4330 $3609 75.2% 74% 70% 77%

CHEMICAL EXPORTS: Recover nicely

Chemical elements Other inorganic chemicals Organic chemicals Fertilizers and fertilizer materials Synthetic rubber and plastic materials Plastics, basic shapes and forms Other chemical products TOTAL Exports to U.S. U.S. share Source: Statistics Canada

Total exports Total imports Trade balance

1988

1990

$120.9 $113.0 $109.3 116.5 114.1 107.0 4.4 -1.1 2.3

1987

1986

$91.9 87.9 4.0

$83.9 81.3 2.5

1987

1986

. . . as chemical trade deficit narrows $ Millions (U.S.)

Chemical exports Chemical imports Chemical trade balance

1990

1989

1988

$6628 $ 6 0 6 3 $6262 $4639 7096 6878 6158 4708 -468 -815 -104 -69

$3961 4200 -239

Source: Statistics Canada

Source: Statistics Canada

$ Millions (U.S.)

$ Billions (U.S.)

1990

1989

1988

1987

$ 179 1045 1702 1422

$ 171 1112 1542 1237

$ 198 1145 1528 1351

$ 167 908 1029 960

1290

1176

1276

859

473

404

383

380

517

423

380

338

$6628 $6063 $6262 $4639 $4604 $4026 $3927 $2938 69.5% 66% 63% 63°/

PRICES: Many chemical prices drop Price index, 1986 = 100

All commodities Chemicals and chemical products Inorganic industrial chemicals Sulfuric acid Chlorine Ammonia Organic industrial chemicals Benzene-toluene-xylene Olefins Synthetic resins Polyethylene3 Polystyrene Thermosets Synthetic fibers Agricultural chemicals Mixed fertilizers Pharmaceuticals Paint and varnish Soaps and cleansers Toilet preparations Pigments, lakes, and toners Inks

1990

1989

109.7 113.8 103.8 111.1 93.0 78.4 118.3 126.0 133.1 111.3 115.7 127.6 119.7 106.6 106.9 104.7 125.2 114.5 116.0 112.9 106.7 103.1

109.4 166.8 105.8 108.6 101.4 84.3 135.0 125.5 161.2 123.0 134.9 140.7 125.9 105.5 102.4 110.8 119.0 111.1 111.9 112.9 105.8 101.5

1988

Change 1989-90

107.2 0.3% 115.3 - 2 . 6 102.6 - 1 . 9 106.8 2.3 101.7 -8.3 88.7 -7.0 135.2 -12.4 98.3 0.4 158.3 -17.4 130.8 - 9 . 5 151.7 -14.2 155.9 - 9 . 3 121.5 - 4 . 9 103.4 1.0 101.3 4.4 111.0 - 5 . 5 114.0 5.2 105.3 3.1 107.3 3.7 109.5 0.0 106.1 0.9 100.9 1.6

a Includes both high- and low-density polyethylene. Source: Statistics Canada

June 24, 1991 C&EN 77

6

Foreign Chemical Industries — Eastern Europe

In 1990, industrial production plummeted 18% in East Europe and 1.2% in the Soviet Union—the worst performance in more than four decades—as centrally planned command systems collapsed much faster than market elements could be introduced. Chemicals did worse than industry overall: Output sank 26% in Romania and Bulgaria, 25% in Poland, and 9% in Czechoslovakia. The malaise continues, with Soviet industrial output down 5% in this year's first quarter, fertilizer output down 8%, sulfuric acid 9%, and plastics 5%.

PRODUCTION GROWTH: Chemicals, like all industry, faced major drop in 1990

MAN-MADE FIBERS: Down substantially for both cellulosic and noncellulosic fibers Production, thousands of metric tons

1990

1989

1988

1987

Change 1989-90

NONCELLULOSIC FIBERS Bulgaria Czechoslovakia

na

61

67

61

143

148

147

142

Hungary

26

32

33

30

Poland

113

169

168

162

Romania

138

170

189

184

U.S.S.R.

na

973

954

904

TOTAL

na

1745 1736 1644

-3% -19 -33 -19 —

CELLULOSIC FIBERS Bulgaria Czechoslovakia Hungary

na

5

5

33

57

60

58

55

4

4

4

4

Poland

36

69

77

76

Romania

na

103

108

103 613

U.S.S.R. TOTAL

na

584

601

na

970

995 1029

-6% 0 -48

% annual change in gross output

1989

1990

1988

1987

1986

3

U.S.S.R. and East Europe

1.3%

3.8%

3.6%

4.4%

-14.1 -25.5

2.2 3.8

5.1 5.8

4.2 5.1

4.0 4.9

All industry Chemicalsb Hungary

-3.7 -9.1

0.8 0.7

2.1 2.1

2.5 3.2

3.2 4.0

All industry Chemicals13 Poland

-4.5 -5.4

-2.5 -3.1

-0.3 1.3

3.5 5.8

1.9 1.1

All industry Chemicals Romania

-23.3 C -24.7 C

-0.5 2.6

5.3 6.4

3.4 4.3

4.7 4.2

All industry Chemicals U.S.S.R.

-19.8 -26.0

-2.1 -3.1

3.1 3.2

2.4 -3.8

7.3 8.3

-1.2 -1.0 na na

1.7 1.4 0.2f -2.5 f

3.9 3.8 2.9 2.2

3.8 4.4 3.1 2.7

4.4 6.3 2.5 4.8

All industry Bulgaria All industry Chemicalsb Czechoslovakia

All industryd Chemicalsd All industry6 Chemicals6

-6.2%

a Includes East Germany, b Includes rubber industry, c Industrial sales of socialized sector, d Figures based on official Soviet statistics, e Figures based on Central Intelligence Agency estimates, giving lower results because of postulated upward bias in official figures. f Preliminary figure, na = not available. Sources: United Nations Economic Commission for Europe and state central statistical bureaus, Central Intelligence Agency, PlanEcon Inc.

AGRICULTURAL CHEMICALS: Fertilizer supplies continue to fall in Soviet Union

na = not available. Source: PlanEcon Inc.

Thousands of metric tons

Soviet chemical output declined in 1989 as that of all industry faltered % annual change in gross output 6

1990

1989

1988

1987

1986

Bulgaria Fertilizer supply3 Pesticide supplyb Czechoslovakia

na na

na na

781 26.3

745 28.5

808 36.5

na

1,565

1,594

1,562

1,702

Fertilizer supply3 Poland

na

1,302

1,418

1,373

1,383

Fertilizer supply3,0 Pesticide supplyb Romania Fertilizer supply3 U.S.S.R.

na na

3,625 21.0

3,277 23.4

3,583 18.4

3,413 14.5

na

1,194

1,426

na

1,386

21,500 24,482 8,900d 9,918 7,000d 8,175 5,600d 6,381

27,196 11,587 8,556 7,044

27,412 11,787 8,564 7,052

26,514 11,475 8,354 6,677

Fertilizer supply3,0 Hungary

1979

80

81

82

83

84

a Preliminary. Source: Central Intelligence Agency

Fertilizer supply3 Nitrogen3 Phosphate3,6 Potassium3

a Nutrient content basis, as N, P 2 0 5 , or K 2 0. b On basis of active substance, c For year ending June 30. d Estimated value, e Includes ground phosphate rock, na = not available. Sources: Department of Agriculture, Central Intelligence Agency, official national statistics from state central statistical bureaus 78

June 24, 1991 C&EN

PRODUCTION: Further declines for most countries' chemical products in 1990 Thousands of metric tons

1989

1988

1987

1986

Thousands of metric tons

1989

6

1988

1987

1986

U.S.S.R. Sulfuric acid

419

587

574

667

655

27,300a

28,276

29,372

28,531

27,847

Phosphate6

94

215

238

283

267

Mineral fertilizers6

31,700a

34,254

37,138

36,334

34,737

Potassium66

180

101

136

117

118

13,500a

14,355

15,815

15,743

15,221

Synthetic ammoniad

576f

681

691

784

763

8,800a

9,657

10,013

9,693

9,279

Plastics

603

638

590

545

426

9,400a

10,233

11,300

10,888

10,228

Sodium hydroxide'

193

204

202

201

202

19,422

20,330

19,931

19,590

Ethylene

234

262

264

270

269

24

38

35

38

35

1850f

3114

3154

3149

2966

1854

2725

2719

2622

2526

1302

1643

1622

1543

1445

Phosphate6

467

945

962

942

948

Potassium6,6

85

137

134

137

133

1768f

1941

1923

1791

1747

Nitrogen

Nitrogenb Phosphate60 Potass ium

b

Synthetic ammoniaJ

na

Plastics6

5,500a

5,763

5,675

5,488

5,345

Sodium hydroxide

3,000a

3,185

3,323

3,288

3,229

Ethylene

na

3,137

3,175

2,977

2,799

Methanol

na

3,331

3,211

3,284

3,219

f

Synthetic rubber

na

2,400

2,435

2,366

2,320

Pesticides9

na

276

317

327

332

BULGARIA Sulfuric acid

na

Mineral fertilizers6

846

840

na

724

588

571

580

na

555

588

443

448

na na 231

169 1,326 328

179 1,342 363

128 1,070 322

132 1,091 420

Sodium hydroxide

na

118

124

104

138

Synthetic rubber Pesticides9

na na

25 19

25 18

24 15

25

Nitrogen6 Phosphate6 Synthetic ammonia' Plastics

CZECHOSLOVAKIA _ Sulfuric acid Mineral fertilizers6 Nitrogen

6

688

807

15

1,033

1,142

1,249

1,264

1,292

877

1,008

1,025

984

1,041

514

604

596

596

614

Pesticides9 POLAND Sulfuric acid 6

Mineral fertilizers Nitrogen6

Synthetic ammoniad Plastics

624

721

723

641

632

Sodium hydroxide

397

434

444

422

427

Ethylene

308

322

328

276

279

Methanol

155

162

168

172

169

Synthetic rubber

103

125

128

117

116

na

11

11

9

8

9

Pesticides

, ROMANIA Sulfuric acid

1112

1687

1825

1693

1971

Mineral fertilizers6

1742

2805

2994

2897

3278

1225f

2035

2130

2096

2315

425f

648

725

665

849

1974f

2744

2804

2784

3037

Nitrogen6 6

Phosphate

60

257

296

313

277

307

Synthetic ammoniad

Potassium6,9

106

108

116

111

120

Plastics

520f

Sodium hydroxide

556

640 763

653 821

638 817

664 846

Ethylene

243

332

335

319

312

Synthetic rubber

102

149

161

152

173

f

34

39

39

47

Phosphate

d

Synthetic ammonia Plastics Sodium hydroxide

na

797

774

781

765

1,174

1,186

1,192

1,150

1,140

335

337

337

332

335

Synthetic rubber

70

75

79

76

76

Pesticides9

17

18

19

18

20

HUNGARY Sulfuric acid

244

482

512

573

540

Mineral fertilizers6

693

903

921

1,067

1,040

9

21

Pesticides

a Approximate figures, b Nutrient content basis, as N, P 2 0 5 , or K 2 0. c Including production of ground phosphate) rock for direct applications and phosphate animal feeds. d Nitrogen content, e Including resins for man-made fibers, f Estimated, g On basis of active substance, h Imported potash added to domestically produced nitrogen and phosphate to form multinutrient fertilizer. I Including regenerated NaOH. na = not available. Sources: Central Intelligence Agency, Department of Agriculture, PlanEcon Inc., official national statistics from state central statistical bureaus

SOVIET FOREIGN TRADE: Rapidly rising trade deficit also affects chemical trade $ Millions

1987 6

Exports

1986

1985

1984

1983

1982

1981

1980

$ 79,380 $ 76,437

$87,196

$91,495

$91,652

$87,168

114,372

114,698

107,316

95,971

88,874

83,315

80,409

80,445

77,846

73,194

-16,200

-5,399

3,424

11,693

8,179

3,881

11,086

11,207

9,322

6,186

7,964

Chemical exports6

na

3,592

3,559

2,979

2,770

2,837

2,707

2,307

2,203

2,275

2,025

Chemical imports6

na

5,404

4,924

4,516

3,990

3,744

3,256

3,216

3,028

3,211

3,275

Chemical trade balance

na

-1,812

-1,365

1,537

-1,220

-907

-549

-909

-825

-1,651

-1,250

Imports6 Trade balance

$ 98,172 $109,299 $110,740 $107,664 $ 97,053

68,473

a Preliminary values, b Free on board, na = not available. Sources: Central Intelligence Agency, U.S.-U.S.S.R. Trade & Economic Council, based on official Soviet statistics and exchange rates for the Soviet foreign exchange ruble

June 24, 1991 C&EN

79

6

Foreign Chemical Industries — Pacific Basin

SOUTH KOREA. INDUSTRY TRENDS: Chemicals up strongly Index, 1985 = 100

1990

1989

1988

Change 1989-90

1987

Chemicals, petroleum, coal, rubber, and plastic products Production 172.9 154.8 150.7 127.6 Shipments 174.4 152.7 146.8 124.5 Inventories 176.1 155.4 128.6 114.2 Industrial chemicals. Production 188.6 156.6 149.3 128.0 151.6 146.1 128.2 184.7 Shipments 107.1 164.6 117.6 183.0 Inventories Other chemical product s Production 205.5 183.0 171.3 133.1 209.4 186.5 170.0 135.6 Shipments 234.6 195.5 159.5 121.7 Inventories Rubber products Production 144.7 128.1 151.1 140.1 143.8 128.1 Shipments 150.9 139.2 122.3 123.1 131.2 119.4 Inventories Plastic products Production 158.9 156.9 159.5 138.1 151.2 145.5 148.3 133.4 Shipments 225.9 193.3 148.3 143.5 Inventories All manufacturing Production 186.5 171.3 166.3 146.6 191.0 171.6 164.6 145.1 Shipments 190.7 162.1 137.6 120.7 Inventories

12% 14 13

Exports Imports'3 Trade balance

J

175 150

y^ y\

100 / ^

Chemicals and related products8

^ ^ 13 12 -1

75 50 1980

1 4 17 9 11 18

1990

1989

1988

1987

$65,016 69,844 -4,828

$62,377 61,465 912

$60,696 51,811 8,886

$47,281 41,020 6,261

2,511 7,434 -4,922

2,050 7,158 -5,108

1,879 6,282 -4,404

1,321 4,595 -3,274

Chemical exports 30 Chemical lmportsbc Chemical trade balance

100

125 12 12 20

FOREIGN TRADE: Imports far outpace exports 3

Production index, 1985 200

All manufacturing 20 22 11

Source: Korean National Statistical Office

$ Millions

Growth picks up in 1990 for South Korean chemicals production

a Free on board, b Includes cost, insurance, freight, c Includes chemicals and related products. Source: Korean Office of Customs Administration

i

i

i

81

82

83

i 84

i 85

i

i 87

86

i

i

I

90

a Includes petroleum, coal, rubber, and plastic products. Source: Korean National Statistical Office

PRODUCTION: Organics post biggest gains Thousands of metric tons

1990

1989

1988

1987

Complex fertilizers Ethylene Urea fertilizers Polyethylene Polyester fibers Propylene Polypropylene Polyvinyl chloride Polystyrene Benzene Synthetic detergents Sodium hydroxide

1926 1054 883 786 730 608 574 526 507 381 342 328

1985 663 888 637 654 375 530 464 434 305 297 295

2076 609 1000 572 593 351 518 455 341 308 278 311

2026 576 911 469 496 328 348 451 304 339 214 262

Change 1989-90

-3% 59 0 23 12 62 8 14 17 25 15 11

Source: Korean National Statistical Office

AUSTRALIA FOREIGN TRADE: Exports growing fastest

PRODUCTION: Plastics ease downward Thousands of metric tons, unless otherwise noted

1990a

1989a

1988a

1987a

Change 1989-90

1990a

1989a

1988a

1987a

3

$37,817

$ 35,465

$ 29,936

$ 23,745

0

Imports

39,510

38,404

29,592

24,568

Trade balance

-1,693

-2,939

344

-823

948

861

650

440

205

190

149

110

3,999

4,046

3,119

2,304

Organic chemicalsd

825

951

806

584

Medicinal products

631

566

472

337

-3,051

-3,185

-2,469

-1,864

$ Millions

Exports' Chemicals Superphosphate13 Sulfuric acid, 100% Ammonium sulfate Acetylene, thousand cubic meters Plastics and resins Detergents and soap Flexible plastic film, sheetsd Polyethylene6 Polypropylene

2659 1464 214 2654

nac 1904 165 nac

nac 1818 179 nac

nac 1678 165 nac

975 319 183 141 19

986 nac nac nac nac

990 nac nac nac nac

904 nac nac nac nac

-23% 30

Medicinal products -1

— —

a Year ending June 30. b Includes double and triple superphosphates expressed in terms of single phosphate (9% P equivalent), c Not available prior to July 1989 because of revised commodity classification, d Includes flexible plates, sheets, foil, and strip of plastics; excludes self-adhesive, floor, wall, and ceiling coverings, vulcanized fibers, plastic foam, and plastics reinforced, laminated, or supported with other materials, e Low and high density, na = not available. Source: Australian Bureau of Statistics

80 June 24, 1991 C&EN

Chemical exports'3 Chemical imports0

Chemical trade balance

Note: Monetary statistics converted from Australian to U.S. dollars on basis of $A1.00 equals: 1987, $0.6636; 1988, $0.7290; 1989, $0.8160; 1990, $0.7697. a Year ending June 30. b Free on board, c Values for customs purposes, free-on-board basis, d Includes organic-inorganic and heterocyclic compounds. Sources: Australian Department of Foreign Affairs & Trade, Reserve Bank of Australia

CHINA PRODUCTION: Big gains for plastics, fibers, and especially soda ash Thousands of metric tons

Synthetic ammonia Fertilizer3 Sulfuric acidb Sodium hydroxide15 Sodium carbonate Plastics

1989

1990

21,251 20,675 19,120 18,547 11,689 11,408 3,211 3,338 3,746 2,983 1,973 2,249

1988

1987

19,725 17,670 10,981 2,925 2,593 1,552

19,486 17,033 9,620 2,735 2,372 1,571

Change 1989-90

3% 3 2 4 26 14

Thousands of metric tons

1990

1989

1988

1987

Man-made fibers Synthetic detergents Ethylene Pesticides Pharmaceuticals Synthetic rubber

1625 1484 1572 229 172 316

1466 1431 1405 224 196 289

1284 1290 1231 202 194 251

1157 1192 839 157 154 218

Change 1989-90

11% 4 12 2 -12 9

a Nutrient content, b 100%. na = not available. Sources: State Statistical Bureau of the People's Republic of China, China Economic News, Central Intelligence Agency, China Statistics Monthly

CHEMICAL IMPORTS: Decline continues in 1990 $ Millions3

Organic chemicals Inorganic chemicals Dyeing, tanning, coloring materials Medicinal and pharmaceutical products Fertilizers'3 Plastic materials, resins, cellulose esters and ethers TOTALc

Change 1989-90

1990

1989

1988

1987

$1131 215 244

$1405 469 226

$1701 448 237

$ 998 422 202

395

311

384

229

27

2605 1498

2364 2206

2335 3558

1399 1470

10 -32

$6650

$7556

$9139

$5008

-20% -54 8

-12%

a Includes cost, insurance, and freight, b Manufactured, c For all chemicals and related products. Source: General Administration of Customs of the People's Republic of China

CHEMICAL EXPORTS: Growing strongly $ Millions"

Organic chemicals Inorganic chemicals Dyeing, tanning, coloring materials Medicinal and pharmaceutical products Essential oils, perfumes, cleansing materials Explosives, pyrotechnic products TOTALb

Change 1989-90

1990

1989

1988

1987

$ 838 842 366

$ 690 794 288

$ 575 762 229

$ 500 553 175

622

549

468

408

13

319

235

183

136

36

211

244

298

183

-13

$3730

$3201

$2897

$2235

21% 6 27

16%

a Free on board, b For all chemicals and related products. Source: General Administration of Customs of the People's Republic of China

TAIWAN. INDUSTRY TRENDS: Chemicals set the pace

PRODUCTION: Many plastics doing well

Industrial production indexes, 1986 = 100

Thousands of metric tons, unless otherwise noted

All manufacturing Chemical materials Basic chemicals Petrochemicals Fertilizers Synthetic fibers Plastics and resins Chemical products

1990

1989

1988

1987

117.3 119.6 114.8 96.0 114.1 142.7 139.1 139.8

119.3 110.3 102.9 92.9 111.3 126.7 126.1 129.1

115.4 108.0 94.4 98.8 113.4 113.5 122.8 125.7

111.2 103.6 96.5 97.1 102.9 109.7 110.6 114.8

Change 1989-90

-2% 8 12 3 3 13 10 8

Source: Taiwan Ministry of Economic Affairs

FOREIGN TRADE: Chemical exports up 6 % $ Millions

Exports" Imports" Trade balance Chemical exports30 Chemical imports"0 Chemical trade balance

1990

1988

$67,214 $66,201 $ 60,585 $53,612 54,716 52,249 34,957 49,656 12,498 13,952 10,929 18,655 5,711 5,397 4,844 3,741 7,621 7,408 5,150 7,051 -1,910 -2,011 -2,207 -1,409

Note: Statistics converted from NT$ to U.S. dollars on basis of $1.00 equals: 1990, NT$26.9; 1989, NT$26.4; 1988, NT$28.6; 1987, NT$31.8. a Free on board, b Includes cost, insurance, and freight, c Includes chemicals, chemical products and plastic and rubber products. Sources: Taiwan Council for Economic Planning & Development, Taiwan Ministry of Finance Department of Statistics, C&EN estimates

Polyester3 Polyvinyl chloride Terephthalic acidb Ethylene Vinyl chloride Sulfuric acid Ammonium sulfate Propylene Acrylonitrile-butadienestyrene Oxygen0 Polyethylene* Styrene Calcium superphosphate Ammonia, anhydrous Xylene Paints Hydrochloric acid Urea Dioctyl lactam Ethylene glycol

1990

1989

1988

1987

1290 921 798 776 665 658 509 398 384

1193 805 583 766 662 768 524 398 311

1100 779 495 852 708 664 484 441 301

1076 773 500 823 699 742 485 442 208

370 360 355 354 263 254 239 234 229 188 178

352 344 301 352 246 239 214 217 237 179 216

350 390 331 315 339 164 247 255 306 167 197

261 375 310 342 296 235 229 251 244 192 195

Change 1989-90

8% 14 37 1 0 -14 -3 0 23 5 5 18 1 7 6 12 8 -3 5 -18

a Filament and fiber, b Pure terephthalic acid, c Millions of cubic meters, d Low and high density. Source: Taiwan Council for Economic Planning & Development

June 24, 1991 C&EN

81