Formation of Nitrile Ylide by Addition of Carbene with Acetonitrile in a

9624 J. Phys. Chem. A, Vol. 105, No. 41, 2001

Additions and Corrections

ADDITIONS AND CORRECTIONS 1999, Volume 103A Ikuo Naito,* Kazuki Nakamura, Tsutomu Kumagai, Akira Oku, Kenzi Hori, Kenji Matsuda, and Hiizu Iwamura: Formation of Nitrile Ylide by Addition of Carbene with Acetonitrile in a Low-Temperature Argon Matrix Page 8192. Table 4 should read as follows: TABLE 4: Calculated NY Bands by Means of RHF/6-31G* Basis Set calculated modified intensity/ measured band/cm-1 band/cm-1 a KM mol-1 band/cm-1 b 478.3 508.9 580.0 618.3 689.2 708.3 779.8 812.8 815.7 861.2 959.0 975.5 997.4 1123.0 1173.1 1310.5 1326.3 1333.4 1455.1 1475.6 1505.2 1534.7 1562.5 1613.8 1619.1 1625.3 1664.6 1697.5 1753.1 1808.3 1818.7 1994.8 3192.0 3270.1 3281.4 3355.6 3372.6 3375.5 3378.0 3381.9 3390.3 3398.4 3415.2 a

431 458 522 556 620 638 702 732 734 775 863 878 898 1011 1056 1179 1194 1200 1310 1328 1355 1381 1406 1452 1457 1463 1498 1528 1578 1627 1637 1795 2873 2943 2953 3020 3035 3038 3040 3044 3051 3059 3074

0.042 0.260 0.111 0.227 0.220 0.167 0.217 0.162 0.350 0.509 0.379 0.475 1.493 0.038 1.083 0.484 0.165 0.017 0.066 0.030 0.579 0.011 0.319 0.055 0.135 0.556 0.388 0.048 0.105 0.138 0.014 2.084 0.568 0.223 0.106 0.052 0.388 0.033 0.035 0.412 0.272 0.074 0.048

418 w 428 w ca. 513 w 532 w 629 w 664 w 698 m 729 m 745 vs 770 s 855 s 884 m 918 vs 1007 m 1042 vs 1173 vs ca. 1184 m ca. 1192 m 1291 w 1306 m 1364 s 1377 vs 1410 vs 1439 s 1447 vs 1489 w 1509 w ? 1591 vs 1615 m ? 1723 s not measured not measured not measured not measured not measured not measured not measured not measured not measured not measured

remarks overlap with other overlap with other

overlap with other overlap with MeCN

overlap with MeCN overlap with MeCN

overlap with MeCN overlap with MeCN overlap with MeCN overlap with MeCN?

Frequencies of modified band have been multiplied by a factor of

0.9.

Published on Web 09/20/2001 10.1021/jp0128170