Jul 13, 1992 - We thank Dr. Harry Ensley for obtaining the NMR spectra. (14) Byers, L. D.;She, H. S.; Alayoff, A. Biochemistry 1979, 18,. 2471-2480. Homolytic ...
Free-radical substitution reactions. Bimolecular homolytic substitutions (SH2 reactions) at saturated multivalent atoms (Ingold, K. U.). A. R. Abramovitch. J. Chem.
Oct 15, 2004 - Charles Bury , Elspeth F. Garman , Helen Mary Ginn , Raimond B. G. Ravelli , Ian Carmichael , Geoff Kneale , John E. McGeehan. Journal of ...
Puerto Rico Nuclear Center, Caparra Heights Station, San Juan, Puerto Rico 00935 (Received March 28, 1975). Publication costs assisted by the Puerto Rico ...
verified by vibrational-frequency analysis at the UHF and MP2 levels of theory. Calculated .... 6-chalcogenyl-1-hexyl radicals (6) (UHF/DZP data in parentheses).
Radical chain cleavage of alkylmetals by photochemically generated iodine atoms. S. Fukuzumi, and J. K. Kochi. J. Org. Chem. , 1980, 45 (13), pp 2654â2662.
Electron spin resonance studies of homolytic substitution reactions. Organoboron, -aluminum, and -gallium compounds. Paul J. Krusic, and Jay K. Kochi.
D. H. Varma , P. Raghunath and M. C. Lin. The Journal of Physical Chemistry A 2010 ... S. Y. Wu , P. Raghunath , J. S. Wu and M. C. Lin. The Journal of Physical ...
University of St. Andrews, School of Chemistry,. St. Andrews, Fife KY16 9ST, U.K.. Received October 9, 1997. Nucleophilic versus Homolytic Substitution.
V. Homolytic aromatic substitution by methyl radicals. William A. ... Comparative QSAR: Radical Reactions of Benzene Derivatives in Chemistry and Biology.
J. Org. Chem. 1992,57,6817-6820
molybdate adds to the C-2 carbonyl of the ester and then displaces the ethanol leaving group resulting in a labile cyclic acvl molybdate ester. The rapid first-order production of pyruvate (no detectable 1 4 in the presence of 0.45 M Mo02-,hobs = 0.12 mi&) indicates that the half-life of this acvl molvbdate intermediate must be
