Free Energy of Iron Oxides - Industrial & Engineering Chemistry (ACS

Publication Date: March 1933. ACS Legacy Archive. Cite this:Ind. Eng. Chem. 1933, 25, 3, 319-327. Note: In lieu of an abstract, this is the article's ...
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Free Energy of Iron Oxides .JOHN

C€ilP#IN AND

DONAIDw. b1ulWiiY. k:niversily of Michigan, Ann Arbor, L l i d i .

7'lre uppliculioii of thermodyrulmics to problems of sled mariufacture is discussed, and the de-

sirabilily of obtaining a complete table of free energies ut steel-making lemperutures is shown. Dala on /he thermal properlies of iron are reviewed, und from these are derived equatioris for the free energy of the various forms of iron referred to beta iron ( I S u contrenieril reference state. The d u h on lhe heat capacities of ferric oxide and ntagrrelile are reviewed and empirical equalioru drrii:ed. An approximate expression for .ierrorr.