Graft Copolymers by a Combination of ATRP and Two Different

The direct ATRP of an azide-functionalized monomer, 3-azidopropyl methacrylate, and ...... One-Pot Syntheses of Amphiphilic Centipede-like Brush Copol...
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Macromolecules 2007, 40, 4439-4445

4439

Graft Copolymers by a Combination of ATRP and Two Different Consecutive Click Reactions Nicolay V. Tsarevsky, Sidi A. Bencherif, and Krzysztof Matyjaszewski* Department of Chemistry, Carnegie Mellon UniVersity, 4400 Fifth AVenue, Pittsburgh, PennsylVania 15213 ReceiVed March 22, 2007; ReVised Manuscript ReceiVed April 23, 2007

ABSTRACT: The epoxide ring in glycidyl butyrate (model compound) and in well-defined copolymers of glycidyl methacrylate (