Hydrocarbon oxidations with oxometalloporphinates. Isolation and

Hailiang Zhao , Kristine Pierloot , Ernie H. G. Langner , Jannie C. Swarts , Jeanet Conradie , and Abhik Ghosh. Inorganic Chemistry 2012 51 (7), 4002-...
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J . Am. Chem. SOC. 1980, 102, 6315-6371

6375

Table I. Product Yields for Cyclohexane Functionahation’ MnTPPX, X= cl Br Br Br Br Br I

solv 6‘

H6

CH, a 2

CH2C1,

8.9 6.0

c6 H6

9.5 0.5 0.98 2.1 6.1

C6H6

5.3

c6 H6

N3

mol ratio, C6H510/ MnTPPX

c6

H6

6‘

H6

RX

ROH

98 (11) 99 (17) 99 (10) 20 (41) 42 (43) 74 (35) >95 >95 (18)

237 (26) 193 (32) 243 (26) 6 (13) 7.4 (7.6) 13 (6) d 120 (23)

% yieldb RR c-C, H,,O 48 ( 5 )