FINAL PROGRAM - C&EN Global Enterprise (ACS Publications)

Nov 6, 2010 - 152nd National ACS Meeting New York City Sept. 11-16, 1966. Chem. ... Miss Hazel Bishop , Ladies' Entertainment. Stewart Cowell , Plant ...
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ASSOCIATIONS

FINAL PROGRAM 152nd National ACS Meeting New York City Sept. 11-16, 1966

ACKNOWLEDGMENTS The cooperation of the New York Section of the American Chemical Society in handling local arrangements for the fall meeting is acknowledged gratefully. Through the efforts of its committees, many interesting and diversified activities have been planned for all registrants. New York Section Committees Miss Hazel Bishop, Ladies' Entertainment Stewart Cowell, Plant Trips Donald D. Wright, Student Personnel Our appreciation is extended to all division secretaries and program chairmen who work so diligently and are so cooperative in helping to assemble the technical program for ACS national meetings. Appreciation is also extended to the New York Convention and Visitors Bureau, Inc. for its fine assistance and helpful suggestions in the preparation for this meeting.

ACS OFFICES AND REGISTRATION AREAS Executive Secretary, ACS Director of Publications Chemical and Engineering News ACS News Service and Press Room Chemical Abstracts Service Employment Clearing House Information Booth Ladies' Hospitality Center Operations

New York Hilton, Gibson Suite (2nd floor) New York Hilton, Rooms # 5 3 7 and # 5 4 0 (5th floor) New York Hilton, Rooms # 5 2 4 and # 5 2 6 (5th floor) New York Hilton, Room # 5 5 1 (5th floor) New York Hilton, Promenade (2nd floor) Statler Hilton, Exhibition Hall (Ballroom floor) New York Hilton, Promenade (2nd floor) New York Hilton, Room #517 (5th floor) Americana, Versailles Ballroom (2nd floor) New York Hilton, Madison Suite (2nd floor) Statler Hilton, Dartmouth Room (Ballroom floor) Waldorf-Astoria, Terrace Court (Park Ave. Lobby)

ACS President's Dinner and General Meeting. Following the practice established at the Chicago meeting in 1964. the President's Dinner is scheduled for Monday evening, Sept. 12. It will be preceded by a reception at 6 P.M. in the East and West Ballroom Foyers of the New York Hilton. The dinner will be held in the East Ballroom of the New York Hilton at 7 P.M. An outstanding after-dinner speaker will be announced at a later date. Tickets may be purchased in advance at $10 each. See order form on page 57. 56 C&EN AUG. 8, 1966

The General Meeting will be held in the West Ballroom of the New York Hilton at 9 P.M. Milton Harris, Chairman of the ACS Board of Directors, will introduce President-Elect Charles G. Overberger, who will announce the 1967 recipients of awards administered by the American Chemical Society. Rudolf Morf, Secretary General of I UP AC. will be honored for his outstanding contributions to international chemistry. Recognition of the 75th anniversary of the founding of the Rhode Island and New York Sections will be made. ACS President W. J. Sparks will present his Presidential Address entitled "Creativity—Competition and Cooperation/' ACS Short Courses. Eight courses, ranging from one to four days and including a laboratory course that will be given three times, will be offered in connection with the New York meeting. See page 59 for details. Advance registration. Persons planning to attend the New York meeting are urged to register in advance. Fill out the advance registration form on page 61 and return it with the appropriate remittance. A meeting identification badge, mixer ticket, and registration receipt will be mailed to advance registrants prior to the meeting. Booklet programs and group event tickets will be available during the regular hours announced for meeting registration. Advance registrants' cards will be posted in the visible file located in the New York Hilton. No check-in prior to attendance at technical sessions will be required. The deadline for receipt of advance registrations is Sept. 2. Requests for refunds will be honored if received by Sept. 9, together with badge, mixer ticket, and receipt. For those who are unable to register in advance, registration facilities will be available during the meeting as follows: Sunday, Sept. 11 3 P.M. to 8 P.M.

Promenade (2nd floor), New York Hilton Rotunda (Ballroom floor), Statler Hilton Terrace Court (Park Ave. entrance), Waldorf-Astoria

Monday, Sept. 12 8 A.M. to 5 P.M.

Promenade (2nd floor), New York Hilton Rotunda (Ballroom floor), Statler Hilton Terrace Court (Park Ave. entrance), Waldorf-Astoria

Tuesday, Sept. 13 8 A.M. to 5 P.M.

Promenade (2nd floor), New York Hilton Rotunda (Ballroom floor), Statler Hilton Terrace Court (Park Ave. entrance), Waldorf-Astoria

3 P.M. to 8 P.M.

Versailles Ballroom Americana

(2nd

floor),

Wednesday, Sept. 14 8 A.M. to 5 P.M.

Versailles Ballroom (2nd floor), Americana Promenade (2nd floor), New York Hilton Rotunda (Ballroom floor), Statler Hilton Terrace Court (Park Ave. en­ trance), Waldorf-Astoria

Thursday, Sept. 15 8 A.M. to 5 P.M.

Versailles Ballroom (2nd floor), Americana Promenade (2nd floor), New York Hilton Rotunda (Ballroom floor), Statler Hilton

Friday, Sept. 16 8 A.M. to Noon

Versailles Ballroom Americana

(2nd

floor)

Tickets for ladies' events will be sold only in the Ladies' Hospitality Center in the New York Hilton; tickets for group events and plant tours will be sold in the ACS registration areas in the Americana, New York Hilton, Statler Hilton, and WaldorfAstoria. See the complete listing of registration fees and the Society's Bylaw Governing Registration on page 60. B a d g e s . It is important that the official badge, supplied at the time of registering, be worn at all times, not only as a courtesy to fellow registrants, but also as an indication that registration has been completed prior to participation in any of the events scheduled. Pocket inserts will be available in the registration areas for those desiring to attend a single technical session. Book exhibit. The 25th Annual Book Exhibit, sponsored by the ACS Division of Chemical Education, again will be held in conjunction with the fall meeting. The exhibit will be in the Versailles Ballroom of the Americana. This will be the largest exhibit to date, with more than 60 publishers participating and more than 1800 books on display. A librarian will be present at all times to assist visitors. The exhibit will be open during the following times : M o n d a y - 9 A.M. to 5 P.M. T u e s d a y - 9 A.M. to 8 P.M. W e d n e s d a y - 8 A.M. to 5 P.M. T h u r s d a y - 8 A.M. to 5 P.M. Friday—8 A.M. to Noon Books will be classified according to subject matter and set into library troughs for easy examination. A new method will be used in classifying the books. Several new categories and subdivisions of some categories will be used for the first time. A complete catalog, classified as to both subject and author, will be published in the September 1966 issue of the Journal of Chemical Education. Copies of that issue and reprints of the catalog section will be available for free distribution at the exhibit. Chemical Abstracts Service open forum. A discussion of present and future plans for handling and disseminating chemi­ cal information will be conducted at 8 P.M. on Wednesday, Sept. 14, in the New York Hilton, Beekman Room. Committee m e e t i n g s . The open meetings of the Standing Committees of the Council and the Committees on Chemical Safety, Nominations and Elections, Patent Matters and Related Legislation, Professional Training, Study Geographic Districting, and the Women's Service Committee will convene in the follow­ ing locations at the times indicated below: Chemical Education (Donald L. Swanson, chairman), Tues­ day, Sept. 13, 2 P.M. to 4 P.M., Americana, Biarritz Suite. Chemical Safety ( Herbert K. Livingston, chairman ), Wednes­ day, Sept. 14, 10 A.M. to 11:30 A.M., New York Hilton, Morgan Suite A. Constitution and Bylaws (David C. Young, chairman), Wednesday, Sept. 14, 2 P.M. to 4 P.M., New York Hilton, Clinton Suite B. Local Section Activities (George W . Campbell, chairman), Wednesday, Sept. 14, 2 P.M. to 4 P.M., New York Hilton, Bryant Suite B.

Membership Affairs (Charles O. Gerfen, chairman), Wednes­ day, Sept. 14, 9 A.M. to Noon, New York Hilton, Bryant Suite B. National Meetings and Divisional Activities (Ambrose G. Whitney, chairman), Tuesday, Sept. 13, 3 P.M. to 4 P.M., New York Hilton, Bryant Suite B. Nominations and Elections (George W. Watt, chairman), Tuesday, Sept. 13, 3 P.M. to 5 P.M., Americana, Provence Suite #46. Patent Matters and Related Legislation (Pauline Newman, chairman), Wednesday, Sept. 14, 11 A.M. to Noon, New York Hilton, Morgan Suite B. Group discussion on the subject of the difference between scientific advance and patentable invention, and the "standards of invention" in chemical patents. Professional Relations and Status ( Joseph Stewart, chairman ), Monday, Sept. 12, 9 A.M. to 11 A.M., Americana, La Loire Suite # 2 and # 3 . Professional Training (Cheves Walling, chairman), Sunday, Sept. 11, 2 P.M. to 5 P.M., New York Hilton, Beekman Room. Publications (Blaine G. McKusick, chairman), Wednesday, Sept. 14, 9 A.M. to 11 A.M., New York Hilton, Clinton Suite B. Study Geographic Districting (Herbert K. Livingston, chair­ m a n ) , Monday, Sept. 12, 2 P.M. to 3 P.M., Americana, La Loire Suite # 2 and # 3 . Women's Service Committee (Gladys H. Swope, chairman), Monday, Sept. 12, 2:15 P.M. to 3 P.M., Wellington, Laurelton Room. Council meeting. The meeting will commence at 9 A.M. on Tuesday, Sept. 13 in the West Ballroom of the New York Hilton. Councilors may check in beginning at 8:15 A.M. Space will be available for ACS members registered for the 152nd national meeting (admission by badge) to observe the Council session; it is hoped that many will take advantage of this opportunity to learn first-hand of the Society's operations as reported to, and acted upon by its "house of representatives." Divisional m e e t i n g rooms. Divisional meeting rooms will be equipped with standard lantern-slide projectors ( 2 " χ 2 " and 3Vt" X 4 " ) , screens, blackboards, flashlight pointers, chalk, and reading desks with public address attachments including lapel microphones. An attempt will be made to furnish motion picture and other special equipment upon the request of the divisions or individuals if notice of such special needs is sent to the National Meetings and Divisional Activities Office of the ACS by Aug. 12. Divisional m e e t i n g s . See pages 70-132 of this program for listing of technical sessions and their locations.

Ticket order form for President's Dinner Tickets for the President's Dinner (see page 56) are available in advance @ $10. Enclose remittance in full (make check payable to the American Chemical Society and send to the National Meetings and Divisional Activities Office, American Chemical Society, 1155 16th St., N.W., Washington, D.C. 20036). .Tickets @ $10. Please print Name:_ Address:City, state, ZIP code:_

AUG. 8, 1966 C&EN 57

Divisional membership. Membership in a division is evidence of your interest in that particular field of chemistry or chemical engineering and in the work of the division. Members of each division are granted at least one special privilege, a reduced rate on the purchase of abstracts. Most divisions offer addi­ tional services. Members of the Society may become members of one or more divisions upon request to the divisional secre­ tary ( s )—see page 59. Divisional Officers. A divisional officers' social hour (6 P.M.) and dinner (7 P.M.) will be held on Thursday, Sept. 15, in the Morgan Suite of the New York Hilton. All divisional officers are urged to attend this function, as well as the meeting sched­ uled Thursday, Sept. 15, 3 P.M. to 5 P.M. in the New York Hilton, Bryant Suite B, to discuss projected divisional programs and other divisional matters of mutual interest. Employment Clearing House. Detailed plans for the opera­ tion of the E C H appear on pages 59-60. Exposition. See page 65 for detailed information on the expo­ sition to be sponsored by the New York Section, ACS. Film program. The Division of Chemical Education will sponsor a film program during the New York meeting. Details appear on page 65. Foreign visitors. The badges of visitors from other countries attending the New York meeting will be marked with a benzene ring or hexagon. Group events. Tickets for all ladies' events will be sold only in the Ladies' Hospitality Center, New York Hilton, Boom # 5 1 7 (5th floor). Tickets for group meals, as well as plant trips, should be purchased well in advance, preferably at the time of registration, at a booth in the registration areas listed in this program. A deadline has been established for the sale of tickets for each event, after which time available tickets will be sold at a sur­ charge of 25 cents per ticket. For all scheduled events, the deadlines are: Breakfasts Luncheons Dinners Ladies' events Plant trips

5 9 2 5 4

P.M. preceding day A.M. same day P.M. same day P.M. preceding day P.M. preceding day

held in 1963 in New York. All ACS members are invited to attend; tickets will be available at group events ticket sales @ $2.00. In addition to recognition of foreign visitors, the Com­ mittee will honor Rudolf Morf, General Secretary of IUPAC, who will be attending the ACS meeting. In recognition of the 20th anniversary of the founding of the broad cultural exchange programs, Fulbright fellowships, and similar programs of the Department of State, it has been suggested that we might include a recognition of these programs in our reception. Former foreign fellows under Guggenheim, NATO, UNESCO, Fulbright, AID, NSF, and other fellowship programs are urged to attend in order to meet both their fellow associates and greet those chemists in attendance from abroad. Ladies' program. Details of an attractive program planned for ladies, under the chairmanship of Hazel Bishop, appear on pages 65-66. The Ladies' Hospitality Center will be located in Boom # 5 1 7 of the New York Hilton. Local section Officers. A Local Section Officers' breakfast will be held at 7:30 A.M. on Wednesday, Sept. 14, in the Biarritz Suite of the Americana. Local section workshop. How local sections can initiate and conduct science quiz contests among junior and senior high school students is the subject of a discussion workshop arranged through the ACS Office of Information Services. Possibilities for use of television will be explored. Representatives of all local sections are encouraged to attend this workshop in the Regency Ballroom, Americana, 9:30 A.M. to 11:30 A.M., Wednesday, Sept. 14. Mixer. The mixer will be held on Monday, Sept. 12, at 10 P.M. in the East Ballroom of the New York Hilton. Admittance will be restricted to those wearing their registration badges and presenting special tickets and to guests of registrants who pay an admission fee of $3.00. For convenience, a registration line will be in operation during the first hour of the mixer. News Service. The ACS News Service will maintain com­ plete press room facilities in Room # 5 5 1 (5th floor) of the New York Hilton.

Northeastern University Chemists' Club.

The recently

formed Northeastern University Chemists' Club will hold an organizational meeting on Wednesday, Sept. 14, 5:30-7:00 P.M., in the Statler Hilton, Hudson Room.

Please cooperate by purchasing tickets early so proper accom­ modations can be arranged. Do not take a chance; only a few tickets will be available at the door of each event. A listing of group events planned may be found on page 64 and in the ladies' and plant trips program.

Plant tours. A detailed listing of the plant tours program begins on page 66.

Hotel reservations. A housing bureau has been organized for the New York meeting. Since all requests for rooms are handled in chronological order, it is recommended that applications be sent to the housing bureau as promptly as possible. In making hotel reservations, please use the coupon on page 63, a map indicating locations is on page 62. Each reservation will be confirmed directly to the individual concerned, indicating the hotel assignment and the price of the room reserved. Please allow the housing bureau reasonable time to process your request before inquiring about it.

planners are urged to attend this meeting scheduled Thursday, Sept. 15, from 3 P.M. to 5 P.M., to coordinate projected divi­ sional programs. The meeting will be held in Bryant Suite Β of the New York Hilton.

Information booth. An information booth will be in operation on the Promenade (2nd floor) of the New York Hilton during the hours announced for registration. Personal messages in writing may be exchanged and a lost-and-found service will be provided. Mail and telegrams should be addressed to the hotel in which you are staying. Communications addressed in care of the American Chemical Society cannot be delivered but will be held at the ACS Information Booth. No one will be paged in divisional meetings. The Society accepts no responsibility for the delivery of mail, telegrams, or telephone messages, but is glad to be of as much service as possible. International reception. The Committee on International Ac­ tivities will sponsor a reception for foreign guests attending the 152nd ACS National Meeting in New York, on Tuesday after­ noon ( 6 - 8 P.M.) Sept. 13, in the New York Hilton, Trianon Ballroom. The reception will be patterned after a similar one 58 C&EN AUG. 8, 1966

Postconvention cruise.

See detailed information below.

Projected divisional program meeting. Divisional program

Women Chemists. A luncheon for women chemists has been scheduled at 12:30 P.M. on Monday, Sept. 12, in the Welling­ ton Hotel, Laurelton Room.

Postconvention cruise The Grace Line's SS Santa Rosa will sail from New York at 7 P.M. on Friday, Sept. 16, for a 13-day specially planned postconvention cruise to the West Indies for ACS members and their families and friends. Ports of call include Curacao, LaGuaira (Caracas), Venezuela; Aruba; Kingston, Jamaica; Port-au-Prince, Haiti; and Ft. Lauderdale, Fla. (Passengers may disembark in Florida, if desired). Fares are available from $535 up, per person, on this American flag luxury cruise ship. A brochure outlining details is available from Vern Ramsing, Travel Consultants, Inc., 1612 Κ St., N.W., Washington, D.C. 20006.

Divisional secretaries' addresses

ACS short courses

Agricultural and Food Chemistry. F. Leo Kauffman, Res. Labs., Swift and Co., Packers and Exchange Ave., Chicago, III. 60609 Analytical Chemistry. Charles V. Banks, Dept. of Chem., Iowa State Univ. of Science and Tech., Ames, Iowa 50010 Biological Chemistry. Otto K. Behrens, Lilly Res. Labs., Eli Lilly & Co., Indianapolis, Ind. 46206 Carbohydrate Chemistry. Louis Long, Jr., U.S. Army, Natick Labs., Natick, Mass. 01760 Cellulose, Wood, and Fiber Chemistry. Mary E. Carter, FMC Corp., Amer. Viscose Div., Marcus Hook, Pa. 19061 Chemical Education. Robert L. Livingston, Dept. of Chem., Purdue Univ., West Lafayette, Ind. 47906 Chemical Literature. Lee N. Starker, Warner-Lambert Res. Inst., 170 Tabor Rd., Morris Plains, N.J. 07950

The following courses will be offered in connection with the New York meeting. Interpretation of Infrared Spectra. Two days, Saturday and Sunday, Sept. 10-11; Norman B. Colthup (American Cyanamid Co.) in charge. Brooklyn College of the City University of New York. Mass Spectrometry. Two days, Saturday and Sunday, Sept. 10-11; Fred W. McLafferty (Purdue University) in charge. Columbia University. Modern Theory of Acids and Bases. One day, Thursday, Sept. 15; Ralph G. Pearson (Northwestern University) in charge. Cooper Union. Molecular Characterization of Polymers. Four days, Wednesday through Saturday, Sept. 14-17; Fred W. Billmeyer, Jr. (Rensselaer Polytechnic Institute) in charge. New York University (Washington Square campus). Molecular Orbital Theory in Organic Chemistry. Two days, Friday and Saturday, Sept. 9-10; Andrew Streitwieser, Jr. ( University of California, Berkeley ) in charge. Queens College of the City University of New York. Photochemistry. Two days, Saturday and Sunday, Sept. 10-11; Howard E. Zimmerman (University of Wisconsin) in charge. Fordham University. Profitable Use of Chemical Information. Two days, Friday and Saturday, Sept. 16-17; Kenneth H. Zabriskie, Jr. (Chemical Abstracts Service) in charge. Long Island University (Brooklyn campus ). Thin-Layer Chromatography. One and one half days; James M. Bobbitt (University of Connecticut) in charge. St. John's University (Queens campus). First session: Friday and Saturday, Sept. 9-10; second session: Monday and Tuesday, Sept. 12-13; third session: Thursday and Friday, Sept. 15-16. For further details and registration coupons, see C&EN, May 30, page 58. For further information about the courses and about housing near the course sites, write to the Education Secretary, American Chemical Society, 1155 16th St., N.W., Washington, D.C. 20036.

Chemical Marketing and Economics. Newman H. Giragosian, General Aniline and Film Corp., 140 W. 51st St., New York, N.Y. 10019 Colloid and Surface Chemistry. Tomlinson Fort, Jr., Chem. Engr. Science Group, Case Inst, of Tech., Univ. Circle, Cleveland, Ohio 44106 Fertilizer and Soil Chemistry. Dr., Trail, B.C., Canada

F. J. L. Miller, 58 Hazlewood

Fluorine Chemistry. Charles B. Colburn, Rohm and Haas Co., Redstone Arsenal, Huntsville, Ala. 35807 Fuel Chemistry. Frank Rusinko, Jr., Speer Carbon Co., Inc., Theresia St., St. Marys, Pa. 15857 History of Chemistry. Sister St. John Nepomucene, Dept. of Chem., Trinity Col., Washington, D.C. 20017 Industrial and Engineering Chemistry. Francesco De Maria, American Machine and Foundry, 689 Hope St., Springdale, Conn. 06879 Inorganic Chemistry. Gregory R. Choppin, Dept. of Chem., Florida State Univ., Tallahassee, Fla. 32306 Medicinal Chemistry. Barry M. Bloom, Chas. Pfizer & Co., Inc., Groton, Conn. 06340

Employment clearing house

Microbial Chemistry and Technology. Peter Hosier, Res. and Dev. Div., Sun Oil Co., Marcus Hook, Pa. 19061

The Employment Clearing House will be located on the Ballroom Floor of the Statler Hilton, Seventh Ave., 32nd to 33rd Streets. It will be open to candidates for employment on Sunday, Sept. 11, at 3 P.M. and to employers on Monday, Sept. 12, at 8 A.M. All users must be in attendance and registered for the meeting. Facilities for meeting registration will be available in the Statler Hilton from 3 to 8 P.M. Sunday, Sept. 11; 8 A.M. to 5 P.M. Monday through Thursday, Sept. 12-15. See page 56 for other meeting registration facilities.

Nuclear Chemistry and Technology. Warren R. Grimes, Oak Ridge National Lab., P.O. Box X, Oak Ridge, Tenn. 37830 Organic Chemistry. Norman A. LeBel, Dept. of Chem., Wayne State Univ., Detroit, Mich. 48202 Organic Coatings and Plastics Chemistry. Kenneth N. Edwards, Dunn-Edwards Corp., 4885 E. 52nd PI., Los Angeles, Calif. 90022

The following E C H hours will be observed:

Petroleum Chemistry. Richard S. Crog, Union Oil Co. of Calif., P.O. Box 76, Brea, Calif. 92621

Sunday ( Registration of applicants only )

3 P.M. to 7 P.M.

Physical Chemistry. Joseph J. Katz, Argonne National Lab., Box 200, 9700 S. Cass Ave., Argonne, III. 60440

Monday through Thursday

8 A.M. to 5 P.M.

Friday

8 A.M. to Noon

Polymer Chemistry. William E. Cass, Dept. of Chem., Northeastern Univ., Boston, Mass. 02115 Rubber Chemistry. George N. Vacca, Bell Telephone Labs., Room 1A258, Murray Hill, N.J. 07971 Water, Air, and Waste Chemistry.

Benjamin F. Willey, Elgin

Softener, Inc., 440 S. McLean Blvd., Elgin, III. 60120

The Chemistry Section of the National Science Foundation will be represented in Room 507 of the New York Hilton f r o m 9:00 A . M . to 5:00 P.M. on Monday, Tuesday, and Wednesday, Sept. 12, 13, 14. Members of the Chemistry Section and representatives f r o m the non-research divisions of the Foundation will be available for consultation.

Candidates for employment All candidates for employment are required: ( 1 ) To be members or paid student affiliâtes of the ACS ( 2 ) To be registered and in attendance at the meeting ( 3 ) To consult a special bulletin board twice daily: (Starting Monday, Sept. 12) sometime between 12:30 P.M. and 1:30 P.M. and 4:45 P.M. and 5 P.M. or 8 A.M. and 8:30 A.M. the following morning Candidates desiring to register in advance may secure application blanks by writing to the American Chemical Society, 1155 Sixteenth St., N.W., Washington, D.C. 20036; requests should mention the New York Meeting. Deadline for receipt of advance registration in the Washington office is Sept. 1. Blanks which are completed and returned by this date will be partially processed thus reducing the time required to complete the registration after the meeting opens. It should be noted, however, that no records are placed on file until after the candidate registers for the meeting and reports his arrival at the Clearing AUG. 8, 1966 C&EN

59

House. Blanks will be available for those who did not obtain them in advance. Candidates may also wish to register for the meeting in advance; see details on page 6 1 . Employers All employers' representatives are required: ( 1 ) To be registered and in attendance at the meeting ( 2 ) To register for the meeting before reviewing Clearing House applications ( 3 ) To agree that no placement charges will be made and that registrants will be advised at the time of first contact of geographical location, name of employer, and nature of position Review of applications by employers' representatives and scheduling of interviews start Monday, Sept. 12, at 8 A.M. Trained assistants will be on hand to familiarize new users with the E C H setup. Reproduction of applicants' records will be available. Complete sets may be purchased for $20, single copies for 25 cents each. These records will be sold only during the week of the meeting; checks will not be accepted in advance. Employers who wish to prepare Position Available notices in advance may obtain the standard forms used for them by writing to the American Chemical Society, 1155 Sixteenth St., N.W., Washington, D.C. 20036. Requests should mention "Position Available" forms, one for each job description. Employer representatives are requested not to return the completed forms to the Washington office but submit them to the clerk in the "Position Available" area after their arrival at the Clearing House. Space will be set aside in the applicant's room for posting these notices.

Award addresses ACS Award in Chromatography and Electrophoresis sponsored by Lab-Line Instruments, Inc., received by Kurt A. Kraus. Address to be presented before the ACS Division of Analytical Chemistry, Monday, Sept. 12, at 2:10 P.M.; see page 74. ACS Award in Biological Chemistry sponsored by Eli Lilly and Company received by Phillips W. Robbins. Address to be presented before the ACS Division of Biological Chemistry, Thursday, Sept. 15, at 11 A.M.; see page 8 1 . ACS Award in the Chemistry of Milk sponsored by The Borden Company Foundation, Inc., received by Bruce L. Larson. Address to be presented before the ACS Division of Biological Chemistry, Wednesday, Sept. 14, at 11:15 A.M.; see page 79. ACS Award in Enzyme Chemistry sponsored by Chas. Pfizer & Co., Inc., received by Samuel B. Weiss. Address to be presented before the ACS Division of Biological Chemistry, Tuesday, Sept. 13, at 10:05 A.M.; see page 77. The Garvan Medal received by Mary L. Petermann. Address to be presented before the ACS Division of Biological Chemistry, Thursday, Sept. 15, at 9:10 A.M.; see page 80.

Society bylaw governing registration Bylaw VI, Sect. 4, governs registration at meetings of the Society. The following pertinent rules shall apply to registration at this meeting: ( a ) Attendance at any national, regional, divisional, or other major meeting of the Society shall be limited to registered persons. ( b ) Each person registering at a meeting of the Society shall classify himself as one of the following: ( 1 ) Member of the Society; ( 2 ) nonmember chemist or chemical engineer residing in the United States; ( 3 ) regularly matriculated student majoring in chemistry or chemical engineering at an American college or university; ( 4 ) foreign visitor; ( 5 ) nonchemist visitor. ( c ) Each registrant at a national meeting of the Society shall pay a registration fee to be fixed by the Board of Directors in accordance with the provisions of paragraphs ( e ) and (f) of this section. ( e ) The registration fee at a national, regional, divisional, or other major meeting for a chemist or a chemical engineer residing in the United States, who is not a Member of the American Chemical Society, shall be greater than the fee charged a Member Such a nonmember shall be furnished with a special badge to differentiate him from other registrants. (f) The registration fee at national, regional, divisional, or other major meetings of the Society for all classes of registrants describea in Sec. 4 ( b ) other than those specified in Sec. 4 ( e ) of this Bylaw, shall be the same as for a member of the Society, except that reduced registration fees may be set by the Board of Directors for a national meeting and by the committee in charge for other meetings for students entitled to the discount in dues provided in the Bylaws, nonchemists or nonchemical engineer members of the family of a registrant, persons wanting to attend a single session, or other special cases approved by the Board of Directors for a national meeting or by the committee in charge for any other meeting. ( h ) The President shall have authority to close any session at any meeting of the Society to nonmembers. Notes. Affiliates of local sections and of divisions are not members of the Society and have no Society privileges; if chemists or chemical engineers, their registration fee is $22. Student affiliates are not members of the Society, but are granted certain concessions. They, as well as student members entitled to discount in ACS dues, may be registered at a fee of $2.00, under the provisions of Sec. 4 ( f ) quoted above. Persons registered at a meeting may purchase tickets for a banquet or group meal for use by husbands, wives, or children, without said husbands, wives, or children being registered. All women visitors who participate in any event of the ladies' program or any activity of the meeting program, except as provided above, must register and pay the appropriate registration fee. Minor children may accompany a parent, without being registered, to any program event for which a ticket has been obtained, provided children are admitted and further provided that the parent is registered for the meeting. Tickets distributed without charge for which the sponsor is charged on the basis of attendance will not be supplied to unregistered persons.

Registration fees New York meeting Chemists or chemical engineers residing in the United States who are not members of the ACS $22.00 ACS members

15.00

Foreign chemists or chemical engineers visiting in the United States and others not chemists or chemical engineers 15.00 Abstracts of papers with Keyword Subject Index will be available in the usual paperback edition about August 10. Standing and advance orders will be filled immediately and shipped by the printer. Advance orders can be placed in connection with your advance registration (see page 61). Abstracts will also be on sale in registration areas at New York. Price of the complete book, with author and subject indexes, is $3.00 to division members who include their Division Dues Receipt Card with order, and $4.00 to all others. Price includes postage. Send your order (with payment to the American Chemical Society) to Special Issues Sales, ACS, 1155 16th St., N.W., Washington, D.C. 20036

60 C&EN AUG. 8, 1966

Members of a registrant's family who are not chemists or chemical engineers 5.00 Persons desiring to attend a single technical session

6.00

Noncommissioned persons in the Armed Forces who are members or were either members of the ACS or regularly enrolled undergraduate or graduate students prior to induction or enlistment 5.00 Students not members or affiliates of the ACS

5.00

Mixer attendance only

3.00

Members eligible for student discount and student affiliates of the ACS 2.00

ADVANCE MEETING REGISTRATION Deadline for Receipt-Sept. 2 F/7/ in the registration form and return it with a check or money order for the proper amount to the National Meetings and Divisional Activities Office, American Chemical Society, 1155 Sixteenth St., NW., Washington, D.C. 20036. To determine the appropriate remittance, see following schedule. Check or money order should he made payable to the American Chemical Society.

(g) Noncommissioned persons in the Armed Forces who are members or were either members of the ACS or regularly enrolled undergraduate students prior to induction or enlistment.

REGISTRATION FEE, $15.00

REGISTRATION FEE, $2.00

(f) Members of a registrant's family who are not chemists or chemical engineers.

(a) Members of the American Chemical Society. (b) Foreign chemists and chemical engineers visiting in the United States. (c) Persons below).

not chemists

or

chemical

engineers

(see

(h) Student affiliates of the American Chemical Society with 1966 dues paid ($3.50 initially or $3.00 renewal). (i) Members enrolled for at least 6 credit hours in a college or university. ABSTRACTS OF PAPERS, $4.00

REGISTRATION FEE, $22.00 (d) Chemists or chemical engineers residing in the United States who are not members of the American Chemical Society. Affiliates of divisions and local sections of the Society are not members of the national organization.

Will be mailed to you before the meeting. If you enclose your Division dues receipt card, deduct $1.00 from price quoted. See page 61 for additional details. REFUNDS

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NEW YORK HOTEL/MOTEL RATES Map Key

No. 1 2 3 4 5 6 7 8 9 10 11 12 13 14

Hotel/motel Americana Barbizon-Plaza City Squire Motor Inn Essex House Governor Clinton Holiday Inn—57th St. New Yorker New York Hilton Park-Sheraton Plaza Sheraton-Atlantic Statler Hilton Waldorf-Astoria Warwick

62 C&EN AUG. 8, 1966

Singles

Doubles

Twins

$16.00-23.00 13.50-17.50 16.00-24.00

$18.00-30.00 17.50-25.50

$18.00-30.00 17.50-25.50 19.00-29.00 27.00 16.00 19.00-20.00 16.00-20.00 20.00-29.00 16.50-21.00 26.00-36.00 15.75-21.00 19.00-23.00 20.00-35.00 20.00-24.00

11.00 15.00 14.00-16.00 18.00 10.00-14.00 13.00-17.00 16.00-24.00 18.00-28.00 13.00-16.00 16.50-21.00 20.00-26.00 10.75-16.00 15.75-21.00 10.00-14.00 15.00-19.00 16.00-29.00 20.00-35.00 16.00-20.00 Rates subject to 5% New York City hotel occupancy tax

Two-room suites 40.00-42.00 42.00 36.00 & up 30.00-40.00 46.00 & up 26.00-35.00 55.00 & up 26.00-33.00 40.00-50.00 45.00-85.00 40.00-45.00

™r B | a n k >

2:00-44.

Symposium on Electric Properties of Polymers 2:20—45.

Joint with Division of Polymer Chemistry C. T. O'Konski, Presiding 2:00-32. 2:30-33. 2:50-34.

3:10— 3:20—35. 3:40-36. 3:55-37.

4:20-38. 4:40— 5:30—

C. T. O'Konski. Electric Polarization in Solutions of Proteins, Nucleic Acids, and Poly electrolytes. J. P. McTague, J. H. Gibbs. Static Polarizability of Solutions of Rodlike Poly electrolytes. H. G. Jerrard, B. R. Jennings. Light Scattering by Macromolecular Solutions Subjected to Electric Fields. Discussion. D . A. Seanor. Evidence for Electronic and Ionic Conductivity in Nylon 66. E. Sacher. The Stark Effect of Methyl Red in Polymer Films. A. Peterlin, J. H. Elwell. Influence of Orienta­ tion on Dielectric Properties of Polyvinylidene Fluoride. I. M. Stillman, H. P. Gregor. Polyacene Radical Ion Exchange Polymers. Discussion. Divisional Social Hour (Joint with Division of Organic Coatings and Plastics Chemistry and Di­ vision of Polymer Chemistry ).

SECTION Β

2:40-46.

3:00-47.

3:20—48. 3:40—49. 4:00-50.

4:20—51.

4:40—52.

J. J. O'Neill, E. D . Goddard. Measurement of the Relative Permeabilities of Lipoidal Substances to Water Vapor. A. E. Kaplan. Hydrogen-Bonding Characteristics of N-Palmitoyl-L-serine Relative to Membrane Transport. K. D . Dreher, J. H. Schulman, A. F. Hofmann. The Surface Chemistry of the Bile Salt Monoglyceride Systems. D . J. Wilkins. The Biological Recognition of Foreign from Native Particles as a Problem in Sur­ face Chemistry. Ε. Μ. Scarpelli. Biological Significance of the Surface-Active Lining of the Mammalian Lung. M. Blank. The Surface Viscosity of the SurfaceActive Extract of Lung. J. A. Bergeron, G. L. Gaines, Jr., W. D. Bellamy. Monolayers of Porphyrin Esters: Spectral Dis­ turbances and Molecular Interactions. D . O. Shah, J. H. Schulman. Enzymic Hydrolysis of Phospholipid Monolayers Employing Surface Pressure and Potential Technique. G. H. Takahashi. Oxygen Consumption and Oxy­ gen Diffusion in Corneal Stroma—A Biological Membrane.

FRIDAY MORNING AND AFTERNOON-

Symposium on New Concepts in Emulsion Polymers Joint with Division of Polymer Chemistry (see page 127)

presiding

Sheraton-Atlantic, Colonial Room (3rd Floor) Symposium on the Biophysical Characterization of Interacting Macromolecular Systems

S. N. Timasheff, Presiding THURSDAY MORNINGSECTION A Sheraton-Atlantic, Colonial Room (3rd Floor)

9:00— 9:05—53. 10:00-54.

Symposium on Surface Chemistry of Biological Systems

M. Blank, Presiding 9:009:059:30-39. 10:00-40. 10:30-41.

M. Blank. Opening Remarks. J. H. Schulman. Introduction. G. Colacicco, Μ. Μ. Rapport, D . Shapiro. Lipid Monolayers: Interaction of Synthetic Dihydroceramide Lactosides with Proteins. V. K. Miyamoto, T. E. Thompson. Some Electri­ cal Properties of Lipid Bilayer Membranes. I. R. Miller. Transport of Ions Across Polyampholyte Monolayers Adsorbed at the Polarized Drop­ ping Mercury Electrode.

92 C&EN AUG. 8f 1966

10:3510:50—55. 11:25-56.

S. N. Timasheff. Introductory Remarks. G. A. Gilbert. Moving Boundary Theory for Re­ acting Systems. J. R. Cann, W. B. Goad. Electrophoresis and Sedimentation of Macromolecules Interacting Reversibly with the Solvent Medium. Coffee Break. J. L. Bethune. Countercurrent Distribution and Gel Filtration of Chemically Reacting Systems. G. Kegeles, J. L. Bethune. Density Gradient Sedimentation of Chemically Reacting Systems.

J. R. Cann, Presiding 2:00—57. 2:35—58. 3:10-

D. A. Yphantis. Equilibrium Sedimentation of In­ teracting Systems. P. G. Squire. Computer Methods of Analyzing Sedimentation Equilibrium Data. Coffee Break.

3:20—59.

3:55-60.

4:30—

Ε. Τ. Adams, Jr. Nonideal Effects in Sedimenta­ tion Equilibrium and Osmometry of Chemically Reacting Systems. S. N. Timashefï, H. Inoue. Light Scattering of Macromolecules Interacting with Solvent Components. H. K. Schachman. Summary and Prospects.

11:40— 12:30— 2:30—

Discussion. Divisional Luncheon. Divisional Business Meeting.

WEDNESDAY MORNINGCity Squire, Constitution Hall (5th Floor) Symposium on Granulated Products Technology

Division of Fertilizer and Soil Chemistry

J. D. Romaine, Presiding 9:009:10-17.

A. B. Phillips, Chairman F. J. L. Miller, Secretary MONDAY MORNING AND AFTERNOON. City Squire, Constitution Hall (5th Floor)

9:30-18. 10:00-19. 10:1510:35- 20.

General A. B. Phillips, Presiding 9:309 : 4 5 - 1. 1 0 : 0 5 - 2. 10:251 0 : 4 5 - 3. 1 1 : 0 5 - 4. 11:25-

A. B. Phillips. Introductory Remarks. G. H. Madany, G. Burnet. Inhibition of the Thermal Decomposition of Ammonium Nitrate. V. J. Russo. A New Concept in the Stabilization of Ammonium Nitrate Prills. Discussion. J. C. Gabriel, A. E. Morrison. The Effect of Various Parameters on the Analysis for Low-Level Fluorides in the Plant Food Industry. J. Ando, J. R. Lehr. Ammoniation Reactions of Superphosphate. Discussion.

F. J . L. Miller, 2:002:10-

2 : 3 0 - 6. 2 : 5 5 - 7. 3:153 : 3 5 - 8. 3 : 5 5 - 9.

4:20-10.

4:40-

Presiding

F . J. L. Miller. Introductory Remarks. V. V. Rendig, H. M. Reisenauer, E. A. McComb. Some Interactions of Nitrogen Supply with Other Plant Nutrients. J. G. A. Fiskell, C. D . Leonard. Copper Fertilization Evaluation by Soil and Citrus Root Analyses. J. W. Hamaker, J. G. Shafer. Loss of 6-Chloro-2trichloromethyl Pyridine from Solid Fertilizer. Discussion. J. E. Fletcher, M. V. Movold. Zinc Fertilizer from Spent Zinc Electrolyte. R. W. Pfeiffer, V. J. DiFranco, L. F . Albright. Production of Alkali Metal Nitrates, Especially Potassium Nitrate, Using Fused Salt Solutions. G. B. Cordell. The Reaction Kinetics of the Production of Ammonium Sulfate from Anhydrite. Discussion.

TUESDAY MORNING.

10:55-21.

11:20-22.

11:40-

J. D. Romaine. Introductory Remarks. R. S. Meline, G. C. Hicks, T. M. Kelso, M. M. Norton. Developments in Production of Granular Urea-Ammonium Phosphate Fertilizers. S. M. Kulifay. Problems in the Granulation of 18-46-0. W. P. Moore, R. R. MacGregor. New Applications of Solid Ammonium Polyphosphate. Discussion. J. B. Pierce, J. P. Harvey. Plastic Deformation of Pellets and Its Effect on the Caking of Fertilizers. T. M. Rosenblatt, P. R. Geissler. Simulated Field Storage Tests of Fertilizers in a Controlled Environmental Chamber. J. C. Francis. Bulk Blending of Fertilizer: Computer Program to Demonstrate the Effects of Raw Material Variability, Mixing, and Segregation on Quality. Discussion.

WEDNESDAY AFTERNOON. City Squire, Constitution Hall (5th Floor) General F. T. Nielsson, Presiding 2:00-23. 2:30-24. 2:50-25. 3:103:30- •26.

4:00-27. 4:15-28.

4:30-

W. J. Sackett, Jr., W. J. Sackett, Sr. Design Studies of Dust Emission Control Equipment for Fertilizer Plants. Q. S. Lee. Sulfur. L. W. Ross, H. C. Lewis. Reactions of Sulfur Oxides with Phosphate Rock. Discussion. J. F . Marten. New Continuous-Flow Systems for Automation in Fertilizer Production Control. T. D. Farr, J. D. Fleming, J. D. Hatfield. The System NH 3 -H,P 3 O 10 -iLO at 0° and 25 °C. H. E. Ulmer, W. C. Meluch. The Application of Density Gradient Techniques to the Determination of Fertilizer Solution Densities. Discussion.

THURSDAY MORNINGCity Squire, Constitution Hall (5th Floor)

Americana, Royal Ballroom Β (2nd Floor) Symposium on Phosphoric Acid Technology

Symposium on Fluid Fertilizer Technology

C. E. Waters, Presiding

A. B. Phillips,

9:00— 9:10-11.

9:30-12. 9:50-13. 10:10— 10:30-14.

10:50-15. 11:15—16.

C. E. Waters. Introductory Remarks. A. W. Frazier, J. P. Smith, J. R. Lehr. Precipi­ tated Impurities in Fertilizers Prepared from WetProcess Phosphoric Acid. E. Pelitti. A New Reactor for the Production of Phosphoric Acid by the Wet Process. G. M. Burkert, J. D . Nickerson. Polyphosphoric Acids—Viscosity Versus Impurities. Discussion. H. Y. Allgood, F . E. Lancaster, Jr., J. A. McCollum. Operating Experience with TVA's Stainless Steel Thermal Phosphoric Acid Production Plant. R. L. Gilbert, Jr. Stability of Calcium Sulfate Hydrates in Wet-Process Phosphoric Acid. A. B. Amin, M. A. Larson. Crystallization of Cal­ cium Sulfate from Phosphoric Acid.

9:009:10-29. 9:30-30. 9:55-31. 10:2010:35-32. 10:55-33. 11:15-34. 11:40-

Presiding

A. R. Phillips. Introductory Remarks. F. P. Achorn, H. L. Kimbrough. Making Suspen­ sion Fertilizers. J. Silverberg, G. Hoffmeister, C. P. Harrison, J. Ando. Nitric Phosphate Suspension Fertilizers. W. C. Scott, J. A. Wilbanks, M. R. Burns. Sus­ pension Fertilizers Produced with TVA's 12-40-0. Discussion. L. A. Barry. Slurry Fertilizers Using Triple Su­ perphosphate. J. M. Potts, H. B. Shaffer, Jr., M. R. Siegel. Am­ monium Polyphosphate Fertilizer Solutions. G. L. Crow, J. Silverberg. Corrosion of Mild Steel by Liquid Fertilizers Made from Ortho- and Superphosphoric Acids. Discussion. AUG. 8f 1966 C&EN 93

Division of Fluorine Chemistry Α. Μ. Lovelace, Chairman C. B. Colburn, Secretary-Treasurer MONDAY MORNING AND AFTERNOON

11:10-15.

11:40— 11:45-16.

12:15— 12:20-

W . W. Doll, J. B. Lando. The Effect of Head-toHead Structure on the Polymorphism of Poly( vinylidene fluoride ). Discussion. G. P. Koo, M. N. Riddell, J. L. O'Toole. Fatigue Properties of Polytetrafluoroethylene and Related Fluoropolymers. Discussion. L. A. Wall. Closing Remarks.

Statler Hilton, West Room (Ballroom Floor) Symposium on Fluorine-Containing Polymers Joint with Division of Polymer Chemistry

TUESDAY AFTERNOON. Statler Hilton, West Room (Ballroom Floor)

L. A. Wall, Presiding 9:009:15— 1. 9:55— 10:00— 2. 10:20— 1 0 : 2 5 - 3. 10:55— 1 1 : 0 0 - 4.

11:25— 1 1 : 3 0 - 5. 11:50— 1 1 : 5 5 - 6.

12:20— 2:00— 7. 2:25— 2:30— 8. 2:55— 3:00— 9. 3:55— 4:00-10.

4:25— 4:30—11.

4:55—

L. A. Wall. Introductory Remarks. W. J. Pummer, J. M. Antonucci. Aromatic Fluorocarbon Polymers. Discussion. J. Thrower, M. A. White. Perfluoro-m-polyphenylenes. Discussion. J. Green, N. Mayes, E. Cottrill. Aromatic Polyrluoronitroso Polymers. Discussion. J. Hollander, F. D. Trischler, R. B. Gosnell. The Synthesis of Polyurethanes from Fluorinated Diisocyanates. Discussion. E. G. Howard, P. B. Sargeant, C. G. Krespan. Polymers Prepared from Fluoroketones. Discussion. A. G. Pittman, D . L. Sharp, B. A. Ludwig. Fluoroalkyl Acrylates Derived from Fluoroketones. Effect of Fluoroalkyl Modification on the Critical Surface Tension. Discussion. N. L. Madison. Copolymerization of Perhaloketones with Epoxides. Discussion. D. Sianesi, G. Caporiccio. Polymerization and Copolymerization Studies on Vinyl Fluoride. Discussion. L. A. Wall. Polymerization of Fluoroolefins and Related Monomers. Discussion. D. W. Brown, L. A. Wall. The Radiation-Induced Copolymerization of Tetrafluoroethylene and 3,3,3Trifluoropropene at High Pressure. Discussion. S. Straus, D. W. Brown. The Thermal Decomposi­ tion of Poly-3,3,3-trifluoropiOpene Made at High Pressure. Discussion.

General—Advances in Fluorine Chemistry J. E. Castle, Presiding 2:00-17. 2:20-18.

2:45-19. 3:05-20.

3:25—21. 3:45-22.

4:05-23.

4:25-24.

WEDNESDAY MORNING AND AFTERNOON. Statler Hilton, West Room (Ballroom Floor) General—Advances in Fluorine Chemistry P. Tarrant, Presiding 9:00-25.

9:20-26.

9:40-27. 10:00-28.

TUESDAY MORNING-

10:20-29.

Statler Hilton, West Room (Ballroom Floor) Symposium on Fluorine-Containing Polymers

10:40-30.

Joint with Division of Polymer Chemistry L. A. Wall, Presiding 9:00-12. 9:55— 10:00-13. 10:35— 10-40—14. 11:05—

D. Mclntyre, D. R. Valentine. Solution Properties of Fluorocarbons and Fluorine Containing Polymers. Discussion. T. W. Bates, W. H. Stockmayer. The Conforma­ tional Analysis of Perfluoroalkanes. Discussion. H . Yu. The Unperturbed Dimension Temperature Coefficients of Some Fluorine-Containing Polymers. Discussion.

94 C&EN AUG. 8, 1966

R. B. Gosnell, J. Hollander, F. D. Trischler, E. S. Harrison. Highly Fluorinated Diamines. J. Hollander, R. B. Gosnell, F. D. Trischler, E. S. Harrison. The Synthesis of Fluorinated Diisocyanates. J. Burdon, G. Chivers, M. Stacey, J. C. Tatlow. Fluorinated Furans. G. A. Grindahl, W. X. Bajzer, O. R. Pierce. The Preparation and Coupling of Some a-Haloperfluoromethyl-s-triazines. J. A. Young, R. L. Dressier. Functionally Active Perfluoroalkyl-s-triazines. W. E. Emerson, E. Dorfman. The Metal OxideCatalyzed Trimerization of Perfluoroalkane Nitriles to Tris-2,4,6-( perfluoroalkyl )triazines. G. A. Olah, M. S. Comisarow, C. A. Cupas, E. Namanworth, C. U. Pittman, Jr. Fluorocarbonium Ions and Fluorinated Carbonium Ions. R. Filler, C-S. Wang. Polyfluoroaryl-Substituted Hydrocarbons and Related Chemistry.

11:00-31. 11:20-32.

P. D. Schuman, E. C. Stump, G. Westmoreland, W. S. Durrell. Hypofluorite Addition to Olefins and the Preparation of Some New Fluorocarbon Monomers. P. Tarrant, A. C. Wright. Aluminum ChlorideInitiated Reactions of Polyhalomethanes with Fluoroolefins. W. T. Miller, Jr., M. J. Roura. T h e Alkylation of Perfluoroolefins with Perhalocarbanions. L. J. Kehoe, D. J. Burton. The C o p p e r ( I ) Chloride-Ethanolamine-Catalyzed Addition of Polyfluorinated Alkanes to Olefins. R. T. Bogan, D. J. Burton. Stereoselectivity in Nucleophilic Displacement Reactions of Polyfluorinated Olefins with Complex Metal Hydrides. A. Streitwieser, Jr., D . Holtz. T h e Tritium Ex­ change of lH-undecafluorobicyclo[2.2.1]heptane with Methanol-^ and Sodium Methoxide. W. P. Norris, W. G. Finnegan. Oxidative Coupling of 3,3,3-Trifluoropropyne. H. Goldwhite, D. G. Rowsell, J. E. Bissey. Reac­ tions of 2,3-DichlorotetrafluoiOpropene with Nucleophiles Containing Phosphorus.

C. B. Colburn, 2:00-33. 2:20-34.

Presiding

M. Lustig, J. K. Rufï, C. B. Colburn. Diphosphorus Tetrafluoride and Diphosphorus Oxytetrafluoride. J. P. Guertin, K. O. Christe, A. E. Pavlath. Preparation of NF 4 + AsF e ".

2:40—35. 3:00-36. 3:20-37. 3:40-38. 4:00—39. 4:20— 5:30—

Α. Β. Ray. Reaction of Boron Trifluoride with Dinitrogen Tetroxide. R. E. Noftle, G. H. Cady. Preparation and Prop­ erties of Some N e w Trifluoromethanesulfonates. K. E. Pullen, G. H. Cady. The Reaction of Xenon Hexafluoride with Stannic Fluoride. J. W. Nebgen, F. I. Metz, W. B. Rose. The 1!,F Nuclear Magnetic Resonance of Oxygen Fluorides. S. Cantor. Predicting Density, Specific Heat, and Thermal Conductivity of Fluoride Melts. Divisional Business Meeting. Divisional Social Hour.

2 : 4 0 - 8.

3:00— 3:10— 9.

3:35— 3:45—10. 4:15— 4:25—11. 4:50—

A. R. Khan, H. L. Feldkirchner. Production of High Methane Content Gas by Steam Reforming of Light Distillates. Discussion. A. M. Squires. A Reaction which Permits the Cyclic Use of Calcined Dolomite to Desulfurize Fuels Undergoing Gasification. Discussion. H. R. Linden. Present Status of Processes for Gasification of Petroleum. Discussion. S. Prahacs. Pyrolytic Gasification of Na, Ca, and M g Base Spent Pulping Liquors. Discussion.

THURSDAY MORNING AND AFTERNOON Symposium on Uses of Fluorine and Fluorides in Nuclear Technology Joint with Division of Nuclear Chemistry and Technology (see pages 108 and 109)

TUESDAY MORNING AND AFTERNOON. Warwick, Warwick Room (Mezzanine) Symposium on Gasification F. C. Shora, Jr., Presiding R. A. Glenn, E. E. Donath, R. J. Grace. Gasifica­ tion of Coal Under Conditions Simulating Stage 2 of the BCR Two-Stage Super-Pressure Process. Discussion. 9:209 : 3 0 - 1 3 . S. J. Gasior, A. J. Forney, J. H. Field. Decaking of Coal in Free Fall. Discussion. 9:459 : 5 5 - 1 4 . V. J. Kavlick, B. S. Lee. Coal Pretreatment in Fluidized Bed. Discussion. 10:101 0 : 2 0 - 1 5 . D. M. Mason, F . C. Schora, Jr. Coal and Char Transformation in Hydrogasification. Discussion. 10:351 0 : 4 5 - 1 6 . J. A. Lacey. The Gasification of Coal in a Pressure Slagging Gasifier. Discussion. 11:051 1 : 1 5 - 1 7 . C. Y. Wen, O. C. Abraham, A. T. Talwalkar. A Kinetic Study of the Reaction of Coal-Char with Hydrogen-Steam Mixture. Discussion. 11:402 : 0 0 - 1 8 . P. S. Lewis, S. Friedman, R. W. Hiteshue. HighB.t.u. Gas by the Direct Conversion of Coal. Discussion. 2:302 : 4 0 - 1 9 . P. A. Lefrancois, Κ. Μ. Barclay, G. T. Skaperdas. Bench-Scale Studies of the Kellogg Coal Gasifica­ tion Process. Discussion. 3:003 : 1 0 - 2 0 . B. S. Lee, E. J. Pyrcioch, F. C. Schora, Jr. Hydrogasification of Pretreated Coal for Pipeline Gas Production. Discussion. 3:253 : 3 5 - 2 1 . A. J. Forney, R. F. Kenny, S. J. Gasior, J. H. Field. Fluid-Bed Gasification of Pretreated PittsburghSeam Coals. Discussion. 3:554 : 0 5 - 2 2 . D. G. Tajbl, H. L. Feldkirchner, A. L. Lee. Cleanup Methanation for Hydrogasification Process. Discussion. 4:259:00-12.

Division of Fuel Chemistry J. D. Clendenin, Chairman Frank Rusinko, Jr., Secretary-Treasurer MONDAY MORNING. Warwick, Warwick Room (Mezzanine) Symposium on Current Analytical Methods for Fuels E. A. Zawadzki, Presiding E. A. Zawadzki. Introductory Remarks. 9:009:10- 1. R. A. Friedel, J. A. Queiser. Inorganic and Organic Analysis by Infrared Spectrometry in Coal Problems. Discussion. 9:309 : 3 5 - 2. J. Thomas, Jr., G. S. Benson, G. M. Hieftje. Meas­ urement of the Surface Area of Coals from the Dynamic Sorption of Carbon Dioxide. Discussion. 9:5510:00- 3. M. L. Kaufman, S. Friedman, I. Wender. Gas Chromatographic Separations of Benzenecarboxylic Acids Derived from Coal. 10:20Discussion. 10:25- 4. P. A. Estep, E. E. Childers, J. J. Kovach, C. Karr, Jr. Quantitative Ultraviolet Analysis of C10-C15 Naphthalenes in Hydrocarbon Oils. 10:45Discussion. 10:50- 5. M. Berman, S. Ergun. Analysis of Sulfur in Coals by X-ray Fluorescence. 11:10Discussion. 11:15- 6. A. Attari. A Micromethod for Total Sulfur D e ­ termination in Nonleaded Light Hydrocarbon Feed­ stocks. 11:35— Discussion.

WEDNESDAY MORNING AND AFTERNOON Warwick, Warwick Room (Mezzanine) Symposium on Combustion Reactions of Fossil Fuels

MONDAY AFTERNOON. Warwick, Warwick Room (Mezzanine)

J. Grumer, Presiding 9-00— 9:10—23.

Symposium on Gasification F. C. Shora, Jr., Presiding 2:00— 2 : 1 0 - 7. 2:30—

F. C. Schora, Jr. Introductory Remarks. P. L. Cottingham, H. C. Carpenter. Gasification of Shale Oil. Discussion.

Catalytic

9:30— 9:40-24. 10:00—

J. Grumer. Introductory Remarks. J. Feinman, D. A. Muskat. Partial Combustion of Fuel Oil with Oxygen and Application to Smelting Iron Ore. Discussion. H. C. Hottel, G. C. Williams, P. C. Wu. T h e Reaction of Coke with Carbon Dioxide. Discussion. AUG. 8, 1966 C&EN 95

10:10-25.

10:3010:40-26. 11:00— 11:1512:30-

2:00-27. 2:202:30-28.

2:503:00-29. 3:20-

J. M. Singer, Ν. Ε. Hanna, R. W. Van Dolah, J. Grumer. Reduction of Incendivity of Hot Gases to Methane and Coal Dust. Discussion. S. A. Weil, W. R. Staats, R. B. Rosenberg. An Analysis of Porous-Plate Combustion Systems. Discussion. Divisional Business Meeting. Divisional Luncheon. Presentation of the Henry H. Storch Award to R. A. Friedel, U.S. Bureau of Mines, Pittsburgh, Pa. R. B. Rosenberg, D. S. Hacker. Formation of Nitrogen Oxides in Aerated Methane Flames. Discussion. J. M. Singer, E. B. Cook, J. Grumer. Flame Char­ acteristics Causing Air Pollution. I. Emission of Oxides of Nitrogen and Carbon Monoxide. Discussion. J. A. Chisholm, Jr., D. L. Klass. Trace Organic Compounds in Natural Gas Combustion. Discussion.

SECTION Β Alfred Werner Centennial Symposium Joint with Division of Inorganic Chemistry (see page 99) TUESDAY AFTERNOON SECTION A Statler Hilton, Cornell and Pennsylvania Rooms (Ballroom Floor) General Ο. Τ. Benfey, Presiding 2:002 : 0 5 - 6. 2 : 2 5 - 7. 2 : 4 5 - 8.

General

3 : 0 5 - 9. 3:30-

Ε. Κ. Diehl, Presiding 3:30-30.

3:453:55-31.

4:15-

R. A. Friedel, J. L. Shultz, A. G. Chemical Composition of Progressive tracts from Coal. Discussion. P. R. Tisot. Alterations in Structure Properties of Green River Oil Shale Treatment. Discussion.

Ο. Τ. Benfey. Introductory Remarks. N. D . Heindel, L. L. Houchins. Thomas C o o p e r Early American Chemist and Educator. Η. Η. Blau. Glass in Pennsylvania and Alexander Silverman. J. C. Cox, Jr. History of Chemical Progress in the State of Oklahoma. A. Sementsov. Optical Asymmetry and Vitalism. Divisional Business Meeting.

Sharkey, Jr. Pyridine Ex­

SECTION Β Alfred Werner Centennial Symposium

and Physical by Thermal

Joint with Division of Inorganic Chemistry (see page 100)

WEDNESDAY MORNINGSECTION A Statler Hilton, Cornell and Pennsylvania Rooms (Ballroom Floor)

Division of The History of Chemistry Ο. Τ. Benfey,

Chairman

General Ο. Τ. Benfey, Presiding 9:30— 9:40—10.

Sister St. John Nepomucene, Secretary-Treasurer

10:05-11. 10:30— 10:40-12.

MONDAY AFTERNOONAlfred Werner Centennial Symposium

11:00—13.

Joint with Division of Inorganic Chemistry (see page 99) 11:30—14. 12:30— TUESDAY MORNING.

2:00— SECTION A

Ο. Τ. Benfey. Introductory Remarks. A. Sementsov. T h e Historical Development of the Systematic Nomenclature in Inorganic Chemistry. J. S. Berber. P h e n o l - Α Historical Survey. Intermission. W. D. Collins, W. S. Clabaugh, E. Wichers. Be­ ginnings of Reagent Chemical Manufacture in the United States. Sister St. John Nepomucene. Following Ethan Allen Hitchcock's Alchemical Journey. S. G. Machelson. Soviet Scientific Holdings in the Library of Congress. Dexter Award Luncheon. Presentation of Award to E. R. Caley, Ohio State University, Columbus. E. R. Caley. Dexter Award Address, Chemistry in the Service of Archaeology.

Statler Hilton, Cornell and Pennsylvania Rooms SECTION Β

(Ballroom Floor) General

Alfred Werner Centennial Symposium

Ο. Τ. Benfey, Presiding

Joint with Division of Inorganic Chemistry (see page 100)

9:30— 9:35— 1. 1 0 : 0 5 - 2. 10:25— 10:35— 3. 11:05— 4. 1 1 : 4 0 - 5.

Ο. Τ. Benfey. Introductory Remarks. J. J. Bulloff. Electronic-Nuclear Change of AtomicMolecular Ideas. IV. The Nuclide Revolution. H. Slaughter, C. Slaughter. A Selected History of Nuclear Structure. Intermission. G. Siemiencow. Dalton—The Father of Modern Chemistry. Η. Μ. Leicester. Boyle, Lomonosov, Lavoisier, and the Corpuscular Theory. P. E. Cholet, W. Q. Hull, J. R. L. Martin. Gustave Le Bon ( 1841-1931 ) - T h e Forgotten Precursor of the Atomic Age.

96 C&EN AUG. 8, 1966

WEDNESDAY AFTERNOON Alfred Werner Centennial Symposium Joint with Division of Inorganic Chemistry (see page 101)

THURSDAY MORNING AND AFTERNOON. Alfred Werner Centennial Symposium Joint with Division of Inorganic Chemistry (see pages 101-2)

2:05-14.

FRIDAY MORNING AND AFTERNOON Alfred Werner Centennial Symposium Joint with Division of Inorganic Chemistry (see page 103)

2:30-15.

2:55-16.

Division of Industrial and Engineering Chemistry R. B. Beckman, Chairman

3:203:35—17.

4:00-18.

F. de Maria, Secretary

4:20—19.

MONDAY MORNING. SECTION A

R. R. Stewart, D . F. Bruley. Thermal Dynamics of a Distributed Parameter Nonadiabatic Humidifica­ tion Process. F. A. Fine, S. G. Bankoff. Control Vector Iteration in Chemical Plant Optimization: T h e Accessory Minimization Problem of Jacobi. G. W. Minard, R. H. Larson. The Use of Com­ puters in the Analysis of Experimental Frequency Response Data. Break. G. A. Coulman. A Computer-Oriented Approxi­ mate Analytic Solution to a Partial Differential Equation. S. W. Sinderson, Jr., J. W. Tierney. The Response of a Tubular Heat Exchanger to Large Step Changes in Spatially Uniform Secondary Condi­ tions. K. I. Mummè. Analog Computer Control of a Dynamic Copolymerization Process.

Plaza, Grand Ballroom (1st Floor) SECTION Β Symposium on Chemical Process Dynamics and Control Plaza, Crystal Room (1st Floor) L. B. Koppel, Presiding L. B. Koppel. Introductory Remarks. K. A. Bishop, C. M. Sliepcevich. A Generalized Pulse Testing Technique for Linear System Identi­ fication. 2. M. C. Millman, S. Katz. Linear Temperature Con­ trol in Batch Reactors. 3. C. L. Smith, P. W. Murrill. Matrix Differential Equations for Process Dynamics. 4. W. F . Stevens, L. A. Wanninger. Dynamic Opti­ mization of the Williams Reactor. 5. T. W. Cadman, R. R. Rothfus, R. I. Kermode. The Design and the Effectiveness of Feedforward Control Systems for Multicomponent Distillation. 6. B. F. Rothenberger, L. Lapidus. The Control of Nonlinear Systems. IV. Quasilinearization with Constraints. 7. R. H. Luecke, M. L. McGuire. Stability Analysis by Liapunov's Direct Method.

9:009 : 0 5 - 1.

9:309:5510:2010:45-

11:10-

11:35-

Selected Papers J. B. Farrell, Presiding 2:002:05-20. 2:30-21.

2:55-22.

3:25-23.

J. B. Farrell. Introductory Remarks. D. E. Garrett. The Chemistry and Origin of Potash Deposits. L. H. Shaffer. An Investigation of the Solubility of Calcium Sulfate in Sea Water and Sea Water Concentrates at Temperatures from Ambient to 65° C. P a r t i . Gypsum. L. A. Bromley, V. A. deSaussure, J. C. Clipp, J. S. Wright. Heat Capacities of Sea Water Solutions at Salinities of 1 to 1 2 % and Temperatures of 2° to 80° C. H. G. Schwartzberg, R. E. Treybal. Fluid Motion in Turbulent Stirred Tanks.

TUESDAY MORNINGSECTION Β

SECTION A

Plaza, Crystal Room (1st Floor)

Plaza, Baroque Room (1st Floor)

Symposium on Simultaneous Heat and Mass Transfer

Symposium on Homogeneous Catalysis—Industrial Applications and Implications

J. H. Olson, Presiding 8:559 : 0 0 - 8.

9 : 3 0 - 9. 10:00-10. 10:30-11.

11:00-12. 11:30-13.

J. H. Olson. Introductory Remarks. J. Braun, C. F. Bonilla. Mass Transfer by Natural Convection Evaporation from a Horizontal Cylinder with Heat Input. J. F. Gajda, P. G. Dunham, K. Fujimura, J. R. Ferron. Measurement of Diflusivities at High Temperatures and Pressures. T. R. Keane. Rate of Growth of Fog Droplets. R. N. Foster, J. B. Butt. Some Surface Transport Effects on Activity in Diffusionally Limited Cata­ lytic Systems. L. V. Majoch, J. H. Olson. Fog Formation in Partial Condensers. D. White, J. J. Carberry. Radial Variations of Heat- and Mass-Transfer Processes in Packed Beds.

B. J. Luberoff, Presiding 9-00— 9:15—24. 10:15—25.

11:05— 11:10—26.

B. J. Luberoff. Introduction. J. Halpern. Homogeneous Catalysis by Coordina­ tion Compounds. G. C. Bond. Comparison of the Phenomena of Homogeneous and Heterogeneous Catalysis by Noble Metals. Discussion. A. W . Gessner. Mass- and Heat-Transfer Effects in Homogeneous Liquid-Phase Reactions.

SECTION Β Plaza, Grand Ballroom (1st Floor) Symposium on the Effectiveness of Process Research and Development

MONDAY AFTERNOON-

L. Friend, Presiding SECTION A Plaza, Grand Ballroom (1st Floor)

9:009:05-27.

Symposium on Chemical Process Dynamics and Control 9:30-28. 10:00-29.

D. R. Coughanowr, Presiding 2:00—

D . R. Coughanowr.

Introductory Remarks.

L. Friend. Introductory Remarks. R. W. Peterson. The Entrepreneurial Approach to Improving the Effectiveness of Research and D e ­ velopment. T. M. Patrick. Roadmap to Profits-the Cost Sheet. C. G. Kirkbride, G. E. Hamilton. Economic Con­ siderations in Effective Process R&D. AUG. 8, 1966 C&EN 97

10:45—30. 11:15—31.

SECTION Β

R. I. Bergman. Effective Catalytic Process Devel­ opment in a Small Company. C. Ε. Barnes. The Innovation Process.

Plaza, Terrace Room (Terrace Level) Symposium on Purchase and Exchange of Technical Know-How Joint with Division of Chemical Marketing and Economics

TUESDAY AFTERNOON.

Β. Μ. Filbert, Presiding SECTION A Plaza, Baroque Room (1st Floor)

Symposium on Homogeneous Catalysis—Industrial Applications and Implications

W. W. Kaeding, Presiding 2:00-32.

2:45-33. 3:203:30-34.

4:004:00-

9:009:15-41.

9:45-42. 10:15-43.

J. Kwiatek, J. K. Seyler. Factors Involved in Catalytic Hydrogénation and Hydrogenolysis by Pentacyanocobaltate Anion. K. A. Taylor. d s Complexes and Their Use as Hydrogénation Catalysts. Discussion. E. N. Frankel, T. L. Mounts, R. O. Butterfield, H. J. Dutton. Mechanism of Homogeneous Hydrogénation of Unsaturated Fatty Esters by Fe ( CO ).-, and Diene-Fe ( CO ) 8. Panel of Previous Speakers. Divisional Tour, Social Hour, and Dinner. See pages 66-68 for details.

10:45—44. 11:15-45. 11:45_46. 12:15—47.

Β. Μ. Filbert. Introductory Remarks. P. W. McGann. Public Policy Issues of Exchange in Technical Know-How on Foreign Trade in Chemicals. E. Brandt. Tariffs and Dumping of Chemical Products. E. K. Stilbert, R. E. Peterson. Licensing-Hazard or Bonanza. P. H. Avon. Transmission of Technical Informa­ tion in the Licensing Framework. T. H. Arnold, Jr., P. J. Whelan. The Nature of Trade Secrets. Η. Β. Roberts. Procedures for Processing Outside Inventions. Κ. Ε. Lunde. Surveillance of Literature. Symposium Luncheon—The United Nations Role in the Chemical Industries of Developing Countries.

WEDNESDAY AFTERNOON. Plaza, Baroque Room (1st Floor) SECTION Β Plaza, Grand Ballroom (1st Floor) Symposium on the Effectiveness of Process Research and Development

S. C. Schuman, Presiding 2:30—35. 3:00—

4:00—

Symposium on Homogeneous Catalysis—Industrial Applications and Implications

R. P. Anderson, Presiding 2 : 00—48. 2:40-49.

I. Pasquon. History of the Development of the Stereospecific Polymerization Process. Panel Discussion: Messrs. Peterson, Patrick, Kirkbride, Hamilton, Bergman, Barnes, Pasquon, and Vladimir Haensel, Universal Oil Products Co., Des Plaines, 111., and P. C. Keith, consultant, Peapack, N.J., and Heinz Heinemann, M. W. Kellogg Co., New Market, N.J. Divisional Tour, Social Hour, and Dinner. See pages 66-68 for details.

3:10—50. 3:40— 3 : 45—51. 4:15-52. 4:40—

Ν. Μ. Bikales. Polymerization by Homogeneous Catalysis. M. Tsutsui, T. Koyano, M. N. Levy. Catalysis at the Atomic Level: Dimerization and Polymeriza­ tion of Ethylene with ττ-Complexes. B. Bogdanovic. π-Allylnickel Compounds as Ho­ mogeneous Catalysts. Discussion. D . H . Busch. Application of The Coordination Template Effect to the Synthesis of Macrocyclic Complexes. N. B. Egen, R. A. Krause. Polysulfide Chelates. A New Ligand Reaction. Panel Discussion.

WEDNESDAY MORNINGSECTION A

Division of Inorganic Chemistry

Plaza, Baroque Room (1st Floor) Symposium on Homogeneous Catalysis—Industrial Applications and Implications

W. M. Manning, Chairman

B. Seligman, Presiding

G. R. Choppin, Secretary-Treasurer

9:00— 9:10—36. 9:50-37. 10:30-38. 11:00— 11:05-39. 11:25—40. 11:40—

B. Seligman. Introductory Remarks. G. Szonyi. Recent Homogeneously Catalyzed Com­ mercial Processes. P. M. Henry. Oxidation of Olefins by P d ( I I ) and Tl(III) R. G. Schultz, D. E. Gross. The Vinylation of Acetic Acid by Higher Olefins. Discussion. L. Friend, L. Wender, J. C. Yarze. Liquid-Phase Oxychlorination Provides High Selectivity Route to Vinyl Chloride. B. Brodwin, H. C. Templeton. Corrosion Problems in Processes Utilizing Homogeneous Catalysis. Panel Discussion.

98 C&EN AUG. 8, 1966

MONDAY MORNING. Statler Hilton, Penn Top South (18th Floor) Opening Lectures

W. M. Manning, Presiding 9:00— 9:10—

1.

10:10—

2.

W. M. Manning. Introductory Remarks. J. C. Bailar, Jr. Developments in Some Phases of Coordination Chemistry Since the Time of Werner. K. W. Bagnall. Recent Advances in Actinide and Lanthanide Chemistry.

MONDAY AFTERNOON

TUESDAY MORNING, SECTION A

SECTION A

Statler Hilton, Penn Top South (18th Floor)

Statler Hilton, Penn Top South (18th Floor)

Symposium on the Chemistry of the Lanthanide and Actinide Elements

Symposium on the Chemistry of the Lanthanide and Actinide Elements

Joint with Division of Nuclear Chemistry and Technology

Joint with Division of Nuclear Chemistry and Technology

T. Moeller, Presiding

P. R. Fields, Presiding

2:00— 2:05—

3.

2:30—

4.

2:55-

5.

3:20-

6.

3:45-

7.

4:10-

8.

T. Moeller. Introductory Remarks. E. F. Westrum, Jr. Developments in Chemical Thermodynamics of the Lanthanides. P. "N. Yocum. Preparation and Identification of Divalent Lanthanide Ions as Dilute Solutes in Alkaline Earth Halide Solid Solutions. J. D. Corbett, R. A. Sallach, D. A. Lokken. Physical Characterization of the Metallic Lal 2 and CeL. and the Phase Lal2.42. L. Eyring. Fluorite-Related Oxide Phases of the Rare Earth and Actinide Elements. W. T. Carnall, P. R. Fields. Recent Develop­ ments in the Theoretical Interpretation of Lan­ thanide and Actinide Absorption Spectra in Solu­ tion. D. M. Gruen, C. W. DeKock. Absorption Spectra of Gaseous Lanthanide Trihalide Molecules.

9:009 : 0 5 - 24. 9 : 3 0 - 25.

9 : 5 0 - 26. 1 0 : 1 0 - 27. 1 0 : 4 0 - 28.

1 1 : 0 5 - 29. 1 1 : 3 0 - 30.

P. R. Fields. Introductory Remarks. M. Fred. Electronic Structure of the Actinide Elements. N. Edelstein, W. Easley, R. McLaughlin. Op­ tical and Electron Paramagnetic Resonance Spec­ troscopy of Actinide Ions in Single Crystals. H. R. Hoekstra, R. H. Marshall. On Some Ura­ nium-Transition Metal Double Oxides. C. Keller. The Solid-State Chemistry of Americium Oxides. R. A. Penneman, L. B. Asprey, T. K. Keenan. Tetra- and Pentavalent Actinide Fluoride Com­ plexes, Protoactinium to Curium. C. E. Thalmayer, D. Cohen. Actinide Chemistry in Saturated Potassium Fluoride Solution. T. W. Newton, F. B. Baker. A Review of the Kinetics of the Aqueous Oxidation-Reduction Re­ actions of Uranium, Neptunium, Plutonium, and Americium.

SECTION Β Statler Hilton, Sky Top (18th Floor)

SECTION Β

Alfred Werner Centennial Symposium Statler Hilton, Sky Top (18th Floor) Joint with Division of The History of Chemistry Alfred Werner Centennial Symposium G. B. Kauffman, Presiding Joint with Division of The History of Chemistry 2:00— 2 : 1 0 - 9. 2 : 3 0 - 10. 3:05— 11. 3 : 4 0 - 12. 4 : 1 5 - 13. 4 : 3 5 - 14.

G. B. Kauffman. Introductory Remarks. S. Soloveichik, H. Krakauer. Alfred Werner. P. S. Cohen. T h e Effect of Fixity of Ideas on the Werner-j0rgensen Controversy. G. B. Kauffman. Some Lesser Known Aspects of the Work and Thought of Alfred Werner. F. R. Morral. Alfred Werner and Cobalt Com­ plexes. A. W. Chester. Polynuclear Cobalt ( H I ) Ammine Complexes. D. H. Wilcox, Jr. Werner and Dyes.

SECTION C Statler Hilton, Penn Top North (18th Floor)

G. B. Kauffman, Presiding 9:00— G. B. Kauffman. Introductory Remarks. 9:05— 3 1 . E. Farber. Industrial Chemistry and Werner's Theories. 9:35— 32. W. C. Fernelius. The Nomenclature of Coordi­ nation Compounds: Pre-Werner to the 1966 IUPAC Report. 10:20— 33. T. Moeller. Coordination Chemistry of the Lanthanide Elements—100 Years of Development and Understanding. 10:55— 34. R. W. Parry. Werner Coordination Theory of the Main Group Elements. 1 1 : 3 0 - 35. W. W. Fogleman, H. N. Ramaswamy, A. TulsiRam, H. B. Jonassen, A. M. Aguiar. Diphosphine Complexes of Nickel and Cobalt.

General

L. Netherton, Presiding 2:00— 15. R. D . Hill. Phenolphthalein as an Acid-Base Indicator in Liquid Ammonia. 2 : 2 0 - 16. J. B. Smart, Μ. Τ. Emerson, J. P. Oliver. Lith­ ium— 7Γ Interactions in But-3-enyllithium. 2:40— 17. A. Lauder, E. C. Bossert, J. J. Lagowski. Fluoroalkylmercurials as Synthetic Intermediates. 3 : 0 0 - 18. H. C. Clark, A. L. Pickard. The Preparation and Properties of Dimethylindium(III) Derivatives. 3 : 2 0 - 19. P. H. Wilks, J. C. Carter. Alkali Metal Salts of Decaboranate ( 12,2- ). 3:40— 20. H. N. S. Lee, A. Wold. Vapor-Phase Reaction Between Anhydrous Aluminum Fluoride and Boron Oxide. 3 : 5 5 - 2 1 . W. L. Jolly, T. Schmitt. Evidence for the Species B H / and B H ( O H ) 2 in Aqueous Solutions. 4 : 2 0 - 22. K. Niedenzu, J. W. Dawson, W. Weber. The Vibrational Spectrum of Borazine. 4 : 4 0 - 23. R. Maruca, O. T. Beachley, Jr., A. W. Laubengayer. Preparation and Some Reactions of Unsymmetrically Substituted Borazines.

SECTION C Statler Hilton, Penn Top North (18th Floor) General

P. L. Timms, Presiding 9:00—36. 9 : 2 0 - 37.

9 : 4 0 - 38. 1 0 : 0 0 - 39.

1 0 : 2 0 - 40.

P. L. Timms. Synthetic Reactions of Boron Monofluoride. J. L. Crist, S. G. Shore, C. W. Schultz. A Study of the Properties and Reactions of Five-Membered Boron-Oxygen and Boron-Sulfur Heterocyclic Ring Systems. K. A. Reynard, L. F. Hohnstedt. A Simple, HighYield Synthesis of Pure Chlorodiorganoboranes. K. J. Wynne, W. L. Jolly. Adducts of Sulfur Nitride with Boron Trihalides and Antimony Pentachloride. H. D . Smith, Jr., L. F. Hohnstedt. The Synthesis and Reactions of l,2-(2-Substituted-l,3,2-dithiabora ) -o-Carboranes. AUG. 8, 1966 C&EN 99

10:40- 41.

1 1 : 0 0 - 42.

1 1 : 2 0 - 43.

1 1 : 4 0 - 44.

A. G. MacDiarmid, Y. L. Baay, S. Κ. Gondal, A. P. Hagen. Synthesis, Properties, and Structure of Silicon Cobalt Tetracarbonyls. W. E. Weibrecht, R. E. Goldsberry. Metal Alkoxide-Induced Cleavage of Silicon-Nitrogen Bonds in Unsymmetrically Alkoxylated Disilazanes. K. W. Morse, J. W. Gilje, R. W. Parry. The Be­ havior of Phosphine Boranes as Bnmsted-Lowry Acids. R. W. Rudolph, R. C. Taylor, R. W. Parry. Fluorophosphine Ligands. III. Syntheses Involving PFJ.

SECTION C Statler Hilton, Penn Top North (18th Floor) General

J. Κ lei η berg, Presiding 2 : 0 0 - 59.

2 : 2 0 - 60.

2 : 4 0 - 61. 3 : 0 0 - 62.

TUESDAY AFTERNOON.

3 : 2 0 - 63.

SECTION A Statler Hilton, Penn Top South (18th Floor) Symposium on the Chemistry of the Lanthanide and Actinide Elements

3 : 4 0 - 64. 4:006:007:00-

J. A. Bedford, S. E. Frazier, M. E. Kenny, J. Hower. Sheetlike Organosilicon Polymers Derived from the Minerals Chrysotile and Apophyllite. R. H. Baney, J. Lipowitz. The Mechanism of the Amine Salt-Catalyzed Silanol Condensation Re­ actions. W. H. Nelson. Dihalobis(2,4-pentanediono)tin( IV) Complexes: Structure and Bonding. K. Moedritzer, J. R. Van Wazer. Equilibria in Three-Dimensional Polymethylsiloxanes. J. A. Morrison, M. A. Ring. An Examination of Alkali Metal Salt Cleavage Reactions of Disilane. R. R. Holmes, R. N. Storey. Molecular Structure and Properties of PfTF.*. Divisional Business Meeting. Divisional Social Hour. Divisional Dinner.

Joint with Division of Nuclear Chemistry and Technology

P. R. Fields, Presiding 2:00— 45. 2 : 2 0 - 46.

2 : 4 0 - 47.

3 : 0 0 - 48. 3:20— 49. 3 : 4 0 - 50.

4 : 0 0 - 51.

4 : 2 5 - 52.

4 : 4 5 - 53.

6:00— 7:00—

WEDNESDAY MORNING-

R. Thompson, J. C. Sullivan. Redox Reactions of Neptunium ( V ). C. Musikas. A Contribution to the Study of the Oxidation Potential of the Berkelium( III )-( IV) Couple in Various Media. L. E. Trevorrow, M. J. Steindler, D. V. Steidl, J. T. Savage. Condensed Phase Equilibria in the System MoF e -UF c . H. R. Hoekstra. Uranyl Metaborate. J. L. Ryan. Octahedral Hexahalide Complexes of the Tri valent Actinides. J. L. Ryan, W. E. Keder. Anionic Acetato Com­ plexes of the Hexavalent Actinides and the Anion Exchange and Amine Extraction of Hexavalent Actinide Acetates. F. K. Fong, M. A. Hiller, F. G. Krajenbrink. Ion Complexing and Valence Change in Rare-EarthDoped CaF 2 . L. B. Asprey, J. S. Coleman, M. J. Reisenfeld. Preparation and Properties of Some Tetravalent Praseodymium Compounds. E. J. Wheelwright, F. P. Roberts, U. L. Upson, L. J. Kirby. Ion Exchange Separation of Kilocurie Quantities of High-Purity Promethium. Divisional Social Hour. Divisional Dinner.

SECTION A Statler Hilton, Penn Top South (18th Floor) Symposium on the Chemistry of the Lanthanide and Actinide Elements Joint with Division of Nuclear Chemistry and Technology

T. Moeller, Presiding 9 : 0 0 - 65.

9 : 2 5 - 66.

9 : 5 0 - 67. 10:15-

1 0 : 4 0 - 69.

1 1 : 0 5 - 70.

1 1 : 3 0 - 71.

SECTION Β

1 1 : 5 0 - 72.

J. B. Walker, G. R. Choppin. Thermodynamic Parameters of Fluoride Complexes of the Lanthanides. R. E. Sievers, K. J. Eisentraut, D. W. Meek, C. S. Springer, Jr. Gas Chromatographic and Nuclear Magnetic Resonance Studies of Rare Earth β-Diketonates. D. L. Ross, J. Blanc. Lanthanide Clathrates as Laser Materials. S. J. Lippard. Nuclear Magnetic Resonance Studies of Eight-Coordinate Rare Earth β-Όίketonates. L. C. Thompson, B. L. Shafer, J. A. Edgar, K. D. Mannila. Complexes of the Rare Earths. IX. iV-Substituted Iminodiacetic Acids. B. Lee, M. D. Lind, J. L. Hoard. Stereochem­ istry of the Ethylenediaminetetraacetato Chelates of the Lanthanide Ln"'+ Ions. D. Cousins, A. Hart. Complexes of Lanthanide Nitrates with Triphenylphosphine Oxide and Triphenylarsine Oxide. E. V. Kleber. Rare Earth Research Trends.

Statler Hilton, Sky Top (18th Floor) Alfred Werner Centennial Symposium

SECTION Β

Joint with Division of The History of Chemistry G. B. Kauffman, Presiding 2:002:05- 54. 2 : 4 0 - 55. 3 : 1 5 - 56. 3 : 5 0 - 57. 4 : 2 5 - 58. 6:007:00-

G. B. Kauffman. Introductory Remarks. R. T. Sanderson. The Role of Coordinate Covalence in Nonmolecular Solids. W. F. Luder. A New Approach to the Chemical Bond. I. New Models in Atomic Structure. R. B. King. Coordination Number, Electronic Configuration, and Ionic Charge as Discrete Vari­ ables in Coordination Chemistry. R. J. Gillespie. Electron-Pair Repulsions and Molecular Shape. W. K. Musker. Square Planar Complexes of the First-Row Transition Metals. Divisional Social Hour. Divisional Dinner.

100 C&EN AUG. 8, 1966

Statler Hilton, Sky Top (18th Floor) Alfred Werner Centennial Symposium Joint with Division of The History of Chemistry

G. B. Kauffman, Presiding 9:00— 9:05-73. 9:40— 74. 1 0 : 1 5 - 75. 1 0 : 5 0 - 76. 1 1 : 2 5 - 77.

G. B. Kauffman. Introductory Remarks. A. E. Martell. The Chelate Effect. G. G. Schlessinger. Complexes of Some Transi­ tion Metals with Polydentate Aliphatic Amines. G. L. Eichorn. The Selectivity of Metal Ions for Coordination Sites on Biological Macromolecules. J. P. Fackler, Jr. Metal β-Ketoenolate Stereo­ chemistry. R. L. Carlin. Vanadyl Acetylacetonate in Solu­ tion.

SECTION C

4:20— 98.

Statler Hilton, Penn Top North (18th Floor)

4 : 4 0 - 99.

General

M. D. Joesten, R. A. Jacob. Octamethylpyrophosphoramide Complexes of Rare Earth Ions. P. A. Pilato, H. A. Eick. The Vaporization Be­ havior of SmG...

R. L. Carroll, Presiding 9 : 0 0 - 78. 9 : 2 0 - 79.

9 : 4 0 - 80. 1 0 : 0 5 - 81. 1 0 : 3 0 - 82.

1 0 : 5 5 - 83. 1 1 : 2 0 - 84. 11:40— 85.

H. R. Allcock, R. L. Kugel. High-MolecularWeight Poly(Alkoxy- and Aryloxyphosphazenes ). H. R. Allcock, R. L. Kugel. High-MolecularWeight Polydichlorophosphazene and Polydiaminophosphazenes. D. D. DesMarteau, G. H. Cady. Phosphoryl Fluorosulfate. H. R. Hays, T. J. Logan. gera-Diphosphinoalkanes. Preparation and Characterization. P. M. Treichel, R. A. Goodrich. The Thermal Rearrangement of Phosphorus Pentafluoride Adducts of Dimethyl Ether and Dimethyl Sulfide. P. M. Treichel, R. A. Goodrich. Synthesis and Characterization of HPFi and H,>PF3. F. B. Clarke, J. W. Lyons. The Alcoholysis of Polyphosphoric Acid. R. L. Carroll, R. E. Mesmer. Isohypophosphate. Kinetics of the Hydrolysis; Potentiometric and NMR Studies on the Acidity and Complexing.

SECTION C Statler Hilton, Penn Top North (18th Floor) General E. L. Amma, Presiding 2:00-100.

2:20-101. 2:40-102. 3:00-103. 3:20-104.

3:40-105.

4:00-106.

WEDNESDAY AFTERNOONSECTION A Statler Hilton, Penn Top South (18th Floor)

4:20-107. 4:40—108.

Alfred Werner Centennial Symposium

R. G. Vranka, E. L. Amma. Electron Deficient Bonding Involving Sulfur Atoms. II. The Crystal Structure of C u i [ S C ( N H 2 ) 2 ] 9 ( N 0 3 ) 4 . F . M. D'ltri, A. I. Popov. Pentamethylenetetrazole Complexes of Some Transition Metal Ions. D. A. Langs, C. R. Hare. The Structure and Spectra of Eight Coordinate C o p p e r ( I I ) . R. F. Fenske, D. D. Radtke. Parameter Free Molecular Orbital Calculations—TiCL and VCL. A. W. Chester, C. H. Brubaker, Jr. The Elec­ tronic Spectrum of the μ-Amidodecamminedicobalt(III) Ion. C. W. DeKock, D. M. Gruen. Electronic Ab­ sorption Spectra of the Gaseous 3d Transition Metal Dichlorides. D. L. Williams, D. W. Smith, R. C. Stoufer. A Model for Anomalous Magnetic Behavior. B. Kratochvil, D. A. Zatko. C o p p e r ( I I ) Oxida­ tion of Thioureas in Acetonitrile. S. K. Madan, M. Sulich. Spectrochemical Studies of N-Methyl-7-thiobutyrolactam Cobalt ( I I ) Complexes.

Joint with Division of The History of Chemistry THURSDAY MORNING.

S. Kirschner, Presiding 2:002:05-

2:40- 87.

3:153 : 5 0 - 89. 4 : 2 5 - 90.

S. Kirschner. Introductory Remarks. J. M. Jenkins, T. J. Huttemann, J. G. Verkade. Metal Complexes Involving a Rearrangement of a Phosphorus-Containing Ligand. K. G. Coskran, T. J. Huttemann, J. G. Verkade. Reactions of Cobalt ( I I ) with P ( O M e ) 3 - F o r m a tion of the Novel Complex Anion [Co 1 ( P (OMe).,)(NO«) 2 ]. F. Basolo. Stereochemistry and Mechanisms of Reactions of Werner Complexes. G. W. Watt, D. G. Upchurch. Some Reactions of Coordinated Ligands. M. M. Jones. The Masking of Ligand Reactivity bv Coordination.

SECTION A Statler Hilton, Penn Top South (18th Floor) Symposium on the Applications of Mass Spectrometry in Inorganic Chemistry

J. L. Margrave, Presiding 9:00—109. 9:30-110. 9:55—111. 10:20—112. 10:45-113.

SECTION Β

11:10-114.

Statler Hilton, Sky Top (18th Floor) 11:35—115.

General

J. L. Franklin. Mass Spectrometric Studies of Chemi-ionization. W. S. Koski, G. R. Hertel. Ion-Molecule Reactions Involving Pentaborane. P. Kebarle. Mass Spectrometric Study of IonSolvent Molecule Interactions in the Gas Phase. C. E. Melton. The Mass Spectrometer as a Radiolytic and a Catalytic Laboratory. T. A. Milne, F. T. Greene. Direct Mass Spectro­ metric Sampling of High-Pressure Systems. I. D. Gay, R. D. Kern. Shock Tube Study of a D,-Ne Mixture from 900° to 2300° K. F. E. Stafford. Electron Impact Ionization Cross Sections. II. Classical Calculations.

R. D. Feltham, Presiding 2 : 0 0 - 91.

2:20— 92.

2 : 4 0 - 93. 3 : 0 0 - 94. 3 : 2 0 - 95. 3 : 4 0 - 96.

4 : 0 0 - 97.

F. A. Hartman, P. J. Pollick, A. Wojcicki. Sulfur Dioxide Insertion Reactions of Some Manganese and Rhenium Pentacarbonyl Complexes Contain­ ing Metal-Carbon Bonds. M. F. Farona, L. M. Frazee. Reactions of Halogenopentacarbonylmanganese ( I ) with Halide and Pseudohalide Ions in Methanol. R. E. Dessy, R. Pohl, P. Weissman. Synthesis of Metal-Metal Bond. R. B. King. Preparation, Alkylation, and Pro­ tonation of Sodium Cyanopentacarbonylmetallates. R. D. Feltham, W. Silverthorn. Bonding in Transition Metal Nitrosyls. B. Frlec, H. H. Hyman. Molybdenum, Tungsten, and Uranium Hexafluorides in Anhydrous Hydro­ gen Fluoride. J. R. Gump, W. E. Kelley. Separation of Yttrium from Neodymium and Some Other Lanthanides.

SECTION Β Statler Hilton, Sky Top (18th Floor) Alfred Werner Centennial Symposium Joint with Division of The History of Chemistry

S. Kirschner, Presiding 9:009:05-116. 9:40-117.

10:00-118. 10:35-119.

S. Kirschner. Introductory Remarks. Β. Ε. Douglas. The Role of Optical Activity in the Development of Coordination Chemistry. S. Kirschner, K. R. Magnell. Optical Activity and the Pfeiffer Effect in Coordination Com­ pounds. K. Nakamoto. Recent Infrared Studies on Werner Complexes. L. Vaska. Stereochemistry and Vibrational Spec­ tra of Hydrido- and Deuteriocarbonyl Complexes. AUG. 8, 1966 C&EN

101

SECTION C

3:15-138.

Statler Hilton, Penn Top North (18th Floor) General

3:50-139.

G. R. Dobson, Presiding

4:25—140.

9:00-120. 9:20-121.

9:40-122. 10:00-123.

10:20-124. 10:40-125.

11:00-126.

P. A. Kilty, R. E. McCarley. Some Reactions of Tantalum ( I V ) Halides with Acetonitrile. T. A. Dougherty, R. E. McCarley. The Structure and Bonding of Tetrabromobis( acetonitrile )niobium(IV). G. H. Carey, A. E. Martell. Formation, Hydroly­ sis, and Olation of U ( I V ) Chelates. F. Screiner, D. W. Osborne, J. G. Malm, G. Mc­ Donald. Thermodynamic Properties of Xenon Hexafhioride. L. W. Houk, G. R. Dobson. Mixed Complexes of the Group VIB Metal Carbonyls. L. V. Interrante, M. A. Bennett, R. S. Nyholm. Group VI Metal-Olefin Complexes. An Unusual Metal-Catalyzed Olefin Isomerization. Β. P. Cotsoradis, R. D. Archer. The Solvolysis of Sodium Dinitrobis( acetylacetonato)cobaltate(III).

11:20-127. 11:40-128.

L. P. Eddy, S. K. McEwen, D. Schwartz. Nickel Complex with 2,2'-Iminobis(acetamidoxime). Ν. Sadasivan, J. A. Kernohan, J. F. Endicott. Preparation and Chemistry of Some Macrocyclic Amine and Schiff Base Amine Complexes of Co­ balt (III).

SECTION C Statler Hilton, Penn Top North (18th Floor) General R. C. Taylor, Presiding 2:00-141.

2:20-142.

2:40-143.

3:00-144.

3:20-145.

3:40—146.

THURSDAY AFTERNOON. SECTION A Statler Hilton, Penn Top South (18th Floor)

4:00—147.

Symposium on Applications of Mass Spectrometry in Inorganic Chemistry

4:20-148.

K. D. Carlson, Presiding

4:40-149.

2:00—129.

2:30—130. 2:55—131.

3:20-132. 3:45-133. 4:10-134.

4:35-135.

M. D. Scheer. Self-Surface Ionization and Its Use in the Characterization of Metal Surfaces at High Temperatures. J. D. McKinley. A Mass Spectrometric Investiga­ tion of the Nickel, Fluorine Surface Reaction. R. F. Porter, F. A. Grimm. Mass Spectrometric Studies of the Photochemical Oxidation of Diborane and Borazine. F. E. Stafford, R. J. Loyd. Automated Data Handling for Inorganic Mass Spectrometry. J. H. Norman, H. G. Staley, W. E. Bell. Vapori­ zation of Noble Metal Oxides—Ruthenium Oxides. R. T. Grimley, D. W. Muenow. Use of the Mass Spectrometer in Angular Distribution Studies of Molecular Effusion. R. T. Grimley, R. P. Burns, M. G. Inghram. Mass Spectrometric Study of the Vaporization of Co­ balt Oxide.

SECTION A Statler Hilton, Penn Top South (18th Floor) Symposium on Applications of Mass Spectrometry in Inorganic Chemistry P. W. Gilles, Presiding 9:00-150. 9:30-151.

10:20-153.

Statler Hilton, Sky Top (18th Floor) Alfred Werner Centennial Symposium

10:45-154.

Joint with Division of The History of Chemistry M. D. Rausch, 2:00— 2:05—136. 2:40—137.

Presiding

M. D. Rausch. Introductory Remarks. M. D. Rausch. The History and Development of Organotransition Metal Chemistry. M. Tsutsui. Arene 7r-Complex Chemistry.

102 C&EN AUG. 8. 1966

M. D. Alexander, H. G. Hamilton, Jr., A. Van Heuvelen. Manganese ( II) Complexes Contain­ ing a Pentadentate Macrocyclic Ligand. L. G. Warner, N. J. Rose, D. H. Busch. Diastereo- and Coordination Isomers of a Macrocyclic Schiff Base Nickel(II) Complex. L. T. Taylor, S. C. Vergez, D. H. Busch. The Coordination Template Effect in o-Aminobenzaldehyde-Metal Ion Systems and Formation of a Novel Chelate Sandwich Compound. R. Eisenberg, H. B. Gray. Trigonal-Prismatic Coordination: The Crystal and Molecular Struc­ ture of Tris(cis-l,2-diphenylethene-l,2-dithiolato)vanadium. M. J. Baker-Hawkes, E. Billig, H. B. Gray. Characterization and Electronic Structures of Metal Complexes Containing Benzene-1,2-dithiolate and Related Ligands. J. J. Zuckerman. Sn11!"" Mossbauer Isomer Shift and Percentage Ionic Character of Tin Bonds. A Cautionary Note. V. A. Maroni, T. G. Spiro. Vibrational Spectra of Polynuclear Hydroxy Complexes of Lead ( I I ) . K. M. Wellman, W. Mungall, T. G. Mecca, C. R. Hare. Optical Rotatory Dispersion Spectra of ( α-Substituted-glycinato ) copper ( II ) Complexes. G. R. Brubaker, B. E. Douglas. Electronic and Circular Dichroism Spectra of Polynuclear 2Aminoethanethiol Complexes.

FRIDAY MORNING.

9:55-152.

SECTION Β

M. Rosenblum, F. W. Abbate. Participation of the Metal Atom in the Reactions of the Iron Group Metallocenes. R. Pettit, L. Watts. The Chemistry of Cyclobutadiene-Iron Tricarbonyl. D. F. Martin. Organometallic-Chelate Com­ pounds: Organometallic Ions as Central Metal Ions.

11:10-155. 11:35-156.

R. W. Kiser, J. G. Dillard, D. L. Dugger. Mass Spectrometry of Inorganic Halides. T. P. Fehlner, R. B. Callen. The Mass Spectrometry of Four Hydrides of Phosphorus. J. F. Ditter, F. J. Gerhart, R. E. Williams. Mass Spectrometry of Boron-Carbon Compounds. P. W. Gilles, J. G. Edwards, J. M. Leitnaker, H. Wiedermeier. Mass Spectrometric Studies of High-Molecular-Weight Boron Sulfides and Metathioboric Acid. R. P. Burns, M. G. Inghram. The Rate of Evapo­ ration from Inorganic Surfaces at High Tempera­ tures. A. W. Tickner, H. Fujisaki, J. B. Westmore. Mass Spectrometric Study of Subliming Selenium. E. D. Cater, R. A. Steiger, B. A. Holler. Mass Spectrometric Determination of Heats of Sublima­ tion and Dissociation Energies of YS, LaS, and PrS.

SECTION B

4:10—175.

Statler Hilton, Sky Top (18th Floor) 4:35-176.

Alfred Werner Centennial Symposium Joint with Division of The History of Chemistry

K. Zmbov, J. L. Margrave. Mass Spectrometric Studies of Rare Earth and Transition Metal Fluorides. F . C. Kohout, F . W . Lampe. A Mass Spectrommetric Investigation of the Nitroxyl ( D N O ) Mole­ cule.

H. Β. Gray, Presiding 9:009:05-157. 9:40-158. 10:15-159. 10:50-160.

11:25-161.

Η. Β. Gray. Introductory Remarks. D. H. Busch. Solvational Control in Spin-State Variations Among Nickel(II) Complexes. R. D. Archer. Intermediate Octahedral Ligand Fields and Substitution Reaction Stereomobility. H. B. Gray, R. Eisenberg, E. I. Steifel. TrigonalPrismatic Coordination. S. T. Spees, Jr., J. R. Perumareddi, A. W . Adamson. Substitution Reactions of Inorganic Complexes. The Prediction of Activation Energies and Reaction Mechanisms by Crystal Field Theory. G. F . Svatos. Nuclear Magnetic Resonance and the Nature of the Coordinate Bond.

SECTION Β Statler Hilton, Sky Top (18th Floor) Alfred Werner Centennial Symposium Joint with Division of The History of Chemistry L. C. W. Baker, Presiding 2:002:05-177. 2:30-178. 3:05-179.

SECTION C

3:40-180.

Statler Hilton, Penn Top North (18th Floor)

4:05-181.

General

L. C. W . Baker. Introductory Remarks. R. T. M. Fraser. Linkage Isomerism. L. C. W. Baker. Heteropoly Acids Since the Time of Alfred Werner. J. J. Bulloff. Color-Center Tagging in Polyheteropolyanion Coordination Chemistry. J. J. Bulloff. Coordination, Cosmo geny, and Earthquakes. S. Soloveichik. The Complexing Ability of Cations and the Tendencies of Ligands Toward Complex Formation.

W. E. Bennett, Presiding 9:00-162. 9:25-163.

9:50-164. 10:15-165.

10:40-166. 11:00-167. 11:20-168.

11:40-169.

W. E. Bennett, R. Krahn. Properties of a WaterSoluble Tetraphenylporphine. E. W. Randall, D. Shaw, D. G. Gillies. NMR Shifts of Elements in Group V of the Periodic Table in Tetraalkyl Derivatives. D. S. Dyer, R. O. Ragsdale. 19F NMR Study of Some New Fluorotitanate Complexes. J. B. DeRoos, J. P. Oliver. NMR Studies on Ex­ change Reactions of Group III Alkyl Derivatives. II. J. J. Zuckerman, C. H. Yoder. Transmission of Substituent Effects Through the N-Si-N System. E. W. Randall, C. H. Yoder, J. J. Zuckerman. Electronic Structure of Group IV gera-Diamines. C. G. Moreland, G. G. Long, G. O. Doak. 19 F NMR Studies on Halogen Exchange Between Compounds of the Type R 3 SbF 2 and R3SbX2. R. Compton, A. J. Vandenbroucke, R. D. Ber­ trand, J. G. Verkade. Unusual Shielding and D e shielding of Group V Compound Protons in Aro­ matic Solvents.

SECTION C Statler Hilton, Penn Top North (18th Floor) General N. Purdie, Presiding 2:00-182.

2:25-183.

2:50-184.

3:15-185.

3:40-186. 4:10—187.

FRIDAY AFTERNOON. SECTION A

4:25—188.

Statler Hilton, Penn Top South (18th Floor)

W . D e W . Horrocks, Jr., R. W. Kluiber, R. A. Low. Ligand Exchange in Divalent Metal Acetylacetonate Complexes. A PMR Study of Rates. J. E. Teggins, D . R. Gano, M. A. Tucker, D. S. Martin, Jr. Tetrabromoplatinate ( II ). Acid Hy­ drolysis and Isotopic Exchange of Ligands with Bromide Ion. D . W . Margerum, H. M. Rosen. The Effect of Coordinated Ligands on the Rate of Replacement of Bound Water in Nickel(II) Complexes. D. H. Huchital, R. G. Wilkins. A Kinetic Study of the Intermediates Formed in the Reaction of Ethylenediaminetetraacetatecobaltate ( II ) with Ferricyanide Ion. K. Wuthrich, R. E. Connick. 1 7 0 NMR Relaxa­ tion in Aqueous Solutions of Vanadyl Perchlorate. O. J. Parker, J. H. Espenson. Vanadium Redox Catalysis of C h r o m i u m ( I I I ) Substitution. N. Purdie, C. A. Vincent. Ultrasonic Absorption Studies on Complex Formation in the Lanthanide Sulfates.

Symposium on Applications of Mass Spectrometry in Inorganic Chemistry

R. W. Kiser, Presiding 2:00-170. 2:30-171.

2:55-172.

3:20-173.

3:45-174.

F . E. Stafford, G. A. Pressley, Jr., A. B. Baylis. Mass Spectrometric Studies of Unstable Species. H. A. Eick, R. M. Jacobs. A Mass Spectrometric Investigation of the Vaporization Behavior of NdUOaS. O. M. Uy, F . J. Kohl, K. D. Carlson. A. Thermo­ dynamic Study of Vapor Species from P 3 N 5 by T.O.F. Mass Spectrometry. J. L. Margrave, J. C. Thompson, C. H. Williams, J. D. McDonald. Silicon-Fluorine Chemistry. V. Appearance Potentials, and Heats of Formation of Perfluorosilanes and Perfluoroborosilanes. B. F . G. Johnson, J. Lewis, I. Williams, J. Wilson. Mass Spectra of Some Transition Metal Carbonyl and Nitrosyl Compounds.

Division of Medicinal Chemistry J. E. Gearien, Chairman Β. Μ. Bloom, Secretary SUNDAY EVENINGS : 00— 9-00—

Divisional Business Meeting, Americana, Georgian RallroomR (3rd Floor). Divisional Mixer, Americana, Georgian Ballroom Β (3rd Floor). AUG. 8, 1966 C&EN 103

MONDAY MORNING AND AFTERNOON. Americana, Georgian Ballroom A (3rd Floor)

4:25—24. 4:40-25.

General J. E. Gearien, Presiding 9 : 0 0 - 1.

9:15— 2. 9 : 3 0 - 3. 9:45— 4. 1 0 : 0 5 - 5. 1 0 : 2 0 - 6.

1 0 : 3 5 - 7.

10:50-8.

1 1 : 0 5 - 9.

11:20-10.

11:35-11.

11:50-12.

12:05-13.

S-H. Chu, H. G. Mautner. Sulfur and Selenium Compounds Related to Acetylcholine and Choline. VII. Isologs of Benzoylthionocholine and 2-Dimethylaminoethyl Thionobenzoate. R. A. Pages, A. Burger. Cyclopropylogs of Histidine and Thyroxine. T. Y. Shen, R. L. Ellis, B. E. Witzel, A. R. Matzuk. Synthesis of Indene Analogs of Indomethacin. P. S. Portoghese, D. A. Williams. Stereochemistry of a- and /3-Methadol. M. L. Fielden, W. J. Welstead, C. D. Lunsford. 5-( ^-Substituted alkyl)-2-oxazolidiones. D. L. Trepanier, E. R. Wagner, G. Harris, A. D. Rudzik. Chemistry and Pharmacology of a Series of Substituted 1,4,5,6-Tetrahydro-a.s-triazines. R. B. Mofïett, L. L. Skaletzky, R. E. Strube, T. L. Pickering. l,l-Diaryl-2-methyl-3-aminopropanols as CNS Stimulants. H. H. Keasling, W. Veldkamp, R. J. Collins, R. B. Mofïett. Structure Activity Relationships in a Series of l,l-Diphenyl-2-methyl-3-aminopropanols. H. J. Brabander, W. B. Wright, Jr., R. A. Hardy, Jr., A. C. Osterberg. l-Aminoalkyl-3-aryl-2-imidazolidinones and Related Compounds as Potential Central Nervous System Depressants. F. J. Villani, P. J. L. Daniels, C. A. Ellis, T. A. Mann, K-C. Wang. Derivatives of 10,11-Dihydro5H-dibenzo[a,