Free Radical Rearrangements in the Decarbonylation of Aldehydes la

The peroxide-catalyzed free radical decarbonylation of aldehydes has been used to study the 1 ..... (i,,m-diphcnylcthyl chloride, eliminates hydrogel1...
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Nov. 5, 1952

FREERADICAL REARRANGEMENTS IN DECARBONYLATION OF ALDEHYDES

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drazine sulfate solution to ethanolic solutions of the fracB~~~~~~~ for his interest and adprofessor tions. After chromatography 011 alumina followed by two crystallizations from ethyl acetate-95% ethanol this was vice during the present investigation and Dr* A* obtained as deep orange needles, m.p. 248.5249' ( d e ~ . ) , ~ *Vandenheuvel, Atlantic Fisheries Experimcntal undepressed on admixture with an authentic sample. Station, Halifax, N. S., in whose laboratory thc

initial observation was made.

(48) C . F.I