Hydrogen Bond Networks: Structure and ... - American Chemical Society

The nature of hydrogen bonding networks following hydrogen bond breaking is ... bond breaking following vibrational relaxation gives rise to a new spe...
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6544

J. Phys. Chem. B 2004, 108, 6544-6554

Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking† John B. Asbury, Tobias Steinel, and M. D. Fayer* Department of Chemistry, Stanford UniVersity, Stanford, California 94305 ReceiVed: September 1, 2003; In Final Form: December 18, 2003

The nature of hydrogen bonding networks following hydrogen bond breaking is investigated using vibrational echo correlation spectroscopy of the hydroxyl stretch of methanol-OD (MeOD) of MeOD oligomers in CCl4. Using ultrafast (