Headspace Solid-Phase Microextraction Coupled to Miniaturized

Feb 19, 2018 - State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of S...
2 downloads 7 Views 2MB Size
Subscriber access provided by the Henry Madden Library | California State University, Fresno

Technical Note

Headspace Solid-Phase Microextraction Coupled to Miniaturized Microplasma Optical Emission Spectrometry for Detection of Mercury and Lead Chengbin Zheng, Ligang Hu, Xiandeng Hou, Bin He, and Guibin Jiang Anal. Chem., Just Accepted Manuscript • DOI: 10.1021/acs.analchem.7b04759 • Publication Date (Web): 19 Feb 2018 Downloaded from http://pubs.acs.org on February 26, 2018

Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.

Analytical Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.

Page 1 of 26 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Analytical Chemistry

1

Headspace

Solid-Phase

Microextraction

Coupled

2

Miniaturized Microplasma Optical Emission Spectrometry

3

for Detection of Mercury and Lead

4 5

Chengbin Zheng†,‡, Ligang Hu†, Xiandeng Hou‡, Bin He†,* and Guibin Jiang†

6



7

Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing

8

100085, China

9



to

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research

Key Laboratory of Green Chemistry & Technology, Ministry of Education, College

10

of Chemistry, Sichuan University, Chengdu, Sichuan 610064, China

11

*Corresponding author:

12

Fax and Phone: +86 010 6284 9334

13

E–mails: [email protected]

14 15

Author Contributions

16

The manuscript was written through contributions of all authors. All authors have

17

given approval to the final version of the manuscript.

18 19

1

ACS Paragon Plus Environment

Analytical Chemistry 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

1

ABSTRACT

2

Despite increased interest in microplasma atomic spectrometry over the past several

3

years, its applications to field analysis of real samples still remain limited due to its

4

low sensitivity. In this work, headspace solid-phase microextraction (HS-SPME)

5

using PDMS/DVB fiber was used as a sample introduction method to improve the

6

sensitivity of a miniature (6.0 cm length × 5.0 cm width × 2.8 cm height) low power

7

(