GULF OIL PLUME TRACKED - C&EN Global Enterprise (ACS

Aug 23, 2010 - THE FIRST PEER-REVIEWED report in a major journal to focus on the catastrophic BP oil spill in the Gulf of Mexico describes an enormous...
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R ICHAR D CA M IL L I/WHO I

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GULF OIL PLUME TRACKED OIL SPILL: First journal report to

characterize deep-sea oil plume

T

HE FIRST PEER-REVIEWED report in a major

journal to focus on the catastrophic BP oil spill in the Gulf of Mexico describes an enormous, persistent plume of hydrocarbons more than 3,000 feet deep moving southwest from the site of the spill to sites up to 22 miles away. In addition, measurements of oxygen levels in the plume show that oil-feeding microbes are not degrading oil as quickly as experts thought. Ocean scientist Richard Camilli, marine chemist Christopher M. Reddy, and colleagues at Woods Hole Oceanographic Institution (WHOI), in Massachusetts, and in Australia collected 57,000 data points during their investigation of the plume, one of several such plumes in the Gulf. The researchers used instruments on a ship and on the submersible automated vehicle Sentry, including a mass spectrometer that tagged a number of easily identifiable components of oil: benzene, toluene, ethylbenzene, and xylenes (Science, DOI: 10.1126/science.1195223). The oil spill, which is now recognized as the largest in history, began on April 20 and dumped an estimated 200 million gal of oil into the ocean until BP engineers stopped the flow with a temporary cap on July 15. Scientists and government officials have issued conflicting reports on the scope of the disaster, most notably regarding the existence and size of underwater plumes. Scientists at the National Oceanic & Atmospheric Administration have characterized several oil plumes in the Gulf, and recently researchers at the University of South Florida announced that samples from the plumes match those from BP’s oil (C&EN, Aug. 2, page 12). The published WHOI study adds credibility to those reports.

During its 10-day mission in June, WHOI’s Sentry zigzagged through the plume, providing definitive boundary information and measuring the rate at which the plume was migrating from the well site. Measurements showed no significant drops in dissolved oxygen, implying that oil is not being quickly degraded by microbes, which consume the gas. Although the NOAA work mainly focused on dispersed oil near the wellhead, the WHOI researchers found “a river of oil in deep water and the current moving surprisingly quickly southwest from the wellhead,” notes Jeffrey Short, an oil spill expert and consultant for Oceana, an environmental advocacy group. The paper’s estimate of the migration rate of dispersed oil in the plume “is the first rate I’ve seen or heard about,” he says. The amount, location, and form of remaining oil from the spill continue to be hotly debated. The federal government’s National Incident Command released a report on Aug. 2 that was widely interpreted to suggest that 75% of the oil had already degraded. However, experts with the University of Georgia, Athens, immediately responded with their own interpretation, saying that almost 80% of the oil persists in the environment.—ELIZABETH WILSON

Images taken by Sentry during its descent through an oil plume near the Deepwater Horizon well show a highly turbid oil-emulsion layer at a depth of 1,065 to 1,300 meters.

PESTICIDES Bayer CropScience, EPA agree to phase out use of aldicarb Bayer CropScience has agreed to voluntarily remove its pesticide aldicarb from the market after EPA determined that the N-methyl carbamate insecticide “no longer meets the agency’s rigorous food safety standards and may pose unacceptable dietary risks, especially to infants and young children.” Under the agreement, farmers can use aldicarb, sold under the trade name Temik, on citrus and potatoes until the end of 2011 and on cotton, dry beans, peanuts, soybeans, sugar beets, and

sweet potatoes until Aug. 31, 2018. Bayer CropScience plans to stop marketing aldicarb worldwide by 2014. Aldicarb has been under scrutiny by EPA for decades because products of the pesticide’s degradation can contaminate groundwater. Exposure to high levels of the pesticide can cause sweating, nausea, dizziness, blurred vision, and gastrointestinal problems. EPA’s most recent dietary risk assessment concluded that exposure to aldicarb from drinking water and food can ex-

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ceed safe levels for infants and children. Bayer CropScience is cooperating with EPA, even though the company does not fully agree with EPA’s risk assessment approach. “For nearly 40 years, Temik has provided farmers with unsurpassed control of destructive pests, without compromising human health or environmental safety,” Bayer CropScience President and CEO William Buckner said in a statement. “We recognize the loss of this tool to growers and will seek innovative solutions to fill this void.”—BRITT ERICKSON