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Homogeneous Transition Metal Catalyzed Reactions
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
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ADVANCES
IN
CHEMISTRY
SERIES
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Homogeneous Transition Metal Catalyzed Reactions William R. Moser, EDITOR Worcester Polytechnic Institute
Donald W. Slocum, EDITOR Western Kentucky
University
Developed from a symposium sponsored by the Catalysis and Surface Science Secretariat of the American Chemical Society
American Chemical Society, Washington, DC 1992
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
230
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L i b r a r y of Congress Cataloging-in-Publication D a t a Homogeneous transition metal catalyzed reactions: developed from a symposium / sponsored by the Catalysis Secretariat at the 199th National Meeting of the American Chemical Society, Boston, Massachusetts, April 22-27, 1990; William R. Moser, editor, Donald W. Slocum, editor. p.
cm.—(Advances in chemistry series, ISSN 0065-2393; 230).
Includes bibliographical references and indexes. ISBN 0-8412-2007-7 1. Catalysis—Congresses.
2. Transition metal catalysts—Congresses.
I. Moser, William R. II. Slocum, D . W. (Donald Warren), 1933. III. American Chemical Society. Catalysis Secretariat. IV. American Chemical Society. Meeting (199th: 1990: Boston, Mass.) V. Series. QD1.A355 no. 230 [QD505] 540 s—dc20 92-356 [546'.6] CIP The paper used in this publication meets the minimum requirements of American National Standard for Information Sciences—Permanence of Paper for Printed Library Materials, ANSI Z39.48-1984.
Copyright © 1992 American Chemical Society All Rights Reserved. The appearance of the code at the bottom of the first page of each chapter in this volume indicates the copyright owner's consent that reprographic copies of the chapter may be made for personal or internal use or for the personal or internal use of specific clients. This consent is given on the condition, however, that the copier pay the stated per-copy fee through the Copyright Clearance Center, Inc., 27 Congress Street, Salem, MA 01970, for copying beyond that permitted by Sections 107 or 108 of the U.S. Copyright Law. This consent does not extend to copying or transmission by any means—graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. The copying fee for each chapter is indicated in the code at the bottom of the first page of the chapter. The citation of trade names and/or names of manufacturers in this publication is not to be construed as an endorsement or as approval by ACS of the commercial products or services referenced herein; nor should the mere reference herein to any drawing, specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that may in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected by law. PRINTED IN T H E U N I T E D STATES O F AMERICA
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
1992 Advisory Board Advances in Chemistry Series
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M. Joan Comstock, Series Editor V. Dean Adams
Bonnie Lawlor
Tennessee Technological University
Institute for Scientific Information
Mark Arnold
John L. Massingill
University of Iowa
David Baker University of Tennessee
Alexis T. Bell University of California—Berkeley
Arindam Bose
Pfizer Central Research
Robert F. Brady, Jr.
Naval Research Laboratory
Margaret A. Cavanaugh
Dow Chemical Company
Robert McGorrin Kraft General Foods
Julius J. Menn
Plant Sciences Institute, U.S. Department of Agriculture
Vincent Pecoraro
University of Michigan
Marshall Phillips
Delmont Laboratories
National Science Foundation
Dennis W. Hess Lehigh University
Hiroshi Ito IBM Almaden Research Center
Madeleine M. Joullie
University of Pennsylvania
Mary A. Kaiser
Ε. I. du Pont de Nemours and Company
Gretchen S. Kohl Dow-Corning Corporation
A. Truman Schwartz Macalaster College
John R. Shapley
University of Illinois at Urbana—Champaign
Stephen A. Szabo Conoco Inc.
Robert A. Weiss University of Connecticut
Peter Willett University of Sheffield (England)
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
FOREWORD T h e A D V A N C E S I N C H E M I S T R Y S E R I E S was founded in 1 9 4 9 by the American
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Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would otherwise be fragmented because their papers would be distributed among several journals or not published at all. Papers are reviewed critically according to A C S editorial standards and receive the careful attention and processing characteristic of A C S publications. Volumes in the A D V A N C E S IN C H E M I S T R Y S E R I E S maintain the integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
ABOUT T H E EDITORS
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W I L L I A M R. M O S E R is a professor of chemical
engineering at the Worcester Polytechnic Institute (WPI). H e received his P h . D . from the Massachusetts Institute of Technology and a B.S. in chemistry and mathematics from M i d dle Tennessee State University. H e is also a member of the Center for Inorganic Membrane Studies at WPI. During the past 28 years his research interests in the catalytic sciences have included homogeneous and heterogeneous catalysis, novel materials synthesis, and in situ reaction monitoring. H e is the inventor of cylindrical internal reflectance reactors (CIR reactors) and optical fiber coupled C I R reactors ( O F C I R reactors) for in situ chemical reaction monitoring, and the high-temperature aerosol decomposition process for metal oxide synthesis of ceramics, catalysts, and superconductors. Moser is a fellow of the New York Academy of Sciences and is a co-founder of the Organic Reactions Catalysis Society. H e is currently chairman-elect of the A C S Division of Petroleum Chemistry, Inc. H e is editor of several books on homogeneous and heterogeneous catalysis and has a variety of publications and patents in the catalysis, zeolite, and materials science fields. DONALD
W.
SLOCUM
was
awarded his
Ph.D.
in chemistry from New York University after obtaining a B.S. in chemistry and a B . A . in English from the University of Rochester. H e served as a research associate at Duke University, assistant professor of chemistry at Carnegie Institute of Technology, full professor of chemistry at Southern Illinois University, and head of the Department of Chemistry at Western Kentucky University. H e has been a senior scientist at Gulf Research and Development Company, program director of the Chemical Dynamics Section of the National Science Foundation, and program leader in the Division of Educational Programs at Argonne National Laboratory. His visiting academic appointments include
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
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the University of Illinois, University of Bristol, University of Cincinnati, Carnegie-Mellon University, and University of Pittsburgh. Slocum is the author of many publications. H e has organized and coordinated international scientific meetings and has directed a large academic research program and a venture industrial research program. H e is a member of the American Association for the Advancement of Science, the American Chemical Society (1991 secretary general of the Catalysis and Surface Science Secretariat), the Chemical Society of Great Britain, Phi Lambda Upsilon, and Sigma X i .
In Homogeneous Transition Metal Catalyzed Reactions; Moser, W., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1992.
