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Adam Wu , Elizabeth A. Mader , Ayan Datta , David A. Hrovat , Weston Thatcher Borden and James M. Mayer. Journal of the American Chemical Society 2009 ...
Dinuclear Cu(II) complexes, CuII2Nn (n = 4 or 5), were recently found to specifically cleave DNA in the presence of a reducing thiol and O2 or in the presence of H2O2 alone. However, CuII2N3 and a closely related mononuclear Cu(II) complex exhibited
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Jul 10, 2015 - Iron TAML activators of peroxides are functional catalase-peroxidase mimics. Switching from hydrogen peroxide (H2O2) to dioxygen (O2) as the primary oxidant was achieved by using a system of reverse micelles of Aerosol OT (AOT) in n-oc
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Feb 28, 2007 - High-Energy-Resolution Fluorescence-Detected X-ray Absorption of the Q ..... Gerard T. Rowe , Elena V. Rybak-Akimova , John P. Caradonna.
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/. Am. Chem. Soc. 1994, 116, 6979-Í980
Hydrogen Tunneling in the Activation of Dioxygen by Tris(pyrazolyI)borate Cobalt Complex
Scheme
a
6979
1
o,
Mg, N2 T|>“CoI 1
-
Tp-Co-N2-CoTp"
-
2
Tp"Co 1.3 kcal/mol), (4) difference in the preexponential factors (/4-factors) resulting from an Arrhenius analysis (An/Ad < 0.6; in the Eyring analysis this appears as a difference in AS*). Figure 1 shows a comparative Eyring plot for the decompositions of 7 and 7-
