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Graphene-anchored cuprous oxide nanoparticles from waste electric cables for electrochemical sensing Sabah Abdelbasir, Said M. El-Sheikh, Victoria M Morgan, Hannah Schmidt, Lisseth Marcela Casso-Hartmann, Diana C Vanegas, Irene Velez-Torres, and Eric S McLamore ACS Sustainable Chem. Eng., Just Accepted Manuscript • DOI: 10.1021/ acssuschemeng.8b02510 • Publication Date (Web): 14 Aug 2018 Downloaded from http://pubs.acs.org on August 15, 2018
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ACS Sustainable Chemistry & Engineering
Graphene-anchored cuprous oxide nanoparticles from waste electric cables for electrochemical sensing S.M. Abdelbasir1,*, S. M. El-Sheikh1, V.L. Morgan2, H. Schmidt2, L.M. Casso-Hartmann3, D.C. Vanegas3, I. Velez-Torres4, E.S. McLamore2,* 1
2
Central Metallurgical Research and Development Institute, P.O. Box: 87, Helwan, 11421, Cairo, Egypt.
Agricultural & Biological Engineering, Institute of Food and Agricultural Sciences, University of Florida, USA 3 4
Food Engineering Department, Universidad del Valle, Colombia
Environmental and Natural Resource Engineering, Universidad del Valle, Colombia
*Corresponding authors. Abelbasir- Central Metallurgical Research and Development Institute (CMRDI)P.O. Box 87 Helwan 11421, Cairo, Egypt;
[email protected] McLamore-1741 Museum Rd, Gainesville, FL 32611;
[email protected] ABSTRACT We demonstrate development of electrochemical nanosensors for planetary health applications using nanocuprous oxide synthesized from recycled materials. Laser scribed graphene electrodes were enhanced with copper liberated from waste cables and cuprous oxide nanospheres were synthesised via precipitation at low temperature using lactose as a reducing agent and four different surfactants as capping agents. These laser scribed electrodes are a low cost, lithographyfree approach to direct synthesis of flexible carbon circuits. Sensors were fabricated by anchoring nanoparticles to flexible graphene electrodes, and then material properties and sensor performance were compared for each surfactant. Surfactant molecular weight and terminal group played an important role in nanoparticle size, band gap, ferromagnetic response, and electron transport. As proof of principle, we show development of catecholamine and mercury sensors for planetary health applications using the best material. Dopamine sensors were linear from of 300 nM to 5 1 ACS Paragon Plus Environment
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µM, with a detection limit (200 nM), response time of 2.4 ± 0.7 sec, and sensitivity of 30 nA µM cm2. Mercury sensors were linear from 0.02-2.5 ppm, with a detection limit of 25 ppb, response time of
