First Group of 1986 ACS PRF Grants Approved - C&EN Global

At its December meeting the ACS Board of Directors approved 143 new or continuing ACS-PRF grants for fundamental research, plus 70 supplements to ...
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First Group of 1986 ACS PRF Grants Approved At its December meeting the ACS Board of Directors approved 143 new or continuing ACS-PRF grants for fundamental research, plus 70 supplements to existing grants for Summer Research Fellowships to benefit faculty or students from four-year colleges. These grants, committing $3,949,267 of the $11.3 million authorized for 1986, were recommended from the 521 proposals considered by the PRF Advisory Board in November of 1985. The last meeting of the PRF Advisory Board to recommend 1986 grants is scheduled for May. Proposals for this meeting will be accepted at least through January. Information and application materials may be obtained from the Petroleum Research Fund, American Chemical Society, 1155—16th St., N.W., Washington, D.C. 20036, or by calling (202) 872-4481. ACS-PRF Grants for Fundamental Research in the Petroleum Field (Type AC) Stephen E. Kesler, Philip A. Meyers, U of Michigan. Composition and Thermal Maturity of Bitumen Associated with MVT Zn-Ba-F Mineralization in East Tennessee. $35,000 Barry B. Snider, Brandeis U. Lewis Acid Catalysis and Carbofunctionalization of Alkenes. $35,000 Chi-yuen Wang, U of California, Berkeley. Evoluation of Temperature and Pore Pressure in Accretionary Complexes. $34,842 Seth D. Rose, Arizona State U. Identification of Transient Intermediates in Pyrimidine Dimer Photosplitting. $35,000 Carlo Floriani, Columbia U. Studies on the Synthesis and Chemical Behavior of the Organometallic Functionalities [M(CH20)] in its Various Forms, Which Play a Fundamental Role in Synthesis Gas Chemistry. $35,000 William T. Winter, Polytechnic U. Structure and Interactions of Plant Gums. $35,000

Emil H. White, Johns Hopkins U. Deamination: the Reaction of Alkyl Diazonium Ions. $35,000 John T. Welch, State U of New York, Albany, Stereoselective Reactions of Fluorinated Esters, Amides, and Carbohydrates. $35,000 James C Weisshaar, U of Wisconsin, Madison. Reactions of Electronic-State-Selected Transition Metal Complexes in the Gas Phase. $52,500 William C Strieder, U of Notre Dame, Thermal Radiation and Conduction in Porous Media. $33,400 Fereydoon Family, Emory U. Dynamic Phenomena in Disordered Systems and Fractal Structure. $35,000 Frank W. Fowler, State U of New York, Stony Brook. 1-Aza Cope Rearrangement and Its Application to Problems in Organic Synthesis. $35,000 David R. Tyler, U of Oregon, Isolobal Analogy in Mechanistic Organometallic Photochemistry. $35,000 Hans J. Reich, U of Wisconsin, Madison. Investigation of Reactive Intermediates in the Lithium/Metalloid Exchange Reaction. $35,000 Robert F. Stallard, Princeton U. Anatomy of Multiple Cretaceous Sapropels, Products of Rhythmic SeaFloor Anoxia. $35,000 Edward E. Waali, U of Montana. Constrained Cycloheptatrienylidenes and Cycloheptatetraenes. Carbon Atom Loss. $35,000 David L. Monts, Lathar Schafer, U of Arkansas. Time-Resolved Studies of Transient Molecular Species by Synchronously Pulsed Optical Excitation and Diagnostic Electron Scattering. $35,000 Harold L. Kohn, U of Houston, General Synthetic Strategies for the Preparation of Vicinal Diamines. $35,000 Herb S. Gutowsky, University of Illinois, UrbanaChampaign. Rotational Spectroscopy of Transient Species. $52,500 James J. Christensen, Reed M. Izatt, Brigham Young U. Ternary Heat of Mixing, Vapor-Liquid Equilibrium, and Liquid-Liquid Equilibrium Values from Binary Heats of Mixing. $35,000 Richard S. Givens, U of Kansas, Photochemistry of Phosphate Esters. $35,000 Helmut Kaiser, U of Missouri, Research Reactor; Stlg E. Friberg, U of Missouri, Rolla. Neutron Scattering and Diffraction Study of Amphiphilic Association Structures Without Water. $35,000 Michael E. Kellman, Northeastern U. Vibrational Dynamics of Molecules. $35,000 Edward I. Solomon, Stanford U. Coordination Chemistry of Copper on ZnO Surfaces. $52,500 Ronald F. Evilia, U of New Orleans. Nuclear Magnetic Resonance Studies in Supercritical Fluids. $35,000

Marcus A. Tius, U of Hawaii, Manoa. Synthesis of Morphine. $35,000 Paul M. Helquist, U of Notre Dame. Synthesis of Complex Carbocyclic Systems Using Iron Alkylidene Complexes. $35,000 Arthur J. Ashe III, U of Michigan. Heterocyclopentadienyl Anions and Heterotropylium Cations. $35,000 Gerald B. Westermann-Clark, U of Florida. Ultrafine Dispersions of Oil/Water Systems Using Electrocapillary Emulsification. $35,000 Robert A. Holwerda, Texas Tech U. Redox Reactivity and 7r-Bonding in Oxo/Sulfido—Bridged Chromium (III) Dimers. $35,000 Duy H. Hua, Kansas State U. Studies in the Regioselectivity of the Addition Reaction of Chiral Sulfinylallyl Anions with Ambident Electrophiles: Reversibility, Mechanism, and Synthetic Utility. $35,000 Glenn A. Crosby, Washington State U. Photophysical and Photochemical Investigation of d8 Complexes Exhibiting Ligand-Ligand Charge-Transfer Excited States. $35,000 Stephen D. Kevan, U of Oregon, Surface Electronic Structure Probed by High Resolution Angle-Resolved Photoemission. $51,500 Rex E. Shepherd, U of Pittsburgh. Ruthenium and Osmium Complexes of Acetylenes. $35,000 David T. Long, Michigan State U. The Origin of Interior Platform Basin Brines: Michigan Basin. $52,500 Stephen F. Nelsen, U of Wisconsin, Madison. Olefin Cation Radical Reactions. $35,000 Ryong-Joon Roe, U of Cincinnati, Applicability of Mean Field Theories to the Mixtures of Block Copolymers and Homopolymers. $52,500 Raymond Siever, Harvard U. Burial Diagenesis of Sandstones in Relation to Foreland Basin Evolution. $35,000 Douglas W. Burbank, U of Southern California. Geochronologic, Stratigraphic, and Tectonic Evolution of the South Pyrenean Basins, Northern Spain. $35,000 Bruce E. Bursten, Ohio State U. Bonding in Organoactinide Complexes. $35,000 Jerome A. Berson, Yale U. Spin Rules and Connectivity in 7r-Conjugated Systems. $35,000 Gary W. Poehlein, Georgia Institute of Technology. Kinetic Model for Nonuniform Emulsion Polymer Particles. $34,750 George M. Homsy, Stanford U. Vortex Methods for Porous Media Flows. $35,000 Charles S. Swindell, Bryn Mawr C. Synthesis of Taxinine. $35,000 Harold W. Moore, U of California, Irvine. Synthesis of Alkynylketenes. $35,000 January 27, 1986 C&EN

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ACS News Mark Cloos, U of Texas, Austin. Hydrocarbon Generation Histories of Forearc Basins: Fission Track Analysis and Thermal Modeling of the Great Valley Forearc Basin, Calif. $52,500 David H. Krinsley, Arizona State U. Diagenesis in Tertiary Gulf Coast Mudrocks and Sandstones. $35,000 Paul C. Painter, Pennsylvania State U. FTIR Studies of Some Polydiacetylenes. $35,000 M. Peter Dreyfuss, Michigan Molecular Institute. Preparation and Properties of Head-to-Head Copolymers of Vinyl Chloride. $35,000 Philip P. Power, U of California, Davis. Structural Investigation of Lithium Derivatives of Low Valent Transition Metal Alkyls, Aryls, and Silyls. $35,000 Shaw Ling Hsu, U of Massachusetts. StructuralProperty Relationships of High Modulus/Strength Liquid Crystalline Polymers. $35,000 Maitland Jones Jr., Princeton U. Bridgehead Double Bonds. $35,000 Gregory L. Hillhouse, U of Chicago. Insertion Reactions of Carbon Suboxide with Organometallic Complexes. $35,000 Leslie S. Forster, U of Arizona. Thermo- and Solvatochromic Emission and Solvent Relaxation in Cr(lll) Complexes. $35,000 Orville T. Beachley Jr., State U of New York, Buffalo. Chemistry of Low Oxidation State Main-Group Compounds. $35,000 Piotr H. Karpinski, Robert W. Thompson, Worcester Polytechnic Institute. Nucleation of Hydroxysodalite Crystals in Hydrothermal Systems. $35,000 Michael I. Page, Huddersfield Polytechnic. Ease of C—N Bond Fission in /^-Lactams. $29,150 Edward M. Stolper, California Institute of Technology. Application of Solid-State Nuclear Magnetic Resonance Spectroscopy to the Study of Protons in Silicate Glass. $35,000

ACS-PRF Grants for FundamentalI Research in the Petroleum Field (Type B)

James R. Maxwell, U of Bristol. Chemistry and Geochemistry of Botryococcenes. $35,000 Karen W. Morse, Utah State U. Organocyanohydroborates: a New Class of Hydroborates and Their Derivatives. $35,000 Simon H. Bauer, Cornell U. Structures of Amorphous Catalysts—Scaling of EXAFS and Diffraction Data for Obtaining Quantitation R.D. Curves. $35,000 Arnold L. Rheingold, U of Delaware. Incorporation of Arsenic and Antimony in Transition-Metal Clusters. $35,000 Louis H. Pignolet, U of Minnesota. Reactivity of Gold and New Gold Alloy Phosphine Compounds. Their Potential in Oxygen and Hydrogen Transfer Catalysis. $35,000 R. Paul Philp, U of Oklahoma. Investigation of the Formation Mechanisms, Structures, and Degradation Mechanisms of Kerogens and Kerogen Precursors. $52,500 Andrew J. Poss, State U of New York, Buffalo. Synthesis of Damsinic Acid. $35,000 Edward R. Grant, Cornell U. Catalytic Reactions of Pulsed Laser Generated Organometallic Hydrides in the Gas Phase. $35,000 Valeria Balogh-Nair, City U of New York, City C. Synthesis of Crosslinking Probes of Rhodopsin and Bacteriorhodopsin. $35,000 Richard L. McCreery, Ohio State U. In-Situ Laser Activation of Electrochemical Processes. $52,500 John W. Hepburn, U of Waterloo. State-to-State Chemical Dynamics Using Coherent Vacuum Ultraviolet Light. $35,000 Jonathan E. Kenny, Tufts U. Internal Conversion Rates in Azulenes. $35,000 Robert H. Morris, U of Toronto. Transition Metal Complexes of Dihydrogen With the H—H Bond Still Intact. $35,000

Alcohols. A Search for Asymmetric Carbocations. $20,000 Laurence E. Strong, Earlham C. Ionization and Dimerization Thermodynamics of Some Substituted Benzoic Acids in Water Solutions. $19,700 Charles M. Onasch, Bowling Green State U. Comparative Study of Primary and Secondary Stylo-- Paul L. Dubin, Indiana U-Purdue U, Indianapolis. Coulombic Complexes of Polyions and Oppositely lites in Sandstones. $17,000 Charged Colloids. $20,000 Burchard D. Carter, Georgia Southwestern C. Paleobiogeography of Late Eocene Echinoids of the3 Victor P. Vitullo, U of Maryland, Baltimore County, cvDeuterium Isotope Effect and Transition State Eastern Gulf Coast Plain. $18,375 Structure in the General Acid Catalyzed Hydrolysis Laura L. Wright, Furman U. Features of Metal Olefin1 of Acetals. $20,000 Bonding in Low Valent Palladium and Platinumn Richard A. Pacer, Indiana U-Purdue U, Fort Wayne. Systems. $20,000 Substoichiometric Radioisotope Dilution Analysis Kenneth L. Stevenson, Indiana U-Purdue U, Ft. Using Lead-210. $20,000 Wayne. Photoinduced Electron-Transfer Chemis-I Jan Tobochnik, Kalamazoo C. Computer Simulatry of Simple Copper(l) Complexes. $20,000 tions and Theoretical Studies of Transport in InhoDonald J. Mitchell, Juniata C. Solid State Extrusion., mogeneous Media. $19,200 of Polymers of Complex and Simple MorpholoHerbert B. Silber, San Jose State U. Metal Ion Coorgies. $20,000 dination Number Changes in Water and Mixed SolSally Chapman, Barnard C. Classical Trajectory vents. $20,000 Studies of Ion-molecule Processes: VibrationalI Relaxation, Charge Transfer, and Reaction. William H. Hendrickson Jr., U of Dallas. Single Electron Transfer in Peroxide-Nucleophile Reactions. $15,000 $20,000 ^___ Etalo A. Secco, St. Francis Xavier U. Studies on1 Simple Sulfate Derivatives Displaying NASICONACS-PRF Grants for Fundamental Type Conductivity Behavior. $15,000 Research in Petroleum (Type G) Rodney F. Boyer, Hope C. Storage and Mobilization of Ferritin Iron. $20,000 Barbara Castens-Seidell, Bryn Mawr C. Testimony of a Siliciclastic Sabkha Complex, Baja California, Curtis L. Hollabaugh, West Georgia C. ExperimentalI Mexico: an Integrated Approach. $18,000 Determination of the Stability of Ti-Minerals DurDavid E. Wigley, U of Arizona. Metal-Metal and Meting Diagenesis and Deep Burial. $20,000 al-Ligand Double Bonds. $18,000 Gary G. Lash, State U of New York, Fredonia. DocuThomas J. Lynch, U of Nevada, Reno. Tris(cyclopenmentation of Scaly Cleavage Development in ani Ancient Trench-Fill Sequence, Central Appalatadienyl) Transition Metal Clusters. $18,000 chians. $20,000 J. Houston Miller, George Washington U. Matrix IsoMargaret V. Merritt, Wellesley C. Oxygen Exchange? lation Studies of Radical-Molecule Reactions. as a Function of Racemization in Optically Active3 $18,000

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January 27, 1986 C&EN

Michael Kahn, U of Illinois, Chicago. Enantiospecific Carbon-Carbon Bond Forming Functionalization of Olefins. $18,000 Declan G. De Paor, Johns Hopkins U. Structural & Strain Analysis of Near-pole Orogenesis: the Eurekan Orogeny, Arctic Archipelago. $18,000 Neal E. Blair, North Carolina State U. Natural Abundance 13C Measurements of Sediment Interstitial Water Acetate. $18,000 Matthew F. Vernon, Columbia U. Primary Photoprocesses in Mononuclear Organometallics. $18,000 Dan G. Imre, U of Washington. Experimental Mapping of "Virtual" States. $18,000 Charles Jaffe, West Virginia U. Two Problems in the Correspondence Between Classical and Quantum Mechanics. $18,000 James P. Dittami, Worcester Polytechnic Institute. Approach to the Synthesis of Koumine. $18,000 John K. Steehler, U of Virginia. Multiresonant Sum and Difference Frequency Spectroscopy of Surfaces and Interfaces. $18,000 Chris A. Broka, U of Illinois, Urbana-Champaign. Development of Methods for the Synthesis of Daphniphyllum Alkaloids and Cyclitols. $18,000 Michael J. Maroney, U of Massachusetts. Models for Nickel Centers in Hydrogenase. $18,000 Timothy P. Hanusa, Vanderbilt U. Reactivity of Sterically-Stabilized Organoalkaline-Earth Complexes with Gaseous Oxides. $18,000 Michael H. Gelb, U of Washington. /3-Lactamase Inhibitors: Design and Mechanism of Action. $18,000 Thomas E. Mallouk, U of Texas, Austin. Synthetic Routes to New Molecular Metals. $18,000 Kim F. Albizati, Wayne State U. Direct Construction of 4-Hydroxypyranosides (Spiroketals) via Novel Initiation of Cation-Olefin Cyclization. Multiple Extensions to Natural Product Synthesis. $18,000 David H. Waldeck, U of Pittsburgh. Experimental Investigations into Liquid State Dynamics. $18,000 James M. Fenton, U of Connecticut. Investigation of Two-Phase Liquid-Liquid and Liquid-Gas Electrochemical Processes. $18,000 David E. Graves, U of Mississippi. Physical Properties of Polycyclic Aromatic Hydrocarbon Interactions with Nucleic Acids. $18,000 Jeffrey M. Stryker, Indiana U. Carbonyl Ylide Equivalents: Neutral and Cationic 2-Oxametallacyclobutane Transition Metal Complexes. $18,000 Ronald L. Fournier, U of Toledo. Investigation of the Effect of Pore Size on the Intrinsic Rate of Naphthalene and 2-Phenylnaphthalene Hydrogenation by Supported Metal Catalysts. $18,000 Steven F. Pedersen, U of California, Berkeley. Reactions Promoted by Metal Imido Formation. New Routes to Functionalized Amines. $18,000 Robert S. Phillips, U of Georgia. Mechanistic Studies and Synthetic Applications of Carbon-Carbon Lyases. $18,000 James E. Roberts, Lehigh U. Selective Observation of Proton NMR from Solid Materials. $18,000 Kip V. Hodges, Massachusetts Institute of Technology. Tertiary Extension in NE Baja California and the Opening of the Gulf of California. $18,000 Mark A. Johnson, Yale U. Vibrational Spectroscopy and Photophysics of Mass-Selected Cluster Ions. $18,000 Ramabhadran Vasudev, Rutgers U. Molecular Photodissociation Dynamics. $18,000 Eric L. Garfunkel, Rutgers U. Adsorption and Catalysis Studies of Ion Implanted Metals. $18,000 Masanori Hara, Rutgers U. Structure-Property Relations of lonomers in Solution. $18,000 Gautam Sen, Florida International U. Petrologic Investigation into the Dumisseau Formation of Southern Haiti: a Probe into the Crust of the Caribbean Sea. $18,000

James W. Herndon, U of Maryland. [4+3] Cycloadditlon Reactions Employing Vinylcarbene-Metal Complexes. $18,000 Syed Qutubuddin, Case Western Reserve U. Laser Light Scattering Studies of Oil-in-Water Microemulsions. $18,000 Daniel J. Repeta, Woods Hole Oceanographic Institution. Carotenoid Diagenesis in Recent Marine Sediments. $18,000 Thomas A. Stephenson, Swarthmore C. Electronic Energy Effects on the Structure and Dynamics of Van der Waals Complexes. $18,000 William C. Miller III, Humboldt State U. Paleobiology Survey of Franciscan Turbidites, Late Mesozoic Central Belt, Northernmost California. $18,000 Patricia B. O'Hara, Amherst C. Thermal Profiles of the Energy Transfer Process in Biomolecules—a Novel Probe of Macromolecular Dynamics. $18,000 Richard N. Biagioni, Grinnell C. Photochemistry of Monohapto Cyclopentadienyl Complexes. $18,000

ACS-PRF Grants for Education (Type SE)

Scientific

Arthur F. Diaz, Royce W. Murray, on behalf of the ACS Division of Colloid & Surface Chemistry. Symposium on Chemistry and Properties of Polymer Films on Electrodes at the ACS national meeting, Anaheim, September 1986. $3400 Michael B. Hall, on behalf of the ACS Division of Physical Chemistry. Symposium on Theory of Metal-Metal Bonding at the ACS national meeting, New York City, April 1986. $2950 Royston H. Filby, Jan F. Branthaver, on behalf of the ACS Division of Petroleum and the Division of Geochemistry. Symposium on Metalloporphyrins and Metal Complexes in Petroleum and Source Rocks; Aspects of Their Geochemistry and Behavior in Processing at the ACS national meeting, New York City, April 1986. $3400 Reginald P. T. Tomkins, on behalf of IUPAC Commission on Solubility Data. Second International Symposium on Solubility Phenomena, Aug. 12-15, 1986, Newark, N.J. $2550 J. M. Moldowan, on behalf of the ACS Division of Geochemistry. Symposium on Geochemistry in Petroleum Exploration at the ACS national meeting, Anaheim, September 1986. $3400 Johannes Smid, on behalf of the ACS Division of Polymer Chemistry. Symposium on Recent Advances in Anionic Polymerization at the ACS national meeting in New York City, April 1986. $3400 A. Welford Castleman Jr., on behalf of the ACS Division of Physical Chemistry. Symposium on Structure, Spectroscopy, and Dynamics of Atomic, Molecular, and Ionic Clusters at the ACS national meeting in New York City, April 1986. $2550 John M. Torkelson, Charles E. Hoyle, on behalf of the ACS Division of Polymer Chemistry. Symposium on Photophysics of Polymer Systems at the ACS national meeting, Anaheim, September 1986. $3400 Peter C Stair, on behalf of the ACS Division of Colloid & Surface Chemistry. Symposium on Molecular Processes on Solid Surfaces: Surface Chemistry Induced by Energized Particles and Lasers at the ACS national meeting in New York City, April 1986. $1700 David Dolphin, on behalf of the ACS Northwest Regional Meeting. Symposium on Organometallic Chemistry in Nature at the ACS Northwest Regional Meeting, Portland, Ore., June 1986. $3400 Robert A. Gastaldo, on behalf of the Paleontological Society. Land Plants—a Short Course at the Paleontological Society Meeting, San Antonio, November 1986. $1700

Robert A. Barford, on behalf of the Federation of Analytical Chemistry and Applied Spectroscopy Societies. Symposium on Solving Problems with Analytical Pyrolysis at the FACSS meeting, St. Louis, FalU986. $3400 Matthew S. Platz, on behalf of the ACS Division of Organic Chemistry. Symposium on Azide Photochemistry at the ACS national meeting, Anaheim, Fall 1986. $2550 John E. Greedan, on behalf of 17th Rare Earth Research Conference in Hamilton, Ont., Canada, in June 1986. $2550 James P. Shoffner, on behalf of American Chemical Society. Project SEED—Supplementary Program for Summer 1986. $15,000

ACS-PRF Summer Research Fellowship Supplements for Faculty Visitors (Type SRF) Gary J. Long, U of Missouri, Rolla. Mbssbauer Effect Study of Organometallic Clusters and Derived Catalysts. $4000 James D. White, Oregon State U. Absolute Configuration and Synthesis of Botryococcene. $4000 Gerald L. Larson, U of Puerto Rico. Mechanisms of Reaction and Synthetic Utility of Optically Active Carbofunctional Organosilanes. $4000 Seth Stein, Northwestern U. Seismological Studies of Mechanical Processes in Oceanic Plates. $4000 James A. Kittrick, Philip E. Rosenberg, Washington State U. Illite: Composition, Stability and Relationship to Muscovite and Phengite. $4000 Peter Pulay, U of Arkansas. Techniques for the Determination of Molecular Potential Surfaces. $4000 Thomas W. Kammer, West Virginia U. Paleoecology of the Pocono Delta Faunas in West Virginia. $4000 Carol A. Venanzi, New Jersey Institute of Technology. Theoretical Studies of Synthetic Enzyme Mimetics. $4000 Robert R. Holmes, U of Massachusetts. Polymeric Organotin Compounds. $4000 Rabindra N. Roy, Drury C. Thermodynamic Study of Aqueous Solutions. $4000 J. William Suggs, Brown U. Approaches to CarbonCarbon and Carbon-Hydrogen Bond Activation. $4000 Dwight A. Sweigart, Brown U. Mechanistic and Synthetic Studies of Nucleophilic Addition to Coordinated 7r-Hydrocarbons. $4000 Bernard Shizgal, U of British Columbia. Kinetic Theory of Electron Swarms with Applications to Gas Discharges and Plasma Chemistry. $4000 W. Kenneth Musker, U of California, Davis. Coordination Chemistry of Mesocyclic Ligands. $4000 George A. Petersson, Wesleyan U. Ab-initio Determination of Rate Constants and Dissociation Energies with Complete Basis Set Correlation Energies. $4000 Michael E. Kurz, Illinois State U. Photolytic Aromatic Substitution Involving Electron Transfer. $4000 Tomas Hudlicky, Virginia Polytechnic Institute & State U. New Methods of C-C Bond Formation: Synthetic Utility of the Vinylogous Reformatsky Reaction. $4000 Brady P. Rhodes, California State U, Fullerton. Comparison of Structural Styles and Metamorphism across the Purcell Trench, Northern, Idaho. $4000 David J. Nesbitt, U of Colorado. State-resolved Infrared Vibrational Dynamics of Supersonic Expansion Cooled Molecules. $4000 Jack K. Crandall, Indiana U. Allene Cyclizations. $4000

D. Michael Heinekey, Yale U. Synthesis and Reactivity of Novel Transition Metal Methylidene Complexes. $4000 Edward C. Lim, Wayne State U. Intramolecular Vibrational Energy Transfer in Aromatic Carbonyl Compounds. $4000 William H. Hersh, U of California, Los Angeles. Syntheses and Reactions of Heterodinuclear Alkylidene-Alkyls. $4000 Miriam Rossi, Vassar C. Designing the Active Site Conformational Requirements of Metabolizing Enzymes. $4000 Allan M. Nishimura, Westmont C. Coherence in Orientationally Disordered Crystals. $4000 Harold W. Pinnick, Bucknell U. Synthesis of Anatoxins. $4000 Elizabeth M. Holt, Oklahoma State U. Structural Investigation of Thermochromic Fluorescent Copper(l) Clusters. $4000 James R. Damewood Jr., U of Delaware. Studies in Molecular Complex Chemistry. $4000 Tim Byrne, Brown U. Deformation Processes in the Early Proterozoic Cape Smith Fold and Thrust Belt, Northern Quebec, Canada. $4000 Lon J. Mathias, U of Southern Mississippi. Supernucleophilic and Phase Transfer Catalysts. $4000 Erhard Rothe, Wayne State U. Molecular and Orbital Alignment in Photodissociation. $4000 Alfred B. Anderson, Case Western Reserve U. Trends and Variations in Bonding at Transition Metal Surfaces. Hydrocarbon Reactions at Saturation Coverage. $4000 John P. Oliver, Wayne State U. On X-Ray Structural, 13 C, and 27A1 NMR Study of Aluminum Derivatives. $4000 George R. Clark II, Ronald R. West, Kansas State U. Microfacies Analysis and Reconstruction of the Environments of Deposition of Two Chaetetid Reefs (Middle Pennsylvania), Southeastern Kansas. $4000 J. Casey Moore, U of California, Santa Cruz. Stratigraphy, Structural Geology, and Fluid Migration: San Juan Accretionary Prism, Southern Dominican Republic. $4000 Eric Noe, Jackson State U. Studies of Rotational Barriers and Conformational Equilibria Using Dynamic NMR Spectroscopy. $4000 Christopher A. Baumann, U of Scranton. Surface Photochemistry. $4000

ACS-PRF Summer Research Fellowship Supplements for Student Visitors (Type SRF) Keith F. Purcell, Kansas State U. Dynamics of Solid State Electron Transfer. $2000 Stephen A. Macko, Memorial U of Newfoundland. Nitrogen Isotopic Composition and Chemical Nature of Petroleum. $2000 Mark S. Gordon, North Dakota State U. Theoretical Studies of Organosilicon Chemistry. $2000 Frank Bottomley, U of New Brunswick. Reactions of Nitrogen Oxides with Organometallic Complexes of the Early Transition Metals. $2000 Michael A. Duncan, U of Georgia. Chemical Reactions of Transition Metal Clusters. $2000 Cynthia J. Burrows, State U of New York, Stony Brook. Regioselective Oxidation of MacrocycleBound Substrates. $2000 James N. Demas, U of Virginia. Structure and Spectroscopy of Metal Complexes in Organized Media. $2000 Mark A. Arnold, U of Iowa. Optical Fiber Biosensors. $2000 Gregory L. Geoffroy, Pennsylvania State U. Photochemistry of Carbene, Carbyne, and Vinylidene Complexes. $2000 January 27, 1986 C&EN

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ACS News Robin D. Rogers, Northern Illinois U. Synthesis and Structural Chemistry of f-Element Organometallic Compounds Having "Electron-Poor" Cyclopentadienyl Ligands. $2000 Alan R. Morgan, U of Toledo. Benzoporphyrins— Synthesis and Properties. $2000 Leo A. Ochrymowycz, U of Wisconsin, Eau Claire. Synthesis of Thiaether Cryptands; Mimetic Ligand for Copper Enzymes. $2000 Paul G. Gassman, U of Minnesota. Reaction of Strained Heterocyclics with Trimethylsilyl Cyanide. $2000 William R. Dolbier Jr., U of Florida. Substituent Effects of the Stereochemistry and Kinetics of Cyclobutene-Butadiene Interconversions and Related Reactions. $2000 Eugene A. Mash Jr., U of Arizona. Chiral, Nonracemic Ketals in Organic Synthesis. $2000 Edward L. Clennan, U of Wyoming. Singlet Oxygenation of Acyclic-1,3-Dienes. $2000 Michael Chetcuti, U of Notre Dame. Mixed-Metal Metallacycle Chemistry. $2000 E. James Davis, U of Washington. Studies of Rate Processes by Optical Resonance Measurements. $2000 Owen A. Moe Jr., Lebanon Valley C. Preparation and Evaluation of an Immobilized ATP Regeneration System Based on Polyphosphate Kinase. $2000 Brad K. Smith, Arizona State U. Experimental Analysis of Pressure Solution in Quartz/Clay Sediments. $2000 Dave G. Seapy, Florida Institute of Technology. Investigation of Photochemical Mechanisms in Rigid Bridged Ring Systems: Intramolecular Excitation Transfer. $2000

David Wenkert, North Texas State U. cv-Acylazomethine Ylid Formation Via 4-Oxazoline Valence Isomerization. $2000 John W. Geissman, U of New Mexico. Paleomagnetic and Structural Investigation of the Tectonic History of the Early Jurassic Humboldt Lopolith and Associated Units, Fencemaker Allochthon, Westcentral Nevada. $2000 Craig E. Barnes, U of Tennessee. New Metallocyclobutane Complexes, Olefin Metathesis Modeling. $2000 Andrew W. Maverick, Washington U. Binuclear Metal Complexes for Redox Reactions of Coordinated Ligands. $2000 Michael H. Gianni, St. Michael's C. Conformational Analysis of 1,3-Dioxacycloalkanes. $2000 Geraldine L. Richmond, U of Oregon. Laser Spectroscopic Studies of Electrode Surfaces. $2000 George Majetich, U of Georgia. Triquinane Syntheses Using Allylsilanes. $2000 Russell C. Petter, U of Pittsburgh. Free Radical Clocks as Probes of Enzyme Mechanism. $2000 Louis Messerle, U of Iowa. Group IV Transition Metal Mono(peralkylcyclopentadienyl) Complex Chemistry. $2000 Phyllis A. Leber, Franklin and Marshall C. Thermal Rearrangement of Exo and Endo-7-Vinylbicyclo[3.2.0]hept-2-ene. $2000 James L. Gole, Georgia Institute of Technology. Characterization of Ligand-Free Copper and Silver Clusters and Their Reactions To Form Metal Clusters Oxides and Halides. $2000 Kenneth M. Doxsee, U of Southern Californa. Cycloaddition Reactions of ^.^-Unsaturated Carbene Complexes of Transition Metals. $2000

CHIRAL/TY, .