Fluorescent Probes for Monitoring Temperature in Organic Solvents

Abstract. We report two fluorophores, N-(1-pyrenylmethyl)-1-pyrenebutanamide and ... Vladimir A. Vlaskin , Nils Janssen , Jos van Rijssel , Rémi Beau...
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Anal. Chem. 1997, 69, 1262-1264

Fluorescent Probes for Monitoring Temperature in Organic Solvents Jianfeng Lou, T. Alan Hatton,* and Paul E. Laibinis*

Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139

We report two fluorophores, N-(1-pyrenylmethyl)-1pyrenebutanamide and N-(1-pyrenylmethyl)-1-pyreneacetamide, that exhibit temperature-dependent emission spectra over the temperature range of 20-100 °C. The fluorophores are readily synthesized via a one-pot process and can be used in dilute form (